Abstract: In this study the adsorption of Cu (II) ions from aqueous solutions on synthetic zeolite NaA was evaluated. The effect of solution temperature and the determination of the kinetic parameters of adsorption of Cu(II) from aqueous solution on zeolite NaA is important in understanding the adsorption mechanism. Variables of the system include adsorption time, temperature (293- 328K), initial solution concentration and pH for the system. The sorption kinetics of the copper ions were found to be strongly dependent on pH (the optimum pH 3-5), solute ion concentration and temperature (293 – 328 K). It was found, the pseudo-second-order model was the best choice among all the kinetic models to describe the adsorption behavior of Cu(II) onto ziolite NaA, suggesting that the adsorption mechanism might be a chemisorptions process The activation energy of adsorption (Ea) was determined as Cu(II) 13.5 kJ mol-1. The low value of Ea shows that Cu(II) adsorption process by zeolite NaA may be an activated chemical adsorption. The thermodynamic parameters (ΔG0, ΔH0, and ΔS0) were also determined from the temperature dependence. The results show that the process of adsorption Cu(II) is spontaneous and endothermic process and rise in temperature favors the adsorption.
Abstract: The mitigation of crop loss due to damaging freezes requires accurate air temperature prediction models. An improved model for temperature prediction in Georgia was developed by including information on seasonality and modifying parameters of an existing artificial neural network model. Alternative models were compared by instantiating and training multiple networks for each model. The inclusion of up to 24 hours of prior weather information and inputs reflecting the day of year were among improvements that reduced average four-hour prediction error by 0.18°C compared to the prior model. Results strongly suggest model developers should instantiate and train multiple networks with different initial weights to establish appropriate model parameters.
Abstract: Groundwater is an essential and vital component of our life support system. The groundwater resources are being utilized for drinking, irrigation and industrial purposes. There is growing concern on deterioration of groundwater quality due to geogenic and anthropogenic activities. Groundwater, being a fragile must be carefully managed to maintain its purity within standard limits. So, quality assessment and management are to be carried out hand-in-hand to have a pollution free environment and for a sustainable use. In order to assess the quality for consumption by human beings and for use in agriculture, the groundwater from the shallow aquifers (dug well) in the Palakkad and Chittur taluks of Bharathapuzha river basin - a paddy dominated agricultural basin (order=8th; L= 209 Km; Area = 6186 Km2), Kerala, India, has been selected. The water samples (n= 120) collected for various seasons, viz., monsoon-MON (August, 2005), postmonsoon-POM (December, 2005) and premonsoon-PRM (April, 2006), were analyzed for important physico-chemical attributes. Spatial and temporal variation of attributes do exist in the study area, and based on major cations and anions, different hydrochemical facies have been identified. Using Gibbs'diagram, rock dominance has been identified as the mechanism controlling groundwater chemistry. Further, the suitability of water for irrigation was determined by analyzing salinity hazard indicated by sodium adsorption ratio (SAR), residual sodium carbonate (RSC) and sodium percent (%Na). Finally, stress zones in the study area were delineated using Arc GIS spatial analysis and various management options were recommended to restore the ecosystem.
Abstract: The case study deals with the semi-quantitative risk
assessment of water resource earmarked for the emergency supply
of population with drinking water. The risk analysis has been based
on previously identified hazards/sensitivities of the elements
of hydrogeological structure and technological equipment of ground
water resource as well as on the assessment of the levels of hazard,
sensitivity and criticality of individual resource elements in the form
of point indexes. The following potential sources of hazard have
been considered: natural disasters caused by atmospheric and
geological changes, technological hazards, and environmental
burdens. The risk analysis has proved that the assessed risks are
acceptable and the water resource may be integrated into a crisis plan
of a given region.
Abstract: In this experimental work, we have shown that the
geometric shape of the grooves (furrows) plays an important role in
sediment dynamics. In addition, the rheological behaviour of solid
discharge does not depend only on the velocity discharge but also on
the geometric shape.
Abstract: The use of a Bayesian Hierarchical Model (BHM) to interpret breath measurements obtained during a 13C Octanoic Breath Test (13COBT) is demonstrated. The statistical analysis was implemented using WinBUGS, a commercially available computer package for Bayesian inference. A hierarchical setting was adopted where poorly defined parameters associated with a delayed Gastric Emptying (GE) were able to "borrow" strength from global distributions. This is proved to be a sufficient tool to correct model's failures and data inconsistencies apparent in conventional analyses employing a Non-linear least squares technique (NLS). Direct comparison of two parameters describing gastric emptying ng ( tlag -lag phase, t1/ 2 -half emptying time) revealed a strong correlation between the two methods. Despite our large dataset ( n = 164 ), Bayesian modeling was fast and provided a successful fitting for all subjects. On the contrary, NLS failed to return acceptable estimates in cases where GE was delayed.
Abstract: This paper studies stability of homogeneous beams
with piezoelectric layers subjected to axial load that is simply
supported at both ends lies on a continuous elastic foundation. The
displacement field of beam is assumed based on first order shear
deformation beam theory. Applying the Hamilton's principle, the
governing equation is established. The influences of applied voltage,
dimensionless geometrical parameter and foundation coefficient on
the stability of beam are presented. To investigate the accuracy of the
present analysis, a compression study is carried out with a known
data.
Abstract: Mathematical models of dynamics employing exterior calculus are mathematical representations of the same unifying principle; namely, the description of a dynamic system with a characteristic differential one-form on an odd-dimensional differentiable manifold leads, by analysis with exterior calculus, to a set of differential equations and a characteristic tangent vector (vortex vector) which define transformations of the system. Using this principle, a mathematical model for economic growth is constructed by proposing a characteristic differential one-form for economic growth dynamics (analogous to the action in Hamiltonian dynamics), then generating a pair of characteristic differential equations and solving these equations for the rate of economic growth as a function of labor and capital. By contracting the characteristic differential one-form with the vortex vector, the Lagrangian for economic growth dynamics is obtained.
Abstract: The crystallization kinetics and phase transformation
of SiO2.Al2O3.0,56P2O5.1,8CaO.0,56CaF2 glass have been
investigated using differential thermal analysis (DTA), x-ray
diffraction (XRD), and scanning electron microscopy (SEM). Glass
samples were obtained by melting the glass mixture at 14500С/120
min. in platinum crucibles. The mixture were prepared from
chemically pure reagents: SiO2, Al(OH)3, H3PO4, CaCO3 and CaF2.
The non-isothermal kinetics of crystallization was studied by
applying the DTA measurements carried out at various heating rates.
The activation energies of crystallization and viscous flow were
measured as 348,4 kJ.mol–1 and 479,7 kJ.mol–1 respectively. Value of
Avrami parameter n ≈ 3 correspond to a three dimensional of crystal
growth mechanism. The major crystalline phase determined by XRD
analysis was fluorapatite (Ca(PO4)3F) and as the minor phases –
fluormargarite (CaAl2(Al2SiO2)10F2) and vitlokite (Ca9P6O24). The
resulting glass-ceramic has a homogeneous microstructure, composed
of prismatic crystals, evenly distributed in glass phase.
Abstract: The concentrations of As, Hg, Co, Cr and Cd were
tested for each soil sample, and their spatial patterns were analyzed
by the semivariogram approach of geostatistics and geographical
information system technology. Multivariate statistic approaches
(principal component analysis and cluster analysis) were used to
identify heavy metal sources and their spatial pattern. Principal
component analysis coupled with correlation between heavy metals
showed that primary inputs of As, Hg and Cd were due to
anthropogenic while, Co, and Cr were associated with pedogenic
factors. Ordinary kriging was carried out to map the spatial patters of
heavy metals. The high pollution sources evaluated was related with
usage of urban and industrial wastewater. The results of this study
helpful for risk assessment of environmental pollution for decision
making for industrial adjustment and remedy soil pollution.
Abstract: Natural gas flow contains undesirable solid particles,
liquid condensation, and/or oil droplets and requires reliable
removing equipment to perform filtration. Recent natural gas
processing applications are demanded compactness and reliability of
process equipment. Since conventional means are sophisticated in
design, poor in efficiency, and continue lacking robust, a supersonic
nozzle has been introduced as an alternative means to meet such
demands.
A 3-D Convergent-Divergent Nozzle is simulated using
commercial Code for pressure ratio (NPR) varies from 1.2 to 2. Six
different shapes of nozzle are numerically examined to illustrate the
position of shock-wave as such spot could be considered as a
benchmark of particle separation. Rectangle, triangle, circular,
elliptical, pentagon, and hexagon nozzles are simulated using Fluent
Code with all have same cross-sectional area.
The simple one-dimensional inviscid theory does not describe the
actual features of fluid flow precisely as it ignores the impact of
nozzle configuration on the flow properties. CFD Simulation results,
however, show that nozzle geometry influences the flow structures
including location of shock wave.
The CFD analysis predicts shock appearance when p01/pa>1.2 for
almost all geometry and locates at the lower area ratio (Ae/At).
Simulation results showed that shock wave in Elliptical nozzle has
the farthest distance from the throat among the others at relatively
small NPR. As NPR increases, hexagon would be the farthest. The
numerical result is compared with available experimental data and
has shown good agreement in terms of shock location and flow
structure.
Abstract: Analysis of reciprocating equipment piston rod leads
to nonlinear elastic-plastic deformation analysis of rod with initial
imperfection under axial dynamic load. In this paper a new and
effective model and analytical formulations are presented to evaluate
dynamic deformation and elastic-plastic stresses of reciprocating
machine piston rod. This new method has capability to account for
geometric nonlinearity, elastic-plastic deformation and dynamic
effects. Proposed method can be used for evaluation of piston rod
performance for various reciprocating machines under different
operation situations. Rod load curves and maximum allowable rod
load are calculated with presented method for a refinery type
reciprocating compressor. Useful recommendations and guidelines
for rod load, rod load reversal and rod drop monitoring are also
addressed.
Abstract: In order to implement flexibility as well as survivable
capacities over passive optical network (PON), a new automatic
random fault-recovery mechanism with array-waveguide-grating
based (AWG-based) optical switch (OSW) is presented. Firstly,
wavelength-division-multiplexing and optical code-division
multiple-access (WDM/OCDMA) scheme are configured to meet the
various geographical locations requirement between optical network
unit (ONU) and optical line terminal (OLT). The AWG-base optical
switch is designed and viewed as central star-mesh topology to
prohibit/decrease the duplicated redundant elements such as fiber and
transceiver as well. Hence, by simple monitoring and routing switch
algorithm, random fault-recovery capacity is achieved over
bi-directional (up/downstream) WDM/OCDMA scheme. When error
of distribution fiber (DF) takes place or bit-error-rate (BER) is higher
than 10-9 requirement, the primary/slave AWG-based OSW are
adjusted and controlled dynamically to restore the affected ONU
groups via the other working DFs immediately.
Abstract: Stress Concentration Factors are significant in
machine design as it gives rise to localized stress when any change in
the design of surface or abrupt change in the cross section occurs.
Almost all machine components and structural members contain
some form of geometrical or microstructural discontinuities. These
discontinuities are very dangerous and lead to failure. So, it is very
much essential to analyze the stress concentration factors for critical
applications like Turbine Rotors. In this paper Finite Element
Analysis (FEA) with extremely fine mesh in the vicinity of the
blades of Steam Turbine Rotor is applied to determine stress
concentration factors. A model of Steam Turbine Rotor is shown in
Fig. 1.
Abstract: Reliable information about tool temperature
distribution is of central importance in metal cutting. In this study,
tool-chip interface temperature was determined in cutting of ST37
steel workpiece by applying HSS as the cutting tool in dry turning.
Two different approaches were implemented for temperature
measuring: an embedded thermocouple (RTD) in to the cutting tool
and infrared (IR) camera. Comparisons are made between
experimental data and results of MSC.SuperForm and FLUENT
software.
An investigation of heat generation in cutting tool was performed
by varying cutting parameters at the stable cutting tool geometry and
results were saved in a computer; then the diagrams of tool
temperature vs. various cutting parameters were obtained. The
experimental results reveal that the main factors of the increasing
cutting temperature are cutting speed (V ), feed rate ( S ) and depth
of cut ( h ), respectively. It was also determined that simultaneously
change in cutting speed and feed rate has the maximum effect on
increasing cutting temperature.
Abstract: The aim of this paper is to present a comparative
study on two different methods for the evaluation of the equilibrium
point of a ship, core issue for designing an On Board Stability System
(OBSS) module that, starting from geometry information of a ship
hull, described by a discrete model in a standard format, and the
distribution of all weights onboard calculates the ship floating
conditions (in draught, heel and trim).
Abstract: Some physical properties of musk lime (Citrus
microcarpa) were determined in this study. The average moisture
content (wet basis) of the fruit was found to be 85.10 (±0.72) %. The
mean of length, width and thickness of the fruit was 26.36 (±0.97),
26.40 (±1.04) and 25.26 (±0.94) mm respectively. The average value
for geometric mean diameter, sphericity, aspect ratio, mass, surface
area, volume, true density, bulk density and porosity was 26.00
(±0.82) mm, 98.67 (±2.04) %, 100.23 (±3.28) %, 10.007 (±0.878) g,
2125.07 (±133.93) mm2, 8800.00 (±731.82) mm3, 1002.87 (±39.16)
kgm-3, 501.70 (±22.58) kgm-3 and 49.89 (±3.15) % respectively.
The coefficient of static friction on four types of structural surface
was found to be varying from 0.238 (±0.025) for glass to 0.247
(±0.024) for steel surface.
Abstract: In this research work, investigations are carried out on
Continuous Wave (CW) Nd:YAG laser welding system after
preliminary experimentation to understand the influencing parameters
associated with laser welding of AISI 304. The experimental
procedure involves a series of laser welding trials on AISI 304
stainless steel sheets with various combinations of process parameters
like beam power, beam incident angle and beam incident angle. An
industrial 2 kW CW Nd:YAG laser system, available at Welding
Research Institute (WRI), BHEL Tiruchirappalli, is used for
conducting the welding trials for this research. After proper tuning of
laser beam, laser welding experiments are conducted on AISI 304
grade sheets to evaluate the influence of various input parameters on
weld bead geometry i.e. bead width (BW) and depth of penetration
(DOP). From the laser welding results, it is noticed that the beam
power and welding speed are the two influencing parameters on
depth and width of the bead. Three dimensional finite element
simulation of high density heat source have been performed for laser
welding technique using finite element code ANSYS for predicting
the temperature profile of laser beam heat source on AISI 304
stainless steel sheets. The temperature dependent material properties
for AISI 304 stainless steel are taken into account in the simulation,
which has a great influence in computing the temperature profiles.
The latent heat of fusion is considered by the thermal enthalpy of
material for calculation of phase transition problem. A Gaussian
distribution of heat flux using a moving heat source with a conical
shape is used for analyzing the temperature profiles. Experimental
and simulated values for weld bead profiles are analyzed for stainless
steel material for different beam power, welding speed and beam
incident angle. The results obtained from the simulation are
compared with those from the experimental data and it is observed
that the results of numerical analysis (FEM) are in good agreement
with experimental results, with an overall percentage of error
estimated to be within ±6%.
Abstract: This research is part of a broad program aimed at
advancing the science and technology involved in the rescue and
rehabilitation of oiled wildlife. One aspect of this research involves
the use of oil-sequestering magnetic particles for the removal of
contaminants from plumage – so-called “magnetic cleansing". This
treatment offers a number of advantages over conventional
detergent-based methods including portability - which offers the
possibility of providing a “quick clean" to the animal upon first
encounter in the field. This could be particularly advantageous
when the contaminant is toxic and/or corrosive and/or where there
is a delay in transporting the victim to a treatment centre. The
method could also be useful as part of a stabilization protocol when
large numbers of affected animals are awaiting treatment. This
presentation describes the design, development and testing of a
prototype field kit for providing a “quick clean" to contaminated
wildlife in the field.
Abstract: Dense slurry flow through centrifugal pump casing
has been modeled using the Eulerian-Eulerian approach with
Eulerian multiphase model in FLUENT 6.1®. First order upwinding
is considered for the discretization of momentum, k and ε terms.
SIMPLE algorithm has been applied for dealing with pressurevelocity
coupling. A mixture property based k-ε turbulence model
has been used for modeling turbulence. Results are validated first
against mesh independence and experiments for a particular set of
operational and geometric conditions. Parametric analysis is then
performed to determine the effect on important physical quantities
viz. solid velocities, solid concentration and solid stresses near the
wall with various operational geometric conditions of the pump.