Abstract: The effect of calcination temperature and MgO crystallite sizes on the structure and catalytic performance of TiO2 supported nano-MgO catalyst for the trans-esterification of soybean oil has been studied. The catalyst has been prepared by deposition precipitation method, characterised by XRD and FTIR and tested in an autoclave at 225oC. The soybean oil conversion after 15 minutes of the trans-esterification reaction increased when the calcination temperature was increased from 500 to 600oC and decreased with further increase in calcination temperature. Some glycerolysis activity was also detected on catalysts calcined at 600 and 700oC after 45 minutes of reaction. The trans-esterification reaction rate increased with the decrease in MgO crystallite size for the first 30 min.
Abstract: Background: Blunt aortic trauma (BAT) includes
various morphological changes that occur during deceleration,
acceleration and/or body compression in traffic accidents. The
various forms of BAT, from limited laceration of the intima to
complete transection of the aorta, depends on the force acting on the
vessel wall and the tolerance of the aorta to injury. The force depends
on the change in velocity, the dynamics of the accident and of the
seating position in the car. Tolerance to aortic injury depends on the
anatomy, histological structure and pathomorphological alterations
due to aging or disease of the aortic wall.
An overview of the literature and medical documentation reveals
that different terms are used to describe certain forms of BAT, which
can lead to misinterpretation of findings or diagnoses. We therefore,
propose a classification that would enable uniform systematic
screening of all forms of BAT. We have classified BAT into three
morphologycal types: TYPE I (intramural), TYPE II (transmural) and
TYPE III (multiple) aortic ruptures with appropriate subtypes.
Methods: All car accident casualties examined at the Institute of
Forensic Medicine from 2001 to 2009 were included in this
retrospective study. Autopsy reports were used to determine the
occurrence of each morphological type of BAT in deceased drivers,
front seat passengers and other passengers in cars and to define the
morphology of BAT in relation to the accident dynamics and the age
of the fatalities.
Results: A total of 391 fatalities in car accidents were included in
the study. TYPE I, TYPE II and TYPE III BAT were observed in
10,9%, 55,6% and 33,5%, respectively. The incidence of BAT in
drivers, front seat and other passengers was 36,7%, 43,1% and
28,6%, respectively. In frontal collisions, the incidence of BAT was
32,7%, in lateral collisions 54,2%, and in other traffic accidents
29,3%. The average age of fatalities with BAT was 42,8 years and of
those without BAT 39,1 years.
Conclusion: Identification and early recognition of the risk factors
of BAT following a traffic accident is crucial for successful treatment
of patients with BAT. Front seat passengers over 50 years of age who
have been injured in a lateral collision are the most at risk of BAT.
Abstract: This study was designed to formulate,
pharmaceutically evaluate a topical skin-care cream (w/o emulsion)
of Aloe Vera versus its vehicle (Base) as control and determine their
effects on Stratum Corneum (SC) water content and Transepidermal
water loss (TEWL). Base containing no extract and a Formulation
containing 3% concentrated extract of Aloe Vera was developed by
entrapping in the inner aqueous phase of w/o emulsion (cream).
Lemon oil was incorporated to improve the odor. Both the Base and
Formulation were stored at 8°C ±0.1°C (in refrigerator), 25°C±0.1°C,
40°C±0.1°C and 40°C± 0.1°C with 75% RH (in incubator) for a
period of 4 weeks to predict their stability. The evaluation parameters
consisted of color, smell, type of emulsion, phase separation,
electrical conductivity, centrifugation, liquefaction and pH. Both the
Base and Formulation were applied to the cheeks of 21 healthy
human volunteers for a period of 8 weeks Stratum corneum (SC)
water content and Transepidermal water loss (TEWL) were
monitored every week to measure any effect produced by these
topical creams. The expected organoleptic stability of creams was
achieved from 4 weeks in-vitro study period. Odor was disappeared
with the passage of time due to volatilization of lemon oil. Both the
Base and Formulation produced significant (p≤0.05) changes in
TEWL with respect to time. SC water content was significantly
(p≤0.05) increased by the Formulation while the Base has
insignificant (p 0.05) effects on SC water content. The newly
formulated cream of Aloe Vera, applied is suitable for improvement
and quantitative monitoring of skin hydration level (SC water
content/ moisturizing effects) and reducing TEWL in people with dry
skin.
Abstract: In this study, the transesterification of palm oil with methanol for biodiesel production was studied by using CaO–ZnO as a heterogeneous base catalyst prepared by incipient-wetness impregnation (IWI) and co-precipitation (CP) methods. The reaction parameters considered were molar ratio of methanol to oil, amount of catalyst, reaction temperature, and reaction time. The optimum conditions–15:1 molar ratio of methanol to oil, a catalyst amount of 6 wt%, reaction temperature of 60 °C, and reaction time of 8 h–were observed. The effects of Ca loading, calcination temperature, and catalyst preparation on the catalytic performance were studied. The fresh and spent catalysts were characterized by several techniques, including XRD, TPR, and XRF.
Abstract: In this research, CaO-ZnO catalysts (with various
Ca:Zn atomic ratios of 1:5, 1:3, 1:1, and 3:1) prepared by incipientwetness
impregnation (IWI) and co-precipitation (CP) methods were
used as a catalyst in the transesterification of palm oil with methanol
for biodiesel production. The catalysts were characterized by several
techniques, including BET method, CO2-TPD, and Hemmett
Indicator. The effects of precursor concentration, and calcination
temperature on the catalytic performance were studied under reaction
conditions of a 15:1 methanol to oil molar ratio, 6 wt% catalyst,
reaction temperature of 60°C, and reaction time of 8 h. At Ca:Zn
atomic ratio of 1:3 gave the highest FAME value owing to a basic
properties and surface area of the prepared catalyst.
Abstract: There is growing interest in biodiesel (fatty acid
methyl ester or FAME) because of the similarity in its properties
when compared to those of diesel fuels. Diesel engines operated on
biodiesel have lower emissions of carbon monoxide, unburned
hydrocarbons, particulate matter, and air toxics than when operated
on petroleum-based diesel fuel. Production of fatty acid methyl ester
(FAME) from rapeseed (nonedible oil) fatty acid distillate having
high free fatty acids (FFA) was investigated in this work. Conditions
for esterification process of rapeseed oil were 1.8 % H2SO4 as
catalyst, MeOH/oil of molar ratio 2 : 0.1 and reaction temperature
65 °C, for a period of 3h. The yield of methyl ester was > 90 % in 1
h.
The amount of FFA was reduced from 93 wt % to less than 2 wt %
at the end of the esterification process. The FAME was pureed by
neutralization with 1 M sodium hydroxide in water solution at a
reaction temperature of 62 °C. The final FAME product met with the
biodiesel quality standard, and ASTM D 6751.
Abstract: Biodiesel is traditionally produced from oleaginous
plants. On the other hand, increasing biodiesel production from these
raw materials could create problems of food supply. Producing
biodiesel from microalgae could help to overcome this difficulty,
because microalgae are rich in lipids and do not compete for arable
lands. However, no studies had compared vegetable and microalgae
oil-based biodiesel in terms of yield, viscosity and heat of
combustion. In the present study, commercial canola and microalgae
oil were therefore transesterified with methanol under a homogenous
alkali catalyst (potassium hydroxide) at 100oC for 1h. The result
showed that microalgae-based oil has a higher yield in biodiesel with
89.7% (g biodiesel/g oil) and a lower kinematic viscosity (22oC) of
4.31 mm/s2 than canola oil.
Abstract: Biodisel is a type of biofuel having similar properties of diesel fuel but lacks substances (undesirable emissions) such as sulfur, nitrogen and aromatic polycyclic. Upon filtration of waste oil, the biodiesel fuel was produced via carrying out transestrification reaction of triglycerides followed by conducting viscosity, density, flash point, cloud point, pour point and copper strip corrosion tests on the samples and comparing with EN14214 and ASTM 6751 standards and all results were found in the permitted limit. The highest yield of biodiesel production reaction was found 46.6435 g when Sodium Hydroxide catalyst in amount of 0.375g was employed, 44.2347 g when Sodium methoxide catalyst in amount of 0.5g was employed and 56.5124 g when acid sulfuric catalyst in amount of 1g was employed and 47.3290 g when two stage reaction was done.
Abstract: Transesterification of candlenut (aleurites moluccana)
oil with methanol using potassium hydroxide as catalyst was
studied. The objective of the present investigation was to produce
the methyl ester for use as biodiesel. The operation variables
employed were methanol to oil molar ratio (3:1 – 9:1), catalyst
concentration (0.50 – 1.5 %) and temperature (303 – 343K). Oil
volume of 150 mL, reaction time of 75 min were fixed as common
parameters in all the experiments. The concentration of methyl ester
was evaluated by mass balance of free glycerol formed which was
analyzed by using periodic acid. The optimal triglyceride conversion
was attained by using methanol to oil ratio of 6:1, potassium
hydroxide as catalyst was of 1%, at room temperature. Methyl ester
formed was characterized by its density, viscosity, cloud and pour
points. The biodiesel properties had properties similar to those of
diesel oil, except for the viscosity that was higher.
Abstract: Biodiesel production with used frying by
transesterification reaction with methanol, using a commercial
kaolinite thermally-activated solid acid catalyst was investigated.
The surface area, the average pore diameter and pore volume of the
kaolinite catalyst were 10 m2/g, 13.0 nm and 30 mm3/g, respectively.
The optimal conditions for the transesterification reaction were
determined to be oil/methanol, in a molar ratio 1:31, temperature 160
ºC and catalyst concentration of 3% (w/w). The yield of fatty acids
methyl esters (FAME) was 92.4% after 2 h of reaction. This method
of preparation of biodiesel can be a positive alternative for utilizing
used frying corn oil for feedstock of biodiesel combined with the
inexpensive catalyst.
Abstract: The objective of the present study was to examine the
dose-response relationships between antioxidant parameters and liver
contaminant levels of Kazakhstan light crude oil (KLCO) in albino
rats. The animals were repeatedly exposed, by intraperitoneal
injection, to low dosages (0.5–1.5 ml/kg) of KLCO. Rats exposed to
these doses levels did not show any apparent symptoms of
intoxication. Serum aminotransferases increased significantly
(p
Abstract: The conventional production of biodiesel from crude
palm oil which contains large amounts of free fatty acids in the
presence of a homogeneous base catalyst confronts the problems of
soap formation and very low yield of biodiesel. To overcome these
problems, free fatty acids must be esterified to their esters in the
presence of an acid catalyst prior to alkaline-catalyzed
transesterification. Sulfated metal oxides are a promising group of
catalysts due to their very high acidity. In this research, aluminadoped
sulfated tin oxide (SO4
2-/Al2O3-SnO2) catalysts were prepared
and used for esterification of free fatty acids in crude palm oil in a
batch reactor. The SO4
2-/Al2O3-SnO2 catalysts were prepared from
different Al precursors. The results showed that different Al
precursors gave different activities of the SO4
2-/Al2O3-SnO2 catalysts.
The esterification of free fatty acids in crude palm oil with methanol
in the presence of SO4
2-/Al2O3-SnO2 catalysts followed first-order
kinetics.
Abstract: Transesterified vegetable oils (biodiesel) are promising alternative fuel for diesel engines. Used vegetable oils are disposed from restaurants in large quantities. But higher viscosity restricts their direct use in diesel engines. In this study, used cooking oil was dehydrated and then transesterified using an alkaline catalyst. The combustion, performance and emission characteristics of Used Cooking oil Methyl Ester (UCME) and its blends with diesel oil are analysed in a direct injection C.I. engine. The fuel properties and the combustion characteristics of UCME are found to be similar to those of diesel. A minor decrease in thermal efficiency with significant improvement in reduction of particulates, carbon monoxide and unburnt hydrocarbons is observed compared to diesel. The use of transesterified used cooking oil and its blends as fuel for diesel engines will reduce dependence on fossil fuels and also decrease considerably the environmental pollution.
Abstract: Nano MgO has been synthesized by hydration and
dehydration method by modifies the commercial MgO. The prepared
MgO had been investigated as a heterogeneous base catalyst for
transesterification process for biodiesel production using palm oil.
TGA, FT-IR and XRD results obtained from this study lie each other
and proved in the formation of nano MgO from decomposition of
Mg(OH)2. This study proved that the prepared nano MgO was a
better base transesterification catalyst compared to commercial MgO.
The nano MgO calcined at 600ºC had gives the highest conversion of
51.3% of palm oil to biodiesel.
Abstract: Chicken fat was employed as a feedstock for
producing of biodiesel by trasesterification reaction with methanol
and alkali catalyst (KOH). In this study chicken fat biodiesel with
1.4% free fatty acid, methanol and various amount of potassium
hydroxide for 2 hour were studied. The progression of reaction and
conversion of triglycerides to methyl ester were checked by IR
spectrum method.
Abstract: A general purpose viscous flow solver Ansys CFX
was used to solve the unsteady three-dimensional (3D) Reynolds
Averaged Navier-Stokes Equation (RANSE) for simulating a 3D
numerical viscous wave tank. A flap-type wave generator was
incorporated in the computational domain to generate the desired
incident waves. Authors have made effort to study the physical
behaviors of Flap type wave maker with governing parameters.
Dependency of the water fill depth, Time period of oscillations and
amplitude of oscillations of flap were studied. Effort has been made
to establish relations between parameters. A validation study was
also carried out against CFD methodology with wave maker theory.
It has been observed that CFD results are in good agreement with
theoretical results. Beaches of different slopes were introduced to
damp the wave, so that it should not cause any reflection from
boundary. As a conclusion this methodology can simulate the
experimental wave-maker for regular wave generation for different
wave length and amplitudes.
Abstract: With the growth of modern civilization and
industrialization in worldwide, the demand for energy is increasing
day by day. Majority of the world-s energy needs are met through
fossil fuels and natural gas. As a result the amount of fossil fuels is
on diminishing from year to year. Since the fossil fuel is nonrenewable,
so fuel price is gouging as a consequence of spiraling
demand and diminishing supply. At present the power generation of
our country is mainly depends on imported fossil fuels. To reduce the
dependency on imported fuel, the use of renewable sources has
become more popular. In Bangladesh coconut is widely growing tree.
Especially in the southern part of the country a large area will be
found where coconut tree is considered as natural asset. So, our
endeavor was to use the coconut oil as a renewable and alternative
fuel. This article shows the prospect of coconut oil as a renewable
and alternative fuel of diesel fuel. Since diesel engine has a versatile
uses including small electricity generation, an experimental set up is
then made to study the performance of a small diesel engine using
different blends of bio diesel converted from coconut oil. It is found
that bio diesel has slightly different properties than diesel. With
biodiesel the engine is capable of running without difficulty.
Different blends of bio diesel (i.e. B80, B60, and B 50 etc.) have
been used to avoid complicated modification of the engine or the fuel
supply system. Finally, a comparison of engine performance for
different blends of biodiesel has been carried out to determine the
optimum blend for different operating conditions.
Abstract: Biodiesel as an alternative fuel for diesel engines has been developed for some three decades now. While it is gaining wide acceptance in Europe, USA and some parts of Asia, the same cannot be said of Africa. With more than 35 countries in the continent depending on imported crude oil, it is necessary to look for alternative fuels which can be produced from resources available locally within any country. Hence this study presents performance of single cylinder diesel engine using blends of shea butter biodiesel. Shea butter was transformed into biodiesel by transesterification process. Tests are conducted to compare the biodiesel with baseline diesel fuel in terms of engine performance and exhaust emission characteristics. The results obtained showed that the addition of biodiesel to diesel fuel decreases the brake thermal efficiency (BTE) and increases the brake specific fuel consumption (BSFC). These results are expected due to the lower energy content of biodiesel fuel. On the other hand while the NOx emissions increased with increase in biodiesel content in the fuel blends, the emissions of carbon monoxide (CO), un-burnt hydrocarbon (UHC) and smoke opacity decreased. The engine performance which indicates that the biodiesel has properties and characteristics similar to diesel fuel and the reductions in exhaust emissions make shea butter biodiesel a viable additive or substitute to diesel fuel.