Abstract: Transesterified vegetable oils (biodiesel) are promising alternative fuel for diesel engines. Used vegetable oils are disposed from restaurants in large quantities. But higher viscosity restricts their direct use in diesel engines. In this study, used cooking oil was dehydrated and then transesterified using an alkaline catalyst. The combustion, performance and emission characteristics of Used Cooking oil Methyl Ester (UCME) and its blends with diesel oil are analysed in a direct injection C.I. engine. The fuel properties and the combustion characteristics of UCME are found to be similar to those of diesel. A minor decrease in thermal efficiency with significant improvement in reduction of particulates, carbon monoxide and unburnt hydrocarbons is observed compared to diesel. The use of transesterified used cooking oil and its blends as fuel for diesel engines will reduce dependence on fossil fuels and also decrease considerably the environmental pollution.
Abstract: A good green building design project, designers should consider not only energy consumption, but also healthy and comfortable needs of inhabitants. In recent years, the Taiwan government paid attentions on both carbon reduction and indoor air quality issues, which be presented in the legislation of Building Codes and other regulations. Taiwan located in hot and humid climates, dampness in buildings leads to significant microbial pollution and building damage. This means that the high temperature and humidity present a serious indoor air quality issue. The interactions between vapor transfers and energy fluxes are essential for the whole building Heat Air and Moisture (HAM) response. However, a simulation tool with short calculation time, property accuracy and interface is needed for practical building design processes. In this research, we consider the vapor transfer phenomenon of building materials as well as temperature and humidity and energy consumption in a building space. The simulation bases on the EMPD method, which was performed by EnergyPlus, a simulation tool developed by DOE, to simulate the indoor moisture variation in a one-zone residential unit based on the Effective Moisture Penetration Depth Method, which is more suitable for practical building design processes.
Abstract: This paper aims at overviewing the topics of a research project (CARDIOSENSOR) on the field of health sciences (biomaterials and biomedical engineering). The project has focused on the development of a nanosensor for the assessment of the risk of cardiovascular diseases by the monitoring of C-reactive protein (CRP), which has been currently considered as the best validated inflammatory biomarker associated to cardiovascular diseases. The project involves tasks such as: 1) the development of sensor devices based on field effect transistors (FET): assembly, optimization and validation; 2) application of sensors to the detection of CRP in standard solutions and comparison with enzyme-linked immunosorbent assay (ELISA); and 3) application of sensors to real samples such as blood and saliva and evaluation of their ability to predict the risk of cardiovascular disease.
Abstract: We report the size dependence of 1D superconductivity in ultrathin (10-130 nm) nanowires produced by coating suspended carbon nanotubes with a superconducting NbN thin film. The resistance-temperature characteristic curves for samples with ≧25 nm wire width show the superconducting transition. On the other hand, for the samples with 10-nm width, the superconducting transition is not exhibited owing to the quantum size effect. The differential resistance vs. current density characteristic curves show some peak, indicating that Josephson junctions are formed in nanowires. The presence of the Josephson junctions is well explained by the measurement of the magnetic field dependence of the critical current. These understanding allow for the further expansion of the potential application of NbN, which is utilized for single photon detectors and so on.
Abstract: Carbon nanotubes (CNTs) possess unique structural,
mechanical, thermal and electronic properties, and have been
proposed to be used for applications in many fields. However, to
reach the full potential of the CNTs, many problems still need to be
solved, including the development of an easy and effective
purification procedure, since synthesized CNTs contain impurities,
such as amorphous carbon, carbon nanoparticles and metal particles.
Different purification methods yield different CNT characteristics
and may be suitable for the production of different types of CNTs. In
this study, the effect of different purification chemicals on carbon
nanotube quality was investigated. CNTs were firstly synthesized by
chemical vapor deposition (CVD) of acetylene (C2H2) on a
magnesium oxide (MgO) powder impregnated with an iron nitrate
(Fe(NO3)3·9H2O) solution. The synthesis parameters were selected
as: the synthesis temperature of 800°C, the iron content in the
precursor of 5% and the synthesis time of 30 min. The liquid phase
oxidation method was applied for the purification of the synthesized
CNT materials. Three different acid chemicals (HNO3, H2SO4, and
HCl) were used in the removal of the metal catalysts from the
synthesized CNT material to investigate the possible effects of each
acid solution to the purification step. Purification experiments were
carried out at two different temperatures (75 and 120 °C), two
different acid concentrations (3 and 6 M) and for three different time
intervals (6, 8 and 15 h). A 30% H2O2 : 3M HCl (1:1 v%) solution
was also used in the purification step to remove both the metal
catalysts and the amorphous carbon. The purifications using this
solution were performed at the temperature of 75°C for 8 hours.
Purification efficiencies at different conditions were evaluated by
thermogravimetric analysis. Thermal and electrical properties of
CNTs were also determined. It was found that the obtained electrical
conductivity values for the carbon nanotubes were typical for organic
semiconductor materials and thermal stabilities were changed
depending on the purification chemicals.
Abstract: This paper focuses on the experimental impacts of
ultrasonic, carbonate and a combination of them on the quality of
fresh kiwi juice. Today, non-thermal methods like ultrasonic, which
have imperceptible effects on some properties of the juice such as
taste, flavor and color, are commonly used for killing
microorganisms.In this paper, some properties of kiwi fruit juice
under ultrasonic, carbonate and a combination of them has been
researched. Those properties include pH, acidity, transparency and
Brix. Its impact on microorganisms has been studied as well.The
results show that using a combination of carbonate and sonicate make
the cavitation more severe without a perceptible effect on nonactivation
of microorganisms.
Abstract: This research studied recycled wastes by Recyclable Material Bank project of 17 universities of Thailand for evaluation of reducing greenhouse gasses emission compared with landfilling activity during January 2011 to December 2011. The results showed that the projects collected total amount of recyclable wastes about 1,626.917 metric ton. The office paper has the largest amount among these recycled wastes (55.61 % of total recycled wastes). Groups of recycled waste can be prioritized from high to low according to their amount as paper, plastic, glass, mixed recyclables and metal, respectively. The project reduced greenhouse gasses emission equivalent to about 5,263.481 metric ton of carbon dioxide. The most significant recycled waste that affects the reduction of greenhouse gasses emission is office paper which is 73.45% of total reduced greenhouse gasses emission. According to amount of reduced greenhouse gasses emission, groups of recycled waste can be prioritized from high to low significances as paper, plastic, metal, mixed recyclables and glass, respectively.
Abstract: The paper provides biomasses characteristics by
proximate analysis (volatile matter, fixed carbon and ash) and
ultimate analysis (carbon, hydrogen, nitrogen and oxygen) for the
prediction of the heating value equations. The heating value
estimation of various biomasses can be used as an energy evaluation.
Thirteen types of biomass were studied. Proximate analysis was
investigated by mass loss method and infrared moisture analyzer.
Ultimate analysis was analyzed by CHNO analyzer. The heating
values varied from 15 to 22.4MJ kg-1. Correlations of the calculated
heating value with proximate and ultimate analyses were undertaken
using multiple regression analysis and summarized into three and two
equations, respectively. Correlations based on proximate analysis
illustrated that deviation of calculated heating values from
experimental heating values was higher than the correlations based
on ultimate analysis.
Abstract: This study shows the effect of carbon towards
molybdenum carbide alloy when exposed to Microwave. This
technique is also known as Microwave Induced Alloying (MIA) for
the preparation of molybdenum carbide. In this study ammonium
heptamolybdate solution and carbon black powder were
heterogeneously mixed and exposed to microwave irradiation for 2
minutes. The effect on amount of carbon towards the produced alloy
on morphological and oxidation states changes during microwave is
presented. In this experiment, it is expected carbon act as a reducing
agent with the ratio 2:7 molybdenum to carbon as the optimum for
the production of molybdenum carbide alloy. All the morphological
transformations and changes in this experiment were followed and
characterized using X-Ray Diffraction and FESEM.
Abstract: A group of Stellite alloys are studied in consideration
of temperature effects on their hardness and wear resistance. The
hardness test is conducted on a micro-hardness tester with a hot stage
equipped that allows heating the specimen up to 650°C. The wear
resistance of each alloy is evaluated using a pin-on-disc tribometer
with a heating furnace built-in that provides the temperature capacity
up to 450°C. The experimental results demonstrate that the hardness
and wear resistance of Stellite alloys behave differently at room
temperature and at high temperatures. The wear resistance of Stellite
alloys at room temperature mainly depends on their carbon content and
also influenced by the tungsten content in the alloys. However, at high
temperatures the wear mechanisms of Stellite alloys become more
complex, involving multiple factors. The relationships between
chemical composition, microstructure, hardness and wear resistance of
these alloys are studied, with focus on temperature effect on these
relations.
Abstract: This study investigates the capacity of granular
activated carbon (GAC) for the storage of methane through the
equilibrium adsorption. An experimental apparatus consist of a dual
adsorption vessel was set up for the measurement of equilibrium
adsorption of methane on GAC using volumetric technique (pressure
decay). Experimental isotherms of methane adsorption were
determined by the measurement of equilibrium uptake of methane in
different pressures (0-50 bar) and temperatures (285.15-328.15°K).
The experimental data was fitted to Freundlich and Langmuir
equations to determine the model isotherm. The results show that the
experimental data is equally well fitted by the both model isotherms.
Using the experimental data obtained in different temperatures the
isosteric heat of methane adsorption was also calculated by the
Clausius-Clapeyron equation from the Sips isotherm model. Results
of isosteric heat of adsorption show that decreasing temperature or
increasing methane uptake by GAC decrease the isosteric heat of
methane adsorption.
Abstract: Increasing concerns over climate change have limited
the liberal usage of available energy technology options. India faces
a formidable challenge to meet its energy needs and provide adequate
energy of desired quality in various forms to users in sustainable
manner at reasonable costs. In this paper, work carried out with an
objective to study the role of various energy technology options
under different scenarios namely base line scenario, high nuclear
scenario, high renewable scenario, low growth and high growth rate
scenario. The study has been carried out using Model for Energy
Supply Strategy Alternatives and their General Environmental
Impacts (MESSAGE) model which evaluates the alternative energy
supply strategies with user defined constraints on fuel availability,
environmental regulations etc. The projected electricity demand, at
the end of study period i.e. 2035 is 500490 MWYr. The model
predicted the share of the demand by Thermal: 428170 MWYr,
Hydro: 40320 MWYr, Nuclear: 14000 MWYr, Wind: 18000 MWYr
in the base line scenario. Coal remains the dominant fuel for
production of electricity during the study period. However, the
import dependency of coal increased during the study period. In
baseline scenario the cumulative carbon dioxide emissions upto 2035
are about 11,000 million tones of CO2. In the scenario of high nuclear
capacity the carbon dioxide emissions reduced by 10 % when nuclear
energy share increased to 9 % compared to 3 % in baseline scenario.
Similarly aggressive use of renewables reduces 4 % of carbon
dioxide emissions.
Abstract: In this study, we report the synthesis and
characterization of nanohydroxyapatite (nHAp) in gelatin-starch
matrix via biomimetic method. Characterization of the samples was
performed using X-ray diffraction (XRD) and Fourier Transform
infrared spectroscopy (FT-IR). The Size and morphology of the
nHAp samples were determined using scanning and transmission
electron microscopy (SEM and TEM). The results reveal that the
shape and morphology of nHAp is influenced by presence of
biopolymers as template. Carbonyl and amino groups from gelatin
and hydroxyl from starch play crucial roles in HAp formation on the
surface of gelatin-starch.
Abstract: There are few studies on eggshell of leatherback turtle
which is endangered species in Thailand. This study was focusing on
the ultrastructure and elemental composition of leatherback turtle
eggshells collected from Andaman Sea Shore, Thailand during the
nesting season using scanning electron microscope (SEM). Three
eggshell layers of leatherback turtle; the outer cuticle layer or
calcareous layer, the middle layer or middle multistrata layer and the
inner fibrous layer were recognized. The outer calcareous layer was
thick and porosity which consisted of loose nodular units of various
crystal shapes and sizes. The loose attachment between these units
resulted in numerous spaces and openings. The middle layer was
compact thick with several multistrata and contained numerous
openings connecting to both outer cuticle layer and inner fibrous
layer. The inner fibrous layer was compact and thin, and composed of
numerous reticular fibers. Energy dispersive X-ray microanalysis
detector revealed energy spectrum of X-rays character emitted from
all elements on each layer. The percentages of all elements were
found in the following order: carbon (C) > oxygen (O) > calcium
(Ca) > sulfur (S) > potassium (K) > aluminum (Al) > iodine (I) >
silicon (Si) > chlorine (Cl) > sodium (Na) > fluorine (F) >
phosphorus (P) > magnesium (Mg). Each layer consisted of high
percentage of CaCO3 (approximately 98%) implying that it was
essential for turtle embryonic development. A significant difference
was found in the percentages of Ca and Mo in the 3layers. Moreover,
transition metal, metal and toxic non-metal contaminations were
found in leatherback turtle eggshell samples. These were palladium
(Pd), molybdenum (Mo), copper (Cu), aluminum (Al), lead (Pb), and
bromine (Br). The contamination elements were seen in the outer
layers except for Mo. All elements were readily observed and
mapped using Smiling program. X-ray images which mapped the
location of all elements were showed. Calcium containing in the
eggshell appeared in high contents and was widely distributing in
clusters of the outer cuticle layer to form CaCO3 structure. Moreover,
the accumulation of Na and Cl was observed to form NaCl which was
widely distributing in 3 eggshell layers. The results from this study
would be valuable on assessing the emergent success in this
endangered species.
Abstract: In the competitive environment of aircraft industries it becomes absolutely necessary to improve the efficiency, performance of the aircrafts to reduce the development and operating costs considerably, in order to capitalize the market. An important contribution to improve the efficiency and performance can be
achieved by decreasing the aircraft weight through considerable
usage of composite materials in primary aircraft structures. In this study, a type of composite material called Carbon Fiber Reinforced
Plastic (CFRP) is explored for the usage is aircraft skin panels. Even
though there were plenty of studies and research has been already
carried out, here a practical example of an aircraft skin panel is taken
and substantiated the benefits of composites material usage over the
metallic skin panel. A crown skin panel of a commercial aircraft is
designed using both metal and composite materials. Stress analysis
has been carried out for both and margin of safety is estimated for the
critical load cases. The skin panels are compared for manufacturing,
tooling, assembly and cost parameters. Detail step by step comparison between metal and composite constructions are studied
and results are tabulated for better understanding.
Abstract: To date, theoretical studies concerning the Carbon
Fiber Reinforced Polymer (CFRP) strengthening of RC beams with
openings have been rather limited. In addition, various numerical
analyses presented so far have effectively simulated the behaviour of
solid beam strengthened by FRP material. In this paper, a two
dimensional nonlinear finite element analysis is presented to validate
against the laboratory test results of six RC beams. All beams had the
same rectangular cross-section geometry and were loaded under four
point bending. The crack pattern results of the finite element model
show good agreement with the crack pattern of the experimental
beams. The load midspan deflection curves of the finite element
models exhibited a stiffer result compared to the experimental beams.
The possible reason may be due to the perfect bond assumption used
between the concrete and steel reinforcement.
Abstract: The nanofiber sheet of Multiwall Cabon Nanotube
(MWCNTs)/Polyacylonitile (PAN) composites was fabricated from
electrospun nanofiber. Firstly the surface of MWCNTs was
chemically modified, comparing two different techniques consisting
of admicellar polymerization and functionalization to improve the
dispersion and prevent the aggregation in the PAN matrix. The
modified MWCNTs were characterized by the dispersion in
dimethylformamide (DMF) solvent, Laser particle size, and FTRaman.
Lastly, DSC, SEM and mechanical properties of the
nanofiber sheet were examined. The results show that the mechanical
properties of the nanofiber sheet prepared from admicellar
polymerization-modified MWCNTs were higher than those of the
others.
Abstract: Coal fly ash (CFA) generated by coal-based thermal
power plants is mainly composed of quartz, mullite, and unburned
carbon. In this study, the effect of unburned carbon on CFA toward
its adsorption capacity was investigated. CFA with various carbon
content was obtained by refluxing it with sulfuric acid having various
concentration at various temperature and reflux time, by heating at
400-800°C, and by sieving into 100-mesh in particle size. To
evaluate the effect of unburned carbon on CFA toward its adsorption
capacity, adsorption of methyl violet solution with treated CFA was
carried out. The research shows that unburned carbon leads to
adsorption capacity decrease. The highest adsorption capacity of
treated CFA was found 5.73 x 10-4mol.g-1.
Abstract: Fats and oils are made of esterified hydrocarbons
(RCOOR-) and this work demonstrates the substitution of R by
multi-walled CNTs (MWNTs). The resultant materials are fluidic, oily,
electrically conducting and excellent lubricants. Esterified MWNTs
can also respond to magnetic field when tubules contain long segments
of Fe
Abstract: Work is focused to the study of unburned carbon in
ash from coal (and wastes) combustion in 8 combustion tests at 3
fluidised-bed power station, at co-combustion of coal and wastes
(also at fluidized bed) and at bench-scale unit simulating coal
combustion in small domestic furnaces. The attention is paid to
unburned carbon contents in bottom ashes and fly ashes at these 8
combustion tests and to morphology of unburned carbons. Specific
surface area of coals, unburned carbons and ashes and the relation of
specific surface area of unburned carbon and the content of volatile
combustibles in coal were studied as well.