Abstract: In the first part of the research work, an electrolyzer (10.16 cm dia and 24.13 cm height) to produce hydrogen and oxygen was constructed for single slice O2/H2 fuel cell using cation exchange membrane. The electrolyzer performance was tested with 23% NaOH, 30% NaOH, 30% KOH and 35% KOH electrolyte solution with current input 4 amp and 2.84 V from the rectifier. Rates of volume of hydrogen produced were 0.159 cm3/sec, 0.155 cm3/sec, 0.169 cm3/sec and 0.163 cm3/sec respectively from 23% NaOH, 30% NaOH, 30% KOH and 35% KOH solution. Rates of volume of oxygen produced were 0.212 cm3/sec, 0.201 cm3/sec, 0.227 cm3/sec and 0.219 cm3/sec respectively from 23% NaOH, 30% NaOH, 30% KOH and 35% KOH solution (1.5 L). In spite of being tested the increased concentration of electrolyte solution, the gas rate does not change significantly. Therefore, inexpensive 23% NaOH electrolyte solution was chosen to use as the electrolyte in the electrolyzer. In the second part of the research work, graphite serpentine flow plates, fiberglass end plates, stainless steel screen electrodes, silicone rubbers were made to assemble the single slice O2/H2 polymer electrolyte membrane fuel cell (PEMFC).
Abstract: Application of nanoparticles as additives in membrane
synthesis for improving the resistance of membranes against fouling
has triggered recent interest in new membrane types. However, most
nanoparticle-enhanced membranes suffer from the tradeoff between
permeability and selectivity. In this study, nano-WS2 was explored as
the additive in membrane synthesis by non-solvent induced phase
separation. Blended PES-WS2 flat-sheet membranes with the
incorporation of ultra-low concentrations of nanoparticles (from 0.025
to 0.25%, WS2/PES ratio) were manufactured and investigated in
terms of permeability, fouling resistance and solute rejection.
Remarkably, a significant enhancement in the permeability was
observed as a result of the incorporation of ultra-low fractions of
nano-WS2 to the membrane structure. Optimal permeability values
were obtained for modified membranes with 0.10%
nanoparticle/polymer concentration ratios. Furthermore, fouling
resistance and solute rejection were significantly improved by the
incorporation of nanoparticles into the membrane matrix. Specifically,
fouling resistance of modified membrane can increase by around 50%.
Abstract: The assessment of surface waters in Enugu metropolis
for fecal coliform bacteria was undertaken. Enugu urban was divided
into three areas (A1, A2 and A3), and fecal coliform bacteria
analysed in the surface waters found in these areas for four years
(2005-2008). The plate count method was used for the analyses. Data
generated were subjected to statistical tests involving; Normality test,
Homogeneity of variance test, correlation test, and tolerance limit
test. The influence of seasonality and pollution trends were
investigated using time series plots. Results from the tolerance limit
test at 95% coverage with 95% confidence, and with respect to EU
maximum permissible concentration show that the three areas suffer
from fecal coliform pollution. To this end, remediation procedure
involving the use of saw-dust extracts from three woods namely;
Chlorophora-Excelsa (C-Excelsa),Khayan-Senegalensis,(CSenegalensis)
and Erythrophylum-Ivorensis (E-Ivorensis) in
controlling the coliforms was studied. Results show that mixture of
the acetone extracts of the woods show the most effective
antibacterial inhibitory activities (26.00mm zone of inhibition)
against E-coli. Methanol extract mixture of the three woods gave best
inhibitory activity (26.00mm zone of inhibition) against S-areus, and
25.00mm zones of inhibition against E-Aerogenes. The aqueous
extracts mixture gave acceptable zones of inhibitions against the
three bacteria organisms.
Abstract: The distributions of stresses and deflection in
rectangular isotropic and orthotropic plates with central
circular hole under transverse static loading have been studied
using finite element method. The aim of author is to analyze
the effect of D/A ratio (where D is hole diameter and A is plate
width) upon stress concentration factor (SCF) and deflection
in isotropic and orthotropic plates under transverse static
loading. The D/A ratio is varied from 0.01 to 0.9. The analysis
is done for plates of isotropic and two different orthotropic
materials. The results are obtained for three different boundary
conditions. The variations of SCF and deflection with respect
to D/A ratio are presented in graphical form and discussed.
The finite element formulation is carried out in the analysis
section of the ANSYS package.
Abstract: Uterine and oviducal fluids are necessary for
capacitation of the spermatozoa and early embryonic development.
The aim of the present study was to determine the effects of estrous
cycle phases (follicular and luteal) on some biological parameters
(enzymes, electrolytes and total proteins) in uterine and oviducal
secretions of ewes. Oviducal and uterine fluids were collected,
diluted and centrifuged. According to our results, concentrations of
GPT, G6PDH, total proteins, K and Na were significantly (P
Abstract: Over 90% of the world trade is carried by the
international shipping industry. As most of the countries are
developing, seaborne trade continues to expand to bring benefits for
consumers across the world. Studies show that world trade will
increase 70-80% through shipping in the next 15-20 years. Present
global fleet of 70000 commercial ships consumes approximately 200
million tonnes of diesel fuel a year and it is expected that it will be
around 350 million tonnes a year by 2020. It will increase the
demand for fuel and also increase the concentration of CO2 in the
atmosphere. So, it-s essential to control this massive fuel
consumption and CO2 emission. The idea is to utilize a diesel-wind
hybrid system for ship propulsion. Use of wind energy by installing
modern wing-sails in ships can drastically reduce the consumption of
diesel fuel. A huge amount of wind energy is available in oceans.
Whenever wind is available the wing-sails would be deployed and
the diesel engine would be throttled down and still the same forward
speed would be maintained. Wind direction in a particular shipping
route is not same throughout; it changes depending upon the global
wind pattern which depends on the latitude. So, the wing-sail
orientation should be such that it optimizes the use of wind energy.
We have made a computer programme in which by feeding the data
regarding wind velocity, wind direction, ship-motion direction; we
can find out the best wing-sail position and fuel saving for
commercial ships. We have calculated net fuel saving in certain
international shipping routes, for instance, from Mumbai in India to
Durban in South Africa. Our estimates show that about 8.3% diesel
fuel can be saved by utilizing the wind. We are also developing an
experimental model of the ship employing airfoils (small scale wingsail)
and going to test it in National Wind Tunnel Facility in IIT
Kanpur in order to develop a control mechanism for a system of
airfoils.
Abstract: Two short sediment cores collected from mangrove
areas of Manori and Thane creeks along Mumbai coast were analysed
for sediment composition and metals (Fe, Mn, Cu, Pb, Co, Ni, Zn, Cr
and V). The statistical analysis of Pearson correlation matrix proved
that there is a significant relationship between metal concentration
and finer grain size in Manori creek while poor correlation was
observed in Thane creek. Based on the enrichment factor, the present
metal to background metal ratios clearly reflected maximum
enrichment of Cu and Pb in Manori creek and Mn in Thane creek.
Geoaccumulation index calculated indicate that the study area is
unpolluted with respect to Fe, Mn, Co, Ni, Zn and Cr in both the
cores while moderately polluted with Cu and Pb in Manori creek.
Based on contamination degree, both the core sediments were found
to be considerably contaminated with metals.
Abstract: Intravitreal injection (IVI) is the most common treatment for eye posterior segment diseases such as endopthalmitis, retinitis, age-related macular degeneration, diabetic retinopathy, uveitis, and retinal detachment. Most of the drugs used to treat vitreoretinal diseases, have a narrow concentration range in which they are effective, and may be toxic at higher concentrations. Therefore, it is critical to know the drug distribution within the eye following intravitreal injection. Having knowledge of drug distribution, ophthalmologists can decide on drug injection frequency while minimizing damage to tissues. The goal of this study was to develop a computer model to predict intraocular concentrations and pharmacokinetics of intravitreally injected drugs. A finite volume model was created to predict distribution of two drugs with different physiochemical properties in the rabbit eye. The model parameters were obtained from literature review. To validate this numeric model, the in vivo data of spatial concentration profile from the lens to the retina were compared with the numeric data. The difference was less than 5% between the numerical and experimental data. This validation provides strong support for the numerical methodology and associated assumptions of the current study.
Abstract: The rheological properties, structure and potential synergistic interactions of whey proteins (1-6%) and inulin (20%) in mixed gels in the presence of CaCl2 was the aim of this study. Whey proteins have a strong influence on inulin gel formation. At low concentrations (2%) whey proteins did not impair in inulin gel formation. At higher concentration (4%) whey proteins impaired inulin gelation and inulin impaired the formation of a Ca2+-induced whey protein network. The presence of whey proteins at a level allowing for protein gel network formation (6%) significantly increased the rheological parameters values of the gels. SEM micrographs showed that whey protein structure was coated by inulin moieties which could make the mixed gels firmer. The protein surface hydrophobicity measurements did not exclude synergistic interactions between inulin and whey proteins, however. The use of an electrophoretic technique did not show any stable inulin-whey protein complexes.