Abstract: The plastic forming process of sheet plate takes an
important place in forming metals. The traditional techniques of tool
design for sheet forming operations used in industry are experimental
and expensive methods. Prediction of the forming results,
determination of the punching force, blank holder forces and the
thickness distribution of the sheet metal will decrease the production
cost and time of the material to be formed. In this paper, multi-stage
deep drawing simulation of an Industrial Part has been presented
with finite element method. The entire production steps with
additional operations such as intermediate annealing and springback
has been simulated by ABAQUS software under axisymmetric
conditions. The simulation results such as sheet thickness
distribution, Punch force and residual stresses have been extracted in
any stages and sheet thickness distribution was compared with
experimental results. It was found through comparison of results, the
FE model have proven to be in close agreement with those of
experiment.
Abstract: Cu-mesoporous TiO2 is developed for removal acid
odor cooperated with ozone assistance and online- regeneration
system with/without UV irradiation (all weather) in study. The results
showed that Cu-mesoporous TiO2 present the desirable adsorption
efficiency of acid odor without UV irradiation, due to the larger
surface area, pore sizeand the additional absorption ability provided by
Cu. In the photocatalysis process, the material structure also benefits
Cu-mesoporous TiO2 to perform the more outstanding efficiency on
degrading acid odor. Cu also postponed the recombination of
electron-hole pairs excited from TiO2 to enhance photodegradation
ability. Cu-mesoporous TiO2 could gain the conspicuous increase on
photocatalysis ability from ozone assistance, but without any benefit
on adsorption. In addition, the online regeneration procedure could
process the used Cu-mesoporous TiO2 to reinstate the adsorption
ability and maintain the photodegradtion performance, depended on
scrubbing, desorping acid odor and reducing Cu to metal state.
Abstract: Extraction of laccase produced by L. polychrous in an
aqueous two-phase system, composed of polyethylene glycol and
phosphate salt at pH 7.0 and 250C was investigated. The effect of
PEG molecular weight, PEG concentration and phosphate
concentration was determined. Laccase preferentially partitioned to
the top phase. Good extraction of laccase to the top phase was
observed with PEG 4000. The optimum system was found in the
system containing 12% w/w PEG 4000 and 16% w/w phosphate salt
with KE of 88.3, purification factor of 3.0-fold and 99.1% yield.
Some properties of the enzyme such as thermal stability, effect of
heavy metal ions and kinetic constants were also presented in this
work. The thermal stability decreased sharply with high temperature
above 60 0C. The enzyme was inhibited by Cd2+, Pb2+, Zn2+ and
Cu2+. The Vmax and Km values of the enzyme were 74.70
μmol/min/ml and 9.066 mM respectively.
Abstract: Municipal solid waste (MSW) comprises of a wide
range of heterogeneous materials generated by individual, household
or organization and may include food waste, garden wastes, papers,
textiles, rubbers, plastics, glass, ceramics, metals, wood wastes,
construction wastes but it is not limited to the above mentioned
fractions. The most common Municipal Solid Waste pretreatment
method in use is thermal pretreatment (incineration) and Mechanical
Biological pretreatment. This paper presents an overview of these
two pretreatment methods describing their benefits and laboratory
scale reactors that simulate landfill conditions were constructed in
order to compare emissions in terms of biogas production and
leachate contamination between untreated Municipal Solid Waste and
Mechanical Biological Pretreated waste. The findings of this study
showed that Mechanical Biological pretreatment of waste reduces the
emission level of waste and the benefit over the landfilling of
untreated waste is significant.
Abstract: Tomato powder has good potential as substitute of tomato paste and other tomato products. In order to protect physicochemical properties and nutritional quality of tomato during dehydration process, investigation was carried out using different drying methods and pretreatments. Solar drier and continuous conveyor (tunnel) drier were used for dehydration where as calcium chloride (CaCl2), potassium metabisulphite (KMS), calcium chloride and potassium metabisulphite (CaCl2 +KMS), and sodium chloride (NaCl) selected for treatment.. lycopene content, dehydration ratio, rehydration ratio and non-enzymatic browning in addition to moisture, sugar and titrable acidity were studied. Results show that pre-treatment with CaCl2 and NaCl increased water removal and moisture mobility in tomato slices during drying of tomatoes. Where CaCl2 used along with KMS the NEB was recorded the least compared to other treatments and the best results were obtained while using the two chemicals in combination form. Storage studies in LDPE polymeric and metalized polyesters films showed less changes in the products packed in metallized polyester pouches and even after 6 months lycopene content did not decrease more than 20% as compared to the control sample and provide extension of shelf life in acceptable condition for 6 months. In most of the quality characteristics tunnel drier samples presented better values in comparison to solar drier.
Abstract: The contact width is important design parameter for
optimizing the design of new metal gasket for asbestos substitution
gasket. The contact width is found have relationship with the helium
leak quantity. In the increasing of axial load value, the helium leak
quantity is decreasing and the contact width is increasing. This study
provides validity method using simulation analysis and the result is
compared to experimental using pressure sensitive paper. The results
denote similar trend data between simulation and experimental result.
Final evaluation is determined by helium leak quantity to check
leakage performance of gasket design. Considering the phenomena of
position change on the convex contact, it can be developed the
optimization of gasket design by increasing contact width.
Abstract: The electrochemical coagulation of a kaolin
suspension was investigated at the currents of 0.06, 0.12, 0.22, 0.44,
0.85 A (corresponding to 0.68, 1.36, 2.50, 5.00, 9.66 mA·cm-2,
respectively) for the contact time of 5, 10, 20, 30, and 50 min. The
TSS removal efficiency at currents of 0.06 A, 0.12 A and 0.22 A
increased with the amount of iron generated by the sacrificial anode,
while the removal efficiencies did not increase proportionally with
the amount of iron generated at the currents of 0.44 and 0.85 A,
where electroflotation was clearly observed. Zeta potential
measurement illustrated the presence of the highly positive charged
particles created by sorption of highly charged polymeric metal
hydroxyl species onto the negative surface charged kaolin particles at
both low and high applied currents. The disappearance of the
individual peaks after certain contact times indicated the attraction
between these positive and negative charged particles causing
agglomeration. It was concluded that charge neutralization of the
individual species was not the only mechanism operating in the
electrocoagulation process at any current level, but electrostatic
attraction was likely to co-operate or mainly operate.
Abstract: Arc welding is an important joining process widely used in many industrial applications including production of automobile, ships structures and metal tanks. In welding process, the moving electrode causes highly non-uniform temperature distribution that leads to residual stresses and different deviations, especially buckling distortions in thin plates. In order to control the deviations and increase the quality of welded plates, a fixture can be used as a practical and low cost method with high efficiency. In this study, a coupled thermo-mechanical finite element model is coded in the software ANSYS to simulate the behavior of thin plates located by a 3-2-1 positioning system during the welding process. Computational results are compared with recent similar works to validate the finite element models. The agreement between the result of proposed model and other reported data proves that finite element modeling can accurately predict the behavior of welded thin plates.
Abstract: This research studied recycled waste by the Recyclable Material Bank Project of 4 universities in the central region of Thailand for the evaluation of reducing greenhouse gas emissions compared with landfilling activity during July 2012 to June 2013. The results showed that the projects collected total amount of recyclable wastes of about 911,984.80 kilograms. Office paper had the largest amount among these recycled wastes (50.68% of total recycled waste). Groups of recycled waste can be prioritized from high to low according to their amount as paper, plastic, glass, mixed recyclables, and metal, respectively. The project reduced greenhouse gas emissions equivalent to about 2814.969 metric tons of carbon dioxide. The most significant recycled waste that affects the reduction of greenhouse gas emissions is office paper which is 70.16% of total reduced greenhouse gasses emission. According to amount of reduced greenhouse gasses emission, groups of recycled waste can be prioritized from high to low significances as paper, plastic, metals, mixed recyclables, and glass, respectively.
Abstract: The aim of this paper is to compare the effectiveness and electrochemical behavior of typical oilfield corrosion inhibitors with previous oilfield corrosion inhibitors under the same electrochemical techniques to control preferential weld corrosion of X65 pipeline steel in artificial seawater saturated with carbon dioxide at a pressure of one bar. A secondary aim is to investigate the conditions under which current reversal takes place. A flow channel apparatus was used in the laboratory to simulate the actual condition that occurs in marine pipelines. Different samples from the parent metal, the weld metal and the heat affected zone in the pipeline steel were galvanically coupled. The galvanic currents flowing between the weld regions were recorded using zero-resistance ammeters and tested under static and flowing conditions in both inhibited and uninhibited media. The results show that a current reversal took place when 30ppm of both green oilfield inhibitors were present, resulting in accelerated weld corrosion.
Abstract: The supported Pd catalysts were analyzed by X-ray
diffraction and X-ray absorption spectroscopy in order to determine
their global and local structure. The average particle size of the
supported Pd catalysts was determined by X-ray diffraction method.
One of the main purposes of the present contribution is to focus on
understanding the specific role of the Pd particle size determined by
X-ray diffraction and that of the support oxide. Based on X-ray
absorption fine structure spectroscopy analysis we consider that the
whole local structure of the investigated samples are distorted
concerning the atomic number but the distances between atoms are
almost the same as for standard Pd sample. Due to the strong
modifications of the Pd cluster local structure, the metal-support
interface may influence the electronic properties of metal clusters
and thus their reactivity for absorption of the reactant molecules.
Abstract: This study investigated the removal efficiency of electrokinetic remediation of copper-contaminated soil at different combinations of enhancement reagents used as anolyte and catholyte. Sodium hydroxide (at 0.1, 0.5, and 1.0 M concentrations) and distilled water were used as anolyte, while lactic acid (at 0.01, 0.1, and 0.5 M concentrations), ammonium citrate (also at 0.01, 0.1, and 0.5 M concentrations) and distilled water were used as catholyte. A continuous voltage application (1.0 VDC/cm) was employed for 240 hours for each experiment. The copper content of the catholyte was determined at the end of the 240-hour period. Optimization was carried out with a Response Surface Methodology - Optimal Design, including F test, and multiple comparison method, to determine which pair of anolyte-catholyte was the most significant for the removal efficiency. "1.0 M NaOH" was found to be the most significant anolyte while it was established that lactic acid was the most significant type of catholyte to be used for the most successful electrokinetic experiments. Concentrations of lactic acid should be at the range of 0.1 M to 0.5 M to achieve maximum percent removal values.
Abstract: Due to the low heavy metal concentrations, the
bottom ash from a 32 MW municipal district heating plant was
determined to be a potential forest fertilizer as such. However,
additional Ca would be needed, because its Ca concentration of 1.9-
% (d.w.) was lower than the statutory Finnish minimum limit value
of 6.0-% (d.w.) for Ca in forest fertilizer. Due to the elevated As
concentration (53.0 mg/kg; d.w.) in the fly ash from the 32 MW
municipal district heating plant, and Cr concentration (620 mg/kg;
d.w.) in the ash fraction (i.e. mixture of the bottom ash and fly ash)
from the 6 MW municipal district heating plant, which exceed the
limit values of 30 mg/kg (d.w.) and 300 mg/kg (d.w.) for As and Cr,
respectively, these residues are not suitable as forest fertilizers.
Although these ash fractions cannot be used as a forest fertilizer as
such, they can be used for the landscaping of landfills or in industrial
and other areas that are closed to the public. However, an
environmental permit is then needed.
Abstract: Change in impedance of an encircling coil is obtained
in the present paper for the case where the electric conductivity and
magnetic permeability of a metal cylindrical tube depend on the
radial coordinate. The system of equations for the vector potential is
solved by means of the Fourier cosine transform. The solution is
expressed in terms of improper integral containing modified Bessel
functions of complex order.
Abstract: Anodizing is an electrochemical process that converts the metal surface into a decorative, durable, corrosion-resistant, anodic oxide finish. Aluminum is ideally suited to anodizing, although other nonferrous metals, such as magnesium and titanium, also can be anodized. The anodic oxide structure originates from the aluminum substrate and is composed entirely of aluminum oxide. This aluminum oxide is not applied to the surface like paint or plating, but is fully integrated with the underlying aluminum substrate, so cannot chip or peel. It has a highly ordered, porous structure that allows for secondary processes such as coloring and sealing. In this experimental paper, we focus on a reliable method for fabricating nanoporous alumina with high regularity. Starting from study of nanostructure materials synthesize methods. After that, porous alumina fabricate in the laboratory by anodization of aluminum oxide. Hard anodization processes are employed to fabricate the nanoporous alumina using 0.3M oxalic acid and 90, 120 and 140 anodized voltages. The nanoporous templates were characterized by SEM and FFT. The nanoporous templates using 140 voltages have high ordered. The pore formation, influence of the experimental conditions on the pore formation, the structural characteristics of the pore and the oxide chemical reactions involved in the pore growth are discuss.
Abstract: Particulate reinforced metal matrix composites
(MMCs) are potential materials for various applications due to their
advantageous of physical and mechanical properties. This paper
presents a study on the performance of stir cast Al2O3 SiC reinforced
metal matrix composite materials. The results indicate that the
composite materials exhibit improved physical and mechanical
properties, such as, low coefficient of thermal expansion, high
ultimate tensile strength, high impact strength, and hardness. It has
been found that with the increase of weight percentage of
reinforcement particles in the aluminium metal matrix, the new
material exhibits lower wear rate against abrasive wearing. Being
extremely lighter than the conventional gray cast iron material, the
Al-Al2O3 and Al-SiC composites could be potential green materials
for applications in the automobile industry, for instance, in making
car disc brake rotors.
Abstract: In this study, the reduction of Cr(VI) by use of scrap
iron, a cheap and locally available industrial waste, was investigated
in continuous system. The greater scrap iron efficiency observed for
the first two sections of the column filling indicate that most of the
reduction process was carried out in the bottom half of the column
filling. This was ascribed to a constant decrease of Cr(VI)
concentration inside the filling, as the water front passes from the
bottom to the top end of the column. While the bottom section of the
column filling was heavily passivated with secondary mineral phases,
the top section was less affected by the passivation process; therefore
the column filling would likely ensure the reduction of Cr(VI) for
time periods longer than 216 hours. The experimental results indicate
that fixed beds columns packed with scrap iron could be successfully
used for the first step of Cr(VI) polluted wastewater treatment.
However, the mass of scrap iron filling should be carefully estimated
since it significantly affects the Cr(VI) reduction efficiency.
Abstract: Matrix metalloproteinases (MMP) are a class of
structural and functional related enzymes involved in altering the
natural elements of the extracellular matrix. Most of the MMP
structures are cristalographycally determined and published in
WorldWide ProteinDataBank, isolated, in full structure or bound to
natural or synthetic inhibitors. This study proposes an algorithm to
replace missing crystallographic structures in PDB database. We
have compared the results of a chosen docking algorithm with a
known crystallographic structure in order to validate enzyme sites
reconstruction there where crystallographic data are missing.
Abstract: High purity hydrogen and the valuable by-product of carbon nanotubes (CNTs) can be produced by the methane catalytic decomposition. The methane conversion and the performance of CNTs were determined by the choices of catalysts and the condition of decomposition reaction. In this paper, Ni/MgO and Ni/O-D (oxidized diamond) catalysts were prepared by wetness impregnation method. The effects of reaction temperature and space velocity of methane on the methane conversion were investigated in a fixed-bed. The surface area, structure and micrography were characterized with BET, XPS, SEM, EDS technology. The results showed that the conversion of methane was above 8% within 150 min (T=500) for 33Ni/O-D catalyst and higher than 25% within 120 min (T=650) for 41Ni/MgO catalyst. The initial conversion increased with the increasing temperature of the decomposition reaction, but their catalytic activities decreased rapidly while at too higher temperature. To decrease the space velocity of methane was propitious to promote the methane conversion, but not favor of the hydrogen yields. The appearance of carbon resulted from the methane decomposition lied on the support type and the condition of catalytic reaction. It presented as fiber shape on the surface of Ni/O-D at the relatively lower temperature such as 500 and 550, but as grain shape stacked on and overlayed on the surface of the metal nickel while at 650. The carbon fiber can form on the Ni/MgO surface at 650 and the diameter of the carbon fiber increased with the decreasing space velocity.
Abstract: This paper aims to study the methodology of building the knowledge of planning adequate punches in order to complete the task of strip layout for shearing processes, using progressive dies. The proposed methodology uses die design rules and characteristics of different types of punches to classify them into five groups: prior use (the punches must be used first), posterior use (must be used last), compatible use (may be used together), sequential use (certain punches must precede some others) and simultaneous use (must be used together). With these five groups of punches, the searching space of feasible designs will be greatly reduced, and superimposition becomes a more effective method of punch layout. The superimposition scheme will generate many feasible solutions, an evaluation function based on number of stages, moment balancing and strip stability is developed for helping designers to find better solutions.