Abstract: Starch/chitosan blend have been prepared via the
solution casting technique. Ionic conductivity for the system was
conducted over a wide range of frequency between 50 Hz-1 MHz and
at temperatures between 303 K and 373 K. Sample with 35 wt% of
NH4NO3 shows the highest conductivity of 3.89 ± 0.79 x 10-5 Scm-1
at room temperature. Conductivity-temperature relationship suggests
that samples are Arrhenian. Power law exponent was obtained
through dielectric loss variation and the trend suggests that the
conduction mechanism of the ions can be represented by the
correlated barrier hopping (CBH) model.
Abstract: The use of synthetic retardants in polymeric insulated
cables is not uncommon in the high voltage engineering to study
electrical treeing phenomenon. However few studies on organic
materials for the same investigation have been carried. .This paper
describes the study on the effects of Oil Palm Empty Fruit Bunch
(OPEFB) microfiller on the tree initiation and propagation in silicone
rubber with different weight percentages (wt %) of filler to insulation
bulk material. The weight percentages used were 0 wt % and 1 wt %
respectively. It was found that the OPEFB retards the propagation of
the electrical treeing development. For tree inception study, the
addition of 1(wt %) OPEFB has increase the tree inception voltage of
silicone rubber. So, OPEFB is a potential retardant to the initiation
and growth of electrical treeing occurring in polymeric materials for
high voltage application. However more studies on the effects of
physical and electrical properties of OPEFB as a tree retardant
material are required.
Abstract: This study fabricates p-type Ni1−xO:Li/n-Si heterojunction solar cells (P+/n HJSCs) by using radio frequency (RF) magnetron sputtering and investigates the effect of substrate temperature on photovoltaic cell properties. Grazing incidence x-ray diffraction, four point probe, and ultraviolet-visible-near infrared discover the optoelectrical properties of p-Ni1-xO thin films. The results show that p-Ni1-xO thin films deposited at 300 oC has the highest grain size (22.4 nm), average visible transmittance (~42%), and electrical resistivity (2.7 Ωcm). However, the conversion efficiency of cell is shown only 2.33% which is lower than the cell (3.39%) fabricated at room temperature. This result can be mainly attributed to interfacial layer thickness (SiOx) reduces from 2.35 nm to 1.70 nm, as verified by high-resolution transmission electron microscopy.
Abstract: The passive electrical properties of a tissue depends
on the intrinsic constituents and its structure, therefore by measuring
the complex electrical impedance of the tissue it might be possible to
obtain indicators of the tissue state or physiological activity [1].
Complete bio-impedance information relative to physiology and
pathology of a human body and functional states of the body tissue or
organs can be extracted by using a technique containing a fourelectrode
measurement setup. This work presents the estimation
measurement setup based on the four-electrode technique. First, the
complex impedance is estimated by three different estimation
techniques: Fourier, Sine Correlation and Digital De-convolution and
then estimation errors for the magnitude, phase, reactance and
resistance are calculated and analyzed for different levels of
disturbances in the observations. The absolute values of relative
errors are plotted and the graphical performance of each technique is
compared.
Abstract: An electrical apparatus for measuring moisture
content was developed by our laboratory and uses dependence of
electrical properties on water content in studied material. Error
analysis of the apparatus was run by measuring different volumes of
water in a simplified specimen, i.e. hollow plexiglass block, in order
to avoid as many side-effects as possible. Obtained data were
processed using both basic and advanced statistics and results were
compared with each other. The influence of water content on
accuracy of measured data was studied as well as the influence of
variation of apparatus' proper arrangement or factual methodics of its
usage. The overall coefficient of variation was 4%. There was no
trend found in results of error dependence on water content.
Comparison with current surveys led to a conclusion, that the studied
apparatus can be used for indirect measurement of water content in
porous materials, with expectable error and under known conditions.
Factual experiments with porous materials are not involved, but are
currently under investigation.
Abstract: In this study, structural, mechanical, thermal and
electrical properties of poly (lactic acid) (PLA) nanocomposites with
low-loaded (0-1.5 wt%) untreated, heat and nitric acid treated multiwalled
carbon nanotubes (MWCNTs) were studied. Among the
composites, untreated 0.5 wt % MWCNTs and acid-treated 1.0 wt%
MWCNTs reinforced PLA show the tensile strength and modulus
values higher than the others. These two samples along with pure
PLA exhibit the stable orthorhombic α-form, whilst other samples
reveal the less stable orthorhombic β-form, as demonstrated by X-ray
diffraction study. Differential scanning calorimetry reveals the
evolution of the mentioned different phases by controlled cooling and
discloses an enhancement of PLA crystallization by nanotubes
incorporation. Thermogravimetric analysis shows that the MWCNTs
loaded sample degraded faster than PLA. Surface resistivity of the
nanocomposites is found to be dropped drastically by a factor of 1013
with a low loading of MWCNTs (1.5 wt%).
Abstract: (Bi0.5Na0.5)TiO3 doped with 8 mol % BaTiO3 powder
(BNT-BT0.08), prepared by sol-gel method was compacted and
sintered by Spark Plasma Sintering (SPS) process. The influence of
SPS temperature on the densification of BNT-BT0.08 ceramic was
investigated. Starting from sol-gel nanopowder of BNT-BT
containing 8 mol % BaTiO3 with an average particles size of about
30 nm, were obtained ceramics with density around 98 % of the
theoretical density value when the SPS temperature used was about
850 °C. The average grain size of the resulting ceramics was 80 nm.
The BNT-BT0.08 ceramic sample obtained by SPS method has shown
good electric properties at various frequencies.
Abstract: End-substitution of quarterthiophene and sexithiophene with hexyl groups leads to highly soluble conjugated oligomers,DZ-dihexylquarterthiophene (DH-4T) and DZ-dihexylsexithiophene (DH-6T). We have characterized these oligomers for optical and electrical properties. We fabricated an organic thin film transistor (OTFT) using the above two air-stable p-type organic semiconductor materials. We obtained a stable characteristic curve. The field effect mobility, Pwas calculated to be 3.2910-4 cm2/Vs for DH-6T based OTFT; while the DH-4T based OTFT had 1.8810-5 cm2/Vs.KeywordsOrganic thin film transistor, DZ-dihexylquarterthiophene, DZ-dihexylsexithiophene.
Abstract: Power systems and transformer are intrinsic apparatus, therefore its reliability and safe operation is important to determine their operation conditions, and the industry uses quality control tests in the insulation design of oil filled transformers. Hence the service period effect on AC dielectric strength is significant. The effect of aging on transformer oil physical, chemical and electrical properties was studied using the international testing methods for the evaluation of transformer oil quality. The study was carried out on six transformers operate in the field and for monitoring periods over twenty years. The properties which are strongly time dependent were specified and those which have a great impact on the transformer oil acidity, breakdown voltage and dissolved gas analysis were defined. Several tests on the transformers oil were studied to know the time of purifying or changing it, moreover prediction of the characteristics of it under different operation conditions.
Abstract: Regarding previous research studies it was concluded
that thin-walled fiber-cement composites are able to conduct electric
current under specific conditions. This property is ensured by using
of various kinds of carbon materials. Though carbon fibers are less
conductive than metal fibers, composites with carbon fibers were
evaluated as better current conductors than the composites with metal
fibers. The level of electric conductivity is monitored by the means of
impedance measurement of designed samples. These composites
could be used for a range of applications such as heating of
trafficable surfaces or shielding of electro-magnetic fields.
The aim of the present research was to design an element with the
ability to monitor internal processes in building structures and
prevent them from collapsing. As a typical element for laboratory
testing there was chosen a concrete column, which was repeatedly
subjected to load by simple pressure with continual monitoring of
changes in electrical properties.
Abstract: Optical properties of sputter-deposited ZnS thin films
were investigated as potential replacements for CBD(chemical bath
deposition) CdS buffer layers in the application of CIGS solar cells.
ZnS thin films were fabricated on glass substrates at RT, 150oC, 200oC,
and 250oC with 50 sccm Ar gas using an RF magnetron sputtering
system. The crystal structure of the thin film is found to be zinc blende
(cubic) structure. Lattice parameter of ZnS is slightly larger than CdS
on the plane and thus better matched with that of CIGS. Within a
400-800 nm wavelength region, the average transmittance was larger
than 75%. When the deposition temperature of the thin film was
increased, the blue shift phenomenon was enhanced. Band gap energy
of the ZnS thin film tended to increase as the deposition temperature
increased. ZnS thin film is a promising material system for the CIGS
buffer layer, in terms of ease of processing, low cost, environmental
friendliness, higher transparency, and electrical properties
Abstract: The ferroelectric behavior of barium strontium
titanate (BST) in thin film form has been investigated in order to
study the possibility of using BST for ferroelectric gate-field effect
transistor (FeFET) for memory devices application. BST thin films
have been fabricated as Al/BST/Pt/SiO2/Si-gate configuration. The
variation of the dielectric constant (ε) and tan δ with frequency have
been studied to ensure the dielectric quality of the material. The
results show that at low frequencies, ε increases as the Ba content
increases, whereas at high frequencies, it shows the opposite
variation, which is attributed to the dipole dynamics. tan δ shows low
values with a peak at the mid-frequency range. The ferroelectric
behavior of the Al/BST/Pt/SiO2/Si has been investigated using C-V
characteristics. The results show that the strength of the ferroelectric
hysteresis loop increases as the Ba content increases; this is attributed
to the grain size and dipole dynamics effect.
Abstract: Carbon nanotubes (CNTs) possess unique structural,
mechanical, thermal and electronic properties, and have been
proposed to be used for applications in many fields. However, to
reach the full potential of the CNTs, many problems still need to be
solved, including the development of an easy and effective
purification procedure, since synthesized CNTs contain impurities,
such as amorphous carbon, carbon nanoparticles and metal particles.
Different purification methods yield different CNT characteristics
and may be suitable for the production of different types of CNTs. In
this study, the effect of different purification chemicals on carbon
nanotube quality was investigated. CNTs were firstly synthesized by
chemical vapor deposition (CVD) of acetylene (C2H2) on a
magnesium oxide (MgO) powder impregnated with an iron nitrate
(Fe(NO3)3·9H2O) solution. The synthesis parameters were selected
as: the synthesis temperature of 800°C, the iron content in the
precursor of 5% and the synthesis time of 30 min. The liquid phase
oxidation method was applied for the purification of the synthesized
CNT materials. Three different acid chemicals (HNO3, H2SO4, and
HCl) were used in the removal of the metal catalysts from the
synthesized CNT material to investigate the possible effects of each
acid solution to the purification step. Purification experiments were
carried out at two different temperatures (75 and 120 °C), two
different acid concentrations (3 and 6 M) and for three different time
intervals (6, 8 and 15 h). A 30% H2O2 : 3M HCl (1:1 v%) solution
was also used in the purification step to remove both the metal
catalysts and the amorphous carbon. The purifications using this
solution were performed at the temperature of 75°C for 8 hours.
Purification efficiencies at different conditions were evaluated by
thermogravimetric analysis. Thermal and electrical properties of
CNTs were also determined. It was found that the obtained electrical
conductivity values for the carbon nanotubes were typical for organic
semiconductor materials and thermal stabilities were changed
depending on the purification chemicals.
Abstract: In this work, an organic compound 5,10,15,20-
Tetrakis(3,5-di-tertbutylphenyl)porphyrinatocopper(II) (TDTBPPCu)
is studied as an active material for thin film electronic devices. To
investigate the electrical properties of TDTBPPCu, junction of
TDTBPPCu with heavily doped n-Si and Al is fabricated.
TDTBPPCu film was sandwiched between Al and n-Si electrodes.
Various electrical parameters of TDTBPPCu are determined. The
current-voltage characteristics of the junction are nonlinear,
asymmetric and show rectification behavior, which gives the clue of
formation of depletion region. This behavior indicates the potential
of TDTBPPCu for electronics applications. The current-voltage and
capacitance-voltage techniques are used to find the different
electronic parameters.
Abstract: n-CdO/p-Si heterojunction diode was fabricated using
sol-gel spin coating technique which is a low cost and easily scalable
method for preparing of semiconductor films. The structural and
morphological properties of CdO film were investigated. The X-ray
diffraction (XRD) spectra indicated that the film was of
polycrystalline nature. The scanning electron microscopy (SEM)
images indicate that the surface morphology CdO film consists of the
clusters formed with the coming together of the nanoparticles. The
electrical characterization of Au/n-CdO/p–Si/Al heterojunction diode
was investigated by current-voltage. The ideality factor of the diode
was found to be 3.02 for room temperature. The reverse current of
the diode strongly increased with illumination intensity of 100
mWcm-2 and the diode gave a maximum open circuit voltage Voc of
0.04 V and short-circuits current Isc of 9.92×10-9 A.
Abstract: Herein, the organic semiconductor methyl orange
(MO), is investigated for the first time for its electronic applications.
For this purpose, Al/MO/n-Si heterojunction is fabricated through
economical cheap and simple “drop casting” technique. The currentvoltage
(I-V) measurements of the device are made at room
temperature under dark conditions. The I-V characteristics of
Al/MO/n-Si junction exhibits asymmetrical and rectifying behavior
that confirms the formation of diode. The diode parameters such as
rectification ratio (RR), turn on voltage (Vturn on), reverse saturation
current (I0), ideality factor (n), barrier height ( b
f ), series resistance
(Rs) and shunt resistance (Rsh) are determined from I-V curves using
Schottky equations. These values of these parameters are also
extracted and verified by applying Cheung’s functions. The
conduction mechanisms are explained from the forward bias I-V
characteristics using the power law.
Abstract: An organic bulk heterojunction (BHJ) was fabricated using a blended film containing Copper (II) tetrakis(4-acumylphenoxy) phthalocyanine (Tc-CuPc) along with [6,6]-Phenyl C61 butyric acid methyl ester (PCBM). Weight ratio between Tc-CuPc and PCBM was 1:1. The electrical properties of Tc-CuPc: PCBM BHJ were examined. Rectifying nature of the BHJ was displayed by current-voltage (I-V) curves, recorded in dark and at various temperatures. At low voltages, conduction was ohmic succeeded by space-charge limiting current (SCLC) conduction at higher voltages in which exponential trap distribution was dominant. Series resistance, shunt resistance, ideality factor, effective barrier height and mobility at room temperature were found to be 526 4, 482 k4, 3.7, 0.17 eV and 2×10-7 cm2V-1s-1 respectively. Temperature effect towards different BHJ parameters was observed under dark condition.