Abstract: This study was carried out to investigate the adverse
effect of industrial wastewater on surface water quality in Gebeng
industrial estate, Pahang, Malaysia. Surface water was collected from
six sampling stations. Physicochemical parameters were
characterized based on in-situ and ex-situ analysis according to
standard methods by American Public Health Association (APHA).
Selected heavy metals were determined by using Inductively Coupled
Plasma Mass Spectrometry (ICP MS). The results revealed that the
concentration of heavy metals such as Pb, Cu, Cd, Cr and Hg were
high in samples. The results also showed that the value of Pb and Hg
were higher in the wet season in comparison to dry season.
According to Malaysia National Water Quality Standard (NWQS)
and Water Quality Index (WQI) all the sampling station were
categorized as class IV (highly polluted). The present study revealed
that the adverse effects of careless disposal of wastes and directly
discharge of effluents affected on surface water quality. Therefore,
the authorities should implement the laws to ensure the proper
practices of wastewater management for environmental sustainability
around the study area.
Abstract: The main objective of incorporating natural fibers such as Henequen microfibers (NF) into the High Density Polyethylene (HDPE) polymer matrix is to reduce the cost and to enhance the mechanical as well as other properties. The Henequen microfibers were chopped manually to 5-7mm in length and added into the polymer matrix at the optimized concentration of 8 wt %. In order to facilitate the link between Henequen microfibers (NF) and HDPE matrix, coupling agent such as Glycidoxy (Epoxy) Functional Methoxy Silane (GPTS) at various concentrations from 0.1%, 0.3%, 0.5%, 0.7%, 0.9% and 1% by weight to the total fibers were added. The tensile strength of the composite increased marginally while % elongation at break of the composites decreased with increase in silane loading by wt %. Tensile modulus and stiffness observed increased at 0.9 wt % GPTS loading. Flexural as well as impact strength of the composite decreased with increase in GPTS loading by weight %. Dielectric strength of the composite also found increased marginally up to 0.5wt % silane loading and thereafter remained constant.
Abstract: The study discussed in this paper was conducted in an
attempt to investigate effects of different drying methods (line dry
and tumble dry) on viscose single jersey fabrics knitted with ring
yarn.
Abstract: Cesium iodide (CsI) melt was injected into anodic aluminum oxide (AAO) template and was solidified to CsI column. The controllable AAO channel size (10~500 nm) can makes CsI column size from 10 to 500 nm in diameter. In order to have a shorter light irradiate from each singe CsI column top to bottom the AAO template was coated a TiO2 nano-film. The TiO2 film acts a refraction film and makes X-ray has a shorter irradiation path in the CsI crystal making a stronger the photo-electron signal. When the incidence light irradiate from air (R=1.0) to CsI’s first surface (R=1.84) the first refraction happen, the first refraction continue into TiO2 film (R=2.88) and produces the low angle of the second refraction. Then the second refraction continue into AAO wall (R=1.78) and produces the third refraction after refractions between CsI and AAO wall (R=1.78) produce the fourth refraction. The incidence light through TiO2 filmand the first surface of CsI then arrive to the second surface of CsI. Therefore, the TiO2 film can has shorter refraction path of incidence light and increase the photo-electron conversion efficiency.
Abstract: By textile science incorporating with electronic
industry, developed textile products start to take part in different
areas such as industry, military, space, medical etc. for health,
protection, defense, communication and automation. Electronic
textiles (e-textiles) are fabrics that contain electronics and
interconnections with them. In this study, two types of base yarns
(cotton and acrylic) and three types of conductive steel yarns with
different linear resistance values (14Ω/m, 30Ω/m, 70Ω/m) were used
to investigate the effect of base yarn type and linear resistance of
conductive yarns on thermal behavior of e-textile structures. Thermal
behavior of samples was examined by thermal camera.
Abstract: Propylene self-metathesis to ethylene and butene was
studied over WOx/SiO2 catalysts at 450oC and atmospheric pressure.
The WOx/SiO2 catalysts were prepared by incipient wetness
impregnation of ammonium metatungstate aqueous solution. It was
found that, adding nano-sized extra supports (SiO2 and TiO2) by
physical mixing with the WOx/SiO2 enhanced propylene conversion.
The UV-Vis and FT-Raman results revealed that WOx could migrate
from the original silica support to the extra support, leading to a
better dispersion of WOx. The ICP-OES results also indicate that
WOx existed on the extra support. Coke formation was investigated
on the catalysts after 10 h time-on-stream by TPO. However, adding
nano-sized extra supports led to higher coke formation which may be
related to acidity as characterized by NH3-TPD.
Abstract: This paper presents the design and fabrication of an
optical window for an optical modulator toward image sensing
applications. An optical window consists of micrometer-order SiO2
capillaries (porous solid) that can modulate transmission light
intensity by moving the liquid in and out of porous solid. A high
optical transmittance of the optical window can be achieved due to
refractive index matching when the liquid is penetrated into the
porous solid. Otherwise, its light transmittance is lower because of
light reflection and scattering by air holes and capillary walls. Silicon
capillaries fabricated by deep reactive ion etching (DRIE) process are
completely oxidized to form the SiO2 capillaries. Therefore, high
aspect ratio SiO2 capillaries can be achieved based on silicon
capillaries formed by DRIE technique. Large compressive stress of
the oxide causes bending of the capillary structure, which is reduced
by optimizing the design of device structure. The large stress of the
optical window can be released via thin supporting beams. A 7.2 mm
x 9.6 mm optical window area toward a fully integrated with the
image sensor format is successfully fabricated and its optical
transmittance is evaluated with and without inserting liquids (ethanol
and matching oil). The achieved modulation range is approximately
20% to 35% with and without liquid penetration in visible region
(wavelength range from 450 nm to 650 nm).
Abstract: Activated carbon is an amorphous carbon chain which
has extremely extended surface area. High surface area of activated
carbon is due to the porous structure. Activated carbon, using a
variety of materials such as coal and cellulosic materials; can be
obtained by both physical and chemical methods. The prepared
activated carbon can be used for decolorize, deodorize and also can
be used for removal of organic and non-organic pollution. In this
study, pomegranate peel was subjected to 800W microwave power
for 1 to 4 minutes. Also fresh pomegranate peel was used for the
reference material. Then ZnCl2 was used for the chemical activation
purpose. After the activation process, activated pomegranate peels
were used for the adsorption of Zn metal (40 ppm) in the waste water.
As a result of the adsorption experiments, removal of heavy metals
ranged from 89% to 85%.
Abstract: Non-water based fixed abrasive polishing was adopted
to manufacture LBO crystal for nano precision surface quality because
of its deliquescent. Ethyl alcohol was selected as the non-water based
slurry solvent and ethanediamine, lactic acid, hydrogen peroxide was
added in the slurry as a chemical additive, respectively. Effect of
different additives with non-water based slurry on material removal
rate, surface topography, microscopic appearances, and surface
roughness were investigated in fixed abrasive polishing of LBO
crystal. The results show the best surface quality of LBO crystal with
surface roughness Sa 8.2 nm and small damages was obtained by
non-water based slurry with lactic acid. Non-water based fixed
abrasive polishing can achieve nano precision surface quality of LBO
crystal with high material removal.
Abstract: Predicting the collapse potential of a structure during
earthquakes is an important issue in earthquake engineering. Many
researchers proposed different methods to assess the collapse
potential of structures under the effect of strong ground motions.
However most of them did not consider degradation and softening
effect in hysteretic behavior. In this study, collapse potential of
SDOF systems caused by dynamic instability with stiffness and
strength degradation has been investigated. An equation was
proposed for the estimation of collapse period of SDOF system which
is a limit value of period for dynamic instability. If period of the
considered SDOF system is shorter than the collapse period then the
relevant system exhibits dynamic instability and collapse occurs.
Abstract: This article presents modeling studies of NiAl alloy
under solid-particle erosion and liquid-drop erosion. In the
solid-particle erosion simulation, attention is paid to the oxide scale
thickness variation on the alloy in high-temperature erosion
environments. The erosion damage is assumed to be deformation wear
and cutting wear mechanisms, incorporating the influence of the oxide
scale on the eroded surface; thus the instantaneous oxide thickness is
the result of synergetic effect of erosion and oxidation. For liquid-drop
erosion, special interest is in investigating the effects of drop velocity
and drop size on the damage of the target surface. The models of
impact stress wave, mean depth of penetration, and maximum depth of
erosion rate (Max DER) are employed to develop various maps for
NiAl alloy, including target thickness vs. drop size (diameter), rate of
mean depth of penetration (MDRP) vs. drop impact velocity, and
damage threshold velocity (DTV) vs. drop size.
Abstract: High performance turf reinforcement mat (HPTRM) is
one of the most advanced flexible armoring technologies for severe
erosion challenges. The effect of turbulence on the slope stability of
an earthen levee strengthened by high performance turf reinforcement
mat (HPTRM) is investigated in this study for combined storm surge
and wave overtopping conditions. The results show that turbulence
has strong influence on the slope stability during the combined storm
surge and wave overtopping conditions. Among the surge height,
peak wave force and turbulent force. The turbulent force has the
ability to stabilize the earthen levee at the large wave force the
turbulent force has strongest effect on the FS. The surge storm acts as
an independent force on the slope stability of the earthen levee. It just
adds to the effects of the turbulent force and wave force on the slope
stability of HPTRM strengthened levee.
Abstract: The biodegradable family of polymers
polyhydroxyalkanoates is an interesting substitute for convectional
fossil-based plastics. However, the manufacturing and environmental
impacts associated with their production via intracellular bacterial
fermentation are strongly dependent on the raw material used and on
energy consumption during the extraction process, limiting their
potential for commercialization. Industrial wastewater is studied in
this paper as a promising alternative feedstock for waste valorization.
Based on results from laboratory and pilot-scale experiments, a
conceptual process design, techno-economic analysis and life cycle
assessment are developed for the large-scale production of the most
common type of polyhydroxyalkanoate, polyhydroxbutyrate.
Intracellular polyhydroxybutyrate is obtained via fermentation of
microbial community present in industrial wastewater and the
downstream processing is based on chemical digestion with
surfactant and hypochlorite. The economic potential and
environmental performance results help identifying bottlenecks and
best opportunities to scale-up the process prior to industrial
implementation. The outcome of this research indicates that the
fermentation of wastewater towards PHB presents advantages
compared to traditional PHAs production from sugars because the
null environmental burdens and financial costs of the raw material in
the bioplastic production process. Nevertheless, process optimization
is still required to compete with the petrochemicals counterparts.
Abstract: In this study, polycaprolactone (PCL) was dissolved
in chloroform:ethanol solvent system at a concentration of 18 w/v %.
1, 2, 4, and 6 droplets of formic acid were added to the prepared 10ml
PCL-chloroform:ethanol solutions separately. Fibrous webs were
produced by electrospinning technique based on the horizontal
working principle. Morphology of the webs was investigated by
using scanning electron microscopy (SEM) whereas fiber diameters
were measured by Image J Software System. The effect of formic
acid addition to the mostly used chloroform solvent on fiber
morphology was examined.
Results indicate that there is a distinct fall in fiber diameter with
the addition of formic acid drops. The average fiber diameter was
measured as 2.22μm in PCL /chloroform:ethanol solution system. On
the other hand, 328nm and 256 nm average fiber diameters were
measured for the samples of 4 drops and 6 drops formic acid added.
This study offers alternative solvent systems to produce nanoscaled,
nontoxic PCL fibrous webs by electrospinning technique.
Abstract: Co-crystal is believed to improve the solubility and
dissolution rates and thus, enhanced the bioavailability of poor water
soluble drugs particularly during the oral route of administration.
With the existing of poorly soluble drugs in pharmaceutical industry,
the screening of co-crystal formation using carbamazepine (CBZ) as
a model drug compound with dicarboxylic acids co-crystal formers
(CCF) namely fumaric (FA) and succinic (SA) acids in ethanol has
been studied. The co-crystal formations were studied by varying the
mol ratio values of CCF to CBZ to access the effect of CCF
concentration on the formation of the co-crystal. Solvent evaporation,
slurry and cooling crystallization which representing the solution
based method co-crystal screening were used. Based on the
differential scanning calorimetry (DSC) analysis, the melting point of
CBZ-SA in different ratio was in the range between 188oC-189oC.
For CBZ-FA form A and CBZ-FA form B the melting point in
different ratio were in the range of 174oC-175oC and 185oC-186oC
respectively. The product crystal from the screening was also
characterized using X-ray powder diffraction (XRPD). The XRPD
pattern profile analysis has shown that the CBZ co-crystals with FA
and SA were successfully formed for all ratios studied. The findings
revealed that CBZ-FA co-crystal were formed in two different
polymorphs. It was found that CBZ-FA form A and form B were
formed from evaporation and slurry crystallization methods
respectively. On the other hand, in cooling crystallization method,
CBZ-FA form A was formed at lower mol ratio of CCF to CBZ and
vice versa. This study disclosed that different methods and mol ratios
during the co-crystal screening can affect the outcome of co-crystal
produced such as polymorphic forms of co-crystal and thereof. Thus,
it was suggested that careful attentions is needed during the screening
since the co-crystal formation is currently one of the promising
approach to be considered in research and development for
pharmaceutical industry to improve the poorly soluble drugs.
Abstract: Dengue outbreaks are affected by biological,
ecological, socio-economic and demographic factors that vary over
time and space. These factors have been examined separately and still
require systematic clarification. The present study aimed to investigate
the spatial-temporal clustering relationships between these factors and
dengue outbreaks in the northern region of Sri Lanka. Remote sensing
(RS) data gathered from a plurality of satellites were used to develop
an index comprising rainfall, humidity and temperature data. RS data
gathered by ALOS/AVNIR-2 were used to detect urbanization, and a
digital land cover map was used to extract land cover information.
Other data on relevant factors and dengue outbreaks were collected
through institutions and extant databases. The analyzed RS data and
databases were integrated into geographic information systems,
enabling temporal analysis, spatial statistical analysis and space-time
clustering analysis. Our present results showed that increases in the
number of the combination of ecological factor and socio-economic
and demographic factors with above the average or the presence
contribute to significantly high rates of space-time dengue clusters.
Abstract: The main goal of this article is to describe the online
flood monitoring and prediction system Floreon+ primarily developed
for the Moravian-Silesian region in the Czech Republic and the basic
process it uses for running automatic rainfall-runoff and
hydrodynamic simulations along with their calibration and
uncertainty modeling. It takes a long time to execute such process
sequentially, which is not acceptable in the online scenario, so the use
of a high performance computing environment is proposed for all
parts of the process to shorten their duration. Finally, a case study on
the Ostravice River catchment is presented that shows actual
durations and their gain from the parallel implementation.
Abstract: The effect of transition metal doping on Pt/Al2O3
catalyst used in propane dehydrogenation reaction at 500°C was
studied. The preparation methods investigated were sequential
impregnation (Pt followed by the 2nd metal or the 2nd metal followed
by Pt) and co-impregnation. The metal contents of these catalysts
were fixed as the weight ratio of Pt per the 2nd metal of around 0.075.
These catalysts were characterized by N2-physisorption, TPR, COchemisorption
and NH3-TPD. It was found that the impregnated 2nd
metal had an effect upon reducibility of Pt due to its interaction with
transition metal-containing structure. This was in agreement with the
CO-chemisorption result that the presence of Pt metal, which is a
result from Pt species reduction, was decreased. The total acidity of
bimetallic catalysts is decreased but the strong acidity is slightly
increased. It was found that the stability of bimetallic catalysts
prepared by co-impregnation and sequential impregnation where the
2nd metal was impregnated before Pt were better than that of
monometallic catalyst (undoped Pt one) due to the forming of Pt sites
located on the transition metal-oxide modified surface. Among all
preparation methods, the sequential impregnation method- having Pt
impregnated before the 2nd metal gave the worst stability because this
catalyst lacked the modified Pt sites and some fraction of Pt sites was
covered by the 2nd metal.
Abstract: The heavy metal pollution degree in the soils around
the Zangezur copper and molybdenum combine in Syunik Marz,
Armenia was assessed. The results of the study showed that heavy
metal pollution degree in the soils mainly decreased with increasing
distance from the open mine and the ore enrichment combine which
indicated that the open mine and the ore enrichment combine were
the main sources of heavy metal pollution. The only exception was
observed in the northern part of the open mine where pollution
degree in the sites (along the open mine) situated 600 meters far from
the mine was higher than that in the sites located 300 meters far from
the mine. This can be explained by the characteristics of relief and air
currents as well as the weak vegetation cover of these sites and the
characteristics of soil structure. According to geo-accumulation index
(I-geo), contamination factor (Cf), contamination degree (Cd) and
pollution load index (PLI) values, the pollution degree in the soils
around the open mine and the ore enrichment combine was higher
than that in the soils around the tailing dumps which was due to the
proper and accurate operation of the Artsvanik tailing damp and the
recultivation of the Voghji tailing dump.
The high Cu and Mo pollution of the soils was conditioned by the
character of industrial activities, the moving direction of air currents
as well as the physicochemical peculiarities of the soils.