Abstract: Geophagic and cosmetic clays are among potential nanomaterial which occur naturally and are of various forms. The use of these nanoclays is a common practice in both rural and urban areas mostly due to tradition and medicinal reasons. These naturally occurring materials can be valuable sources of nanomaterial by serving as nanocomposites. The need to ascertain the safety of these materials is the motivation for this research. Physical Characterization based on the hue value and microbiological qualities of the nanoclays were carried out. The Microbial analysis of the clay samples showed considerable contamination with both bacteria and fungi with fungal contaminants taking the lead. This observation may not be unlikely due to the ability of fungi species to survive harsher growth conditions than bacteria. ‘Atike pupa’ showed no bacterial growth. The clay with the largest bacterial count was Calabash chalk (Igbanke), while that with the highest fungal count was ‘Eko grey’. The most commonly isolated bacteria in this study were Clostridium spp. and Corynebacterium spp. while fungi included Aspergillus spp. These results are an indication of the need to subject these clay materials to treatments such as heating before consumption or topical usage thereby ascertaining their safety.
Abstract: It is the aim of this paper to place the role of innovation in economic development in its theoretical context through a literature review. The review compares classical economic theory and the neoclassical theories of “equilibrium in the markets” and “perfectly competitive markets” with the Schumpeterian theory. It was found that Schumpeter’s role in contributing towards economic development theories, and by creating awareness of the role of innovation in these theories is of immeasurable importance. His contribution led to a change in economic thinking, although this was only realized much later than when his theories were first published. The neo-Schumpeterian thinking expanded on the Schumpeterian theory by studying innovation within a system of interaction among different role players. Studies on innovation should be founded in the neo-Schumpeterian school of thought in order to accommodate the complexity of the innovation system concept.
Abstract: This work assessed some properties of three pedons on a toposequence in Ijah-Gbagyi district in Niger State, Nigeria. The pedons were designated as JG1, JG2 and JG3 representing the upper, middle and lower slopes respectively. The surface soil was characterized by dark yellowish brown (10YR3/4) color at the JG1 and JG2 and very dark grayish brown (10YR3/2) color at JG3. Sand dominated the mineral fraction and its content in the surface horizon decreased down the slope, whereas silt content increased down the slope due to sorting by geological and pedogenic processes. Although organic carbon (OC), total nitrogen (TN) and available phosphorus (P) were rated high, TN and available P decreased down the slope. High cation exchange capacity (CEC) was an indication that the soils have high potential for plant nutrients retention. The pedons were classified as Typic Haplustepts/ Haplic Cambisols (Eutric), Plinthic Petraquepts/ Petric Plinthosols (Abruptic) and Typic Endoaquepts/ Endogleyic Cambisols (Endoclayic).
Abstract: Paleoclimate was reconstructed by the clay mineral
assemblages of shale units of Pabdeh (Paleocene- Oligocene), Gurpi
(Upper Cretaceous), Kazhdumi (Albian-Cenomanian) and Gadvan
(Aptian-Neocomian) formations in the Bangestan anticline. To
compare with clay minerals assemblages in these formations,
selected samples also taken from available formations in drilled wells
in Ahvaz, Marun, Karanj, and Parsi oil fields. Collected samples
prepared using standard clay mineral methodology. They were
treated as normal, glycolated and heated oriented glass slides. Their
identification was made on X-Ray diffractographs. Illite % varies
from 8 to 36. Illite quantity increased from Pabdeh to Gurpi
Formation. This may be due to dominant dry climate. Kaolinite is in
range of 12-49%. Its variation style in different formations could be a
marker of climate changes from wet to dry which is supported by the
lithological changes. Chlorite (4-28%) can also be detected in those
samples without any kaolinite. Mixed layer minerals as the mixture
of illite-chlorite and illite-vermiculite-montmorillonite are varied
from 6 to 36%, decreased during Kazhdumi deposition from the base
to the top. This result may be according to decreasing of illite
leaching process. Vermiculite was also determined in very less
quantity and found in those units without kaolinite. Montmorillonite
varies from 8 to 43%, and its presence is due to terrestrial
depositional condition. Stratigraphical documents is also supported
this idea that clay mineral distribution is a function of the climate
changes. It seems, thus, the present results can be indicated a possible
procedure for ancient climate changes evaluation.
Abstract: When dealing with safety in structures, the connections between structural components play an important role. Robustness of a structure as a whole depends both on the load- bearing capacity of the structural component and on the structures capacity to resist total failure, even though a local failure occurs in a component or a connection between components. To avoid progressive collapse it is necessary to be able to carry out a design for connections. A connection may be executed with anchors to withstand local failure of the connection in structures built with prefabricated components. For the design of these anchors, a model is developed for connections in structures performed in prefabricated autoclaved aerated concrete components. The design model takes into account the effect of anchors placed close to the edge, which may result in splitting failure. Further the model is developed to consider the effect of reinforcement diameter and anchor depth. The model is analytical and theoretically derived assuming a static equilibrium stress distribution along the anchor. The theory is compared to laboratory test, including the relevant parameters and the model is refined and theoretically argued analyzing the observed test results. The method presented can be used to improve safety in structures or even optimize the design of the connections
Abstract: The direct synthesis process of dimethyl ether (DME)
from syngas in slurry reactors is considered to be promising because
of its advantages in caloric transfer. In this paper, the influences of
operating conditions (temperature, pressure and weight hourly space
velocity) on the conversion of CO, selectivity of DME and methanol
were studied in a stirred autoclave over Cu-Zn-Al-Zr slurry catalyst,
which is far more suitable to liquid phase dimethyl ether synthesis
process than bifunctional catalyst commercially. A Langmuir-
Hinshelwood mechanism type global kinetics model for liquid phase
DME direct synthesis based on methanol synthesis models and a
methanol dehydration model has been investigated by fitting our
experimental data. The model parameters were estimated with
MATLAB program based on general Genetic Algorithms and
Levenberg-Marquardt method, which is suitably fitting experimental
data and its reliability was verified by statistical test and residual
error analysis.
Abstract: Microbial-induced calcite precipitation (MICP) is a
relatively green and sustainable soil improvement technique. It
utilizes biochemical process that exists naturally in soil to improve
engineering properties of soils. The calcite precipitation process is
uplifted by the mean of injecting higher concentration of urease
positive bacteria and reagents into the soil. The main objective of this
paper is to provide an overview of the factors affecting the MICP in
soil. Several factors were identified including nutrients, bacteria type,
geometric compatibility of bacteria, bacteria cell concentration,
fixation and distribution of bacteria in soil, temperature, reagents
concentration, pH, and injection method. These factors were found to
be essential for promoting successful MICP soil treatment.
Furthermore, a preliminary laboratory test was carried out to
investigate the potential application of the technique in improving the
shear strength and impermeability of a residual soil specimen. The
results showed that both shear strength and impermeability of
residual soil improved significantly upon MICP treatment. The
improvement increased with increasing soil density.
Abstract: Zirconium diamine and triamine complexes can possess biological activities. These complexes were synthesised via the reaction of equimolar quantities of 1,10-phenanthroline {NC3H3(C6H2)NC3H3} (L1) or 4-4-amino phenazone {ONC6H5(NH)CH(NH2} (L2) or diphenyl carbizon {HNNCO(NH)2(C6H5)} (L3) with a Zirconium Salt {ZrOCl2} in a 1:1 ratio to form complexes [{NC3H3(C6H2)NC3H3}ZrOCl2}] [ZrOCl2L1], [{(O2NC6H4(NH)(NH2)}ZrOCl2] [ZrOCl2L2] and [{HNNCO(NH)2(C6H5)ZrOCl2}] [ZrOCl2L3] respectively. They were characterised using Fourier Transform Infrared (FT-IR) and UV-Visible spectroscopy. Also a variable temperature study of these complexes was completed, using UV-Visible spectroscopy to observe electronic transitions under temperature control. Also a DFT study was done on these complexes via the information from FT-IR and UV-Visible spectroscopy.
These complexes were found to show different inhibition to the growth of bacterial strains of Bacillus spp. & Klebsiella spp. & E. coli & Proteus spp. & Pseudomona spp. at different concentrations (0.001, 0.2 and 1M). For better understanding these complexes were examined by using a Density Functional Theory (DFT) calculation.
Abstract: Ice cover County has a significant impact on rivers as it affects with the ice melting capacity which results in flooding, restrict navigation, modify the ecosystem and microclimate. River ices are made up of different ice types with varying ice thickness, so surveillance of river ice plays an important role. River ice types are captured using infrared imaging camera which captures the images even during the night times. In this paper the river ice infrared texture images are analysed using first-order statistical methods and secondorder statistical methods. The second order statistical methods considered are spatial gray level dependence method, gray level run length method and gray level difference method. The performance of the feature extraction methods are evaluated by using Probabilistic Neural Network classifier and it is found that the first-order statistical method and second-order statistical method yields low accuracy. So the features extracted from the first-order statistical method and second-order statistical method are combined and it is observed that the result of these combined features (First order statistical method + gray level run length method) provides higher accuracy when compared with the features from the first-order statistical method and second-order statistical method alone.
Abstract: The alternative technique for sterilization of culture
medium to replace autoclaving was carried out. For sterilization of
culture medium without autoclaving, some commercial pure essential
oils, bergamot oil, betel oil, cinnamon oil, lavender oil and turmeric
oil, were tested alone or in combinations with some disinfectants,
10% povidone-iodine and 2% iodine + 2.4% potassium iodide. Each
essential oil or combination was added to 25-mL Murashige and
Skoog (MS) medium before medium was solidified in a 120-mL
container, kept for 2 weeks before evaluating sterile conditions.
Treated media, supplemented with essential oils, were compared to
control medium, autoclaved at 121 degree Celsius for 15 min. In
vitro sterile conditions were found 20 – 100% from these treated
media compared to 100% sterile condition from autoclaved medium.
Treated media obtained 100% sterile conditions were chosen for
culturing chrysanthemum shoots. It was found that 10% povidoneiodine
in combination with cinnamon oil (3:1) and 2% iodine + 2.4%
potassium iodide in combination with lavender oil (1:3) at the
concentration of 36 3L/25 mL medium provided the promising
growth of shoot explants.
Abstract: Optical Coherence Tomography (OCT) combined
with the Confocal Microscopy, as a noninvasive method, permits the
determinations of materials defects in the ceramic layers depth. For
this study 256 anterior and posterior metal and integral ceramic fixed
partial dentures were used, made with Empress (Ivoclar), Wollceram
and CAD/CAM (Wieland) technology. For each investigate area 350
slices were obtain and a 3D reconstruction was perform from each
stuck. The Optical Coherent Tomography, as a noninvasive method,
can be used as a control technique in integral ceramic technology,
before placing those fixed partial dentures in the oral cavity. The
purpose of this study is to evaluate the capability of En face Optical
Coherence Tomography (OCT) combined with a fluorescent method
in detection and analysis of possible material defects in metalceramic
and integral ceramic fixed partial dentures. As a conclusion,
it is important to have a non invasive method to investigate fixed
partial prostheses before their insertion in the oral cavity in order to
satisfy the high stress requirements and the esthetic function.
Abstract: Both prognostic and diagnostic modes of a 3D baroclinic
model in hydrodynamic and sediment transport models of
the Princeton Ocean Model (POM) were conducted to separate
prognose and diagnose effects of different hydrodynamic factors on
transport of suspended sediment discharged from the rivers to the
Gulf of Thailand (GoT). Both transport modes of suspended sediment
distribution in the GoT were numerically simulated. It could be
concluded that the suspended sediment discharged from the rivers
around the GoT. Most of sediments in estuaries and coastal areas are
deposited outside the GoT under the condition of wind-driven current,
and very small amount of the sediments of them are transported
faraway. On the basis of wind forcing, sediments from the lower
GoT to the upper GoT are mainly transported south-northwestward
and also continuously moved north-southwestward. An obvious 3D
characteristic of suspended sediment transport is produced in the
wind-driven current residual circulation condition. In this study, the
transport patterns at the third layer are generally consistent with
the typhoon-induced strong currents in two case studies of Typhoon
Linda 1997. The case studies presented the prognostic and diagnostic
modes during 00UTC28OCT1997 to 12UTC06NOV1997 in a short
period with the current condition for pre-operation of the suspended
sediment transport model in estuaries and coastal areas.
Abstract: In this paper, the generalized (2+1)-dimensional Calogero-Bogoyavlenskii-Schiff (shortly CBS) equations are investigated. We employ the Hirota-s bilinear method to obtain the bilinear form of CBS equations. Then by the idea of extended homoclinic test approach (shortly EHTA), some exact soliton solutions including breather type solutions are presented.
Abstract: The construction of a civil structure inside a urban
area inevitably modifies the outdoor microclimate at the building
site. Wind speed, wind direction, air pollution, driving rain, radiation
and daylight are some of the main physical aspects that are subjected
to the major changes. The quantitative amount of these modifications
depends on the shape, size and orientation of the building and on its
interaction with the surrounding environment.The flow field over a
flat roof model building has been numerically investigated in order to
determine two-dimensional CFD guidelines for the calculation of the
turbulent flow over a structure immersed in an atmospheric boundary
layer. To this purpose, a complete validation campaign has been
performed through a systematic comparison of numerical simulations
with wind tunnel experimental data.Several turbulence models and
spatial node distributions have been tested for five different vertical
positions, respectively from the upstream leading edge to the
downstream bottom edge of the analyzed model. Flow field
characteristics in the neighborhood of the building model have been
numerically investigated, allowing a quantification of the capabilities
of the CFD code to predict the flow separation and the extension of
the recirculation regions.The proposed calculations have allowed the
development of a preliminary procedure to be used as a guidance in
selecting the appropriate grid configuration and corresponding
turbulence model for the prediction of the flow field over a twodimensional
roof architecture dominated by flow separation.
Abstract: Agricultural waste is mainly composed of cellulose
and hemicelluloses which can be converted to sugars. The
inexpensive reducing sugar from durian peel was obtained by
hydrolysis with HCl concentration at 0.5-2.0% (v/v). The hydrolysis
range of time was for 15-60 min when the mixture was autoclaved at
121 °C. The result showed that acid hydrolysis efficiency (AHE)
highest to 80.99% at condition is 2.0%concentration for 15 min.
Reducing sugar highest to 56.07 g/litre at condition is 2.0%
concentration for 45min. Total sugar highest to 59.83 g/litre at
condition is 2.0%concentration for 45min, which was not significant
(p < 0.05) with condition 2.0% concentration for 30 min and 1.5 %
concentration for 45 and 60 min. The increase in concentration
increased AHE, reducing sugar and total sugar. The hydrolysis time
had no effect on AHE, reducing sugar and total sugar. The maximum
reducing sugars of each concentration were at hydrolysis time 45
min .The hydrolysated were analysis by HPLC, the results revealed
that the principle of sugar were glucose, fructose and xylose.
Abstract: The environmental performance of rapeseed oil (RO)
and rapeseed methyl ester(RME) from winter rape as fuels produced
in Romanian agroclimate is analyzed in this paper. The proposed
methodology is life cycle assessment (LCA) and takes into
consideration the influence of grain production and agroclimatic
conditions. This study shows favorable results first for RO and then
for RME. When compared to diesel fuel, both studied biofuels show
better results in the following impact categories: Abiotic depletion
potential (ADP), Ozone layer depletion (ODP) and Photochemical
ozone creation potential (POCP).Furthermore, the environmental
performance of the two biofuels studied can be improved by
changing the type of fertilizer used and also by using biofuels instead
of diesel in the field works.
Abstract: Plant tissue culture is an important in vitro technology applied for agricultural and industrial production. A sterile condition of culture medium is one of the main aspects. The alternative technique for medium sterilization to replace autoclaving was carried out. For sterilization of plant tissue culture medium without autoclaving, ten commercial pure essential oils and 5 disinfectants were tested. Each essential oil or disinfectant was added to a 20-mL Murashige and Skoog (MS) medium before medium was solidified in a 120-mL container, kept for 2 weeks before evaluating sterile conditions. Treated media, supplemented with essential oils or disinfectants, were compared to control medium, autoclaved at 121 degree Celsius for 15 min. Sterile conditions of MS medium were found 100% from betel oil or clove oil (18 mL/20 mL medium), cinnamon oil (36 mL/20 mL medium), lavender oil or holy basil oil (108 mL/20 mL medium), and lemon oil or tea tree oil or turmeric oil (252 mL/20 mL medium), compared to 100% sterile condition from autoclaved medium. For disinfectants, 2% iodine + 2.4% potassium iodide, 2% merbromine solution, 10% povidone-iodine, 6% sodium hypochlorite or 0.1% thimerosal at 36 mL/20 mL medium provided 100% sterile conditions. Furthermore, growth of new shoots from chrysanthemum node explants on treated media (fresh weight, shoot length, root length and number of node) were also reported and discussed in the comparison of those on autoclaved medium.
Abstract: The charnockitic and associated granitic rocks of Akure area were studied for their field and petrographic relationship's. The outcrops locations were plotted in Surfer 8. The granitic rock exhibits a porphyritic texture and outcrops in the north-eastern side of the study area while the charnockitics outcrop in the central/western part. An essentially dark coloured and fine grained intrusive exhibiting xenoliths and xenocrysts (plagioclase phenocrysts) of the granite outcrops between the granitic and charnockitic rocks. Mineralogically, the central rock combines the content of the other two indicating that it is most likely a product of their hybridization. The charnockitic magma is believed to have intruded and assimilated the granite substantially thereby contaminating itself and consequently emplacing the hybrid. The presented model of emplacement elucidates the hybridization proposal. Conclusively, the charnockitics are believed to be (a) younger than the granite, (b) of Pan-African age and (c) of igneous origin.
Abstract: Neoclassical and functionalist explanations of self
organization in multiagent systems have been criticized on several accounts including unrealistic explication of overadapted agents and
failure to resolve problems of externality. The paper outlines a more
elaborate and dynamic model that is capable of resolving these dilemmas. An illustrative example where behavioral diversity is
cobred in a repeated nonzero sum task via evolutionary computing is
presented.
Abstract: Rice husk is a lignocellulosic source that can be
converted to ethanol. Three hundreds grams of rice husk was mixed
with 1 L of 0.18 N sulfuric acid solutions then was heated in an
autoclave. The reaction was expected to be at constant temperature
(isothermal), but before that temperature was achieved, reaction has
occurred. The first liquid sample was taken at temperature of 140 0C
and repeated every 5 minute interval. So the data obtained are in the
regions of non-isothermal and isothermal. It was observed that the
degradation has significant effects on the ethanol production. The
kinetic constants can be expressed by Arrhenius equation with the
frequency factors for hydrolysis and sugar degradation of 1.58 x 105
1/min and 2.29 x 108 L/mole/min, respectively, while the activation
energies are 64,350 J/mole and 76,571 J/mole. The highest ethanol
concentration from fermentation is 1.13% v/v, attained at 220 0C.