Dielectric Studies on Nano Zirconium Dioxide Synthesized through Co-Precipitation Process
Nano sized zirconium dioxide in monoclinic phase (m-ZrO2) has been synthesized in pure form through co-precipitation processing at different calcination temperatures and has been characterized by several techniques such as XRD, FT-IR, UV-Vis Spectroscopy and SEM. The dielectric and capacitance values of the pelletized samples have been examined at room temperature as the functions of frequency. The higher dielectric constant value of the sample having larger grain size proves the strong influence of grain size on the dielectric constant.
[1] F. Kazemi, A. Saberi, S. Malek-Ahmadi, S. Sohrabi, H.R. Rezaie And M. Tahriri, "A novel method for synthesis of metastable Tetragonal zirconia nanopowders at low temperatures", Ceramics - Silikáty , vol.55, no. 1, pp. 26-30, Jan. 2011
[2] A.U. Limaye, J.J. Helble, "Secondary atomization as a mechanism for
controlling the size of ceramic nanoparticles produced by combustion
aerosol synthesis", J. Aerosol Sci., vol.35,no.5, pp. 599, May. 2004.
[3] G. Cao, Nanostructures and Nanomaterials: Synthesis, Properties and
Applications. London: Imperial College Press, 2004, . pp. 47-75.
[4] M.J. Mayo, J.R. Seidensticker, D.C. Hague, A.H. Carim, " Surface
chemistry effects on the processing and superplastic properties of
nanocrystalline oxide ceramics", Nanostruct. Mater., vol. 11, no. 2, pp.
271-282, March 1999.
[5] T. Chraska, A.H. King, C.C. Berndt, "On the size-dependent phase
transformation in nanoparticulate zirconia", Mater. Sci. Eng. A., vol.
286, pp. 169 -178, 2000.
[6] M. Gell, "Application Opputunities for Nanostructured Materials and Coatings", Mater. Sci. Eng. A,vol. 204, no. 1,2. pp. 246- 251
[7] H. Gleiter, "Materials with ultrafine microstructures: Retrospectives and
perspectives", Nanostruct. Mater., vol., no. 1, pp. 1-19, Jan. 1992.
[8] D. S. Bae, E. J. Kim, S. W. Park and K. S. Han., "Synthesis and
characterization of nanosized ZnxMn1-xFe2O4 powders by glycothermal process, J. Mater sci foru, vol. 486, pp. 436-439, 2005.
[9] M.M. Rashad, H.M. Baioumy, "Effect of thermal treatment on the
crystal structure and morphology of zirconia nanopowders produced by
three different routes", J. Mater. Process. Tech., vol. 195, pp. 178-185,
2008.
[10] Gong-Yi Guo, Yu-Li Chen, " Nearly pure monoclinic nanocrystalline
zirconia", J. Solid State Chem., vol. 178, pp. 1675-1682 2005.
[11] D.G. Lamas, A.M. Rosso, M. S.Anzorena, A. Fernandez, M.G. Bellino,
M.D. Cabezas, N.E. Walso¨e de Reca and A.F. Craievich, "Crystal
structure of pure ZrO2 nanopowders", Scripta Materialia, vol. 55, pp.
553-556, May 2006.
[12] F. Kazemi, F. Arianpour, S. Malek-Ahmadi, S. Sohrabi, H.R. Rezaie, A.
Saberi, "A novel method for synthesis of metastable tetragonal zirconia
nano powder at low temperatures", Materials Research Bulletin,
doi:10.1016/j.materresbull.2011.06.010, June, 2011.
[13] T.Prabhakaran, J.Hemalatha, "Combustion synthesis and
characterization of highly crystalline single phase nickel ferrite
nanoparticles", J. Alloys. Comp., vol. 509, no.25, pp. 7071-7077, June
2011.
[14] H.P. Klug, L.E. Alexander, X-ray Diffraction Procedure, New York:
Wiley Inter Science, 1954, pp. 504.
[15] M. Picquart, T. López, R. Gómez, E. Torres, A. Moreno and J. Garcia,
"Dehydration And Crystallization Process In Sol-Gel Zirconia Thermal
and spectroscopic study", Journal of Thermal Analysis and
Calorimetry, Vol. 76, pp. 755
[16] H. R. Sahu and G. R. Rao, "Characterization of combustion synthesized
zirconia powder by UV-vis, IR and other techniques", Bull. Mater. Sci.,
Vol. 23, no. 5, pp. 349-354, October 2000.
[17] A. Powers and H. B. Gray, "Characterization of the thermal dehydration
of zirconium oxide halide octahydrates", Inorg. Chem., vol. 12, no. 11,
pp. 2721-2726, Nov. 1973.
[18] S. F. Wang, F. Gu, M. K. Lu, Z. S.Yang, G. J. Zhou, H. P. Zhang, Y.
Y. Zhou, S. M. Wang, "Structure evolution and photoluminescence
properties of ZrO2:Eu3+ nanocrystals", Opt. Mater., vol. 28, no. 10, pp.
1222 - 1226, July 2006.
[19] V. S. R. Channua, R. R. Kallurub, M. Schlesin, "Synthesis and
characterization of ZrO2 nanoparticles for optical and electrochemical
applications', Colloids and Surfaces A: Physicochem. Eng. Aspects, vol.
386, pp. 151-157, 2011.
[20] X. S. Fang, C. H Ye, T. Xie, Z.Y. Wong, J.W. Zhao and L.D. Zhang, "
Regular MgO nanoflowers and their enhanced dielectric responses,
Appl. Phys. Lett., vol. 88, pp. 013101 - 013103, Jan.2006.
[1] F. Kazemi, A. Saberi, S. Malek-Ahmadi, S. Sohrabi, H.R. Rezaie And M. Tahriri, "A novel method for synthesis of metastable Tetragonal zirconia nanopowders at low temperatures", Ceramics - Silikáty , vol.55, no. 1, pp. 26-30, Jan. 2011
[2] A.U. Limaye, J.J. Helble, "Secondary atomization as a mechanism for
controlling the size of ceramic nanoparticles produced by combustion
aerosol synthesis", J. Aerosol Sci., vol.35,no.5, pp. 599, May. 2004.
[3] G. Cao, Nanostructures and Nanomaterials: Synthesis, Properties and
Applications. London: Imperial College Press, 2004, . pp. 47-75.
[4] M.J. Mayo, J.R. Seidensticker, D.C. Hague, A.H. Carim, " Surface
chemistry effects on the processing and superplastic properties of
nanocrystalline oxide ceramics", Nanostruct. Mater., vol. 11, no. 2, pp.
271-282, March 1999.
[5] T. Chraska, A.H. King, C.C. Berndt, "On the size-dependent phase
transformation in nanoparticulate zirconia", Mater. Sci. Eng. A., vol.
286, pp. 169 -178, 2000.
[6] M. Gell, "Application Opputunities for Nanostructured Materials and Coatings", Mater. Sci. Eng. A,vol. 204, no. 1,2. pp. 246- 251
[7] H. Gleiter, "Materials with ultrafine microstructures: Retrospectives and
perspectives", Nanostruct. Mater., vol., no. 1, pp. 1-19, Jan. 1992.
[8] D. S. Bae, E. J. Kim, S. W. Park and K. S. Han., "Synthesis and
characterization of nanosized ZnxMn1-xFe2O4 powders by glycothermal process, J. Mater sci foru, vol. 486, pp. 436-439, 2005.
[9] M.M. Rashad, H.M. Baioumy, "Effect of thermal treatment on the
crystal structure and morphology of zirconia nanopowders produced by
three different routes", J. Mater. Process. Tech., vol. 195, pp. 178-185,
2008.
[10] Gong-Yi Guo, Yu-Li Chen, " Nearly pure monoclinic nanocrystalline
zirconia", J. Solid State Chem., vol. 178, pp. 1675-1682 2005.
[11] D.G. Lamas, A.M. Rosso, M. S.Anzorena, A. Fernandez, M.G. Bellino,
M.D. Cabezas, N.E. Walso¨e de Reca and A.F. Craievich, "Crystal
structure of pure ZrO2 nanopowders", Scripta Materialia, vol. 55, pp.
553-556, May 2006.
[12] F. Kazemi, F. Arianpour, S. Malek-Ahmadi, S. Sohrabi, H.R. Rezaie, A.
Saberi, "A novel method for synthesis of metastable tetragonal zirconia
nano powder at low temperatures", Materials Research Bulletin,
doi:10.1016/j.materresbull.2011.06.010, June, 2011.
[13] T.Prabhakaran, J.Hemalatha, "Combustion synthesis and
characterization of highly crystalline single phase nickel ferrite
nanoparticles", J. Alloys. Comp., vol. 509, no.25, pp. 7071-7077, June
2011.
[14] H.P. Klug, L.E. Alexander, X-ray Diffraction Procedure, New York:
Wiley Inter Science, 1954, pp. 504.
[15] M. Picquart, T. López, R. Gómez, E. Torres, A. Moreno and J. Garcia,
"Dehydration And Crystallization Process In Sol-Gel Zirconia Thermal
and spectroscopic study", Journal of Thermal Analysis and
Calorimetry, Vol. 76, pp. 755
[16] H. R. Sahu and G. R. Rao, "Characterization of combustion synthesized
zirconia powder by UV-vis, IR and other techniques", Bull. Mater. Sci.,
Vol. 23, no. 5, pp. 349-354, October 2000.
[17] A. Powers and H. B. Gray, "Characterization of the thermal dehydration
of zirconium oxide halide octahydrates", Inorg. Chem., vol. 12, no. 11,
pp. 2721-2726, Nov. 1973.
[18] S. F. Wang, F. Gu, M. K. Lu, Z. S.Yang, G. J. Zhou, H. P. Zhang, Y.
Y. Zhou, S. M. Wang, "Structure evolution and photoluminescence
properties of ZrO2:Eu3+ nanocrystals", Opt. Mater., vol. 28, no. 10, pp.
1222 - 1226, July 2006.
[19] V. S. R. Channua, R. R. Kallurub, M. Schlesin, "Synthesis and
characterization of ZrO2 nanoparticles for optical and electrochemical
applications', Colloids and Surfaces A: Physicochem. Eng. Aspects, vol.
386, pp. 151-157, 2011.
[20] X. S. Fang, C. H Ye, T. Xie, Z.Y. Wong, J.W. Zhao and L.D. Zhang, "
Regular MgO nanoflowers and their enhanced dielectric responses,
Appl. Phys. Lett., vol. 88, pp. 013101 - 013103, Jan.2006.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:56888", author = "K. Geethalakshmi and T. Prabhakaran and J. Hemalatha", title = "Dielectric Studies on Nano Zirconium Dioxide Synthesized through Co-Precipitation Process", abstract = "Nano sized zirconium dioxide in monoclinic phase (m-ZrO2) has been synthesized in pure form through co-precipitation processing at different calcination temperatures and has been characterized by several techniques such as XRD, FT-IR, UV-Vis Spectroscopy and SEM. The dielectric and capacitance values of the pelletized samples have been examined at room temperature as the functions of frequency. The higher dielectric constant value of the sample having larger grain size proves the strong influence of grain size on the dielectric constant.
", keywords = "capacitance, dielectric constant, m-ZrO2, nano
zirconia", volume = "6", number = "4", pages = "319-4", }
