Abstract: Nano sized zirconium dioxide in monoclinic phase (m-ZrO2) has been synthesized in pure form through co-precipitation processing at different calcination temperatures and has been characterized by several techniques such as XRD, FT-IR, UV-Vis Spectroscopy and SEM. The dielectric and capacitance values of the pelletized samples have been examined at room temperature as the functions of frequency. The higher dielectric constant value of the sample having larger grain size proves the strong influence of grain size on the dielectric constant.
Abstract: Sandwich panels are widely used in the construction
industry for their ease of assembly, light weight and efficient thermal
performance. They are composed of two RC thin outer layers
separated by an insulating inner layer. In this research the inner
insulating layer is made of lightweight Autoclaved Aerated Concrete
(AAC) blocks which has good thermal insulation properties and yet
possess reasonable mechanical strength. The shear strength of the
AAC infill is relied upon to replace the traditionally used insulating
foam and to provide the shear capacity of the panel. A
comprehensive experimental program was conducted on full scale
sandwich panels subjected to bending. In this paper, detailed
numerical modeling of the tested sandwich panels is reported. Nonlinear
3-D finite element modeling of the composite action of the
sandwich panel is developed using ANSYS. Solid elements with
different crashing and cracking capabilities and different constitutive
laws were selected for the concrete and the AAC. Contact interface
elements are used in this research to adequately model the shear
transfer at the interface between the different layers. The numerical
results showed good correlation with the experimental ones
indicating the adequacy of the model in estimating the loading
capacity of panels.
Abstract: Chlorine is one of the most abundant elements in
nature, which undergoes a complex biogeochemical cycle. Chlorine
bound in some substances is partly responsible for atmospheric ozone
depletion and contamination of some ecosystems. As due to
international regulations anthropogenic burden of volatile
organochlorines (VOCls) in atmosphere decreases, natural sources
(plants, soil, abiotic formation) are expected to dominate VOCl
production in the near future. Examples of plant VOCl production are
methyl chloride, and bromide emission from (sub)tropical ferns,
chloroform, 1,1,1-trichloroethane and tetrachloromethane emission
from temperate forest fern and moss. Temperate forests are found to
emit in addition to the previous compounds tetrachloroethene, and
brominated volatile compounds. VOCls can be taken up and further
metabolized in plants. The aim of this work is to identify and
quantitatively analyze the formed VOCls in temperate forest
ecosystems by a cryofocusing/GC-ECD detection method, hence
filling a gap of knowledge in the biogeochemical cycle of chlorine.
Abstract: Analysis for the propagation of elastic waves in
arbitrary anisotropic plates is investigated, commencing with a
formal analysis of waves in a layered plate of an arbitrary anisotropic
media, the dispersion relations of elastic waves are obtained by
invoking continuity at the interface and boundary of conditions on
the surfaces of layered plate. The obtained solutions can be used for
material systems of higher symmetry such as monoclinic,
orthotropic, transversely isotropic, cubic, and isotropic as it is
contained implicitly in the analysis. The cases of free layered plate
and layered half space are considered separately. Some special cases
have also been deduced and discussed. Finally numerical solution of
the frequency equations for an aluminum epoxy is carried out, and
the dispersion curves for the few lower modes are presented. The
results obtained theoretically have been verified numerically and
illustrated graphically.
Abstract: The nickel and gold nanoclusters as supported
catalysts were analyzed by XAS, XRD and XPS in order to
determine their local, global and electronic structure. The present
study has pointed out a strong deformation of the local structure of
the metal, due to its interaction with oxide supports. The average
particle size, the mean squares of the microstrain, the particle size
distribution and microstrain functions of the supported Ni and Au
catalysts were determined by XRD method using Generalized Fermi
Function for the X-ray line profiles approximation. Based on EXAFS
analysis we consider that the local structure of the investigated
systems is strongly distorted concerning the atomic number pairs.
Metal-support interaction is confirmed by the shape changes of the
probability densities of electron transitions: Ni K edge (1s →
continuum and 2p), Au LIII-edge (2p3/2 → continuum, 6s, 6d5/2 and
6d3/2). XPS investigations confirm the metal-support interaction at
their interface.
Abstract: Oxygen and carbon isotopes records of multi-species planktonic, benthic foraminifera and bulk carbonate sample from Central Java Indonesia demonstrate that warm sea surface temperature occurred during the Miocene. Planktonic δ18O values from this study consistently lighter (-4 to -3 ‰PDB) than previous studies that indicate sea surface temperature during Miocene in this area was warm than tropical/equatorial localities. A surprising decrease of oxygen isotopic composition was recorded at ±14 Ma where the maximum of δ18O values is -4.87 ‰PDB for Orbulina universa, -5.02 ‰PDB for Globigerinoides sacculifer and -4.30 ‰PDB for Globoquadrina dehiscens, this event we predict as Middle Miocene Optimum. Warming of sea surface temperature we interpret as related to the development of Western Pacific Warm Pool where warm water from Pacific Ocean through the Indonesian seaway appears to remain during Miocene. Our result also show increasing suddenly of oxygen isotope values of planktic, benthic and bulk carbonate sample from ± 12 Ma, the increasing cooled surface water relatively high degree with Late Miocene global cooling climate or we predict that due to closing of Indonesian Gateway.
Abstract: Plants are commonly known for its positive
correlation in reducing temperature. Since it can benefit buildings by
modifying the microclimate, it-s also believed capable of reducing
the internal temperature. Various experiments have been done in
Universiti Sains Malaysia, Penang to investigate the comparison in
thermal benefits between two rooms, one being a typical control
room (exposed wall) and the other a biofacade room (plant shaded
wall). The investigations were conducted during non-rainy season for
approximately a month. Climbing plant Psophocarpus
tetrogonobulus from legume species was selected as insulation for
the biofacade wall. Conclusions were made on whether the biofacade
can be used to tackle the energy efficiency, based on the parameters
taken into consideration.
Abstract: The complexity of lignocellulosic biomass requires
a pretreatment step to improve the yield of fermentable sugars. The
efficient pretreatment of corn cobs using microwave and potassium
hydroxide and enzymatic hydrolysis was investigated. The
objective of this work was to characterize the optimal condition of
pretreatment of corn cobs using microwave and potassium
hydroxide enhance enzymatic hydrolysis. Corn cobs were
submerged in different potassium hydroxide concentration at varies
temperature and resident time. The pretreated corn cobs were
hydrolyzed to produce the reducing sugar for analysis. The
morphology and microstructure of samples were investigated by
Thermal gravimetric analysis (TGA, scanning electron microscope
(SEM), X-ray diffraction (XRD). The results showed that lignin
and hemicellulose were removed by microwave/potassium
hydroxide pretreatment. The crystallinity of the pretreated corn
cobs was higher than the untreated. This method was compared
with autoclave and conventional heating method. The results
indicated that microwave-alkali treatment was an efficient way to
improve the enzymatic hydrolysis rate by increasing its
accessibility hydrolysis enzymes.
Abstract: The paper presents the results of research on trends in shaping of multifamily buildings in Poland on the example of Wrocław, after Polish accession to the European Union. The study is conducted within the research project: “Trends in creating of multifamily housing development since 2004, on the Wrocław study case" supported by Polish Ministry of Science and Higher Education and will be completed in November 2011. The research involves multifamily buildings completed in the last decade, in term of fundamental urbanization factors such as: building-s coefficient area, useable area, green area (biologically active surface), intensity of building development, amount of dwellings, dwelling area, amount of parking places, numbers of floors, etc. The analysis of these indicators was conducted based on the date obtained in the study of approximately one hundred new housing units, completed in Wroclaw. The analysis attempts to formulate the main trends in creating of housing policy in Poland during the last 10 years in reference to local urban policy.
Abstract: Polyurethanes (PURs) are very versatile polymeric
materials with a wide range of physical and chemical properties.
PURs have desirable properties such as high abrasion resistance, tear
strength, shock absorption, flexibility and elasticity. Although they
have relatively poor thermal stability, this can be improved by using
treated clay. Polyurethane/clay nanocomposites have been
synthesized from renewable sources. A polyol for the production of
polyurethane by reaction with an isocyanate was obtained by the
synthesis of palm oil-based oleic acid with glycerol. Dodecylbenzene
sulfonic acid (DBSA) was used as catalyst and emulsifier. The
unmodified clay (kunipia-F) was treated with cetyltrimethyl
ammonium bromide (CTAB-mont) and octadodecylamine (ODAmont).
The d-spacing in CTAB-mont and ODA-mont were 1.571 nm
and 1.798 nm respectively and larger than that of the pure-mont
(1.142 nm). The organoclay was completely intercalated in the
polyurethane, as confirmed by a wide angle x-ray diffraction
(WAXD) pattern.
The results showed that adding clay demonstrated better thermal
stability in comparison with the virgin polyurethane. Onset
degradation of pure PU is at 200oC, and is lower than that of the
CTAB-mont PU and ODA-mont PU which takes place at about
318oC and 330oC, respectively. The mechanical properties (including
the dynamic mechanical properties) of pure polyurethane (PU) and
PU/clay nanocomposites, were measured. The modified organoclay
had a remarkably beneficial effect on the strength and elongation at
break of the nanocomposites, which both increased with increasing
clay content with the increase of the tensile strength of more than
214% and 267% by the addition of only 5 wt% of the
montmorillonite CTAB-mont PU and ODA-mont PU, respectively.
Abstract: Low silica type X (LSX) Zeolite is one of useful
material in many manufacturing due to the advantage properties
including high surface area, stability, microporous crystalline
aluminosilicates and positive ion in an extra–framework. The LSX
was used rice husk silica source which obtained by leaching with
hydrochloric acid and calcination at 500 C. To improve the
synthesis method, the LSX was crystallizated in Teflon–lined
autoclave will expedite deceasing of the amorphous particles. The
mixed gel with composition of 5.5 Na2O : 1.65 K2O : Al2O3 : 2.2
SiO2 : 122 H2O was crystallized in different container
(Polypropylene bottom and Teflon–lined autoclave). The obtained
powder was characterized by X–ray diffraction (XRD), X–ray
fluorescence spectrometry, N2 adsorption-desorption analysis BET
surface area Scanning electron microscopy (SEM) and Fourier
transform infrared spectroscopy to justify the quality of zeolite. The
results showed the crystallized zeolite in Teflon lined autoclave has
102.8 nm of crystal size, 286 m2/g of surface area and fewer amounts
of round amorphous particles when compared with the crystallized
zeolite in Polypropylene.
Abstract: Novel Coconut oil nanofluids of various concentrations have been prepared through ultrasonically assisted sol-gel method. The structural and morphological properties of the copper oxide nanoparticle have been analyzed with respectively and it revealed the monoclinic end-centered structure of crystallite and shuttle like flake morphology of agglomerates. Ultrasonic studies have been made for the nanofluids at different temperatures. The molecular interactions responsible for the changes in acoustical parameter with respect to concentration and temperature are discussed.
Abstract: This paper reports on the results of experimental
investigations of flash evaporation from superheated jet issues
vertically upward from a round straight nozzle of 81.3 mm diameter.
For the investigated range of jet superheat degree and velocity, it was
shown that flash evaporation enhances with initial temperature
increase. Due to the increase of jet inertia and subsequently the delay
of jet shattering, increase of jet velocity was found to result in
increase of evaporation "delay period". An empirical equation
predicts the jet evaporation completion height was developed, this
equation is thought to be useful in designing the flash evaporation
chamber. In attempts for enhancement of flash evaporation, use of
steel wire mesh located at short distance downstream was found
effective with no consequent pressure drop.
Abstract: Field mapping activity for an active volcano mainly in
the Torrid Zone is usually hampered by several problems such as steep
terrain and bad atmosphere conditions. In this paper we present a
simple solution for such problem by a combination Synthetic Aperture
Radar (SAR) and geostatistical methods. By this combination, we
could reduce the speckle effect from the SAR data and then estimate
roughness distribution of the pyroclastic flow deposits. The main
purpose of this study is to detect spatial distribution of new pyroclastic
flow deposits termed as P-zone accurately using the β°data from two
RADARSAT-1 SAR level-0 data. Single scene of Hyperion data and
field observation were used for cross-validation of the SAR results.
Mt. Merapi in central Java, Indonesia, was chosen as a study site and
the eruptions in May-June 2006 were examined. The P-zones were
found in the western and southern flanks. The area size and the longest
flow distance were calculated as 2.3 km2 and 6.8 km, respectively. The
grain size variation of the P-zone was mapped in detail from fine to
coarse deposits regarding the C-band wavelength of 5.6 cm.
Abstract: Rockfall is a kind of irregular geological disaster. Its
destruction time, space and movements are highly random. The impact
force is determined by the way and velocity rocks move. The
movement velocity of a rockfall depends on slope gradient of its
moving paths, height, slope surface roughness and rock shapes. For
effectively mitigate and prevent disasters brought by rockfalls, it is
required to precisely calculate the moving paths of a rockfall so as to
provide the best protective design. This paper applies Colorado
Rockfall Simulation Program (CRSP) as our study tool to discuss the
impact of slope shape and surface roughness on the moving paths of a
single rockfall. The analytical results showed that the slope, m=1:1,
acted as the threshold for rockfall bounce height on a monoclinal slight
slope. When JRC ´╝£ 1.2, movement velocity reduced and bounce
height increased as JCR increased. If slope fixed and JRC increased,
the bounce height of rocks increased gradually with reducing
movement velocity. Therefore, the analysis on the moving paths of
rockfalls with CRSP could simulate bouncing of falling rocks. By
analyzing moving paths, velocity, and bounce height of falling rocks,
we could effectively locate impact points of falling rocks on a slope.
Such analysis can be served as a reference for future disaster
prevention and control.
Abstract: The kinetics of palm oil catalytic cracking over
aluminum containing mesoporous silica Al-MCM-41 (5% Al) was
investigated in a batch autoclave reactor at the temperatures range of
573 – 673 K. The catalyst was prepared by using sol-gel technique
and has been characterized by nitrogen adsorption and x-ray
diffraction methods. Surface area of 1276 m2/g with average pore
diameter of 2.54 nm and pore volume of 0.811 cm3/g was obtained.
The experimental catalytic cracking runs were conducted using 50 g
of oil and 1 g of catalyst. The reaction pressure was recorded at
different time intervals and the data were analyzed using Levenberg-
Marquardt (LM) algorithm using polymath software. The results
show that the reaction order was found to be -1.5 and activation
energy of 3200 J/gmol.
Abstract: In this study, production possibilities of hydrogen and/or methane via SCWG from black grape residues have been investigated. For this aim, grape residues which remain as a byproduct of the wine making process have been used. Since utilization from grape residues is limited due to the high moisture content, supercritical water gasification is the most convenient method. The effect of the gasification temperature and type of catalyst on supercritical water gasification have been investigated. Gasification experiments were performed in a batch autoclave at four different temperatures 300, 400, 500 and 600°C. K2CO3 and Trona (NaHCO3.Na2CO3·2H2O) were used as catalyst. Real biomass types of black grape residues have been successfully gasified and the product gas (hydrogen, methane, carbon dioxide, carbon monoxide and a small amount of ethane and ethylene) were identified by using gas chromatography. A TOC analyzer was used to determine total organic carbon (TOC) content of aqueous phase. The amounts of carboxylic acids, aldehydes, ketones, furfurals and phenols present in the aqueous solutions were analyzed by high performance liquid chromatography. When the temperature increased from 300°C to 600°C, mol% of H2 in gas products increased. The presence of catalysts improves the hydrogen yield. Trona showed gasification activity to be similar to that of K2CO3. It may be concluded that the use of Trona instead of commercially produced catalysts, can be preferably used in the gasification of biomass in supercritical water.
Abstract: This paper presents the visual control flow support of Visual Modeling and Transformation System (VMTS), which facilitates composing complex model transformations out of simple transformation steps and executing them. The VMTS Visual Control Flow Language (VCFL) uses stereotyped activity diagrams to specify control flow structures and OCL constraints to choose between different control flow branches. This work discusses the termination properties of VCFL and provides an algorithm to support the termination analysis of VCFL transformations.
Abstract: Open urban public spaces comprise an important
element for the development of social, cultural and economic
activities of the population in the modern cities. These spaces are also
considered regulators of the region-s climate conditions, providing
better thermal, visual and auditory conditions which can be optimized
by the application of appropriate strategies of bioclimatic design. The
paper focuses on the analysis and evaluation of the recent unification
of the open spaces in the centre of Xanthi, a medium – size city in
northern Greece, from a bioclimatic perspective, as well as in the
creation of suitable methodology. It is based both on qualitative
observation of the interventions by fieldwork research and
assessment and on quantitative analysis and modeling of the research
area.
Abstract: For sterilization of Phalaenopsis culture medium without autoclaving, selected single sterilizing agents and in combinations were added to a 25ml Hyponex medium in a 120ml glass container. Treated liquid and solid media, supplemented with sterilizing agents, were compared to a control medium, autoclaved at 121°C for 15min. It was found that 90(L of 10% povidone-iodine, 150(L of 5.25% sodium hypochlorite, 150(L of 2% mercurochrome, 90(L of 2.5% iodine + 2.5% potassium iodine in combination with 10% providone-iodine (1:3) and 30(L of 2.5% iodine + 2.5% potassium iodide in combination with 2% mercurochrome showed 100% sterile conditions in liquid medium but provided 75, 100, 50, 75 and 80% sterile conditions, respectively, in solid medium. For growth of Phalaenopsis protocorms, 90(L of 10% povidone-iodine in liquid Hyponex medium gave the comparable growth of protocorms to control medium while 150(L of 5.25% sodium hypochlorite in solid medium provided the promising growth of protocorms. Growth of protocorms, whole fresh weight, numbers of leaf and root, root length and number of protocorm-like bodies, was discussed.