Abstract: The present study investigates the effectiveness of
newly designed clayey pellets (fired clay pellets diameter sizes of 5
and 8 mm, and unfired clay pellets with the diameter size of 15 mm)
as the beds in the column adsorption process. The adsorption
experiments in the batch mode were performed before the column
experiment with the purpose to determine the order of adsorbent
package in the column which was to be designed in the investigation.
The column experiment was performed by using a known mass of the
clayey beds and the volume of the waste printing developer, which
was purified. The column was filled in the following order: fired clay
pellets of the diameter size of 5 mm, fired clay pellets of the diameter
size of 8 mm, and unfired clay pellets of the diameter size of 15 mm.
The selected order of the adsorbents showed a high removal
efficiency for zinc (97.8%) and copper (81.5%) ions. These
efficiencies were better than those in the case of the already existing
mode adsorption. The obtained experimental data present a good
basis for the selection of an appropriate column fill, but further
testing is necessary in order to obtain more accurate results.
Abstract: In the present study, a numerical approach to describe the pyrolysis of a single solid particle of wood is used to study the influence of various conditions such as particle size, heat transfer coefficient, reactor temperature and heating rate. The influence of these parameters in the change of the duration of the pyrolysis cycle was studied. Mathematical modeling was employed to simulate the heat, mass transfer, and kinetic processes inside the reactor. The evolutions of the mass loss as well as the evolution of temperature inside the thick piece are investigated numerically. The elaborated model was also employed to study the effect of the reactor temperature and the rate of heating on the change of the temperature and the local loss of the mass inside the piece of wood. The obtained results are in good agreement with the experimental data available in the literature.
Abstract: An Energetic and exergetic analysis is conducted on a
Steam Turbine Power Plant of an existing Phosphoric Acid Factory.
The heat recovery systems used in different parts of the plant are also
considered in the analysis. Mass, thermal and exergy balances are
established on the main compounds of the factory. A numerical code
is established using EES software to perform the calculations
required for the thermal and exergy plant analysis. The effects of the
key operating parameters such as steam pressure and temperature,
mass flow rate as well as seawater temperature, on the cycle
performances are investigated. A maximum Exergy Loss Rate of about 72% is obtained for the
melters, followed by the condensers, heat exchangers and the pumps.
The heat exchangers used in the phosphoric acid unit present
exergetic efficiencies around 33% while 60% to 72% are obtained for
steam turbines and blower. For the explored ranges of HP steam
temperature and pressure, the exergy efficiencies of steam turbine
generators STGI and STGII increase of about 2.5% and 5.4%
respectively. In the same way optimum HP steam flow rate values,
leading to the maximum exergy efficiencies are defined.
Abstract: Nanotechnology in pristine sense refers to building of
structures at atomic and molecular scale. Meticulously
nanotechnology encompasses the nanomaterials with at least one
dimension size ranging from 1 to 100 nanometres. Unlike the literal
meaning of its name, nanotechnology is a massive concept beyond
imagination. This paper predominantly deals with relevance of
nanotechnology in automotive industries. New generation of
automotives looks at nanotechnology as an emerging trend of
manufacturing revolution. Intricate shapes can be made out of fairly
inexpensive raw materials instead of conventional fabrication
process. Though the current era have enough technology to face
competition, nanotechnology can give futuristic implications to pick
up the modern pace. Nanotechnology intends to bridge the gap
between automotives with superior technical performance and their
cost fluctuation. Preliminarily, it is an area of great scientific interest
and a major shaper of many new technologies. Nanotechnology can
be an ideal building block for automotive industries, under constant
evolution offering a very wide scope of activity. It possesses huge
potential and is still in the embryonic form of research and
development.
Abstract: Biodiesel is widely investigated to solve the twin
problem of depletion of fossil fuel and environmental degradation.
The main objective of the present work is to compare performance,
emissions, and combustion characteristics of biodiesel derived from
cotton seed oil in a diesel engine with the baseline results of
petrodiesel fuel. Tests have been conducted on a single cylinder, four
stroke CIDI diesel engine with a speed of 1500 rpm and a fixed
compression ratio of 17.5 at different load conditions. The
performance parameters evaluated include brake thermal efficiency,
brake specific fuel consumption, brake power, indicated mean
effective pressure, mechanical efficiency, and exhaust gas
temperature. Regarding combustion study, cylinder pressure, rate of
pressure rise, net heat release rate, cumulative heat release, mean gas
temperature, mass fraction burned, and fuel line pressure were
evaluated. The emission parameters such as carbon monoxide, carbon
dioxide, un-burnt hydrocarbon, oxides of nitrogen, and smoke
opacity were also measured by a smoke meter and an exhaust gas
analyzer and compared with baseline results. The brake thermal
efficiency of cotton seed oil methyl ester (CSOME) was lower than
that of petrodiesel and brake specific fuel consumption was found to
be higher. However, biodiesel resulted in the reduction of carbon
dioxide, un-burnt hydrocarbon, and smoke opacity at the expense of
nitrogen oxides. Carbon monoxide emissions for biodiesel was higher
at maximum output power. It has been found that the combustion
characteristics of cotton seed oil methyl ester closely followed those
of standard petrodiesel. The experimental results suggested that
biodiesel derived from cotton seed oil could be used as a good
substitute to petrodiesel fuel in a conventional diesel without any
modification.
Abstract: The study assessed the effectiveness of Pawpaw
(Carica papaya) wood in reducing the concentrations of heavy
metals in wastewater acting as a bio-sorbent. The following heavy
metals were considered; Zinc, Cadmium, Lead, Copper, Iron,
Selenium, Nickel and Manganese. The physiochemical properties of
Carica papaya stem were studied. The experimental sample was
sourced from the trunk of a felled matured pawpaw tree. Wastewater
for experimental use was prepared by dissolving soil samples
collected from a dump site at Owerri, Imo state of Nigeria in water.
The concentration of each metal remaining in solution as residual
metal after bio-sorption was determined using Atomic absorption
Spectrometer. The effects of pH and initial heavy metal concentration
were studied in a batch reactor. The results of Spectrometer test
showed that there were different functional groups detected in the
Carica papaya stem biomass. There was increase in metal removal as
the pH increased for all the metals considered except for Nickel and
Manganese. Optimum bio-sorption occurred at pH 5.9 with 5g/100ml
solution of bio-sorbent. The results of the study showed that the
treated wastewater is fit for irrigation purpose based on Canada
wastewater quality guideline for the protection of Agricultural
standard. This approach thus provides a cost effective and
environmentally friendly option for treating wastewater.
Abstract: With the advancement of knowledge about the utility
and impact of sustainability, its feasibility has been explored into
different walks of life. Scientists, however; have established their
knowledge in four areas viz environmental, economic, social and
cultural, popularly termed as four pillars of sustainability. Aspects of
environmental and economic sustainability have been rigorously
researched and practiced and huge volume of strong evidence of
effectiveness has been founded for these two sub-areas. For the social
and cultural aspects of sustainability, dependable evidence of
effectiveness is still to be instituted as the researchers and
practitioners are developing and experimenting methods across the
globe. Therefore, the present research aimed to identify globally used
practices of social and cultural sustainability and through evidence
synthesis assess their outcomes to determine the effectiveness of
those practices. A PICO format steered the methodology which
included all populations, popular sustainability practices including
walkability/cycle tracks, social/recreational spaces, privacy, health &
human services and barrier free built environment, comparators
included ‘Before’ and ‘After’, ‘With’ and ‘Without’, ‘More’ and
‘Less’ and outcomes included Social well-being, cultural coexistence,
quality of life, ethics and morality, social capital, sense of
place, education, health, recreation and leisure, and holistic
development. Search of literature included major electronic
databases, search websites, organizational resources, directory of
open access journals and subscribed journals. Grey literature,
however, was not included. Inclusion criteria filtered studies on the
basis of research designs such as total randomization, quasirandomization,
cluster randomization, observational or single studies
and certain types of analysis. Studies with combined outcomes were
considered but studies focusing only on environmental and/or
economic outcomes were rejected. Data extraction, critical appraisal
and evidence synthesis was carried out using customized tabulation,
reference manager and CASP tool. Partial meta-analysis was carried
out and calculation of pooled effects and forest plotting were done.
As many as 13 studies finally included for final synthesis explained
the impact of targeted practices on health, behavioural and social
dimensions. Objectivity in the measurement of health outcomes
facilitated quantitative synthesis of studies which highlighted the
impact of sustainability methods on physical activity, Body Mass
Index, perinatal outcomes and child health. Studies synthesized
qualitatively (and also quantitatively) showed outcomes such as
routines, family relations, citizenship, trust in relationships, social
inclusion, neighbourhood social capital, wellbeing, habitability and
family’s social processes. The synthesized evidence indicates slight
effectiveness and efficacy of social and cultural sustainability on the
targeted outcomes. Further synthesis revealed that such results of this
study are due weak research designs and disintegrated implementations. If architects and other practitioners deliver their
interventions in collaboration with research bodies and policy
makers, a stronger evidence-base in this area could be generated.
Abstract: Sewage sludge is a biomass resource that can create a
solid fuel and electricity. Utilizing sewage sludge as a renewable
energy can contribute to the reduction of greenhouse gases. In Japan,
the "National Plan for the Promotion of Biomass Utilization" and the
“Priority Plan for Social Infrastructure Development" were approved
at cabinet meetings in December 2010 and August 2012, respectively,
to promote the energy utilization of sewage sludge. This study
investigated costs and greenhouse gas emission in different sewage
sludge treatments with technologies for energy from sewage sludge.
Expenses were estimated based on capital costs and O&M costs
including energy consumption of solid fuel plants and biogas power
generation plants for sewage sludge. Results showed that the cost of
sludge digestion treatment with solid fuel technologies was 8% lower
than landfill disposal. The greenhouse gas emission of sludge
digestion treatment with solid fuel technologies was also 6,390t as
CO2 smaller than landfill disposal. Biogas power generation reduced
the electricity of a wastewater treatment plant by 30% and the cost by
5%.
Abstract: This study investigated the effects of thermal
treatment on Tualang honey sample in terms of honey colour and
heat-induced small metabolites. The heating process was carried out
in a temperature controlled water batch at 90oC for 4 hours. The
honey samples were put in cylinder tubes with the dimension of 1 cm
diameter and 10 cm length for homogenous heat transfer. The results
found that the thermal treatment produced not only
hydroxylmethylfurfural, but also other harmful substances such as
phthalic anhydride and radiolytic byproducts. The degradation of
honey protein was due to the detection of free amino acids such as
cysteine and phenylalanine in heat-treated honey samples. Sugar
dehydration was also occurred because fragmented di-galactose was
identified based on the presence of characteristic ions in the mass
fragmentation pattern. The honey colour was found getting darker as
the heating duration was increased up to 4 hours. Approximately, 60
mm PFund of increment was noticed for the honey colour with the
colour change rate of 14.8 mm PFund per hour. Based on the
principal component analysis, the score plot clearly shows that the
chemical profile of Tualang honey was significantly altered after 2
hours of heating at 90oC.
Abstract: Hydrogen produced by means of polymer electrolyte
membrane electrolyzer (PEME) is one of the most promising
methods due to clean and renewable energy source. In the process,
some energy loss due to mass transfer through a PEM is caused by
diffusion, electro-osmotic drag, and the pressure difference between
the cathode channel and anode channel. In PEME, water molecules
and ionic particles transferred between the electrodes from anode to
cathode, Extensive mixing of the hydrogen and oxygen at anode
channel due to gases cross-over must be avoided. In recent times the
consciousness of safety issue in high pressure PEME where the
oxygen mix with hydrogen at anode channel could create, explosive
conditions have generated a lot of concern. In this paper, the steady
state and simulation analysis of gases crossover in PEME on the
temperature and pressure effect are presented. The simulations have
been analysis in MATLAB based on the well-known Fick’s Law of
molecular diffusion. The simulation results indicated that as
temperature increases, there is a significant decrease in operating
voltage.
Abstract: This study evaluated the acute toxicity and tissue
distribution of intravenously administered gold nanoparticles
(AuNPs) in male rabbits. Rabbits were exposed to single dose of
AuNPs (300 μg/ kg). Toxic effects were assessed via general
behavior, hematological parameters, serum biochemical parameters,
and histopathological examination of various rabbits’ organs.
Inductively coupled plasma–mass spectrometry (ICP-MS) was used
to determine gold concentrations in tissue samples collected at
predetermined time intervals. After one week, AuNPs exerted no
obvious acute toxicity in rabbits. However, inflammatory reactions
were observed in liver, lungs and kidneys accompanied with mild
absolute neutrophilia and significant monocytosis. The highest gold
levels were found in the spleen and liver followed by lungs, and
kidneys. These results indicated that AuNPs could be distributed
extensively to various tissues in the body, but primarily in the spleen
and liver.
Abstract: Biochar can be produced from the waste matter and its
application has been associated with returning of carbon in large
amounts into the soil. The impacts of this material on physical and
chemical properties of soil have been described. The biggest part of
the research work is dedicated to the hypothesis of this material’s
toxic effects on the soil life regarding its effect on the soil biological
component. At present, it has been worked on methods which could
eliminate these undesirable properties of biochar. One of the
possibilities is to mix biochar with organic material, such as compost,
or focusing on the natural processes acceleration in the soil. In the
experiment has been used as the addition of compost as well as the
elimination of toxic substances by promoting microbial activity in
aerated water environment. Biochar was aerated for 7 days in a
container with a volume of 20 l. This way modified biochar had six
times higher biomass production and reduce mineral nitrogen
leaching. Better results have been achieved by mixing biochar with
compost.
Abstract: The underutilization of biomass resources in the
Philippines, combined with its growing population and the rise in
fossil fuel prices confirms demand for alternative energy sources. The
goal of this paper is to provide a comparison of MODIS-based and
Landsat-based agricultural land cover maps when used in the
estimation of rice hull’s available energy potential. Biomass resource
assessment was done using mathematical models and remote sensing
techniques employed in a GIS platform.
Abstract: In Algeria, the conditioning units of dates, generate
significant quantities of waste arising from sorting deviations. This
biomass, until then considered as a waste with high impact on the
environment can be transformed into high value added product. It is
possible to develop common dates of low commercial value, and put
on the local and international market a new generation of products
with high added values such as bio ethanol. Besides its use in
chemical synthesis, bio ethanol can be blended with gasoline to
produce a clean fuel while improving the octane.
Abstract: A number of studies have been conducted recently to
investigate the influence of randomly oriented fibers on some
engineering properties of cohesive and cohesionless soils. However,
few studies have been carried out on freezing-thawing behavior of
fine-grained soils modified with discrete fiber inclusions and additive
materials. This experimental study was performed to investigate the
effect of randomly distributed polypropylene fibers (PP) and some
additive materials [e.g.., borogypsum (BG), fly ash (FA) and cement
(C)] on freezing-thawing durability (mass losses) of a fine-grained
soil for 6, 12, and 18 cycles. The Taguchi method was applied to the
experiments and a standard L9 orthogonal array (OA) with four
factors and three levels were chosen. A series of freezing-thawing
tests were conducted on each specimen. 0-20% BG, 0-20% FA, 0-
0.25% PP and 0-3% of C by total dry weight of mixture were used in
the preparation of specimens. Experimental results showed that the
most effective materials for the freezing-thawing durability (mass
losses) of the samples were borogypsum and fly ash. The values of
mass losses for 6, 12 and 18 cycles in optimum conditions were
16.1%, 5.1% and 3.6%, respectively.
Abstract: Rotary entrainment is a phenomenon in which the
interface of two immiscible fluids are subjected to external flux by
means of rotation. Present work reports the experimental study on
rotary motion of a horizontal cylinder between the interface of air and
water to observe the penetration of gas inside the liquid. Experiments
have been performed to establish entrainment of air mass in water
alongside the cylindrical surface. The movement of tracer and seeded
particles has been tracked to calculate the speed and path of the
entrained air inside water. Simplified particle image velocimetry
technique has been used to trace the movement of particles/tracers at
the moment they are injected inside the entrainment zone and
suspended beads have been used to replicate the particle movement
with respect to time in order to determine the flow dynamics of the
fluid along the cylinder. Present paper establishes a thorough experimental analysis of the
rotary entrainment phenomenon between air and water keeping in
interest the extent to which we can intermix the two and also to study
its entrainment trajectories.
Abstract: This study investigates the influence of low
temperature thermo-chemical pretreatment of organic food waste on
performance of COD solubilisation. Both temperature and alkaline
agent were reported to have effect on solubilizing any possible
biomass including organic food waste. The three independent
variables considered in this pretreatment were temperature (50-90oC),
pretreatment time (30-120 minutes) and alkaline concentration,
sodium hydroxide, NaOH (0.7-15 g/L). The maximal condition
obtained were 90oC, 15 g/L NaOH for 2 hours. Solubilisation has
potential in enhancing methane production by providing high amount
of soluble components at early stage during anaerobic digestion.
Abstract: A theoretical study of a humidification
dehumidification solar desalination unit has been carried out to
increase understanding the effect of weather conditions on the unit
productivity. A humidification-dehumidification (HD) solar
desalination unit has been designed to provide fresh water for
population in remote arid areas. It consists of solar water collector
and air collector; to provide the hot water and air to the desalination
chamber. The desalination chamber is divided into humidification
and dehumidification towers. The circulation of air between the two
towers is maintained by the forced convection. A mathematical
model has been formulated, in which the thermodynamic relations
were used to study the flow, heat and mass transfer inside the
humidifier and dehumidifier. The present technique is performed in
order to increase the unit performance. Heat and mass balance has
been done and a set of governing equations has been solved using the
finite difference technique. The unit productivity has been calculated
along the working day during the summer and winter sessions and
has compared with the available experimental results. The average
accumulative productivity of the system in winter has been ranged
between 2.5 to 4 (kg/m2)/day, while the average summer productivity
has been found between 8 to 12 (kg/m2)/day.
Abstract: Audio visual communication is a type of collective
expression. Due to inform the masses, give direction to opinions, and
establish public opinion, audio visual communication must be
subjected to special restrictions. This has been stipulated in both the
Constitution and the European Human Rights Agreement. This paper
aims to review freedom of expression and its restriction in audio
visual media. For this purpose, the authorization of the Radio and
Television Supreme Council to impose sanctions as an independent
administrative authority empowered to regulate the field of audio
visual communication has been reviewed with regard to freedom of
expression and its limits.
Abstract: In order to investigate the prebiotic potential of
oligosaccharides prepared by chemical hydrolysis of water-soluble
polysaccharides (WSP) from Zizyphus lotus leaves, the effect of
oligosaccharides on bacterial growth was studied. The chemical
composition of WSP was evaluated by colorimetric assays revealed
the average values: 7.05±0.73% proteins and 86.21±0.74%
carbohydrates, among them 64.81±0.42% is neutral sugar and the rest
16.25±1.62% is uronic acids. The characterization of
monosaccharides was determined by high performance anion
exchange chromatography with pulsed amperometric detection
(HPAEC-PAD) was found to be composed of galactose (23.95%),
glucose (21.30%), rhamnose (20.28%), arabinose (9.55%), and
glucuronic acid (22.95%). The effects of oligosaccharides on the
growth of lactic acid bacteria were compared with those of fructooligosaccharide
(RP95). The oligosaccharides concentration was
1g/L of Man, Rogosa, Sharpe broth. Bacterial growth was assessed
during 2, 4.5, 6.5, 9, 12, 16 and 24 h by measuring the optical density
of the cultures at 600 nm (OD600) and pH values. During
fermentation, pH in broth cultures decreased from 6.7 to 5.87±0.15.
The enumeration of lactic acid bacteria indicated that
oligosaccharides led to a significant increase in bacteria (P≤0.05)
compared to the control. The fermentative metabolism appeared to be
faster on RP95 than on oligosaccharides from Zizyphus lotus leaves.
Both RP95 and oligosaccharides showed clear prebiotic effects, but
had differences in fermentation kinetics because of to the different
degree of polymerization. This study shows the prebiotic
effectiveness of oligosaccharides, and provides proof for the selection
of leaves of Zizyphus lotus for use as functional food ingredients.