Abstract: Among different droplet manipulations, controlled droplet-splitting is of great significance due to its ability to increase throughput and operational capability. Furthermore, unequal droplet-splitting can provide greater flexibility and a wider range of dilution factors. In this study, we developed two-dimensional, time-dependent complex fluid dynamics simulations to model droplet formation in a flow focusing device, followed by splitting in a Y-shaped junction with sub-channels of unequal widths. From the results obtained from the numerical study, we correlated the diameters of the droplets in the sub-channels to the Weber number, thereby demarcating the droplet splitting and non-splitting regimes.
Abstract: Ultrasound (US) is widely used in medical field for
a variety diagnostic techniques but, in recent years, it has also
been creating great interest for therapeutic aims. Regarding drug
delivery, the use of US as an activation source provides better
spatial delivery confinement and limits the undesired side effects.
However, at present there is no complete characterization
at a fundamental level of the different signals produced by
sono-activated nanocarriers. Therefore, the aim of this study
is to obtain a metrological characterization of the cavitation
phenomena induced by US through three parallel investigation
approaches. US was focused into a channel of a customized
phantom in which a solution with oxygen-loaded nanodroplets
(OLNDs) was led to flow and the cavitation activity was
monitored. Both quantitative and qualitative real-time analysis
were performed giving information about the dynamics of
bubble formation, oscillation and final implosion with respect
to the working acoustic pressure and the type of nanodroplets,
compared with pure water. From this analysis a possible
interpretation of the observed results is proposed.
Abstract: In this study, hyaluronic acid (HA) microgels were developed for the goal of protein delivery. First, a hyaluronic acid-tyramine conjugate (HA-TA) was synthesized with a degree of substitution of 13 TA moieties per 100 disaccharide units. Then, HA-TA microdroplets were produced using a water in oil emulsion method and crosslinked in the presence of horseradish peroxidase (HRP) and hydrogen peroxide (H2O2). Loading capacity and the release kinetics of lysozyme and BSA, as model proteins, were investigated. It was shown that lysozyme, a cationic protein, can be incorporated efficiently in the HA microgels, while the loading efficiency for BSA, as a negatively charged protein, is low. The release profile of lysozyme showed a sustained release over a period of one month. The results demonstrated that the HA-TA microgels are a good carrier for spatial delivery of cationic proteins for biomedical applications.
Abstract: Strain sensors based on a change in resistance are
well established for the measurement of forces, stresses, or material
fatigue. Within the scope of this paper, fully additive manufactured
strain sensors were produced using an ink of silver nanoparticles.
Their behavior was evaluated by periodic tensile tests. Printed
strain sensors exhibit two advantages: Their measuring grid is
adaptable to the use case and they do not need a carrier-foil,
as the measuring structure can be printed directly onto a thin
sprayed varnish layer on the aluminum specimen. In order to
compare quality characteristics, the sensors have been manufactured
using two different technologies, namely aerosoljet-printing and
micropipette-dispensing. Both processes produce structures which
exhibit continuous features (in contrast to what can be achieved with
droplets during inkjet printing). Briefly summarized the results show
that aerosoljet-printing is the preferable technology for specimen with
non-planar surfaces whereas both technologies are suitable for flat
specimen.
Abstract: In the present work we developed an image processing
algorithm to measure water droplets characteristics during dropwise
condensation on pillared surfaces. The main problem in this process is
the similarity between shape and size of water droplets and the pillars.
The developed method divides droplets into four main groups based
on their size and applies the corresponding algorithm to segment each
group. These algorithms generate binary images of droplets based
on both their geometrical and intensity properties. The information
related to droplets evolution during time including mean radius and
drops number per unit area are then extracted from the binary images.
The developed image processing algorithm is verified using manual
detection and applied to two different sets of images corresponding
to two kinds of pillared surfaces.
Abstract: Various processes are modelled using a discrete phase,
where particles are seeded from a source. Such particles can represent
liquid water droplets, which are affecting the continuous phase by
exchanging thermal energy, momentum, species etc. Discrete phases
are typically modelled using parcel, which represents a collection of
particles, which share properties such as temperature, velocity etc.
When coupling the phases, the exchange rates are integrated over
the cell, in which the parcel is located. This can cause spikes and
fluctuating exchange rates. This paper presents an alternative method of coupling a discrete
and a continuous plug flow phase. This is done using triangular
parcels, which span between nodes following the dynamics of single
droplets. Thus, the triangular parcels are propagated using the corner
nodes. At each time step, the exchange rates are spatially integrated
over the surface of the triangular parcels, which yields a smooth
continuous exchange rate to the continuous phase. The results shows that the method is more stable, converges
slightly faster and yields smooth exchange rates compared with
the steam tube approach. However, the computational requirements
are about five times greater, so the applicability of the alternative
method should be limited to processes, where the exchange rates are
important. The overall balances of the exchanged properties did not
change significantly using the new approach.
Abstract: A hybrid quasi-steady thermal lattice Boltzmann model was used to study the combined effects of temperature and contact angle on the movement of slugs and droplets of oil in water (O/W) system flowing between two parallel plates. The model static contact angle due to the deposition of the O/W droplet on a flat surface with simulated hydrophilic characteristic at different fluid temperatures, matched very well the proposed theoretical calculation. Furthermore, the model was used to simulate the dynamic behavior of droplets and slugs deposited on the domain’s upper and lower surfaces, while subjected to parabolic flow conditions. The model accurately simulated the contact angle hysteresis for the dynamic droplets cases. It was also shown that at elevated temperatures the required power to transport the mixture diminished remarkably.
Abstract: With the rapid development of national modern industry, people begin to pay attention to environmental pollution and harm caused by industrial dust. Based on above, a numerical study on the dedusting technology of industrial environment was conducted. The dynamic models of multicomponent particles collision and coagulation, breakage and deposition are developed, and the interaction of water droplet and aerosol particle in 2-Dimension flow field was researched by Eulerian-Lagrangian method and Multi-Monte Carlo method. The effects of the droplet scale, movement speed of droplet and the flow field structure on scavenging efficiency were analyzed. The results show that under the certain condition, 30μm of droplet has the best scavenging efficiency. At the initial speed 1m/s of droplets, droplets and aerosol particles have more time to interact, so it has a better scavenging efficiency for the particle.
Abstract: The reduction of water content in crude oil emulsions reduces pipeline corrosion potential and increases the productivity. Chemical emulsification of crude oil emulsions is one of the methods available to reduce the water content. Presence of demulsifier causes the film layer between the crude oil emulsion and water droplets to become unstable leading to the acceleration of water coalescence. This research has been performed to study the improvement performance of a chemical demulsifier by silica nanoparticles. The silica nano-particles have been synthesized by sol-gel technique and precipitation using poly vinyl alcohol (PVA) and poly ethylene glycol (PEG) as surfactants and then nano-particles are added to the demulsifier. The silica nanoparticles were characterized by Particle Size Analyzer (PSA) and SEM. Upon the addition of nanoparticles, bottle tests have been carried out to separate and measure the water content. The results show that silica nano-particles increase the demulsifier efficiency by about 40%.
Abstract: Philip Morris International (PMI) is developing a range
of novel tobacco products with the potential to reduce individual
risk and population harm in comparison to smoking cigarettes.
One of these products is the Tobacco Heating System 2.2 (THS
2.2), (named as the Electrically Heated Tobacco System (EHTS) in
this paper), already commercialized in a number of countries (e.g.,
Japan, Italy, Switzerland, Russia, Portugal and Romania). During use,
the patented EHTS heats a specifically designed tobacco product
(Electrically Heated Tobacco Product (EHTP)) when inserted into
a Holder (heating device). The EHTP contains tobacco material in
the form of a porous plug that undergoes a controlled heating process
to release chemical compounds into vapors, from which an aerosol
is formed during cooling. The aim of this work was to investigate
the aerosol formation characteristics for realistic operating conditions
of the EHTS as well as for relevant gas mixture compositions
measured in the EHTP aerosol consisting mostly of water, glycerol
and nicotine, but also other compounds at much lower concentrations.
The nucleation process taking place in the EHTP during use when
operated in the Holder has therefore been modeled numerically using
an extended Classical Nucleation Theory (CNT) for multicomponent
gas mixtures. Results from the performed simulations demonstrate
that aerosol droplets are formed only in the presence of an aerosol
former being mainly glycerol. Minor compounds in the gas mixture
were not able to reach a supersaturated state alone and therefore
could not generate aerosol droplets from the multicomponent gas
mixture at the operating conditions simulated. For the analytically
characterized aerosol composition and estimated operating conditions
of the EHTS and EHTP, glycerol was shown to be the main aerosol
former triggering the nucleation process in the EHTP. This implies
that according to the CNT, an aerosol former, such as glycerol
needs to be present in the gas mixture for an aerosol to form
under the tested operating conditions. To assess if these conclusions
are sensitive to the initial amount of the minor compounds and to
include and represent the total mass of the aerosol collected during
the analytical aerosol characterization, simulations were carried out
with initial masses of the minor compounds increased by as much
as a factor of 500. Despite this extreme condition, no aerosol
droplets were generated when glycerol, nicotine and water were
treated as inert species and therefore not actively contributing to the
nucleation process. This implies that according to the CNT, an aerosol
cannot be generated without the help of an aerosol former, from
the multicomponent gas mixtures at the compositions and operating
conditions estimated for the EHTP, even if all minor compounds are
released or generated in a single puff.
Abstract: The effects of flame-holder position, the ratio of flame
holder diameter to combustion chamber diameter and injection angle
on fuel propulsive droplets sizing and effective mass fraction have
been studied by a cold flow. We named the mass of fuel vapor inside
the flammability limit as the effective mass fraction. An empty
cylinder as well as a flame-holder which are a simulator for duct
combustion has been considered. The airflow comes into the cylinder
from one side and injection operation will be done by four nozzles
which are located on the entrance of cylinder. To fulfill the
calculations a modified version of KIVA-3V code which is a
transient, three-dimensional, multiphase, multi component code for
the analysis of chemically reacting flows with sprays, is used.
Abstract: Since 1920, the industry has almost completely
changed the rivets production techniques for the manufacture of
permanent welding join production of structures and manufacture of
other products. The welding arc is the process more widely used in
industries. This is accomplished by the heat of an electric arc which
melts the base metal while the molten metal droplets are transferred
through the arc to the welding pool, protected from the atmosphere
by a gas curtain. The GMAW (Gas metal arc welding) process is
influenced by variables such as: current, polarity, welding speed,
electrode: extension, position, moving direction; type of joint,
welder's ability, among others. It is remarkable that the knowledge
and control of these variables are essential for obtaining satisfactory
quality welds, knowing that are interconnected so that changes in one
of them requiring changes in one or more of the other to produce the
desired results. The optimum values are affected by the type of base
metal, the electrode composition, the welding position and the quality
requirements. Thus, this paper proposes a new methodology, adding
the variable vibration through a mechanism developed for GMAW
welding, in order to improve the mechanical and metallurgical
properties which does not affect the ability of the welder and enables
repeatability of the welds made. For confirmation metallographic
analysis and mechanical tests were made.
Abstract: This paper reports a novel actuating design that uses
the shear deformation of a piezoelectric actuator to deflect a
bulge-diaphragm for driving an array microdroplet ejector. In essence,
we employed a circular-shaped actuator poled radial direction with
remnant polarization normal to the actuating electric field for inducing
the piezoelectric shear effect. The array microdroplet ejector consists
of a shear type piezoelectric actuator, a vibration plate, two chamber
plates, two channel plates and a nozzle plate. The vibration, chamber
and nozzle plate components are fabricated using nickel
electroforming technology, whereas the channel plate is fabricated by
etching of stainless steel. The diaphragm displacement was measured
by the laser two-dimensional scanning vibrometer. The ejected
droplets of the microejector were also observed via an optic
visualization system.
Abstract: In this study, polycaprolactone (PCL) was dissolved
in chloroform:ethanol solvent system at a concentration of 18 w/v %.
1, 2, 4, and 6 droplets of formic acid were added to the prepared 10ml
PCL-chloroform:ethanol solutions separately. Fibrous webs were
produced by electrospinning technique based on the horizontal
working principle. Morphology of the webs was investigated by
using scanning electron microscopy (SEM) whereas fiber diameters
were measured by Image J Software System. The effect of formic
acid addition to the mostly used chloroform solvent on fiber
morphology was examined.
Results indicate that there is a distinct fall in fiber diameter with
the addition of formic acid drops. The average fiber diameter was
measured as 2.22μm in PCL /chloroform:ethanol solution system. On
the other hand, 328nm and 256 nm average fiber diameters were
measured for the samples of 4 drops and 6 drops formic acid added.
This study offers alternative solvent systems to produce nanoscaled,
nontoxic PCL fibrous webs by electrospinning technique.
Abstract: Wet scrubbers have found widespread use in cleaning
contaminated gas streams because of their ability to remove
particulates and based on the applications of scrubbing of marine
engine exhaust gases by spraying sea-water. In order to examine the
flow characteristics inside the scrubber, the model is designated with
flow properties of hot air and water sprayer. The flow dynamics of
evaporation of hot air by the injection of water droplets is the key
factor considered in this paper. The flow behavior inside the scrubber
was investigated from the previous works and to sum up the
evaporation rate with respect to the concentration of water droplets are
predicted to bring out the competent modelling. The numerical
analysis using CFD facilitates in understanding the problem better and
empathies the behavior of the model over its entire operating envelope.
Abstract: This paper presents the application of the Discrete
Component Model for heating and evaporation to multi-component
biodiesel fuel droplets in direct injection internal combustion engines.
This model takes into account the effects of temperature gradient,
recirculation and species diffusion inside droplets. A distinctive
feature of the model used in the analysis is that it is based on the
analytical solutions to the temperature and species diffusion
equations inside the droplets. Nineteen types of biodiesel fuels are
considered. It is shown that a simplistic model, based on the
approximation of biodiesel fuel by a single component or ignoring
the diffusion of components of biodiesel fuel, leads to noticeable
errors in predicted droplet evaporation time and time evolution of
droplet surface temperature and radius.
Abstract: The theoretical approach is developed to describe the
change of drops in the atmosphere of own steam and buffer gas under
irradiation. It is shown that the irradiation influences on size of stable
droplet and on the conditions under which the droplet exists. Under
irradiation the change of drop becomes more complex: the not
monotone and periodical change of size of drop becomes possible.
All possible solutions are represented by means of phase portrait. It is
found all qualitatively different phase portraits as function of critical
parameters: rate generation of clusters and substance density.
Abstract: The most important problem occurs on oil spills in sea
water is to reduce the oil spills size. This study deals with the
development of high pressurized nozzle using dispersion method for
oil leakage in offshore. 3D numerical simulation results were
obtained using ANSYS Fluent 13.0 code and correlate with the
experimental data for validation. This paper studies the contribution
of the process on flow speed and pressure of the flow from two
different geometrical designs of nozzles and to generate a spray
pattern suitable for dispersant application. Factor of size distribution
of droplets generated by the nozzle is calculated using pressures
ranging from 2 to 6 bars. Results obtain from both analyses shows a
significant spray pattern and flow distribution as well as distance.
Results also show a significant contribution on the effect of oil
leakage in terms of the diameter of the oil spills break up.
Abstract: An appropriate model to predict the size of the droplets
resulting from the break-up with the structures will help in a better
understanding and modeling of the two-phase flow calculations in the
simulation of a reactor core loss-of-coolant accident (LOCA). A
droplet behavior impacting on a hot surface above the Leidenfrost
temperature was investigated. Droplets of known size and velocity
were impacted to an inclined plate of hot temperature, and the
behavior of the droplets was observed by a high-speed camera. It was
found that for droplets of Weber number higher than a certain value,
the higher the Weber number of the droplet the smaller the secondary
droplets. The COBRA-TF model over-predicted the measured
secondary droplet sizes obtained by the present experiment. A simple
model for the secondary droplet size was proposed using the mass
conservation equation. The maximum spreading diameter of the
droplets was also compared to previous correlations and a fairly good
agreement was found. A better prediction of the heat transfer in the
case of LOCA can be obtained with the presented model.
Abstract: The primary objective of this paper is to study the thermal effects of the electric arc on the breaker apparatus contacts for forecasting and improving the contact durability. We will propose a model which takes account of the main influence factors on the erosion contacts. This phenomenon is very complicated because the amount of ejected metal is not necessarily constituted by the whole melted metal bath but this depends on the balance of forces on the contact surface. Consequently, to calculate the metal ejection coefficient, we propose a method which consists in comparing the experimental results with the calculated ones. The proposed model estimates the mass lost by vaporization, by droplets ejection and by the extraction mechanism of liquid or solid metal. In the one-dimensional geometry, to calculate of the contact heating, we used Green’s function which expresses the point source and allows the transition to the surface source. However, for the two- dimensional model we used explicit and implicit numerical methods. The results are similar to those found by Wilson’s experiments.