Abstract: The present work reports an effect of surface- modification of indium tin oxide (ITO) particles with chemicals on their electronic conductivity properties. Examined chemicals were polyvinyl alcohol (nonionic polymer), poly(diallyl dimethyl ammonium chloride) (cationic polymer), poly(sodium 4-styrene-sulfonate) (anionic polymer), (2-aminopropyl) trimethoxy silane (APMS) (silane coupling agent with amino group), and (3-mercaptopropyl) trimethoxy silane (MPS) (silane coupling agent with thiol group). For all the examined chemicals, volume resistivities of surface-modified ITO particles did not increase much when they were aged in air at 80 oC, compared to a volume resistivity of un-surface-modified ITO particles. Increases in volume resistivities of ITO particles surface-modified with the silane coupling agents were smaller than those with the polymers, since hydrolysis of the silane coupling agents and condensation of generated silanol and OH groups on ITO particles took place to provide efficient immobilization of them on particles. The APMS gave an increase in volume resistivity smaller than the MPS, since a larger solubility in water of APMS providing a larger amount of APMS immobilized on particles.
Abstract: Lightweight and efficient structures have the aim to
enhance the efficiency of the components in various industries.
Toward this end, composites are one of the most widely used
materials because of durability, high strength and modulus, and low
weight. One type of the advanced composites is grid-stiffened
composite (GSC) structures, which have been extensively considered
in aerospace, automotive, and aircraft industries. They are one of the
top candidates for replacing some of the traditional components,
which are used here. Although there are a good number of published
surveys on the design aspects and fabrication of GSC structures, little
systematic work has been reported on their material modification to
improve their properties, to our knowledge. Matrix modification
using nanoparticles is an effective method to enhance the flexural
properties of the fibrous composites. In the present study, a silanecoupling
agent (3-glycidoxypropyltrimethoxysilane/3-GPTS) was
introduced onto the silica (SiO2) nanoparticle surface and its effects
on the three-point flexural response of isogrid E-glass/epoxy
composites were assessed. Based on the Fourier Transform Infrared
Spectrometer (FTIR) spectra, it was inferred that the 3-GPTS
coupling agent was successfully grafted onto the surface of SiO2
nanoparticles after modification. Flexural test revealed an
improvement of 16%, 14%, and 36% in stiffness, maximum load and
energy absorption of the isogrid specimen filled with 3 wt.% 3-
GPTS/SiO2 compared to the neat one. It would be worth mentioning
that in these structures, considerable energy absorption was observed
after the primary failure related to the load peak. In addition, 3-
GPTMS functionalization had a positive effect on the flexural
behavior of the multiscale isogrid composites. In conclusion, this
study suggests that the addition of modified silica nanoparticles is a
promising method to improve the flexural properties of the gridstiffened
fibrous composite structures.
Abstract: Durian skin is a newly explores natural fibre
potentially reinforced polyolefin for diverse applications. In this
work, investigation on the effect of coupling agent, maleic anhydride
polypropylene (MAPP) on the mechanical, morphological, and
thermal properties of polypropylene (PP) reinforced with durian skin
fibre (DSF) was conducted. The presence of 30 wt% DSF
significantly reduced the tensile strength of PP-DSF composite.
Interestingly, even though the same trend goes to PP-DSF with the
presence of MAPP, the reduction is only about 4% relative to
unreinforced PP and 18% higher than PP-DSF without MAPP
(untreated composite or UTC). The used of MAPP in treated
composite (TC) also increased the tensile modulus, flexural
properties and degradation temperature. The enhanced mechanical
properties are consistent with good interfacial interaction as
evidenced under scanning electron microscopy.
Abstract: The main objective of incorporating natural fibers such as Henequen microfibers (NF) into the High Density Polyethylene (HDPE) polymer matrix is to reduce the cost and to enhance the mechanical as well as other properties. The Henequen microfibers were chopped manually to 5-7mm in length and added into the polymer matrix at the optimized concentration of 8 wt %. In order to facilitate the link between Henequen microfibers (NF) and HDPE matrix, coupling agent such as Glycidoxy (Epoxy) Functional Methoxy Silane (GPTS) at various concentrations from 0.1%, 0.3%, 0.5%, 0.7%, 0.9% and 1% by weight to the total fibers were added. The tensile strength of the composite increased marginally while % elongation at break of the composites decreased with increase in silane loading by wt %. Tensile modulus and stiffness observed increased at 0.9 wt % GPTS loading. Flexural as well as impact strength of the composite decreased with increase in GPTS loading by weight %. Dielectric strength of the composite also found increased marginally up to 0.5wt % silane loading and thereafter remained constant.
Abstract: It is well known that enhancing interfacial adhesion
between inorganic filler and matrix resin in a composite lead to
favorable properties such as excellent mechanical properties, high
thermal resistance, prominent electric insulation, low expansion
coefficient, and so on. But it should be avoided that much excess of
coupling agent is reacted due to a negative impact of their final
composite-s properties. There is no report to achieve classification of
the bonding state excepting investigation of coating layer thickness.
Therefore, the analysis of the bonding state of the coupling agent
reacted with the filler surface such as BN particles with less functional
group and silica particles having much functional group was
performed by thermal gravimetric analysis and pyrolysis GC/MS. The
reacted number of functional groups on the silane-coupling agent was
classified as a result of the analysis. Thus, we succeeded in classifying
the reacted number of the functional groups as a result of this study.
Abstract: The stab resistance performance of newly developed
fabric composites composed of hexagonal paper honeycombs, filled
with shear thickening fluid (STF), and woven Kevlar® fabric or
UHMPE was investigated in this study. The STF was prepared by
dispersing submicron SiO2 particles into polyethylene glycol (PEG).
Our results indicate that the STF-Kevlar composite possessed lower
penetration depth than that of neat Kevlar. In other words, the
STF-Kevlar composite can attain the same energy level in
stab-resistance test with fewer layers of Kevlar fabrics than that of the
neat Kevlar fabrics. It also indicates that STF can be used for the
fabrication of flexible body armors and can provide improved
protection against stab threats. We found that the stab resistance of the
STF-Kevlar composite increases with the increase of SiO2
concentration in STF. Moreover, the silica particles functionalized
with silane coupling agent can further improve the stab resistance.
Abstract: Alkali treated oil palm empty fruit bunch (EFB) fibres
(TEFBF) and untreated EFBF fibers (UEFBF) were incorporated in
polypropylene (PP) with and without malic anhydride grafted PP
(MAPP) and magnesium hydroxide as flame retardant (FR) to
produce TEFBF-PP and UEFBF-PP composites by the melt casting
method. The composites were characterized by mechanical and
burning tests along with a scanning electron microscope and Fourier
transform infrared spectroscopy. The significant improvement in
flexural modulus (133%) and flame retardant property (60%) of
TEFBF-PP composite with MAPP and FR is observed. The improved
mechanical property is discussed by the development of encapsulated
textures.