Abstract: Investigation of soil properties like Cation Exchange
Capacity (CEC) plays important roles in study of environmental
reaserches as the spatial and temporal variability of this property
have been led to development of indirect methods in estimation of
this soil characteristic. Pedotransfer functions (PTFs) provide an
alternative by estimating soil parameters from more readily available
soil data. 70 soil samples were collected from different horizons of
15 soil profiles located in the Ziaran region, Qazvin province, Iran.
Then, multivariate regression and neural network model (feedforward
back propagation network) were employed to develop a
pedotransfer function for predicting soil parameter using easily
measurable characteristics of clay and organic carbon. The
performance of the multivariate regression and neural network model
was evaluated using a test data set. In order to evaluate the models,
root mean square error (RMSE) was used. The value of RMSE and
R2 derived by ANN model for CEC were 0.47 and 0.94 respectively,
while these parameters for multivariate regression model were 0.65
and 0.88 respectively. Results showed that artificial neural network
with seven neurons in hidden layer had better performance in
predicting soil cation exchange capacity than multivariate regression.
Abstract: Lightweight ceramic materials in the form of bricks
and blocks are widely used in modern construction. They may be
obtained by adding of rice husk, rye straw, etc, as porous forming
materials. Rice husk is a major by-product of the rice milling
industry. Its utilization as a valuable product has always been a
problem. Various technologies for utilization of rice husk through
biological and thermochemical conversion are being developed.
The purpose of this work is to develop lightweight ceramic
materials with clay matrix and filler of rice husk and examine their
main physicomechanical properties. The results obtained allow to
suppose that the materials synthesized on the basis of waste materials
can be used as lightweight materials for construction purpose.
Abstract: In the forming of ceramic materials the plasticity
concept is commonly used. This term is related to a particular
mechanical behavior when clay is mixed with water. A plastic
ceramic material shows a permanent strain without rupture
when a compressive load produces a shear stress that exceeds
the material-s yield strength. For a plastic ceramic body it
observes a measurable elastic behavior before the yield
strength and when the applied load is removed. In this work, a
mathematical model was developed from applied concepts of
the plasticity theory by using the stress/strain diagram under
compression.
Abstract: Bentonitic material from South Aswan, Egypt was evaluated in terms of mineral-ogy and chemical composition as bleaching clay in refining of transformer oil before and after acid activation and thermal treatment followed by acid leaching using HCl and H2SO4 for different contact times. Structural modification and refining power of bento-nite were investigated during modification by means of X-ray diffraction and infrared spectroscopy. The results revealed that the activated bentonite could be used for refining of transformer oil. The oil parameters such as; dielectric strength, viscosity and flash point had been improved. The dielectric breakdown strength of used oil increased from 29 kV for used oil treated with unactivated bentonite to 74 kV after treatment with activated bentonite. Kinematic Viscosity changed from 19 to 11 mm2 /s after treatment with activated bentonite. However, flash point achieved 149 ºC.
Abstract: According to the European laws, there is the
possibility of reusing the washing wastes for the environmental
requalification of quarry lakes. The paper deals with the
hydrogeological aspects involved in this possibility, as the
introduction of finest wastes in the quarry lakes can generate
alterations of the hydrogeological setting of the area, and problems
for the future accessibility of the zone. To evaluate the
hydrogeological compatibility of the washing wastes reuse in quarry
lakes a groundwater numerical model was carried out, pointing out
both the hydrogeological feasibility of this intervention and some
guide lines for its optimization, in terms of inflow point with regard
the groundwater flow direction and loss of volume in the quarry lake.
Abstract: The acidity of different raw Jordanian clays
containing zeolite, bentonite, red and white kaolinite and diatomite
was characterized by means of temperature programmed desorption
(TPD) of ammonia, conversion of 2-methyl-3-butyn-2-ol (MBOH),
FTIR and BET-measurements. FTIR spectra proved presence of
silanol and bridged hydroxyls on the clay surface. The number of
acidic sites was calculated from experimental TPD-profiles. We
observed the decrease of surface acidity correlates with the decrease
of Si/Al ratio except for diatomite. On the TPD-plot for zeolite two
maxima were registered due to different strength of surface acidic
sites. Values of MBOH conversion, product yields and selectivity
were calculated for the catalysis on Jordanian clays. We obtained that
all clay samples are able to convert MBOH into a major product
which is 3-methyl-3-buten-1-yne (MBYNE) catalyzed by acid
surface sites with the selectivity close to 70%. There was found a
correlation between MBOH conversion and acidity of clays
determined by TPD-NH3, i.e. the higher the acidity the higher the
conversion of MBOH. However, diatomite provided the lowest
conversion of MBOH as result of poor polarization of silanol groups.
Comparison of surface areas and conversions revealed the highest
density of active sites for red kaolinite and the lowest for zeolite and
diatomite.
Abstract: This paper studies the application of a variety of
sawdust materials in the production of lightweight insulating bricks.
First, the mineralogical and chemical composition of clays was determined. Next, ceramic bricks were fabricated with different
quantities of materials (3–6 and 9 wt. % for sawdust, 65 wt. % for grey clay, 24–27 and 30 wt. % for yellow clay and 2 wt% of tuff).
These bricks were fired at 800 and 950 °C. The effect of adding this sawdust on the technological behaviour of the brick was assessed by
drying and firing shrinkage, water absorption, porosity, bulk density
and compressive strength. The results have shown that the optimum
sintering temperature is 950 °C. Below this temperature, at 950 °C,
increased open porosity was observed, which decreased the compressive strength of the bricks. Based on the results obtained, the
optimum amounts of waste were 9 wt. % sawdust of eucalyptus, 24 wt. % shaping moisture and 1.6 particle size diameter. These percentages produced bricks whose mechanical properties were
suitable for use as secondary raw materials in ceramic brick
production.
Abstract: The purpose of this article is to study the effects of
plants cover on overland flow and, therefore, its influences on the
amount of eroded and transported soil. In this investigation, all the
experiments were conducted in the LEGHYD laboratory using a
rainfall simulator and a soil tray. The experiments were conducted
using an experimental plot (soil tray) which is 2m long, 0.5 m wide
and 0.15 m deep. The soil used is an agricultural sandy soil (62,08%
coarse sand, 19,14% fine sand, 11,57% silt and 7,21% clay). Plastic
rods (4 mm in diameter) were used to simulate the plants at different
densities: 0 stem/m2 (bared soil), 126 stems/m², 203 stems/m², 461
stems/m² and 2500 stems/m²). The used rainfall intensity is 73mm/h
and the soil tray slope is fixed to 3°. The results have shown that the
overland flow velocities decreased with increasing stems density, and
the density cover has a great effect on sediment concentration.
Darcy–Weisbach and Manning friction coefficients of overland flow
increased when the stems density increased. Froude and Reynolds
numbers decreased with increasing stems density and, consequently,
the flow regime of all treatments was laminar and subcritical. From
these findings, we conclude that increasing the plants cover can
efficiently reduce soil loss and avoid denuding the roots plants.
Abstract: In the present work, an attempt has been made to
understand the feasibility of using UHF technique for identification
of any corona discharges/ arcing in insulating material due to water
droplets. The sensors of broadband type are useful for identification
of such discharges. It is realised that arcing initiated by liquid droplet
radiates UHF signals in the entire bandwidth up to 2 GHz. The
frequency content of the UHF signal generated due to corona/arcing
is not much varied in epoxy nanocomposites with different weight
percentage of clay content. The exfoliated/intercalated properties
were analysed through TEM studies. It is realized that corona
initiated discharges are of intermittent process. The hydrophobicity
of the material characterized through contact angle measurement. It
is realized that low Wt % of nanoclay content in epoxy resin reduces
the surface carbonization due to arcing/corona discharges. The results
of the study with gamma irradiated specimen indicates that contact
angle, discharge inception time and evaporation time of the liquid are
much lower than the virgin epoxy nanocomposite material.
Abstract: The study aimed to identify the nature of autistic
talent, the manifestations of their weak central coherence, and their
sensory characteristics. The case study consisted of four talented
autistic males. Two of them in drawing, one in clay formation and
one in jigsaw puzzle. Tools of data collection were Group Embedded
Figures Test, Block Design Test, Sensory Profile Checklist Revised,
Interview forms and direct observation. Results indicated that talent
among autistics emerges in limited domain and being extraordinary
for each case. Also overlapping construction properties. Indeed, they
show three perceptual aspects of weak central coherence: The weak
in visual spatial-constructional coherence, the weak in perceptual
coherence and the weak in verbal – semantic coherence. Moreover,
the majority of the study cases used the three strategies of weak
central coherence (segmentation, obliqueness and rotation). As for
the sensory characteristics, all study cases have numbers of that
characteristics that especially emerges in the visual system.
Abstract: Soft clays are defined as cohesive soil whose water
content is higher than its liquid limits. Thus, soil-cement mixing is
adopted to improve the ground conditions by enhancing the strength
and deformation characteristics of the soft clays. For the above
mentioned reasons, a series of laboratory tests were carried out to
study some fundamental mechanical properties of cement stabilized
soft clay. The test specimens were prepared by varying the portion of
ordinary Portland cement to the soft clay sample retrieved from the
test site of RECESS (Research Centre for Soft Soil). Comparisons
were made for both homogeneous and columnar system specimens
by relating the effects of cement stabilized clay of for 0, 5 and 10 %
cement and curing for 3, 28 and 56 days. The mechanical properties
examined included one-dimensional compressibility and undrained
shear strength. For the mechanical properties, both homogeneous and
columnar system specimens were prepared to examine the effect of
different cement contents and curing periods on the stabilized soil.
The one-dimensional compressibility test was conducted using an
oedometer, while a direct shear box was used for measuring the
undrained shear strength. The higher the value of cement content, the
greater is the enhancement of the yield stress and the decrease of
compression index. The value of cement content in a specimen is a
more active parameter than the curing period.
Abstract: CTMA-bentonite and BTEA-Bentonite prepared by Na-bentonite cation exchanged with cetyltrimethylammonium(CTMA) and benzyltriethylammonium (BTEA). Products were characterized by XRD and IR techniques.The d001 spacing value of CTMA-bentonite and BTEA-bentonite are 7.54Å and 3.50Å larger than that of Na-bentonite at 100% cation exchange capacity, respectively. The IR spectrum showed that the intensities of OH stretching and bending vibrations of the two organoclays decreased greatly comparing to untreated Na-bentonite. Batch experiments were carried out at 303 K, 318 K and 333 K to obtain the sorption isotherms of Crystal violet onto the two organoclays. The results show that the sorption isothermal data could be well described by Freundlich model. The dynamical data for the two organoclays fit well with pseudo-second-order kinetic model. The adsorption capacity of CTMA-bentonite was found higher than that of BTEA-Bentonite. Thermodynamic parameters such as changes in the free energy (ΔG°), the enthalpy (ΔH°) and the entropy (ΔS°) were also evaluated. The overall adsorption process of Crystal violet onto the two organoclays were spontaneous, endothermic physisorption. The CTMA-bentonite and BTEA-Bentonite could be employed as low-cost alternatives to activated carbon in wastewater treatment for the removal of color which comes from textile dyes.
Abstract: Arsenic in the sediments of the ash lagoons of the coal-fired power plant in Pagbilao, Quezon Province in the Philippines was sequentially extracted to determine its potential for leaching to the groundwater and the adjacent marine environment. Results show that 89% of the As is bound to the quasi-crystalline Fe/Mn oxides and hydroxide matrix in the sediments, whereas, the adsorbed and exchangeable As hosted by the clay minerals, representing those that are easiest to release from the sediment matrix, is below 10% of the acid leachable As. These As in these sediment matrices represent the possible maximum amount of As that can be released and supplied to the groundwater and the adjacent marine environment. Of the 89% reducible As, up to 4% is associated with the easily reducible variety, whereas, the rest is more strongly bonded by the moderately reducible variety. Based on the long-term As content of the lagoon water, the average desorption rate of As is calculated to be very low -- 0.3-0.5% on the average and 0.6% on the maximum. This indicates that As is well-fixed by its sediment matrices in the ash lagoon, attenuating the influx of As into the adjacent groundwater and marine environments.
Abstract: Investigation of sandy clay behavior is important since
urban development demands mean that sandy clay areas are
increasingly encountered, especially for transportation
infrastructures. This paper presents the results of the finite element
analysis of the direct shear test (under three vertical loading 44, 96
and 192 kPa) and discusses the effects of different parameters such as
cohesion, friction angle and Young's modulus on the shear strength of
sandy clay. The numerical model was calibrated against the
experimental results of large-scale direct shear tests. The results have
shown that the shear strength was increased with increase in friction
angle and cohesion. However, the shear strength was not influenced
by raising the friction angle at normal stress of 44 kPa. Also, the
effect of different young's modulus factors on stress-strain curve was
investigated.
Abstract: In this paper, the effect of modified clay on the
mechanical efficiency of epoxy resin is examined. Studies by X ray
diffraction and microscopic transient electron method show that
modified clay distribution in polymer area is intercalated kind.
Examination the results of mechanical tests shows that existence of
modified clay in epoxy area increases pressure yield strength, tension
module and nano composite fracture toughness in relate of pure
epoxy. By microscopic examinations it is recognized too that the
action of toughness growth of this kind of nano composite is due to
crack deflection, formation of new surfaces and fracture of clay piles.
Abstract: In this research work, poly (acrylonitrile-butadienestyrene)/
polypropylene (ABS/PP) blends were processed by melt
compounding in a twin-screw extruder. Upgrading of the thermal
characteristics of the obtained materials was attempted by the
incorporation of organically modified montmorillonite (OMMT), as
well as, by the addition of two types of compatibilizers;
polypropylene grafted with maleic anhydride (PP-g-MAH) and ABS
grafted with maleic anhydride (ABS-g-MAH). The effect of the
above treatments was investigated separately and in combination.
Increasing the PP content in ABS matrix seems to increase the
thermal stability of their blend and the glass transition temperature
(Tg) of SAN phase of ABS. From the other part, the addition of ABS
to PP promotes the formation of its β-phase, which is maximum at 30
wt% ABS concentration, and increases the crystallization temperature
(Tc) of PP. In addition, it increases the crystallization rate of PP.The
β-phase of PP in ABS/PP blends is reduced by the addition of
compatibilizers or/and organoclay reinforcement. The incorporation
of compatibilizers increases the thermal stability of PP and reduces
its melting (ΔΗm) and crystallization (ΔΗc) enthalpies. Furthermore it
decreases slightly the Tgs of PP and SAN phases of ABS/PP blends.
Regarding the storage modulus of the ABS/PP blends, it presents a
change in their behavior at about 10°C and return to their initial
behavior at ~110°C. The incorporation of OMMT to no compatibilized
and compatibilized ABS/PP blends enhances their storage modulus.
Abstract: The objectives of this study are to determine the
effects of soil cover type on characteristics of leachates generated
from landfill lysimeters. Four lysimeters with diameter and height
of 0.15 and 3.00 m, respectively, were prepared. Three lysimeters
were filled with municipal waste and three different cover soil types
i.e. sandy loam soil, silty loam soil and clay soil while another
lysimeter was filled solely with municipal waste. The study was
conducted in the rainy season. Leachate quantities were measured
every day and leachate characteristics were determined once a week.
The cumulative leachate quantity from the lysimeter filled solely
with municipal waste was found to be around 27% higher than the
lysimeters using cover soils. There were no any differences of the
cumulative leachate amounts generated from the lysimeters using
three types of soils. The comparison of the total mass of pollutants
generated from all lysimeters showed that the lysimeter filled solely
with municipal waste generated the maximum quantities of
pollutants. Among the lysimeters using different types of soils, the
lysimeter using sandy loam soil generated the lowest amount of most
of pollutants, compared with the lysimeters using silty loam and clay
soils. It can be concluded that in term of pollutant attenuation in the
leachate, a sandy loam is the most suitable soil to be used as a cover
soil in the landfill.
Abstract: This research investigates the suitability of fuel oil in
improving gypseous soil. A detailed laboratory tests were carried-out
on two soils (soil I with 51.6% gypsum content, and soil II with
26.55%), where the two soils were obtained from Al-Therthar site
(Al-Anbar Province-Iraq).
This study examines the improvement of soil properties using the
gypsum material which is locally available with low cost to minimize
the effect of moisture on these soils by using the fuel oil. This study
was conducted on two models of the soil gypsum, from the Tharthar
area. The first model was sandy soil with Gypsum content of (51.6%)
and the second is clayey soil and the content of Gypsum is (26.55%).
The program included tests measuring the permeability and
compressibility of the soil and their collapse properties. The shear
strength of the soil and the amounts of weight loss of fuel oil due to
drying had been found. These tests have been conducted on the
treated and untreated soils to observe the effect of soil treatment on
the engineering properties when mixed with varying degrees of fuel
oil with the equivalent of the water content.
The results showed that fuel oil is a good material to modify the
basic properties of the gypseous soil of collapsibility and
permeability, which are the main problems of this soil and retained
the soil by an appropriate amount of the cohesion suitable for
carrying the loads from the structure.
Abstract: The objective of this study is to evaluate the threshold
stress of the clay with sand subgrade soil. Threshold stress can be
defined as the stress level above which cyclic loading leads to
excessive deformation and eventual failure. The thickness
determination of highways formations using the threshold stress
approach is a more realistic assessment of the soil behaviour because
it is subjected to repeated loadings from moving vehicles. Threshold
stress can be evaluated by plastic strain criterion, which is based on
the accumulated plastic strain behaviour during cyclic loadings [1].
Several conditions of the all-round pressure the subgrade soil namely,
zero confinement, low all-round pressure and high all-round pressure
are investigated. The threshold stresses of various soil conditions are
determined. Threshold stress of the soil are 60%, 31% and 38.6% for
unconfined partially saturated sample, low effective stress saturated
sample, high effective stress saturated sample respectively.
Abstract: Ranong province has the best kaolin, and it is the most
useful of all the clay types used in ceramic making. Until recently,
there has been only one community business making ceramics in
Ranong province. And this business could not build the mix of body
and glaze from their raw material without assistance. Considering
these problems, this research is aimed to test the composition of
ceramic body and glaze which suit. Kaolin from Ranong is the raw
material which these search focuses on. All other raw materials use in
the investigation will come from southern Thailand, kaolin and
limestone from Ranong province, ball clay from Surat Thani
province, white sand from Songkhla province, and feldspar from
Nakhon Si Thammarat province. Results can be used to develop the
efficiency of industrial production which in return will enhance the
business process.