Abstract: In this research the level of mercury is analyzed in
muscle tissue of Otolithes ruber retailed in Hamedan, Iran were
determined by flame atomic absorption spectrometry after wet
digestion. Analysis of mercury was carried out by
spectrophotometrically. The average concentration of Hg in muscle
tissue of Otolithes ruber was 0.030±0.026 -g/g so lower than to
compare with the Maximum Allowable Concentration determined by
FAO/WHO Codex Alimentarius Commission.
Abstract: Inorganic nanoparticles filled polymer composites
have extended their multiple functionalities to various applications,
including mechanical reinforcement, gas barrier, dimensional
stability, heat distortion temperature, flame-retardant, and thermal
conductivity. Sodium stearate-modified calcium carbonate (CaCO3)
nanoparticles were prepared using surface modification method. The
results showed that sodium stearate attached to the surface of CaCO3
nanoparticles with the chemical bond. The effect of modified CaCO3
nanoparticles on thermal properties of polypropylene (PP) was
studied by means of differential scanning calorimetry (DSC) and
Thermogravimetric analysis (TGA). It was found that CaCO3
significantly affected the crystallization temperature and
crystallization degree of PP. Effect of the modified CaCO3 content on
mechanical properties of PP/CaCO3 nanocomposites was also
studied. The results showed that the modified CaCO3 can effectively
improve the mechanical properties of PP. In comparison with PP, the
impact strength of PP/CaCO3 nanocomposites increased by about
65% and the hardness increased by about 5%.
Abstract: The aim of this research is to evaluate surface
roughness and develop a multiple regression model for surface roughness as a function of cutting parameters during the turning of
flame hardened medium carbon steel with TiN-Al2O3-TiCN coated inserts. An experimental plan of work and signal-to-noise ratio (S/N)
were used to relate the influence of turning parameters to the
workpiece surface finish utilizing Taguchi methodology. The effects
of turning parameters were studied by using the analysis of variance (ANOVA) method. Evaluated parameters were feed, cutting speed,
and depth of cut. It was found that the most significant interaction among the considered turning parameters was between depth of cut and feed. The average surface roughness (Ra) resulted by TiN-Al2O3-
TiCN coated inserts was about 2.44 μm and minimum value was 0.74 μm. In addition, the regression model was able to predict values for surface roughness in comparison with experimental values within
reasonable limit.
Abstract: The mixture formation prior to the ignition process
plays as a key element in the diesel combustion. Parametric studies of
mixture formation and ignition process in various injection parameter
has received considerable attention in potential for reducing
emissions. Purpose of this study is to clarify the effects of injection
pressure on mixture formation and ignition especially during ignition
delay period, which have to be significantly influences throughout the
combustion process and exhaust emissions. This study investigated
the effects of injection pressure on diesel combustion fundamentally
using rapid compression machine. The detail behavior of mixture
formation during ignition delay period was investigated using the
schlieren photography system with a high speed camera. This method
can capture spray evaporation, spray interference, mixture formation
and flame development clearly with real images. Ignition process and
flame development were investigated by direct photography method
using a light sensitive high-speed color digital video camera. The
injection pressure and air motion are important variable that strongly
affect to the fuel evaporation, endothermic and prolysis process
during ignition delay. An increased injection pressure makes spray tip
penetration longer and promotes a greater amount of fuel-air mixing
occurs during ignition delay. A greater quantity of fuel prepared
during ignition delay period thus predominantly promotes more rapid
heat release.
Abstract: Combustion of sprays is of technological importance, but its flame behavior is not fully understood. Furthermore, the multiplicity of dependent variables such as pressure, temperature, equivalence ratio, and droplet sizes complicates the study of spray combustion. Fundamental study on the influence of the presence of liquid droplets has revealed that laminar flames within aerosol mixtures more readily become unstable than for gaseous ones and this increases the practical burning rate. However, fundamental studies on turbulent flames of aerosol mixtures are limited particularly those under near mono-dispersed droplet conditions. In the present work, centrally ignited expanding flames at near atmospheric pressures are employed to quantify the burning rates in gaseous and aerosol flames. Iso-octane-air aerosols are generated by expansion of the gaseous pre-mixture to produce a homogeneously distributed suspension of fuel droplets. The effects of the presence of droplets and turbulence velocity in relation to the burning rates of the flame are also investigated.
Abstract: In this paper, an automated algorithm to estimate and remove the continuous baseline from measured spectra containing both continuous and discontinuous bands is proposed. The algorithm uses previous information contained in a Continuous Database Spectra (CDBS) to obtain a linear basis, with minimum number of sampled vectors, capable of representing a continuous baseline. The proposed algorithm was tested by using a CDBS of flame spectra where Principal Components Analysis and Non-negative Matrix Factorization were used to obtain linear bases. Thus, the radical emissions of natural gas, oil and bio-oil flames spectra at different combustion conditions were obtained. In order to validate the performance in the baseline estimation process, the Goodness-of-fit Coefficient and the Root Mean-squared Error quality metrics were evaluated between the estimated and the real spectra in absence of discontinuous emission. The achieved results make the proposed method a key element in the development of automatic monitoring processes strategies involving discontinuous spectral bands.
Abstract: Fire disaster is the major factor to endanger the public
and environmental safety. People lost their life during fire disaster
mainly be attributed to the dense smoke and toxic gas under
combustion, which hinder the escape of people and the rescue of
firefighters under fire disaster. The smoke suppression effect of
several transitional metals oxide on the epoxy resin treated with
intumescent flame retardant and titanate couple agent
(EP/IFR/Titanate) system have been investigated. The results showed
manganese dioxide has great effect on reducing the smoke density rate
(SDR) of EP/IFR/Titanate system; however it has little effect to reduce
the maximum smoke density (MSD) of EP/IFR/Titanate system.
Copper oxide can decrease the maximum smoke density (MSD) and
smoke density rate of EP/IFR/Titanate system substantially. The MSD
and SDR of EP/IFR/Titanate system can reduce 20.3% and 39.1%
respectively when 2% of copper oxide is introduced.
Abstract: Zinc borates can be used as multi-functional
synergistic additives with flame retardant additives in polymers. Zinc
borate is white, non-hygroscopic and powder type product. The most
important properties are low solubility in water and high dehydration
temperature. Zinc borates dehydrate above 290°C and anhydrous zinc
borate has thermal resistance about 400°C. Zinc borates can be
synthesized using several methods such as hydrothermal and solidstate
processes. In this study, the solid-state method was applied at
low temperatures of 600oC and 700oC using the starting materials of
ZnO and H3BO3 with several mole ratios. The reaction time was
determined as 4 hours after some preliminary experiments. After the
synthesis, the crystal structure and the morphology of the products
were examined by X-Ray Diffraction (XRD) and Fourier Transform
Infrared Spectroscopy (FT-IR). As a result the forms of ZnB4O7,
Zn3(BO3)2, ZnB2O4 were synthesized and obtained along with the
unreacted ZnO.
Abstract: Present study focuses on studying the oscillatory
behavior of jet diffusion flames. At a particular jet exit velocity, the
flames are seen to exhibit natural flickering. Initially the flickering
process is not continuous. In this transition region as well as in the
continuous flickering regime, the flickering displays multiple
frequency oscillations. The response of the flame to the exit velocity
profile of the burner is also studied using three types of burners. The
entire range of natural flickering is investigated by capturing high
speed digital images and processing them using a MATLAB code.
Abstract: Smoke from domestic wood burning has been
identified as a major contributor to air pollution, motivating detailed
emission measurements under controlled conditions. A series of
experiments was performed to characterise the emissions from wood
combustion in a fireplace and in a woodstove of two common species
of trees grown in Spain: Pyrenean oak (Quercus pyrenaica) and
black poplar (Populus nigra). Volatile organic compounds (VOCs) in
the exhaust emissions were collected in Tedlar bags, re-sampled in
sorbent tubes and analysed by thermal desorption-gas
chromatography-flame ionisation detection. Pyrenean oak presented
substantially higher emissions in the woodstove than in the fireplace,
for the majority of compounds. The opposite was observed for
poplar. Among the 45 identified species, benzene and benzenerelated
compounds represent the most abundant group, followed by
oxygenated VOCs and aliphatics. Emission factors obtained in this
study are generally of the same order than those reported for
residential experiments in the USA.
Abstract: Understanding of how and where NOx formation
occurs in industrial burner is very important for efficient and clean
operation of utility burners. Also the importance of this problem is
mainly due to its relation to the pollutants produced by more burners
used widely of gas turbine in thermal power plants and glass and steel
industry.
In this article, a numerical model of an industrial burner operating
in MILD combustion is validated with experimental data.. Then
influence of air flow rate and air temperature on combustor
temperature profiles and NOX product are investigated. In order to
modification this study reports on the effects of fuel and air dilution
(with inert gases H2O, CO2, N2), and also influence of lean-premixed
of fuel, on the temperature profiles and NOX emission.
Conservation equations of mass, momentum and energy, and
transport equations of species concentrations, turbulence, combustion
and radiation modeling in addition to NO modeling equations were
solved together to present temperature and NO distribution inside the
burner.
The results shows that dilution, cause to a reduction in value of
temperature and NOX emission, and suppresses any flame
propagation inside the furnace and made the flame inside the furnace
invisible. Dilution with H2O rather than N2 and CO2 decreases further
the value of the NOX. Also with raise of lean-premix level, local
temperature of burner and the value of NOX product are decreases
because of premixing prevents local “hot spots" within the combustor
volume that can lead to significant NOx formation. Also leanpremixing
of fuel with air cause to amount of air in reaction zone is
reach more than amount that supplied as is actually needed to burn
the fuel and this act lead to limiting NOx formation
Abstract: Column leach test has been performed to examine the
behavior of leaching of sodium, calcium and potassium in landfills.
In the column leach apparatus, two different layers of contaminated
and uncontaminated soils of different height ratios (ratio of depth of
contaminated soil to the depth of uncontaminated soil) are taken.
Water is poured from an overhead tank at a particular flowrate to the
inlet of the soil column for a certain ponding depth over the
contaminated soil. Subsequent infiltration causes leaching and the
leachates are collected from the bottom of the column. The
concentrations of Na, Ca and K in the leachate are measured using
flame photometry. The experiments are further extended by changing
the rates of flow from the overhead tank to the inlet of the column in
achieving the same ponding depth. The experiments are performed
for different scenarios in which the height ratios are altered and the
variations of concentrations of Na, Ca, and K are observed. The study
brings an estimation of leaching in landfill sites for different heights
and precipitation intensity where a ponding depth is maintained over
the landfill. It has been observed that the leaching behavior of Na,
Ca, and K are not similar. Calcium exhibits highest amount of
leaching compared to Sodium and Potassium under similar
experimental conditions.
Abstract: A new chelating resin is prepared by coupling
Amberlite XAD-4 with 1-amino-2-naphthole through an azo spacer.
The resulting sorbent has been characterized by FT-IR, elemental
analysis and thermogravimetric analysis (TGA) and studied for
preconcentrating of Cu (II) using flame atomic absorption
spectrometry (FAAS) for metal monitoring. The optimum pH value
for sorption of the copper ions was 6.5. The resin was subjected to
evaluation through batch binding of mentioned metal ion.
Quantitative desorption occurs instantaneously with 0.5 M HNO3.
The sorption capacity was found 4.8 mmol.g-1 of resin for Cu (II) in
the aqueous solution. The chelating resin can be reused for 10 cycles
of sorption-desorption without any significant change in sorption
capacity. A recovery of 99% was obtained the metal ions with 0.5 M
HNO3 as eluting agent. The method was applied for metal ions
determination from industrial waste water sample.
Abstract: The objective of this work is to investigate the
turbulent reacting flow in a three dimensional combustor with
emphasis on the effect of inlet swirl flow through a numerical
simulation. Flow field is analyzed using the SIMPLE method which is
known as stable as well as accurate in the combustion modeling, and
the finite volume method is adopted in solving the radiative transfer
equation. In this work, the thermal and flow characteristics in a three
dimensional combustor by changing parameters such as equivalence
ratio and inlet swirl angle have investigated. As the equivalence ratio
increases, which means that more fuel is supplied due to a larger inlet
fuel velocity, the flame temperature increases and the location of
maximum temperature has moved towards downstream. In the mean
while, the existence of inlet swirl velocity makes the fuel and
combustion air more completely mixed and burnt in short distance.
Therefore, the locations of the maximum reaction rate and temperature
were shifted to forward direction compared with the case of no swirl.
Abstract: Results are presented from a combined experimental
and modeling study undertaken to understand the effect of fuel spray
angle on soot production in turbulent liquid spray flames. The
experimental work was conducted in a cylindrical laboratory furnace
at fuel spray cone angle of 30º, 45º and 60º. Soot concentrations
inside the combustor are measured by filter paper technique. The soot
concentration is modeled by using the soot particle number density
and the mass density based acetylene concentrations. Soot oxidation
occurred by both hydroxide radicals and oxygen molecules. The
comparison of calculated results against experimental measurements
shows good agreement. Both the numerical and experimental results
show that the peak value of soot and its location in the furnace
depend on fuel spray cone angle. An increase in spray angle enhances
the evaporating rate and peak temperature near the nozzle. Although
peak soot concentration increase with enhance of fuel spray angle but
soot emission from the furnace decreases.
Abstract: In today-s era of plasma and laser cutting, machines using oxy-acetylene flame are also meritorious due to their simplicity and cost effectiveness. The objective to devise a Computer controlled Oxy-Fuel profile cutting machine arose from the increasing demand for metal cutting with respect to edge quality, circularity and lesser formation of redeposit material. The System has an 8 bit micro controller based embedded system, which assures stipulated time response. A new window based Application software was devised which takes a standard CAD file .DXF as input and converts it into numerical data required for the controller. It uses VB6 as a front end whereas MS-ACCESS and AutoCAD as back end. The system is designed around AT89C51RD2, powerful 8 bit, ISP micro controller from Atmel and is optimized to achieve cost effectiveness and also maintains the required accuracy and reliability for complex shapes. The backbone of the system is a cleverly designed mechanical assembly along with the embedded system resulting in an accuracy of about 10 microns while maintaining perfect linearity in the cut. This results in substantial increase in productivity. The observed results also indicate reduced inter laminar spacing of pearlite with an increase in the hardness of the edge region.
Abstract: Cooktop burners are widely used nowadays. In
cooktop burner design, nozzle efficiency and greenhouse
gas(GHG) emissions mainly depend on heat transfer from the
premixed flame to the impinging surface. This is a complicated
issue depending on the individual and combined effects of various
input combustion variables. Optimal operating conditions for
sustainable burner design were rarely addressed, especially in the
case of multiple slot-jet burners. Through evaluating the optimal
combination of combustion conditions for a premixed slot-jet
array, this paper develops a practical approach for the sustainable
design of gas cooktop burners. Efficiency, CO and NOx emissions
in respect of an array of slot jets using premixed flames were
analysed. Response surface experimental design were applied to
three controllable factors of the combustion process, viz.
Reynolds number, equivalence ratio and jet-to-vessel distance.
Desirability Function Approach(DFA) is the analytic technique
used for the simultaneous optimization of the efficiency and
emission responses.
Abstract: The objective of this study is to investigate fire
behaviors, experimentally and numerically, in a scaled version of an
underground station. The effect of ventilation velocity on the fire is
examined. Fire experiments are simulated by burning 10 ml
isopropyl alcohol fuel in a fire pool with dimensions 5cm x 10cm x 4
mm at the center of 1/100 scaled underground station model. A
commercial CFD program FLUENT was used in numerical
simulations. For air flow simulations, k-ω SST turbulence model and
for combustion simulation, non-premixed combustion model are
used. This study showed that, the ventilation velocity is increased
from 1 m/s to 3 m/s the maximum temperature in the station is found
to be less for ventilation velocity of 1 m/s. The reason for these
experimental result lies on the relative dominance of oxygen supply
effect on cooling effect. Without piston effect, maximum temperature
occurs above the fuel pool. However, when the ventilation velocity
increased the flame was tilted in the direction of ventilation and the
location of maximum temperature moves along the flow direction.
The velocities measured experimentally in the station at different
locations are well matched by the CFD simulation results. The
prediction of general flow pattern is satisfactory with the smoke
visualization tests. The backlayering in velocity is well predicted by
CFD simulation. However, all over the station, the CFD simulations
predicted higher temperatures compared to experimental
measurements.
Abstract: The nexus between language and culture is so
intertwined and very significant that language is largely seen as a
vehicle for cultural transmission. Culture itself refers to the aggregate
belief system of a people, embellishing its corporate national image
or brand. If we conceive national rebranding as a campaign to
rekindle the patriotic flame in the consciousness of a people towards
its sociocultural imperatives and values, then, Nigerian indigenous
linguistic flame has not been ignited. Consequently, the paper
contends that the current national rebranding policy remains a myth
in the confines of the elitists' intellectual squabble. It however
recommends that the use of our indigenous languages should be
supported by adequate legislation and also propagated by Nollywood
in order to revamp and sustain the people’s interest in their local
languages. Finally, the use of the indigenous Nigerian languages
demonstrates patriotism, an important ingredient for actualizing a
genuine national rebranding.
Abstract: Alkali treated oil palm empty fruit bunch (EFB) fibres
(TEFBF) and untreated EFBF fibers (UEFBF) were incorporated in
polypropylene (PP) with and without malic anhydride grafted PP
(MAPP) and magnesium hydroxide as flame retardant (FR) to
produce TEFBF-PP and UEFBF-PP composites by the melt casting
method. The composites were characterized by mechanical and
burning tests along with a scanning electron microscope and Fourier
transform infrared spectroscopy. The significant improvement in
flexural modulus (133%) and flame retardant property (60%) of
TEFBF-PP composite with MAPP and FR is observed. The improved
mechanical property is discussed by the development of encapsulated
textures.