Abstract: The great majority of the applications of thermal isolation in the strip of drops and averages temperatures (up to 200ºC), it is made of materials aggressive nature, such an as glass wool, rock wool, polystyrene, EPS among others. Such materials, in spite of the effectiveness in the retention of the flow of heat, possess considerable cost and when discarded they are long years to be to decompose. In that context, trying to adapt the world politics the about of the preservation of the environment, a study began with intention of developing a material composite, with properties of thermal, originating from insulating industrial residues. In this research, the behavior of the composite was analyzed, as submitted the fire. For this, the reaction rehearsals were accomplished to the fire for the composites 2:1; 1:1; 1:2 and for the Latex, based in the "con" experiment in agreement with the norm ASTM - E 1334 - 90. As consequence, in function of the answers of the system was possible to be observed to the acting of each mixture proportion.
Abstract: This study attempts to understand the effect of different UV irradiation methods on the intercalation of LDPE/MMT nanocomposites, and its molecular behavior at certain isothermal crystallization temperature. Three different methods of UV exposure were employed using single composition of LDPE/MMT nanocomposites. All samples were annealed for 5 hours at a crystallization temperature of 100oC. The crystallization temperature was chosen to be at large supercooling temperature to ensure quick and complete crystallization. The raw material of LDPE consisted of two stable monoclinic and orthorhombic phases according to XRD results. The thermal behavior of both phases acted differently when UV exposure method was changed. The monoclinic phase was more dependent on the method used compared to the orthorhombic phase. The intercalation of clay, as well as, the non-isothermal crystallization temperature, has also shown a clear dependency on the type of UV exposure. A third phase that is thermally less stable was also observed. Its respond to UV irradiation was greater since it contains low molecular weight entities which make it more vulnerable to any UV exposure.
Abstract: E-glass-epoxy laminated composites having different fiber volume fractions (40, 50, 60 and 70) were fabricated with and without the addition of nanoclay. Flexural strength and tensile strength of the composite laminates were determined. It was observed that, with increasing the fiber volume fraction (Vf) of fiber from 40 to 60, the ability of nanoclay to enhance the tensile and flexural strength of E-glass-epoxy composites decreases significantly. At 70Vf, the tensile and flexural strength of the nanoclay reinforced E-glass-epoxy were found to be lowest when compared to the E-glass-epoxy composite made without the addition of nanoclay. Based on the obtained data and microstructure of the tested samples, plausible mechanism for the observed trends has been proposed. The enhanced mechanical properties for nanoclay reinforced E-glass-epoxy composites for 40-60 Vf, due to higher interface toughness coupled with strong interfilament bonding may have ensured the homogeneous load distribution across all the glass fibers. Results in the decrease in mechanical properties at 70Vf, may be due to the inability of the matrix to bind the nanoclay and glass-fibers.
Abstract: Effective treatment of ground instability is essential when managing the impacts associated with historic mining. A field trial was undertaken by the Coal Authority to investigate the geotechnical performance and potential use of composite materials comprising resin and fill or stone to safely treat surface collapses, such as crown-holes, associated with shallow mining. Test pits were loosely filled with various granular fill materials. The fill material was injected with commercially available silicate and polyurethane resin foam products. In situ and laboratory testing was undertaken to assess the geotechnical properties of the resultant composite materials. The test pits were subsequently excavated to assess resin permeation. Drilling and resin injection was easiest through clean limestone fill materials. Recycled building waste fill material proved difficult to inject with resin; this material is thus considered unsuitable for use in resin composites. Incomplete resin permeation in several of the test pits created irregular ‘blocks’ of composite. Injected resin foams significantly improve the stiffness and resistance (strength) of the un-compacted fill material. The stiffness of the treated fill material appears to be a function of the stone particle size, its associated compaction characteristics (under loose tipping) and the proportion of resin foam matrix. The type of fill material is more critical than the type of resin to the geotechnical properties of the composite materials. Resin composites can effectively support typical design imposed loads. Compared to other traditional treatment options, such as cement grouting, the use of resin composites is potentially less disruptive, particularly for sites with limited access, and thus likely to achieve significant reinstatement cost savings. The use of resin composites is considered a suitable option for the future treatment of shallow mining collapses.
Abstract: The present study is based on the three-dimensional digital analysis by the finite elements method of the mechanical loading effect on the delamination of unidirectional and multidirectional stratified composites. The aim of this work is the determination of the release energy rate G in mode I and the Von Mises equivalent constraint distribution along the damaged area under the influence of several parameters such as the applied load and the delamination size. The results obtained in this study show that the unidirectional composite laminates have better mechanical resistance one the loading line than the multidirectional composite laminates.
Abstract: The tribological test with Pin-On-Disc configuration
measures friction and wear properties in dry or lubricated sliding
surfaces of a variety of materials and coatings. Polymeric matrix
composites loaded with mineral filler were used, 1%, 3%, 10%, 30%,
and 50% mass percentage of filler, to reduce the material cost by
using mineral tailings. Using a pin-on-disc tribometer to quantify
coefficient of friction and wear resistance of the specimens. The
parameters known to performing the test were 300 rpm rotation,
normal load of 16N and duration of 33.5 minutes. The composite
with 10% mineral filler performed better, considering that the wear
resistance was good when compared to the other compositions and an
average low coefficient of friction, in the order of μ ≤ 0.15.
Abstract: The combination of the properties of graphene oxide
(OG) and PVDF homopolymer makes their combined composite
materials as multifunctional systems with great potential. Knowledge
of the molecular structure is essential for better use. In this work, the
degradation of PVDF polymer exposed to gamma irradiation in
oxygen atmosphere in high dose rate has been studied and compared
to degradation of PVDF/OG composites. The samples were irradiated
with a Co-60 source at constant dose rate, with doses ranging from
100 kGy to 1,000 kGy. In FTIR data shown that the formation of
oxidation products was at the both samples with formation of
carbonyl and hydroxyl groups amongst the most prevalent products
in the pure PVDF samples. In the other hand, the composites samples
exhibit less presence of degradation products with predominant
formation of carbonyl groups, these results also seen in the UV-Vis
analysis. The results show that the samples of composites may have
greater resistance to the irradiation process, since they have less
degradation products than pure PVDF samples seen by spectroscopic
techniques.
Abstract: Sisal leaves were subjected to enzymatic retting
method to extract the sisal fibre. A portion of the fibre was pretreated
with alkali (NaOH), and further treated with benzoyl chloride
and silane treatment reagents. Both the treated and untreated Sisal
fibre composites were used to fabricate the composite by hand lay-up
technique using unsaturated polyester resin. Tensile, flexural, water
absorption, density, thickness swelling and chemical resistant tests
were conducted and evaluated on the composites. Results obtained
for all the parameters showed an increase in the treated fibre
compared to untreated fibre. FT-IR spectra results ascertained the
inclusion of benzoyl and silane groups on the fibre surface. Scanning
electron microscopy (SEM) result obtained showed variation in the
morphology of the treated and untreated fibre. Chemical modification
was found to improve adhesion of the fibre to the matrix, as well as
physico-mechanical properties of the composites.
Abstract: The combination of multi–walled carbon nanotubes
(MWCNTs) with polymers offers an attractive route to reinforce the
macromolecular compounds as well as the introduction of new
properties based on morphological modifications or electronic
interactions between the two constituents. As they are only a few
nanometers in dimension, it offers ultra-large interfacial area per
volume between the nano-element and polymer matrix. Nevertheless,
the use of MWCNTs as a rough material in different applications has
been largely limited by their poor processability, insolubility, and
infusibility. Studies concerning the nanofiller reinforced polymer
composites are justified in an attempt to overcome these limitations.
This work presents one preliminary study of MWCNTs dispersion
into the PVDF homopolymer. For preparation, the composite
components were diluted in n,n-dimethylacetamide (DMAc) with
mechanical agitation assistance. After complete dilution, followed by
slow evaporation of the solvent at 60°C, the samples were dried.
Films of about 80 μm were obtained. FTIR and UV-Vis
spectroscopic techniques were used to characterize the
nanocomposites. The appearance of absorption bands in the FTIR
spectra of nanofilled samples, when compared to the spectrum of
pristine PVDF samples, are discussed and compared with the UV-Vis
measurements.
Abstract: This paper investigates the application of metallic
coatings on high fiber volume fraction carbon/epoxy polymer matrix
composites. For the grip of the metallic layer, a method of modifying
the surface of the composite by introducing a mixture of copper and
steel powder (filler powders) which can reduce the impact of thermal
spray particles. The powder was introduced to the surface at the time
of the forming. Arc spray was used to project the zinc coating layer.
The substrate was grit blasted to avoid poor adherence. The porosity, microstructure, and morphology of layers are
characterized by optical microscopy, SEM and image analysis. The
samples were studied also in terms of hardness and erosion resistance.
This investigation did not reveal any visible evidence damage to the
substrates. The hardness of zinc layer was about 25.94 MPa and the
porosity was around (∼6.70%). The erosion test showed that the zinc
coating improves the resistance to erosion. Based on the results
obtained, we can conclude that thermal spraying allows the production
of protective coating on PMC. Zinc coating has been identified as a
compatible material with the substrate. The filler powders layer
protects the substrate from the impact of hot particles and allows
avoiding the rupture of brittle carbon fibers.
Abstract: Some of the main causes for degradation of polymeric materials are thermal aging, hydrolysis, oxidation or chemical degradation by acids, alkalis or water. The first part of this paper provides a brief summary of advances in technology, methods and specification of composite materials for relining as a rehabilitation technique for sewage systems. The second part summarizes an investigation on frequently used composite materials for relining in Sweden, the rubber filled epoxy composite and reinforced polyester composite when they were immersed in deionized water or in dry conditions, and elevated temperatures up to 80°C in the laboratory. The tests were conducted by visual inspection, microscopy, Dynamic Mechanical Analysis (DMA), Differential Scanning Calorimetry (DSC) as well as mechanical testing, three point bending and tensile testing.
Abstract: The rheological response of blends obtained from
quaternized polysulfone and polyvinyl alcohol in N-methyl-2-
pyrrolidone as against structural peculiarity of polymers from the
blend, composition of polymer mixtures, as well as the types of
interactions were investigated. Results show that the variation of
polyvinyl alcohol composition in the studied system determines
changes of the rheological properties, suggesting that the PVA acts as
a plasticizer. Consequently, rheological behavior of complex system,
described by the nonlinear flow curve, indicates the impact of
polyvinil alcohol content to polysulfone solution, in order to facilitate
the subsequently preparation of bioactive membranes.
Abstract: Nanofibers are defined as fibers with diameters less
than 100 nanometers. In this study, behaviours of activated carbon
nanofiber (ACNF), carbon nanofiber (CNF), polyacrylonitrile/ carbon
nanotube (PAN/CNT), polyvinyl alcohol/nanosilver (PVA/Ag) in
proton exchange membrane (PEM) fuel cells are investigated
experimentally. This material was used as gas diffusion layer (GDL)
in PEM fuel cells. In this study, the electrical conductivities of
nanofiber and nanofiber/nanoparticles have been studied to
understand their effects on PEM fuel cell performance. According to
the experimental results, the maximum electrical conductivity
performance of the fuel cell with nanofiber was found to be at
PVA/Ag (at UConn condition). The electrical conductivities of CNF,
ACNF, PAN/CNT are lower for PEM. The resistance of cell with
PVA/Ag is lower than the resistance of cell with PAN/CNT, ACNF,
CNF.
Abstract: This work aims to investigate the structure–property
relationship in ternary nanocomposites consisting of polypropylene
as the matrix, polyamide 66 as the minor phase and treated nanoclay
DELLITE 67G as the reinforcement. All PP/PA66/Nanoclay systems
with polypropylene grafted maleic anhydride PP-g-MAH as a
compatibilizer were prepared via melt compounding and
characterized in terms of nanoclay content. Morphological structure
was investigated by scanning electron microscopy. The rheological
behavior of the nanocomposites was determined by various methods,
viz melt flow index (MFI) and parallel plate rheological
measurements. The PP/PP-g-MAH/PA66 nanocomposites showed a homogeneous
morphology supporting the compatibility improvement between PP,
PA66, and nanoclay. SEM results revealed the formation of
nanocomposites as the nanoclay was intercalated and exfoliated. In
the ternary nanocomposites, the rheological behavior showed that, the
complex viscosity is increased with increasing the nanoclay. The results showed that the use of nanoclay affects the variations
of storage modulus (G′), loss modulus (G″) and the melt elasticity.
Abstract: This paper presents the effects of mixing procedures
on mechanical properties of flyash-based geopolymer matrices
containing nanosilica (NS) at 0.5%, 1.0%, 2.0%, and 3.0% by weight.
Comparison is made with conventional mechanical dry-mixing of NS
with flyash and wet-mixing of NS in alkaline solutions. Physical and
mechanical properties are investigated using X-Ray Diffraction
(XRD) and Scanning Electron Microscope (SEM). Results show that
generally the addition of NS particles enhanced the microstructure
and improved flexural and compressive strengths of geopolymer
nanocomposites. However, samples, prepared using dry-mixing
approach, demonstrate better physical and mechanical properties
comparing to wet-mixing samples.
Abstract: Low density polyethylene (LDPE) nanocomposites
with 3, 5 and 7 wt. % cobalt ferrite (CoFe2O4) nanopowder fabricated
with extrusion mixing and followed up by hot press to reach compact
samples. The transmission/reflection measurements were carried out
with a network analyzer in the frequency range of 8-12 GHz. By
increasing the percent of CoFe2O4 nanopowder, reflection loss (S11)
increases, while transferring loss (S21) decreases. Reflectivity (R)
calculations made using S11 and S21. Increase in percent of CoFe2O4
nanopowder up to 7 wt. % in composite leaded to higher reflectivity
amount, and revealed that increasing the percent of CoFe2O4
nanopowder up to 7 wt. % leads to further microwave absorption in
8-12 GHz range.
Abstract: Lightweight and efficient structures have the aim to
enhance the efficiency of the components in various industries.
Toward this end, composites are one of the most widely used
materials because of durability, high strength and modulus, and low
weight. One type of the advanced composites is grid-stiffened
composite (GSC) structures, which have been extensively considered
in aerospace, automotive, and aircraft industries. They are one of the
top candidates for replacing some of the traditional components,
which are used here. Although there are a good number of published
surveys on the design aspects and fabrication of GSC structures, little
systematic work has been reported on their material modification to
improve their properties, to our knowledge. Matrix modification
using nanoparticles is an effective method to enhance the flexural
properties of the fibrous composites. In the present study, a silanecoupling
agent (3-glycidoxypropyltrimethoxysilane/3-GPTS) was
introduced onto the silica (SiO2) nanoparticle surface and its effects
on the three-point flexural response of isogrid E-glass/epoxy
composites were assessed. Based on the Fourier Transform Infrared
Spectrometer (FTIR) spectra, it was inferred that the 3-GPTS
coupling agent was successfully grafted onto the surface of SiO2
nanoparticles after modification. Flexural test revealed an
improvement of 16%, 14%, and 36% in stiffness, maximum load and
energy absorption of the isogrid specimen filled with 3 wt.% 3-
GPTS/SiO2 compared to the neat one. It would be worth mentioning
that in these structures, considerable energy absorption was observed
after the primary failure related to the load peak. In addition, 3-
GPTMS functionalization had a positive effect on the flexural
behavior of the multiscale isogrid composites. In conclusion, this
study suggests that the addition of modified silica nanoparticles is a
promising method to improve the flexural properties of the gridstiffened
fibrous composite structures.
Abstract: Polymeric composites are being increasingly used as
repair material for repairing critical infrastructures such as building,
bridge, pressure vessel, piping and pipeline. Technique in repairing
damaged pipes is one of the major concerns of pipeline owners.
Considerable researches have been carried out on the repair of
corroded pipes using composite materials. This article attempts a
short review of the subject matter to provide insight into various
techniques used in repairing corroded pipes, focusing on a wide range
of composite repair systems. These systems including pre-cured
layered, flexible wet lay-up, pre-impregnated, split composite sleeve
and flexible tape systems. Both advantages and limitations of these
repair systems were highlighted. Critical technical aspects have been
discussed through the current standards and practices. Research gaps
and future study scopes in achieving more effective design
philosophy are also presented.
Abstract: This experimental study consists of a characterization
of epoxy grout where an amount of 2% of graphene nanoplatelets
particles were added to commercial epoxy resin to evaluate their
behavior regarding neat epoxy resin. Compressive tests, tensile tests
and flexural tests were conducted to study the effect of graphene
nanoplatelets on neat epoxy resin. By comparing graphene-based and
neat epoxy grout, there is no significant increase of strength due to
weak interface in the graphene nanoplatelets/epoxy composites.
From this experiment, the tension and flexural strength of graphenebased
epoxy grouts is slightly lower than ones of neat epoxy grout.
Nevertheless, the addition of graphene has produced more consistent
results according to a smaller standard deviation of strength.
Furthermore, the graphene has also improved the ductility of the
grout, hence reducing its brittle behaviour. This shows that the
performance of graphene-based grout is reliably predictable and able
to minimise sudden rupture. This is important since repair design of
damaged pipeline is of deterministic nature.
Abstract: Over the last two decades, externally bonded fiber
reinforced polymer (FRP) composites bonded to concrete substrates
has become a popular method for strengthening reinforced concrete
(RC) highway and railway bridges. Such structures are exposed to
severe cyclic loading throughout their lifetime often resulting in
fatigue damage to structural components and a reduction in the
service life of the structure. Since experimental and numerical results
on the fatigue performance of FRP-to-concrete joints are still limited,
the current research focuses on assessing the fatigue performance of
externally bonded FRP-to-concrete joints using a direct shear test.
Some early results indicate that the stress ratio and the applied cyclic
stress level have a direct influence on the fatigue life of the externally
bonded FRP. In addition, a calibrated finite element model is
developed to provide further insight into the influence of certain
parameters such as: concrete strength, FRP thickness, number of
cycles, frequency, and stiffness on the fatigue life of the FRP-toconcrete
joints.