Abstract: Air pollution is a major environmental health
problem, affecting developed and developing countries around the
world. Increasing amounts of potentially harmful gases and
particulate matter are being emitted into the atmosphere on a global
scale, resulting in damage to human health and the environment.
Petroleum-related air pollutants can have a wide variety of adverse
environmental impacts. In the crude oil production sectors, there is a
strong need for a thorough knowledge of gaseous emissions resulting
from the flaring of associated gas of known composition on daily
basis through combustion activities under several operating
conditions. This can help in the control of gaseous emission from
flares and thus in the protection of their immediate and distant
surrounding against environmental degradation.
The impacts of methane and non-methane hydrocarbons emissions
from flaring activities at oil production facilities at Kuwait Oilfields
have been assessed through a screening study using records of flaring
operations taken at the gas and oil production sites, and by analyzing
available meteorological and air quality data measured at stations
located near anthropogenic sources. In the present study the
Industrial Source Complex (ISCST3) Dispersion Model is used to
calculate the ground level concentrations of methane and nonmethane
hydrocarbons emitted due to flaring in all over Kuwait
Oilfields.
The simulation of real hourly air quality in and around oil
production facilities in the State of Kuwait for the year 2006,
inserting the respective source emission data into the ISCST3
software indicates that the levels of non-methane hydrocarbons from
the flaring activities exceed the allowable ambient air standard set by
Kuwait EPA. So, there is a strong need to address this acute problem
to minimize the impact of methane and non-methane hydrocarbons
released from flaring activities over the urban area of Kuwait.
Abstract: To compare Healing Effects of an
Ayurvedic Preparation and Silver Sulfadiazine on burn wounds in
Albino Rats.
Methods: Albino rats– 30 male / female rats weighing between
150-200 g were used in the study. They were individually housed and
maintained on normal diet and water ad libitum. Partial thickness
burn wounds were inflicted, on overnight-starved animals under
pentobarbitone (30mg/kg, i.p.) anaesthesia, by pouring hot molten
wax at 80oC into a plastic cylinder of 300 mm2 circular openings
placed on the shaven back of the animal. Apart from the drugs under
investigation no local/ systemic chemotherapeutic cover will be
provided to animals. All the animals were assessed for the percentage
of wound contraction, signs of infection, scab formation and
histopathological examination.
Results: Percentage of wound healing was significantly better in
the test ointment group compared to the standard. Signs of infection
were observed in more animals in the test ointment group compared
to the standard. Scab formation also took place earlier in the test
ointment group compared to standard. Epithelial regeneration and
healing profile was better in the test ointment compared to the
standard. Moreover the test ointment group did not show any raised
margins in the wound or blackish discoloration as was observed in
silver sulfadiazine group.
Conclusion: The burn wound healing effect of the ayurvedic
ointment under study is better in comparison to standard therapy of
silver sulfadiazine. The problem of infection encountered with the
test ointment can be overcome by changing the concentrations and
proportions of the ingredients in the test ointment which constitutes
the further plan of the study.
Abstract: This study deals with evaluation of influence of salinity (NaCl) onto equilibrium of Cu and Ni removal from aqueous solutions by natural sorbent – zeolite. Equilibrium data were obtained by batch experiments. The salinity of the aqueous solution was influenced by dissolving NaCl in distilled water. It was studied in the range of NaCl concentrations from 1 g.l-1 to 100g.l-1. For Cu sorption there is a significant influence of salinity. The maximum capacity of zeolite for Cu was decreasing with growing concentration of NaCl. For Ni sorption there is not so significant influence of salinity as for Cu. The maximum capacity of zeolite for Ni was slightly decreasing with growing concentration of NaCl.
Abstract: Biological Ammonia removal (nitrification), the
oxidation of ammonia to nitrate catalyzed by bacteria, is a key part of
global nitrogen cycling. In the first step of nitrification,
chemolithoautotrophic ammonia oxidizer transform ammonia to
nitrite, this subsequently oxidized to nitrate by nitrite oxidizing
bacteria. This process can be affected by several factors. In this study
the effect of influent COD on biological ammonia removal in a
bench-scale biological reactor was investigated. Experiments were
carried out using synthetic wastewater. The initial ammonium
concentration was 25mgNH4
+-N L-1. The effect of COD between
247.55±1.8 and 601.08±3.24mgL-1 on biological ammonia removal
was investigated by varying the COD loading supplied to reactor.
From the results obtained in this study it could be concluded in the
range of 247.55±1.8 to 351.35±2.05mgL-1, there is a direct
relationship between amount of COD and ammonia removal.
However more than 351.35±2.05 up to 601.08±3.24mgL-1 were
found an indirect relationship between them.
Abstract: Rapid urbanization, industrialization and population
growth have led to an increase in number of automobiles that cause
air pollution. It is estimated that road traffic contributes 60% of air
pollution in urban areas. A case by case assessment is required to
predict the air quality in urban situations, so as to evolve certain
traffic management measures to maintain the air quality levels with
in the tolerable limits. Calicut city in the state of Kerala, India has
been chosen as the study area. Carbon Monoxide (CO) concentration
was monitored at 15 links in Calicut city and air quality performance
was evaluated over each link. The CO pollutant concentration values
were compared with the National Ambient Air Quality Standards
(NAAQS), and the CO values were predicted by using CALINE4 and
IITLS and Linear regression models. The study has revealed that
linear regression model performs better than the CALINE4 and
IITLS models. The possible association between CO pollutant
concentration and traffic parameters like traffic flow, type of vehicle,
and traffic stream speed was also evaluated.
Abstract: Economically transformers constitute one of the largest investments in a Power system. For this reason, transformer condition assessment and management is a high priority task. If a transformer fails, it would have a significant negative impact on revenue and service reliability. Monitoring the state of health of power transformers has traditionally been carried out using laboratory Dissolved Gas Analysis (DGA) tests performed at periodic intervals on the oil sample, collected from the transformers. DGA of transformer oil is the single best indicator of a transformer-s overall condition and is a universal practice today, which started somewhere in the 1960s. Failure can occur in a transformer due to different reasons. Some failures can be limited or prevented by maintenance. Oil filtration is one of the methods to remove the dissolve gases and prevent the deterioration of the oil. In this paper we analysis the DGA data by regression method and predict the gas concentration in the oil in the future. We bring about a comparative study of different traditional methods of regression and the errors generated out of their predictions. With the help of these data we can deduce the health of the transformer by finding the type of fault if it has occurred or will occur in future. Additional in this paper effect of filtration on the transformer health is highlight by calculating the probability of failure of a transformer with and without oil filtrating.
Abstract: Studies were carried out to determine the in vitro
susceptibility of the typhoid pathogens to combined action of Euphorbia hirta, Euphorbia heterophylla and Phyllanthus niruri. Clinical isolates of the typhoid bacilli were subjected to susceptibility testing using agar diffusion technique and the minimum inhibitory
concentration (MIC) determined with tube dilution technique. These
isolates, when challenged with doses of the extracts from the three
medicinal plants showed zones of inhibition as wide as 26±0.2mm, 22±0.1mm and 18±0.0mm respectively. The minimum inhibitory concentration (MIC) revealed organisms inhibited at varying
concentrations of extracts: E. hirta (S. typhi 0.250mg/ml, S. paratyphi A 0.125mg/ml, S. paratyphi B 0.185mg/ml and S. paratyphi C 0.225mg/ml), E. heterophylla (S. typhi 0.280mg/ml, S. paratyphi A
0.150mg/ml, S. paratyphi B 0.200mg/ml and S. paratyphi C 0.250mg/ml) and P. niruri (S. typhi 0.150mg/ml, S. paratyphi A 0.100mg/ml, S. paratyphi B 0.115mg/ml and S. paratyphi C 0.125mg/ml). The results of the synergy between the three plants in
the ration of 1:1:1 showed very low MICs for the test pathogens as follows S. typhi 0.025mg/ml, S. paratyphi A 0.080mg/ml, S. paratyphi B 0.015mg/ml and S. paratyphi C 0.10mg/ml with the
diameter zone of inhibition (DZI) ranging from 35±0.2mm,
28±0.4mm, 20±0.1mm and 32±0.3mm respectively. The secondary
metabolites were identified using simple methods and HPLC. Organic components such as anthroquinones, different alkaloids,
tannins, 6-ethoxy-1,2,3,4-tetrahydro-2,2,4-trimethyl and steroids were identified. The prevalence of Salmonellae, a deadly infectious disease, is still very high in parts of Nigeria. The synergistic action of these three plants is very high. It is concluded that pharmaceutical companies should take advantage of these findings to develop new
anti-typhoid drugs from these plants.
Abstract: Candida albicans ATCC 10231 had low endogenous activity of the alternative oxidase compared with that of C. albicans ATCC 10261. In C. albicans ATCC 10231 the endogenous activity declined as the cultures aged. Alternative oxidase activity could be induced in C. albicans ATCC 10231 by treatment with cyanide, but the induction of this activity required the presence of oxygen which could be replaced, at least in part, with high concentrations of potassium ferricyanide. We infer from this that the expression of the gene encoding the alternative oxidase is under the control of a redoxsensitive transcription factor.
Abstract: The purpose of this article is to analyze the market structure as well as the degree of concentration in insurance markets in new EU member states. The analysis was conducted using several most commonly used concentration indicators such as concentration ratio, Herfindahl-Hirschman index and entropy index. These indicators were calculated for the 2000-2010 period on the basis of total gross written premium as the most relevant indicator of market power in insurance markets. The results of the analysis showed that in all observed countries the level of concentration decreased, though with significantly different intensity. Yet, in some countries, the level of concentration remains very high.
Abstract: Pretreatment of oil palm empty fruit bunch (OPEFB) with N-Methylmorpholine-N-oxide (NMMO) to enhance biogas production was investigated. The pretreatments were performed at 90 and 120ºC for 1, 3, and 5 h using three different concentrations of NMMO of 73%, 79%, and 85%. The pretreated OPEFB was subsequently anaerobically digested to produce biogas. After pretreatment, there were no significant changes of the main composition of OPEFB and the maximum total solid recovery was 92%. The amorphous phase was increased up to 78% at pretreatment condition using 85% NMMO solution for 3 h at 120oC. In general, higher concentration of NMMO and higher temperature resulted in increased amorphous form and higher biogas production. The best results of biogas production reached enhancement of methane yield of 148% compared to the untreated OPEFB and increased in digestion of 94% compared to starch as reference.
Abstract: The Niger Delta Region of Nigeria is home to about
20 million people and 40 different ethnic groups. The region has an
area of seventy thousand square kilometers (70,000 KM2) of
wetlands, formed primarily by sediments deposition and makes up
7.5 percent of Nigeria's total landmass. The notable ecological zones
in this region includes: coastal barrier islands; mangrove swamp
forests; fresh water swamps; and lowland rainforests. This incredibly
naturally-endowed ecosystem region, which contains one of the
highest concentrations of biodiversity on the planet, in addition to
supporting abundant flora and fauna, is threatened by the inhuman act
known as gas flaring. Gas flaring is the combustion of natural gas
that is associated with crude oil when it is pumped up from the
ground. In petroleum-producing areas such as the Niger Delta region
of Nigeria where insufficient investment was made in infrastructure
to utilize natural gas, flaring is employed to dispose of this associated
gas. This practice has impoverished the communities where it is
practiced, with attendant environmental, economic and health
challenges. This paper discusses the adverse environmental and
health implication associated with the practice, the role of
Government, Policy makers, Oil companies and the Local
communities aimed at bring this inhuman practice to a prompt end.
Abstract: This study aimed to detect and to identify the main
strains of airborne microorganisms present in the Shanghai Metro
system. Samples were collected using agar plates exposed to the air
and microorganisms were identified using catalase, plasma coagulase
and hymolytic analysis. The results show that the concentration of
mildew present within a newly opened metro line was significantly
higher than for other lines. Differences among underground and
elevated stations can be attributed to differences in passenger flow and
the environment surrounding the stations. Additionally, the
investigation indicated that bacteria reached maximum levels at
different times on weekdays and weekends. The bacteria in the Metro
stations were identified as primarily Gram positive, consisting mainly
of coagulase-negative staphylococcus strains (CNS).
Abstract: In July 2012, an indoor/outdoor monitoring
programme was undertaken in two university sports facilities: a
fronton and a gymnasium. Comfort parameters (temperature, relative
humidity, CO and CO2) and total volatile organic compounds
(VOCs) were continuously monitored. Concentrations of NO2,
carbonyl compounds and individual VOCs were obtained. Low
volume samplers were used to collect particulate matter (PM10). The
minimum ventilation rates stipulated for acceptable indoor air quality
were observed in both sports facilities. It was found that cleaning
activities may have a large influence on the VOC levels. Acrolein
was one of the most abundant carbonyl compounds, showing
concentrations above the recommended limit. Formaldehyde was
detected at levels lower than those commonly reported for other
indoor environments. The PM10 concentrations obtained during the
occupancy periods ranged between 38 and 43μgm-3 in the fronton and
from 154 to 198μgm-3 in the gymnasium.
Abstract: Aptamers are useful tools in microorganism
researches, diagnoses, and treatment. Aptamers are specific target
molecules formed by oligonucleic acid molecules, and are not
decomposed by alcohol. Aptamers used to detect Mycobacterium
tuberculosis (MTB) have been proved to have specific affinity to the
outer membrane proteins of MTB. This article presents a biosensor
chip set with aptamers for early detection of MTB with high specificity
and sensitivity, even in very low concentration. Meanwhile, we have
already made a modified hydrophobic facial mask module with
internal rendering hydrophobic for effectively collecting M.
tuberculosis.
Abstract: A new chelating resin is prepared by coupling Amberlite XAD-4 with 1-amino-2-naphthole through an azo spacer. The resulting sorbent has been characterized by FT-IR, elemental analysis and thermogravimetric analysis (TGA) and studied for preconcentrating of Fe (II) using flame atomic absorption spectrometry (FAAS) for metal monitoring. The optimum pH value for sorption of the iron ions was 6.5. The resin was subjected to evaluation through batch binding of mentioned metal ion. Quantitative desorption occurs instantaneously with 0.5 M HNO3. The sorption capacity was found 4.1 mmol.g-1 of resin for Fe (II) in the aqueous solution. The chelating resin can be reused for 10 cycles of sorption-desorption without any significant change in sorption capacity. A recovery of 97% was obtained the metal ions with 0.5 M HNO3 as eluting agent. The method was applied for metal ions determination from industrial waste water sample.
Abstract: The present models and simulation algorithms of intracellular stochastic kinetics are usually based on the premise that diffusion is so fast that the concentrations of all the involved species are homogeneous in space. However, recents experimental measurements of intracellular diffusion constants indicate that the assumption of a homogeneous well-stirred cytosol is not necessarily valid even for small prokaryotic cells. In this work a mathematical treatment of diffusion that can be incorporated in a stochastic algorithm simulating the dynamics of a reaction-diffusion system is presented. The movement of a molecule A from a region i to a region j of the space is represented as a first order reaction Ai k- ! Aj , where the rate constant k depends on the diffusion coefficient. The diffusion coefficients are modeled as function of the local concentration of the solutes, their intrinsic viscosities, their frictional coefficients and the temperature of the system. The stochastic time evolution of the system is given by the occurrence of diffusion events and chemical reaction events. At each time step an event (reaction or diffusion) is selected from a probability distribution of waiting times determined by the intrinsic reaction kinetics and diffusion dynamics. To demonstrate the method the simulation results of the reaction-diffusion system of chaperoneassisted protein folding in cytoplasm are shown.
Abstract: Heat powered solid sorption is a feasible alternative to
electrical vapor compression refrigeration systems. In this paper,
activated carbon (powder type Maxsorb and fiber type ACF-A10)-
CO2 based adsorption cooling cycles are studied using the pressuretemperature-
concentration (P-T-W) diagram. The specific cooling
effect (SCE) and the coefficient of performance (COP) of these two
cooling systems are simulated for the driving heat source
temperatures ranging from 30 ºC to 90 ºC in terms of different
cooling load temperatures with a cooling source temperature of 25
ºC. It is found from the present analysis that Maxsorb-CO2 couple
shows higher cooling capacity and COP. The maximum COPs of
Maxsorb-CO2 and ACF(A10)-CO2 based cooling systems are found
to be 0.15 and 0.083, respectively. The main innovative feature of
this cooling cycle is the ability to utilize low temperature waste heat
or solar energy using CO2 as the refrigerant, which is one of the best
alternative for applications where flammability and toxicity are not
allowed.
Abstract: Understanding the consumption and production of
various metabolites of fibroblast conditioned media is needed for its
proper and optimized use in expansion of pluripotent stem cells. For
this purpose, we have used the HPLC method to analyse the
consumption of glucose and the production of lactate over time by
mouse embryonic fibroblasts. The experimental data have also been
compared with mathematical model fits. 0.025 moles of lactate was
produced after 72 hrs while the glucose concentration decreased from
0.017 moles to 0.011 moles. The mathematical model was able to
predict the trends of glucose consumption and lactate production.
Abstract: Enhancement of the performance of a reverse osmosis
(RO) unit through periodic control is studied. The periodic control
manipulates the feed pressure and flow rate of the RO unit. To ensure
the periodic behavior of the inputs, the manipulated variables (MV)
are transformed into the form of sinusoidal functions. In this case, the
amplitude and period of the sinusoidal functions become the
surrogate MV and are thus regulated via nonlinear model predictive
control algorithm. The simulation results indicated that the control
system can generate cyclic inputs necessary to enhance the closedloop
performance in the sense of increasing the permeate production
and lowering the salt concentration. The proposed control system can
attain its objective with arbitrary set point for the controlled outputs.
Successful results were also obtained in the presence of modeling
errors.
Abstract: The time dependent progress of a chemical reaction over a flat horizontal plate is here considered. The problem is solved through the group similarity transformation method which reduces the number of independent by one and leads to a set of nonlinear ordinary differential equation. The problem shows a singularity at the chemical reaction order n=1 and is analytically solved through the perturbation method. The behavior of the process is then numerically investigated for n≠1 and different Schmidt numbers. Graphical results for the velocity and concentration of chemicals based on the analytical and numerical solutions are presented and discussed.