Abstract: The major environmental risk of soil pollution is the
contamination of groundwater by infiltration of organic and inorganic
pollutants which can cause a serious menace. To prevent this risk and
to protect the groundwater, we proceeded in this study to test the
reliability of a biosolid as barrier to prevent the migration of very
dangerous pollutants as ‘Cadmium’ through the different soil layers. In this study, we tried to highlight the effect of several parameters
such as: turbidity (different cycle of Hydration/Dehydration),
rainfall, effect of initial Cd(II) concentration and the type of soil.
These parameters allow us to find the most effective manner to
integrate this barrier in the soil. From the results obtained, we found a
significant effect of the barrier. Indeed, the recorded passing
quantities are lowest for the highest rainfall; we noted also that the
barrier has a better affinity towards higher concentrations; the most
retained amounts of cadmium has been in the top layer of the two
types of soil tested, while the lowest amounts of cadmium are
recorded in the bottom layers of soils.
Abstract: Hard coatings are widely used in cutting and forming
tool industries. Titanium Nitride (TiN) possesses good hardness,
strength, and corrosion resistance. The coating properties are
influenced by many process parameters. The coatings were deposited
on steel substrate by changing the process parameters such as
substrate temperature, nitrogen flow rate and target power in a D.C
planer magnetron sputtering. The structure of coatings were analysed
using XRD. The hardness of coatings was found using Micro
hardness tester. From the experimental data, a regression model was
developed and the optimum response was determined using Response
Surface Methodology (RSM).
Abstract: Zinc borates are used as a multi-functional flame
retardant additive for its high dehydration temperature. In this study,
the method of ultrasonic mixing was used in the synthesis of zinc
borates. The reactants of zinc oxide (ZnO) and boric acid (H3BO3)
were used at the constant reaction parameters of 90°C reaction
temperature and 55 min of reaction time. Several molar ratios of
ZnO:H3BO3 (1:1, 1:2, 1:3, 1:4 and 1:5) were conducted for the
determination of the optimum reaction ratio. Prior to synthesis the
characterization of the synthesized zinc borates were made by X-Ray
Diffraction (XRD) and Fourier Transform Infrared Spectroscopy
(FT-IR). From the results Zinc Oxide Borate Hydrate
[Zn3B6O12.3.5H2O], were synthesized optimum at the molar ratio of
1:3, with a reaction efficiency of 95.2%.
Abstract: River Hindon is an important river catering the
demand of highly populated rural and industrial cluster of western
Uttar Pradesh, India. Water quality of river Hindon is deteriorating at
an alarming rate due to various industrial, municipal and agricultural
activities. The present study aimed at identifying the pollution
sources and quantifying the degree to which these sources are
responsible for the deteriorating water quality of the river. Various
water quality parameters, like pH, temperature, electrical
conductivity, total dissolved solids, total hardness, calcium, chloride,
nitrate, sulphate, biological oxygen demand, chemical oxygen
demand, and total alkalinity were assessed. Water quality data
obtained from eight study sites for one year has been subjected to the
two multivariate techniques, namely, principal component analysis
and cluster analysis. Principal component analysis was applied with
the aim to find out spatial variability and to identify the sources
responsible for the water quality of the river. Three Varifactors were
obtained after varimax rotation of initial principal components using
principal component analysis. Cluster analysis was carried out to
classify sampling stations of certain similarity, which grouped eight
different sites into two clusters. The study reveals that the
anthropogenic influence (municipal, industrial, waste water and
agricultural runoff) was the major source of river water pollution.
Thus, this study illustrates the utility of multivariate statistical
techniques for analysis and elucidation of multifaceted data sets,
recognition of pollution sources/factors and understanding
temporal/spatial variations in water quality for effective river water
quality management.
Abstract: Over the last two decades, externally bonded fiber
reinforced polymer (FRP) composites bonded to concrete substrates
has become a popular method for strengthening reinforced concrete
(RC) highway and railway bridges. Such structures are exposed to
severe cyclic loading throughout their lifetime often resulting in
fatigue damage to structural components and a reduction in the
service life of the structure. Since experimental and numerical results
on the fatigue performance of FRP-to-concrete joints are still limited,
the current research focuses on assessing the fatigue performance of
externally bonded FRP-to-concrete joints using a direct shear test.
Some early results indicate that the stress ratio and the applied cyclic
stress level have a direct influence on the fatigue life of the externally
bonded FRP. In addition, a calibrated finite element model is
developed to provide further insight into the influence of certain
parameters such as: concrete strength, FRP thickness, number of
cycles, frequency, and stiffness on the fatigue life of the FRP-toconcrete
joints.
Abstract: Fluctuations of Schottky diode parameters in a
structure of the mixer are investigated. These fluctuations are
manifested in two ways. At the first, they lead to fluctuations in the
transfer factor that is lead to the amplitude fluctuations in the signal
of intermediate frequency. On the basis of the measurement data of
1/f noise of the diode at forward current, the estimation of a spectrum
of relative fluctuations in transfer factor of the mixer is executed.
Current dependence of the spectrum of relative fluctuations in
transfer factor of the mixer and dependence of the spectrum of
relative fluctuations in transfer factor of the mixer on the amplitude
of the heterodyne signal are investigated. At the second, fluctuations
in parameters of the diode lead to occurrence of 1/f noise in the
output signal of the mixer. This noise limits the sensitivity of the
mixer to the value of received signal.
Abstract: This article developed an ion thruster optic system
sputter erosion depth numerical 3D model by IFE-PIC (Immersed
Finite Element-Particle-in-Cell) and Mont Carlo method, and
calculated the downstream surface sputter erosion rate of accelerator
grid; compared with LIPS-200 life test data. The results of the
numerical model are in reasonable agreement with the measured data.
Finally, we predicted the lifetime of the 20cm diameter ion thruster via
the erosion data obtained with the model. The ultimate result
demonstrated that under normal operating condition, the erosion rate
of the grooves wears on the downstream surface of the accelerator grid
is 34.6μm⁄1000h, which means the conservative lifetime until
structural failure occurring on the accelerator grid is 11500 hours.
Abstract: Green and renewable energy is getting extraordinary
consideration today, because of ecological concerns made by blazing
of fossil powers. Photovoltaic and wind power generation are the
basic decisions for delivering power in this respects. Producing
power by the sun based photovoltaic systems is known to the world,
yet control makers may get confounded to pick between on-grid and
off-grid systems. In this exploration work, an endeavor is made to
compare the off-grid (stand-alone) and on-grid (grid-connected)
frameworks. The work presents relative examination, between two
distinctive PV frameworks situated at V.V.P. Engineering College,
Rajkot. The first framework is 100 kW remain solitary and the
second is 60 kW network joined. The real-time parameters compared
are; output voltage, load current, power in-flow, power output,
performance ratio, yield factor, and capacity factor. The voltage
changes and the power variances in both frameworks are given
exceptional consideration and the examination is made between the
two frameworks to judge the focal points and confinements of both
the frameworks.
Abstract: Online measurement of the product quality is a
challenging task in cement production, especially in the production of
Celitement, a novel environmentally friendly hydraulic binder. The
mineralogy and chemical composition of clinker in ordinary Portland
cement production is measured by X-ray diffraction (XRD) and
X-ray fluorescence (XRF), where only crystalline constituents can be
detected. But only a small part of the Celitement components can be
measured via XRD, because most constituents have an amorphous
structure. This paper describes the development of algorithms
suitable for an on-line monitoring of the final processing step of
Celitement based on NIR-data. For calibration intermediate products
were dried at different temperatures and ground for variable
durations. The products were analyzed using XRD and
thermogravimetric analyses together with NIR-spectroscopy to
investigate the dependency between the drying and the milling
processes on one and the NIR-signal on the other side. As a result,
different characteristic parameters have been defined. A short
overview of the Celitement process and the challenging tasks of the
online measurement and evaluation of the product quality will be
presented. Subsequently, methods for systematic development of
near-infrared calibration models and the determination of the final
calibration model will be introduced. The application of the model on
experimental data illustrates that NIR-spectroscopy allows for a quick
and sufficiently exact determination of crucial process parameters.
Abstract: Average temperatures worldwide are expected to
continue to rise. At the same time, major cities in developing
countries are becoming increasingly populated and polluted.
Governments are tasked with the problem of overheating and air
quality in residential buildings. This paper presents the development
of a model, which is able to estimate the occupant exposure
to extreme temperatures and high air pollution within domestic
buildings. Building physics simulations were performed using the
EnergyPlus building physics software. An accurate metamodel is
then formed by randomly sampling building input parameters and
training on the outputs of EnergyPlus simulations. Metamodels are
used to vastly reduce the amount of computation time required when
performing optimisation and sensitivity analyses. Neural Networks
(NNs) have been compared to a Radial Basis Function (RBF)
algorithm when forming a metamodel. These techniques were
implemented using the PyBrain and scikit-learn python libraries,
respectively. NNs are shown to perform around 15% better than RBFs
when estimating overheating and air pollution metrics modelled by
EnergyPlus.
Abstract: The purposes of this study were to: 1) investigate
operation conditions of SME automotive part industry in Bangkok
and vicinity and 2) to compare operation problem levels of SME
automotive part industry in Bangkok and vicinity according to the
sizes of the enterprises. Samples in this study included 196
entrepreneurs of SME automotive part industry in Bangkok and
vicinity derived from simple random sampling and calculation from
R. V. Krejcie and D. W. Morgan’s tables. Research statistics included
frequency, percentage, mean, standard deviation, and T-test. The
results revealed that in general the problem levels of SME automotive
part industry in Bangkok and vicinity were high. When considering
in details, it was found that the problem levels were high at every
aspect, i.e. personal, production, export, finance, and marketing
respectively. The comparison of the problem levels according to the
sizes of the enterprises revealed statistically significant differences at
.05. When considering on each aspect, it was found that the aspect
with the statistical difference at .05 included 5 aspects, i.e.
production, marketing, finance, personal, and export. The findings
also showed that small enterprises faced more severe problems than
those of medium enterprises.
Abstract: Highly stable and homogeneously dispersed amino
acid coated silver nanoparticles (ANP) of ≈ 10 nm diameter, ranging
from 420 to 430 nm are prepared on AgNO3 solution addition to gum
of Azadirachta indica solution at 373.15 K. The amino acids were
selected based on their polarity. The synthesized nanoparticles were
characterized by UV-Vis, FTIR spectroscopy, HR-TEM, XRD, SEM
and 1H-NMR. The coated nanoparticles were used as catalyst for the
reduction of methylene blue dye in presence of Sn(II) in aqueous,
anionic and cationic micellar media. The rate of reduction of dye was
determined by measuring the absorbance at 660 nm,
spectrophotometrically and followed the order: Kcationic > Kanionic >
Kwater. After 12 min and in absence of the ANP, only 2%, 3% and 6%
of the dye reduction was completed in aqueous, anionic and cationic
micellar media respectively while, in presence of ANP coated by
polar neutral amino acid with non-polar -R group, the reduction
completed to 84%, 95% and 98% respectively. The ANP coated with
polar neutral amino acid having non-polar -R group, increased the
rate of reduction of the dye by 94, 3205 and 6370 folds in aqueous,
anionic and cationic micellar media respectively. Also, the rate of
reduction of the dye increased by three folds when the micellar media
was changed from anionic to cationic when the ANP is coated by a
polar neutral amino acid having a non-polar -R group.
Abstract: Carbon dioxide is one of the major greenhouse gas
(GHG) contributors. It is an obligation of the industry to reduce the
amount of carbon dioxide emission to the acceptable limits.
Tremendous research and studies are reported in the past and still the
quest to find the suitable and economical solution of this problem
needed to be explored in order to develop the most plausible absorber
for carbon dioxide removal. Amino acids can be potential alternate
solvents for carbon dioxide capture from gaseous streams. This is due
to its ability to resist oxidative degradation, low volatility and its
ionic structure. In addition, the introduction of promoter-like
piperazine to amino acid helps to further enhance the solubility. In
this work, the effect of piperazine on thermo physical properties and
solubility of β-Alanine aqueous solutions were studied for various
concentrations. The measured physicochemical properties data was
correlated as a function of temperature using least-squares method
and the correlation parameters are reported together with it respective
standard deviations. The effect of activator piperazine on the CO2
loading performance of selected amino acid under high-pressure
conditions (1bar to 10bar) at temperature range of (30 to 60)oC was
also studied. Solubility of CO2 decreases with increasing temperature
and increases with increasing pressure. Quadratic representation of
solubility using Response Surface Methodology (RSM) shows that
the most important parameter to optimize solubility is system
pressure. The addition of promoter increases the solubility effect of
the solvent.
Abstract: This study investigated the effects of thermal
treatment on Tualang honey sample in terms of honey colour and
heat-induced small metabolites. The heating process was carried out
in a temperature controlled water batch at 90oC for 4 hours. The
honey samples were put in cylinder tubes with the dimension of 1 cm
diameter and 10 cm length for homogenous heat transfer. The results
found that the thermal treatment produced not only
hydroxylmethylfurfural, but also other harmful substances such as
phthalic anhydride and radiolytic byproducts. The degradation of
honey protein was due to the detection of free amino acids such as
cysteine and phenylalanine in heat-treated honey samples. Sugar
dehydration was also occurred because fragmented di-galactose was
identified based on the presence of characteristic ions in the mass
fragmentation pattern. The honey colour was found getting darker as
the heating duration was increased up to 4 hours. Approximately, 60
mm PFund of increment was noticed for the honey colour with the
colour change rate of 14.8 mm PFund per hour. Based on the
principal component analysis, the score plot clearly shows that the
chemical profile of Tualang honey was significantly altered after 2
hours of heating at 90oC.
Abstract: This paper presents numerical analysis in terms of
buckling resistance of GFRP sandwich infill panels system under the
influence of increased temperature on the foam core. Failure mode
under in-plane compression is studied by means of numerical analysis
with ABAQUS platform. Parameters considered in this study are
contact length and both the type of foam for core and the variation of
its module elastic under the thermal influence. Increment of
temperature is considered in static cases and only applied to core.
Indeed, it is proven that the effect of temperature alters the mechanical
properties of the entire panel system. Moreover, the rises of
temperature result in a decrease in strength of the panel. This is due to
the polymeric nature of this material. Additionally, the contact length
also displays the effect on performance of infill panel. Their
significance factors are based on type of polymer for core. Therefore,
by comparing difference type of core material, the variation can be
reducing.
Abstract: Inspired by the Formula-1 competition, IMechE
(Institute of Mechanical Engineers) and Formula SAE (Society of
Mechanical Engineers) organize annual competitions for University
and College students worldwide to compete with a single-seat racecar
they have designed and built. Design of the chassis or the frame is a
key component of the competition because the weight and stiffness
properties are directly related with the performance of the car and the
safety of the driver. In addition, a reduced weight of the chassis has
direct influence on the design of other components in the car. Among
others, it improves the power to weight ratio and the aerodynamic
performance. As the power output of the engine or the battery
installed in the car is limited to 80 kW, increasing the power to
weight ratio demands reduction of the weight of the chassis, which
represents the major part of the weight of the car. In order to reduce
the weight of the car, ION Racing team from University of
Stavanger, Norway, opted for a monocoque design. To ensure
fulfilment of the competition requirements of the chassis, the
monocoque design should provide sufficient torsional stiffness and
absorb the impact energy in case of possible collision. The study reported in this article is based on the requirements for
Formula Student competition. As part of this study, diverse
mechanical tests were conducted to determine the mechanical
properties and performances of the monocoque design. Upon a
comprehensive theoretical study of the mechanical properties of
sandwich composite materials and the requirements of monocoque
design in the competition rules, diverse tests were conducted
including 3-point bending test, perimeter shear test and test for
absorbed energy. The test panels were homemade and prepared with
equivalent size of the side impact zone of the monocoque, i.e. 275
mm x 500 mm, so that the obtained results from the tests can be
representative. Different layups of the test panels with identical core
material and the same number of layers of carbon fibre were tested
and compared. Influence of the core material thickness was also
studied. Furthermore, analytical calculations and numerical analysis
were conducted to check compliance to the stated rules for Structural
Equivalency with steel grade SAE/AISI 1010. The test results were
also compared with calculated results with respect to bending and
torsional stiffness, energy absorption, buckling, etc. The obtained results demonstrate that the material composition
and strength of the composite material selected for the monocoque
design has equivalent structural properties as a welded frame and thus
comply with the competition requirements. The developed analytical
calculation algorithms and relations will be useful for future
monocoque designs with different lay-ups and compositions.
Abstract: Rivers have transient storage or dead zones where
injected pollutants or solutes are entrapped for considerable period of
time, known as residence time, before being released into the main
flowing zones of rivers. In this study, a new empirical expression for
residence time, implementing genetic programming on published
dispersion data, has been derived. The proposed expression uses few
hydraulic and geometric characteristics of rivers which are normally
known to the authorities. When compared with some reported
expressions, based on various statistical indices, it can be concluded
that the proposed expression predicts the residence time of pollutants
in natural rivers more accurately.
Abstract: This paper aimed to introduce the solution of concrete
slump recovery using chemical admixture type-F (superplasticizer,
naphthalene base) to the practice in order to solve unusable concrete
problem due to concrete loss its slump, especially for those tropical
countries that have faster slump loss rate. In the other hand, randomly
adding superplasticizer into concrete can cause concrete to segregate.
Therefore, this paper also develops the estimation model used to
calculate amount of second dose of superplasticizer need for concrete
slump recovery. Fresh properties of ordinary Portland cement
concrete with volumetric ratio of paste to void between aggregate
(paste content) of 1.1-1.3 with water-cement ratio zone of 0.30 to
0.67 and initial superplasticizer (naphthalene base) of 0.25%-1.6%
were tested for initial slump and slump loss for every 30 minutes for
one and half hour by slump cone test. Those concretes with slump
loss range from 10% to 90% were re-dosed and successfully
recovered back to its initial slump. Slump after re-dosed was tested
by slump cone test. From the result, it has been concluded that, slump
loss was slower for those mix with high initial dose of
superplasticizer due to addition of superplasticizer will disturb
cement hydration. The required second dose of superplasticizer was
affected by two major parameters, which were water-cement ratio
and paste content, where lower water-cement ratio and paste content
cause an increase in require second dose of superplasticizer. The
amount of second dose of superplasticizer is higher as the solid
content within the system is increase, solid can be either from cement
particles or aggregate. The data was analyzed to form an equation use
to estimate the amount of second dosage requirement of
superplasticizer to recovery slump to its original.
Abstract: Microcantilevers are the basic MEMS devices, which
can be used as sensors, actuators and electronics can be easily built
into them. The detection principle of microcantilever sensors is based
on the measurement of change in cantilever deflection or change in its
resonance frequency. The objective of this work is to explore the
analogies between mechanical and electrical equivalent of
microcantilever beams. Normally scientists and engineers working in
MEMS use expensive software like CoventorWare, IntelliSuite,
ANSYS/Multiphysics etc. This paper indicates the need of developing
electrical equivalent of the MEMS structure and with that, one can
have a better insight on important parameters, and their interrelation of
the MEMS structure. In this work, considering the mechanical model
of microcantilever, equivalent electrical circuit is drawn and using
force-voltage analogy, it is analyzed with circuit simulation software.
By doing so, one can gain access to powerful set of intellectual tools
that have been developed for understanding electrical circuits Later
the analysis is performed using ANSYS/Multiphysics - software based
on finite element method (FEM). It is observed that both mechanical
and electrical domain results for a rectangular microcantlevers are in
agreement with each other.
Abstract: Both steady and unsteady turbulent mixed convection
heat transfer in a 3D lid-driven enclosure, which has constant heat
flux on the middle of bottom wall and with isothermal moving
sidewalls, is reported in this paper for working fluid with Prandtl
number Pr = 0.71. The other walls are adiabatic and stationary. The
dimensionless parameters used in this research are Reynolds number,
Re = 5000, 10000 and 15000, and Richardson number, Ri = 1 and 10.
The simulations have been done by using different turbulent methods
such as RANS, URANS, and LES. The effects of using different k-ε
models such as standard, RNG and Realizable k-ε model are
investigated. Interesting behaviours of the thermal and flow fields
with changing the Re or Ri numbers are observed. Isotherm and
turbulent kinetic energy distributions and variation of local Nusselt
number at the hot bottom wall are studied as well. The local Nusselt
number is found increasing with increasing either Re or Ri number.
In addition, the turbulent kinetic energy is discernibly affected by
increasing Re number. Moreover, the LES results have shown good
ability of this method in predicting more detailed flow structures in
the cavity.