Abstract: In this study, the feasibility of incorporating ceramic
waste from bricks (perforated brick and double hollow brick) and
extruded polystyrene (XPS) waste, is analysed.
Results show that it is possible to incorporate up to 25% of
ceramic waste and 4% of XPS waste over the weight of gypsum in a
gypsum matrix. Furthermore, with the addition of ceramic waste an
8% of surface hardness increase and a 25% of capillary water
absorption reduction can be obtained. On the other hand, with the
addition of XPS, a 26% reduction of density and a 37% improvement
of thermal conductivity can be obtained.
The obtained results are favorable to use these materials in order to
produce prefabricated gypsum and also as material for interior
cladding walls.
Abstract: It is an established fact that polymers have several
physical limitations such as low stiffness and low resistance to
impact on loading. Hence, polymers do not usually have requisite
mechanical strength for application in various fields. The
reinforcement by high strength fibers provides the polymer
substantially enhanced mechanical properties and makes them more
suitable for a large number of diverse applications. This research
evaluates the effects of particulate Cow bone and Groundnut shell
additions on the mechanical properties and microstructure of cow
bone and groundnut shell reinforced epoxy composite in order to
assess the possibility of using it as a material for engineering
applications. Cow bone and groundnut shell particles reinforced with
epoxy (CBRPC and GSRPC) was prepared by varying the cow bone
and groundnut shell particles from 0-25 wt% with 5 wt% intervals. A
Hybrid of the Cow bone and Groundnut shell (HGSCB) reinforce
with epoxy was also prepared. The mechanical properties of the
developed composites were investigated. Optical microscopy was
used to examine the microstructure of the composites. The results
revealed that mechanical properties did not increase uniformly with
additions in filler but exhibited maximum properties at specific
percentages of filler additions. From the Microscopic evaluation, it
was discovered that homogeneity decreases with increase in % filler,
this could be due to poor interfacial bonding.
Abstract: In recent years a new method of combination
treatment for cancer has been developed and studied that has led to
significant advancements in the field of cancer therapy. Hyperthermia
is a traditional therapy that, along with a creation of a medically
approved level of heat with the help of an alternating magnetic AC
current, results in the destruction of cancer cells by heat. This paper
gives details regarding the production of the spherical nanocomposite
PVA/γ-Fe2O3 in order to be used for medical purposes such as tumor
treatment by hyperthermia. To reach a suitable and evenly distributed
temperature, the nanocomposite with core-shell morphology and
spherical form within a 100 to 200 nanometer size was created using
phase separation emulsion, in which the magnetic nano-particles γ-
Fe2O3 with an average particle size of 20 nano-meters and with
different percentages of 0.2, 0.4, 0.5 and 0.6 were covered by
polyvinyl alcohol. The main concern in hyperthermia and heat
treatment is achieving desirable specific absorption rate (SAR) and
one of the most critical factors in SAR is particle size. In this project
all attempts has been done to reach minimal size and consequently
maximum SAR. The morphological analysis of the spherical
structure of the nanocomposite PVA/γ-Fe2O3 was achieved by SEM
analyses and the study of the chemical bonds created was made
possible by FTIR analysis. To investigate the manner of magnetic
nanocomposite particle size distribution a DLS experiment was
conducted. Moreover, to determine the magnetic behavior of the γ-
Fe2O3 particle and the nanocomposite PVA/γ-Fe2O3 in different
concentrations a VSM test was conducted. To sum up, creating
magnetic nanocomposites with a spherical morphology that would be
employed for drug loading opens doors to new approaches in
developing nanocomposites that provide efficient heat and a
controlled release of drug simultaneously inside the magnetic field,
which are among their positive characteristics that could significantly
improve the recovery process in patients.
Abstract: We report herein the development and preliminary mechanical characterization of fully-dense multi-wall carbon nanotube (MWCNT)-reinforced ceramics and glasses based on a completely new methodology termed High Shear Compaction (HSC). The tubes are introduced and bound to the matrix grains by aid of polymeric binders to form flexible green bodies which are sintered and densified by spark plasma sintering to unprecedentedly high densities of 100% of the pure-matrix value. The strategy was validated across a PyrexTM glass / MWCNT composite while no identifiable factors limit application to other types of matrices. Nondestructive evaluation, based on ultrasonics, of the dynamic mechanical properties of the materials including elastic, shear and bulk modulus as well as Poisson’s ratio showed optimum property improvement at 0.5 %wt tube loading while evidence of nanoscalespecific energy dissipative characteristics acting complementary to nanotube bridging and pull-out indicate a high potential in a wide range of reinforcing and multifunctional applications.
Abstract: Aluminium matrix composites with alumina
reinforcements give superior mechanical & physical properties. Their
applications in several fields like automobile, aerospace, defense,
sports, electronics, bio-medical and other industrial purposes are
becoming essential for the last several decades. In the present work,
fabrication of hybrid composite was done by Stir casting technique
using Al 6061 as a matrix with alumina and silicon carbide (SiC) as
reinforcement materials. The weight percentage of alumina is varied
from 2 to 4% and the silicon carbide weight percentage is maintained
constant at 2%. Hardness and wear tests are performed in the as cast
and heat treated conditions. Age hardening treatment was performed
on the specimen with solutionizing at 550°C, aging at two
temperatures (150 and 200°C) for different time durations. Hardness
distribution curves are drawn and peak hardness values are recorded.
Hardness increase was very sensitive with respect to the decrease in
aging temperature. There was an improvement in wear resistance of
the peak aged material when aged at lower temperature. Also
increase in weight percent of alumina, increases wear resistance at
lower temperature but opposite behavior was seen when aged at
higher temperature.
Abstract: This study focuses on a novel method for dispersion
and distribution of reinforcement under high intensive shear stress to
produce metal composites. The polyacrylonitrile (PAN)-based short
carbon fiber (Csf) and Nextel 610 alumina fiber were dispersed under
high intensive shearing at mushy zone in semi-solid of A356 by a
novel method. The bundles and clusters were embedded by
infiltration of slurry into the clusters, thus leading to a uniform
microstructure. The fibers were embedded homogenously into the
aluminum around 576-580°C with around 46% of solid fraction.
Other experiments at 615°C and 568°C which are contained 0% and
90% solid respectively were not successful for dispersion and
infiltration of aluminum into bundles of Csf. The alumina fiber has
been cracked by high shearing load. The morphologies and
crystalline phase were evaluated by SEM and XRD. The adopted
thixo-process effectively improved the adherence and distribution of
Csf into Al that can be developed to produce various composites by
thixomixing.
Abstract: In contrast with literal meaning of nano, researchers
have been achieved mega adventures in this area and every day more
nanomaterials are being introduced to the market. After long time
application of fossil-based plastics, nowadays accumulation of their
waste seems to be a big problem to the environment. On the other
hand, mankind has more attention to safety and living environment.
Replacing common plastic packaging materials with degradable ones
that degrade faster and convert to non-dangerous components like
water and carbon dioxide have more attractions; these new materials
are based on renewable and inexpensive sources of starch and
cellulose. However, the functional properties of them do not suitable
for packaging. At this point, nanotechnology has an important role.
Utilizing of nanomaterials in polymer structure will improve
mechanical and physical properties of them; nanocrystalline cellulose
(NCC) has this ability. This work has employed a chemical method to
produce NCC and starch bio nanocomposite containing NCC. X-Ray
Diffraction technique has characterized the obtained materials.
Results showed that applied method is a suitable one as well as
applicable one to NCC production.
Abstract: This paper presents the results of an experimental
study undertaken to evaluate the local bond stress-slip response of
short embedment of reinforcing bars in normal concrete (NC) and
high performance fiber reinforced cement composites (HPFRCC)
blocks. Long embedment was investigated as well to gain insights on
the distribution of strain, slip, bar stress and bond stress along the bar
especially in post-yield range. A total of 12 specimens were tested,
by means of pull-out of the reinforcing bars from concrete blocks. It
was found that the enhancement of local bond strength can be
reached up to 50% and ductility of the bond behavior was improved
significantly if HPFRCC is used. Also, under a constant strain at
loaded end, HPFRCC has delayed yielding of bars at other location
from the loaded end. Hence, the reduction of bond stress was slower
for HPFRCC in comparison with NC. Due to the same reason, the
total slips at loaded end for HPFRCC was smaller than NC as
expected. Test results indicated that HPFRCC has better bond slip
behavior which makes it a suitable material to be employed in
anchorage zone such as beam-column joints.
Abstract: Microstructural and electrical properties of
Cu-chromium alloy (Cu-Cr) dispersed with vapor-grown carbon fiber
(VGCF) prepared by powder metallurgy (P/M) process have been
investigated. Cu-0.7 mass% Cr pre-alloyed powder (Cu-Cr) made by
water atomization process was used as raw materials, which contained
solid solute Cr elements in Cu matrix. The alloy powder coated with
un-bundled VGCF by using oil coating process was consolidated at
1223 K in vacuum by spark plasma sintering, and then extruded at
1073 K. The extruded Cu-Cr alloy (monolithic alloy) had 209.3 MPa
YS and 80.4 IACS% conductivity. The extruded Cu-Cr with 0.1
mass% VGCF composites revealed a small decrease of YS compared
to the monolithic Cu-Cr alloy. On the other hand, the composite had a
higher electrical conductivity than that of the monolithic alloy. For
example, Cu-Cr with 0.1 mass% VGCF composite sintered for 5 h
showed 182.7 MPa YS and 89.7 IACS% conductivity. In the case of
Cu-Cr with VGCFs composites, the Cr concentration was observed
around VGCF by SEM-EDS analysis, where Cr23C6 compounds were
detected by TEM observation. The amount of Cr solid solution in the
matrix of the Cu-Cr composites alloy was about 50% compared to the
monolithic Cu-Cr sintered alloy, and resulted in the remarkable
increment of the electrical conductivity.
Abstract: Non-crimp 3D orthogonal fabric composite is one of
the textile-based composite materials that are rapidly developing
light-weight engineering materials. The present paper focuses on
geometric and micromechanical modeling of non-crimp 3D
orthogonal carbon fabric and composites reinforced with it for
aerospace applications. In this research meso-finite element (FE)
modeling employs for stress analysis in different load conditions.
Since mechanical testing of expensive textile carbon composites with
specific application isn't affordable, simulation composite in a virtual
environment is a helpful way to investigate its mechanical properties
in different conditions.
Abstract: Al6061 alloy base matrix, reinforced with particles of
silicon carbide (10 wt %) and Graphite powder (1wt%), known as
hybrid composites have been fabricated by liquid metallurgy route
(stir casting technique) and optimized at different parameters like
applied load, sliding speed and sliding distance by taguchi method. A
plan of experiment generated through taguchi technique was used to
perform experiments based on L27 orthogonal array. The developed
ANOVA and regression equations are used to find the optimum
coefficient of friction and wear under the influence of applied load,
sliding speed and sliding distance. On the basis of “smaller the best”
the dry sliding wear resistance was analysed and finally confirmation
tests were carried out to verify the experimental results.
Abstract: An Australian manufacturer has fabricated an
innovative GFRP sandwich panel made from E-glass fiber skin and a
modified phenolic core for structural applications. Debonding, which
refers to separation of skin from the core material in composite
sandwiches, is one of the most common types of damage in
composites. The presence of debonding is of great concern because it
not only severely affects the stiffness but also modifies the dynamic
behaviour of the structure. Generally it is seen that the majority of
research carried out has been concerned about the delamination of
laminated structures whereas skin-core debonding has received
relatively minor attention. Furthermore it is observed that research
done on composite slabs having multiple skin-core debonding is very
limited. To address this gap, a comprehensive research investigating
dynamic behaviour of composite panels with single and multiple
debonding is presented. The study uses finite-element modelling and
analyses for investigating the influence of debonding on free
vibration behaviour of single and multilayer composite sandwich
panels. A broad parametric investigation has been carried out by
varying debonding locations, debonding sizes and support conditions
of the panels in view of both single and multiple debonding.
Numerical models were developed with Strand7 finite element
package by innovatively selecting the suitable elements to diligently
represent their actual behavior. Three-dimensional finite element
models were employed to simulate the physically real situation as
close as possible, with the use of an experimentally and numerically
validated finite element model. Comparative results and conclusions
based on the analyses are presented. For similar extents and locations
of debonding, the effect of debonding on natural frequencies appears
greatly dependent on the end conditions of the panel, giving greater
decrease in natural frequency when the panels are more restrained.
Some modes are more sensitive to debonding and this sensitivity
seems to be related to their vibration mode shapes. The fundamental
mode seems generally the least sensitive mode to debonding with
respect to the variation in free vibration characteristics. The results
indicate the effectiveness of the developed three dimensional finite
element models in assessing debonding damage in composite
sandwich panels.
Abstract: The main objective of incorporating natural fibers such as Henequen microfibers (NF) into the High Density Polyethylene (HDPE) polymer matrix is to reduce the cost and to enhance the mechanical as well as other properties. The Henequen microfibers were chopped manually to 5-7mm in length and added into the polymer matrix at the optimized concentration of 8 wt %. In order to facilitate the link between Henequen microfibers (NF) and HDPE matrix, coupling agent such as Glycidoxy (Epoxy) Functional Methoxy Silane (GPTS) at various concentrations from 0.1%, 0.3%, 0.5%, 0.7%, 0.9% and 1% by weight to the total fibers were added. The tensile strength of the composite increased marginally while % elongation at break of the composites decreased with increase in silane loading by wt %. Tensile modulus and stiffness observed increased at 0.9 wt % GPTS loading. Flexural as well as impact strength of the composite decreased with increase in GPTS loading by weight %. Dielectric strength of the composite also found increased marginally up to 0.5wt % silane loading and thereafter remained constant.
Abstract: Dental porcelain composites reinforced and toughened
by 20 wt.% tetragonal zirconia (3Y-TZP) were processed by hot
pressing at 1000°C. Two types of particles were tested: yttriastabilized
zirconia (ZrO2–3%Y2O3) agglomerates and pre-sintered
yttria-stabilized zirconia (ZrO2–3%Y2O3) particles. The composites
as well as the reinforcing particles were analyzed by the means of
optical and Scanning Electron Microscopy (SEM), Energy Dispersion
Spectroscopy (EDS) and X-Ray Diffraction (XRD). The mechanical
properties were obtained by the transverse rupture strength test. Wear
tests were also performed on the composites and monolithic
porcelain. The best mechanical results were displayed by the
porcelain reinforced with the pre-sintered ZrO2–3%Y2O3
agglomerates.
Abstract: The problem of toughening in brittle materials
reinforced by fibers is complex, involving all of the mechanical
properties of fibers, matrix and the fiber/matrix interface, as well as
the geometry of the fiber. Development of new numerical methods
appropriate to toughening simulation and analysis is necessary. In
this work, we have performed simulations and analysis of toughening
in brittle matrix reinforced by randomly distributed fibers by means
of the discrete elements method. At first, we put forward a
mechanical model of toughening contributed by random fibers. Then
with a numerical program, we investigated the stress, damage and
bridging force in the composite material when a crack appeared in the
brittle matrix. From the results obtained, we conclude that: (i) fibers
of high strength and low elasticity modulus are beneficial to
toughening; (ii) fibers of relatively high elastic modulus compared to
the matrix may result in substantial matrix damage due to spalling
effect; (iii) employment of high-strength synthetic fibers is a good
option for toughening. We expect that the combination of the discrete
element method (DEM) with the finite element method (FEM) can
increase the versatility and efficiency of the software developed. The
present work can guide the design of ceramic composites of high
performance through the optimization of the parameters.
Abstract: Rice husk and kenaf filled with calcium carbonate
(CaCO3) and high density polyethylene (HDPE) composite were
prepared separately using twin-screw extruder at 50rpm. Different
filler loading up to 30 parts of rice husk particulate and kenaf fiber
were mixed with the fixed 30% amount of CaCO3 mineral filler to
produce rice husk/CaCO3/HDPE and kenaf/CaCO3/HDPE hybrid
composites. In this study, the effects of natural fiber for both rice
husk and kenaf in CaCO3/HDPE composite on physical, mechanical
and morphology properties were investigated. Field Emission
Scanning Microscope (FeSEM) was used to investigate the impact
fracture surfaces of the hybrid composite. The property analyses
showed that water absorption increased with the presence of kenaf
and rice husk fillers. Natural fibers in composite significantly
influence water absorption properties due to natural characters of
fibers which contain cellulose, hemicellulose and lignin structures.
The result showed that 10% of additional natural fibers into hybrid
composite had caused decreased flexural strength, however additional
of high natural fiber (>10%) filler loading has proved to increase its
flexural strength.
Abstract: In the present work, the dielectric properties of
Epoxy/MWCNT-muscovite HYBRID and MIXED composites based
on a ratio 30:70 were studied. The multi-wall carbon nanotubes
(MWCNT) were prepared using two methods: (a) MWCNTmuscovite
hybrids were synthesised by chemical vapour deposition
(CVD) and (b) physically mixing muscovite with MWCNT. The
effects of different preparation of the composites and filler loading
were evaluated. It was revealed that the dielectric constants of
HYBRID epoxy composites are slightly higher than MIXED epoxy
composites. It was also indicated that the dielectric constant increased
by increasing the MWCNT filler loading.
Abstract: Chemical vapor deposition (CVD) diamond coated
cutting tool has excellent cutting performance, it is the most ideal tool
for the processing of nonferrous metals and alloys, composites,
nonmetallic materials and other difficult-to-machine materials
efficiently and accurately. Depositing CVD diamond coating on the
cemented carbide with high cobalt content can improve its toughness
and strength, therefore, it is very important to research on the
preparation technology and cutting properties of CVD diamond coated
cemented carbide cutting tool with high cobalt content. The
preparation technology of boron-doped diamond (BDD) coating has
been studied and the coated drills were prepared. BDD coating were
deposited on the drills by using the optimized parameters and the SEM
results show that there are no cracks or collapses in the coating.
Cutting tests with the prepared drills against the silumin and aluminum
base printed circuit board (PCB) have been studied. The results show
that the wear amount of the coated drill is small and the machined
surface has a better precision. The coating does not come off during
the test, which shows good adhesion and cutting performance of the
drill.
Abstract: In the present work, fly ash geopolymer based
composites including polyester (PES) waste were studied. Specimens
of three compositions were prepared: (a) fly ash geopolymer with 5%
PES waste; (b) fly ash geopolymer mortar with 5% PES waste; (c) fly
ash geopolymer mortar with 6.25% PES waste. Compressive and
bending strength measurements, water absorption test and
determination of thermal conductivity coefficient were performed.
The results showed that the addition of sand in a mixture of
geopolymer with 5% PES content led to higher compressive strength,
while it increased water absorption and reduced thermal conductivity
coefficient. The increase of PES addition in geopolymer mortars
resulted in a more dense structure, indicated by the increase of
strength and thermal conductivity and the decrease of water
absorption.
Abstract: In this work, we report, a systematic study on the
structural and optical properties of Pr-doped ZnO nanostructures and
PVA:Zn98Pr2O polymer matrix nanocomposites free standing films.
These particles are synthesized through simple wet chemical route
and solution casting technique at room temperature, respectively.
Structural studies carried out by X-ray diffraction method confirm
that the prepared pure ZnO and Pr doped ZnO nanostructures are in
hexagonal wurtzite structure and the microstrain is increased upon
doping. TEM analysis reveals that the prepared materials are in sheet
like nature. Absorption spectra show free excitonic absorption band
at 370 nm and red shift for the Pr doped ZnO nanostructures. The
PVA:Zn98Pr2O composite film exhibits both free excitonic and PVA
absorption bands at 282 nm. Fourier transform infrared spectral
studies confirm the presence of A1 (TO) and E1 (TO) modes of Zn-O
bond vibration and the formation of polymer composite materials.