Abstract: Ceramics comprise the largest proportion of Korea-s cultural heritage currently preserved (Cited from “The Beauty of Old Ceramics of Korea" written by Yoon Yong-iee). Thus, this researcher conducted this investigation in an attempt to gain insight into Korea-s past culture and the lost period of the colonial period and the Korean War by looking into the ceramics. Korea, China and Japan are part of the similar cultural bloc within the East Asian region. Their porcelains manifest distinctive characteristics by each nation along with similarities. Thus, this research seeks to find the distinctive characteristics of the Korean porcelain by conducting comparative analysis of the similarities and distinctive characteristics. These distinctive characteristics are manifested effectively in the colors of the porcelains following the materials that can be obtained in Korea, China and Japan and production method. Likewise, this research seeks to identify the characteristics of the Korean porcelains- colors based on the comparative analysis of the porcelain colors. The reasons that porcelains were selected were because they are the most well preserved cultural remains in Korea and since they have both similarities and distinctive characteristics due to the cultural interchanges among Korea, China and Japan, which facilitates comparative study. The research targets include Korea, China and Japan-s porcelains. By comparing the colors of the porcelains from Korea, China and Japan that have their distinctive characteristics, this research seeks to identify Korea-specific porcelain colors. These colors derive from the materials that can be obtained only in Korea, and they are affected by the ideologies that governed at the time. This research is meaningful in the sense that this identifies the colors that embraces the Korean culture and provides important data by leveraging the study of the characteristics of the Korea-specific porcelains.
Abstract: The alumosilicate ceramics with mullite crystalline phase are used in various branches of science and technique. The mullite refractory ceramics with high porosity serve as a heat insulator and as a constructional materials [1], [2]. The purpose of the work was to sinter high porosity ceramic and to increase the quantity of mullite phase in this mullite, mullite-corundum ceramics. Two types of compositions were prepared at during the experiment. The first type is compositions with commercial alumina and silica oxides. The second type is from mixing these oxides with 10, 20 and 30 wt.%. of kaolin. In all samples the Al2O3 and SiO2 were in 2.57:1 ratio, because that was conformed to mullite stechiometric compositions (3Al2O3.2SiO2). The types of alumina oxides were α-Al2O3 (d50=4µm) and γ-Al2O3 (d50=80µm). Ratios of α-: γ-Al2O3 were (1:1) or (1:3). The porous materials were prepared by slip casting of suspension of raw materials. The aluminium paste (0.18 wt.%) was used as a pore former. Water content in the suspensions was 26-47 wt.%. Pore formation occurred as a result of hydrogen formation in chemical reaction between aluminium paste and water [2]. The samples were sintered at the temperature of 1650°C and 1750°C for one hour. The increasing amount of kaolin, α-: γ-Al2O3 at the ratio (1:3) and sintering at the highest temperature raised the quantity of mullite phase. The mullite phase began to dominate over the corundum phase.
Abstract: The present research focus on the processing of mullite-based ceramics from oil refinery industrial wastes and byproducts of agricultural industry and on the investigating of silane modified surface of ceramics. Two waste products were used as initial material – waste aluminum oxide and waste rice husk. The burning - out additives used were waste rise husk. It is known that the oxide ceramics surface is hydrophilic due to the presence of – OH groups in it. The nature of ceramic surface regarding permeation of water and hydrocarbons can be changed by further treatment with silanes. The samples were studied mainly by X-ray analysis, FT-IR absorbance measurements and microscopic analysis. The X-ray analyses showed the phase composition depends on the firing temperature and on the purity of the starting alumina. Two kind of silanes were used for the transformation of surface from hydrophilic to hydrophobic – trimethoxymethylsilane (TMMS) and trimethylclorsilane (TMCS).
Abstract: (Bi0.5Na0.5)TiO3 doped with 8 mol % BaTiO3 powder
(BNT-BT0.08), prepared by sol-gel method was compacted and
sintered by Spark Plasma Sintering (SPS) process. The influence of
SPS temperature on the densification of BNT-BT0.08 ceramic was
investigated. Starting from sol-gel nanopowder of BNT-BT
containing 8 mol % BaTiO3 with an average particles size of about
30 nm, were obtained ceramics with density around 98 % of the
theoretical density value when the SPS temperature used was about
850 °C. The average grain size of the resulting ceramics was 80 nm.
The BNT-BT0.08 ceramic sample obtained by SPS method has shown
good electric properties at various frequencies.
Abstract: Ultrasonic machining (USM) is a non-traditional
machining process being widely used for commercial machining of
brittle and fragile materials such as glass, ceramics and
semiconductor materials. However, USM could be a viable
alternative for machining a tough material such as titanium; and this
aspect needs to be explored through experimental research. This
investigation is focused on exploring the use of ultrasonic machining
for commercial machining of pure titanium (ASTM Grade-I) and
evaluation of tool wear rate (TWR) under controlled experimental
conditions. The optimal settings of parameters are determined
through experiments planned, conducted and analyzed using Taguchi
method. In all, the paper focuses on parametric optimization of
ultrasonic machining of pure titanium metal with TWR as response,
and validation of the optimized value of TWR by conducting
confirmatory experiments.
Abstract: Municipal solid waste (MSW) comprises of a wide
range of heterogeneous materials generated by individual, household
or organization and may include food waste, garden wastes, papers,
textiles, rubbers, plastics, glass, ceramics, metals, wood wastes,
construction wastes but it is not limited to the above mentioned
fractions. The most common Municipal Solid Waste pretreatment
method in use is thermal pretreatment (incineration) and Mechanical
Biological pretreatment. This paper presents an overview of these
two pretreatment methods describing their benefits and laboratory
scale reactors that simulate landfill conditions were constructed in
order to compare emissions in terms of biogas production and
leachate contamination between untreated Municipal Solid Waste and
Mechanical Biological Pretreated waste. The findings of this study
showed that Mechanical Biological pretreatment of waste reduces the
emission level of waste and the benefit over the landfilling of
untreated waste is significant.
Abstract: This paper presents an exact solution and a finite element method (FEM) for a Piezoceramic Rod under static load. The cylindrical rod is made from polarized ceramics (piezoceramics) with axial poling. The lateral surface of the rod is traction-free and is unelectroded. The two end faces are under a uniform normal traction. Electrically, the two end faces are electroded with a circuit between the electrodes, which can be switched on or off. Two cases of open and shorted electrodes (short circuit and open circuit) will be considered. Finally, a finite element model will be used to compare the results with an exact solution. The study uses ABAQUS (v.6.7) software to derive the finite element model of the ceramic rod.
Abstract: New lead-free ferroelectric relaxor ceramics were
prepared by conventional solid-state synthesis in the BaTiO3-Bi2O3-
Y2O3 systems. Some of these ceramics present a ferroelectric relaxor
with transition temperature close to room temperature. These new
materials are very interesting for applications and can replace leadbased
ceramic to prevent the toxic pollutions during the preparation
state. In the other hand, the energy band diagram shows the
potentiality of these compounds for the solar energy conversion.
Thus, some compositions have been tested successfully for H2
production upon visible light. The best activity occurs in alkaline
media with a rate evolution of about 0.15 mL g-1 mn-1 and a quantum
yield of 1% under polychromatic light.
Abstract: The paper deals with calculation of the parameters of
ceramic material from a set of destruction tests of ceramic heads of
total hip joint endoprosthesis. The standard way of calculation of the
material parameters consists in carrying out a set of 3 or 4 point
bending tests of specimens cut out from parts of the ceramic material
to be analysed. In case of ceramic heads, it is not possible to cut out
specimens of required dimensions because the heads are too small (if
the cut out specimens were smaller than the normalised ones, the
material parameters derived from them would exhibit higher strength
values than those which the given ceramic material really has). On
that score, a special testing jig was made, in which 40 heads were
destructed. From the measured values of circumferential strains of the
head-s external spherical surface under destruction, the state of stress
in the head under destruction was established using the final elements
method (FEM). From the values obtained, the sought for parameters
of the ceramic material were calculated using Weibull-s weakest-link
theory.
Abstract: Li1.5Al0.5Ti1.5 (PO4)3(LATP) has received much
attention as a solid electrolyte for lithium batteries. In this study, the
LATP solid electrolyte is prepared by the co-precipitation method
using Li3PO4 as a Li source. The LATP is successfully prepared and
the Li ion conductivities of bulk (inner crystal) and total (inner crystal
and grain boundary) are 1.1 × 10-3 and 1.1 × 10-4 S cm-1, respectively.
These values are comparable to the reported values, in which Li2C2O4
is used as the Li source. It is conclude that the LATP solid electrolyte
can be prepared by the co-precipitation method using Li3PO4 as the Li
source and this procedure has an advantage in mass production over
previous procedure using Li2C2O4 because Li3PO4 is lower price
reagent compared with Li2C2O4.
Abstract: Simulation of occlusal function during laboratory
material-s testing becomes essential in predicting long-term
performance before clinical usage. The aim of the study was to assess
the influence of chamfer preparation depth on failure risk of heat
pressed ceramic crowns with and without zirconia framework by
means of finite element analysis. 3D models of maxillary central
incisor, prepared for full ceramic crowns with different depths of the
chamfer margin (between 0.8 and 1.2 mm) and 6-degree tapered
walls together with the overlying crowns were generated using
literature data (Fig. 1, 2). The crowns were designed with and
without a zirconia framework with a thickness of 0.4 mm. For all
preparations and crowns, stresses in the pressed ceramic crown,
zirconia framework, pressed ceramic veneer, and dentin were
evaluated separately. The highest stresses were registered in the
dentin. The depth of the preparations had no significant influence on
the stress values of the teeth and pressed ceramics for the studied
cases, only for the zirconia framework. The zirconia framework
decreases the stress values in the veneer.
Abstract: Fatigue behaviors of Lead Zirconate Titanate (PZT)
ceramics under different amplitude of bipolar electrical loads have
been investigated. Fatigue behavior is represented by the change of
hysteresis loops and remnant polarization. Three levels of electrical
load amplitudes (1.00, 1.25 and 1.50 kV /mm) were applied in this
experimental. It was found that the remnant polarization decreased
significantly with the number of loading cycles. The degree of fatigue
degradation depends on the amplitude of electric field. The higher
amplitude exhibits the greater fatigue degradation.
Abstract: This study investigated a strategy of blending lead-laden sludge and Al-rich precursors to reduce the release of metals from the stabilized products. Using PbO as the simulated lead-laden sludge to sinter with γ-Al2O3 by Pb:Al molar ratios of 1:2 and 1:12, PbAl2O4 and PbAl12O19 were formed as final products during the sintering process, respectively. By firing the PbO + γ-Al2O3 mixtures with different Pb/Al molar ratios at 600 to 1000 °C, the lead transformation was determined through X-ray diffraction (XRD) data. In Pb/Al molar ratio of 1/2 system, the formation of PbAl2O4 is initiated at 700 °C, but an effective formation was observed above 750 °C. An intermediate phase, Pb9Al8O21, was detected in the temperature range of 800-900 °C. However, different incorporation behavior for sintering PbO with Al-rich precursors at a Pb/Al molar ratio of 1/12 was observed during the formation of PbAl12O19 in this system. In the sintering process, both temperature and time effect on the formation of PbAl2O4 and PbAl12O19 phases were estimated. Finally, a prolonged leaching test modified from the U.S. Environmental Protection Agency-s toxicity characteristic leaching procedure (TCLP) was used to evaluate the durability of PbO, Pb9Al8O21, PbAl2O4 and PbAl12O19 phases. Comparison for the leaching results of the four phases demonstrated the higher intrinsic resistance of PbAl12O19 against acid attack.
Abstract: Ranong province has the best kaolin, and it is the most
useful of all the clay types used in ceramic making. Until recently,
there has been only one community business making ceramics in
Ranong province. And this business could not build the mix of body
and glaze from their raw material without assistance. Considering
these problems, this research is aimed to test the composition of
ceramic body and glaze which suit. Kaolin from Ranong is the raw
material which these search focuses on. All other raw materials use in
the investigation will come from southern Thailand, kaolin and
limestone from Ranong province, ball clay from Surat Thani
province, white sand from Songkhla province, and feldspar from
Nakhon Si Thammarat province. Results can be used to develop the
efficiency of industrial production which in return will enhance the
business process.
Abstract: Abrasive Jet Machining is an Unconventional
machining process in which the metal is removed from brittle and
hard material in the form of micro-chips. With increase in need of
materials like ceramics, composites, in manufacturing of various
Mechanical & Electronic components, AJM has become a useful
technique for micro machining. The present study highlights the
influence of different parameters like Pressure, SOD, Time, Abrasive
grain size, nozzle diameter on the Metal removal of FRP (Fiber
Reinforced Polymer) composite by Abrasive jet machining. The
results of the Experiments conducted were analyzed and optimized
with TAGUCHI method of Optimization and ANOVA for Optimal
Value.
Abstract: Nowadays, engineering ceramics have significant
applications in different industries such as; automotive, aerospace,
electrical, electronics and even martial industries due to their
attractive physical and mechanical properties like very high hardness
and strength at elevated temperatures, chemical stability, low friction
and high wear resistance. However, these interesting properties plus
low heat conductivity make their machining processes too hard,
costly and time consuming. Many attempts have been made in order
to make the grinding process of engineering ceramics easier and
many scientists have tried to find proper techniques to economize
ceramics' machining processes. This paper proposes a new diamond
plunge grinding technique using ultrasonic vibration for grinding
Alumina ceramic (Al2O3). For this purpose, a set of laboratory
equipments have been designed and simulated using Finite Element
Method (FEM) and constructed in order to be used in various
measurements. The results obtained have been compared with the
conventional plunge grinding process without ultrasonic vibration
and indicated that the surface roughness and fracture strength
improved and the grinding forces decreased.
Abstract: Properties of cement pastes with fine-ground ceramics
used as an alternative binder replacing Portland cement up to 20% of
its mass are investigated. At first, the particle size distribution of
cement and fine-ground ceramics is measured using laser analyser.
Then, the material properties are studied in the early hardening
period up to 28 days. The hydration process of studied materials is
monitored by electrical conductivity measurement using TDR
sensors. The changes of materials- structures within the hardening are
observed using pore size distribution measurement. The compressive
strength measurements are done as well. Experimental results show
that the replacement of Portland cement by fine-ground ceramics in
the amount of up to 20% by mass is acceptable solution from the
mechanical point of view. One can also assume similar physical
properties of designed materials to the reference material with only
Portland cement as binder.
Abstract: A numerical study on the heat transfer in the thermal
barrier coatings and the substrates of a parallel-plate enclosure is
carried out. Some of the thermal barrier coatings, such as ceramics, are
semitransparent and are of interest for high-temperature applications
where radiation effects are significant. The radiative transfer equations
and the energy equations are solved by using the discrete ordinates
method and the finite difference method. Illustrative results are
presented for temperature distributions in the coatings and the opaque
walls under various heating conditions. The results show that the
temperature distribution is more uniform in the interior portion of each
coating away from its boundary for the case with a larger average of
varying refractive index and a positive gradient of refractive index
enhances radiative transfer to the substrates.
Abstract: Commercial hydroxyapatite (HA) was reinforced by
adding 2, 5, and 10 wt % of 28.5%CaO-28.5%P2O5-38%Na2 O-
5%CaF2 based glass and then sintered. Although HA shows good
biocompatibility with the human body, its applications are limited to
non load-bearing areas and coatings due to its poor mechanical
properties. These mechanical properties can be improved
substantially with addition of glass ceramics by sintering. In this
study, the effects of sintering hydroxyapatite with above specified
phosphate glass additions are quantified. Each composition was
sintered over a range of temperatures. Scanning electron microscopy
and x-ray diffraction were used to characterize the microstructure and
phases of the composites. The density, microhardness, and
compressive strength were measured using Archimedes Principle,
Vickers Microhardness Tester (at 0.98 N), and Instron Universal
Testing Machine (cross speed of 0.5 mm/min) respectively. These
results were used to indicate which composition provided suitable
material for use in hard tissue replacement. Composites containing 10
wt % glass additions formed dense HA/TCP (tricalcium phosphate)
composite materials possessing good compressive strength and
hardness than HA. In-vitro bioactivity was assessed by evaluating
changes in pH and Ca2+ ion concentration of SBF-simulated body
fluid on immersion of these composites in it for two weeks.
Abstract: Considering toxicity of heavy metals and their
accumulation in domestic wastes, immobilization of lead and
cadmium is envisaged inside glass-ceramics. We particularly
focused this work on calcium-rich phases embedded in a
glassy matrix.
Glass-ceramics were synthesized from glasses doped with
12 wt% and 16 wt% of PbO or CdO. They were observed and
analyzed by Electron MicroProbe Analysis (EMPA) and
Analytical Scanning Electron Microscopy (ASEM). Structural
characterization of the samples was performed by powder XRay
Diffraction.
Diopside crystals of CaMgSi2O6 composition are shown to
incorporate significant amounts of cadmium (up to 9 wt% of
CdO). Two new crystalline phases are observed with very
high Cd or Pb contents: about 40 wt% CdO for the cadmiumrich
phase and near 60 wt% PbO for the lead-rich phase. We
present complete chemical and structural characterization of
these phases. They represent a promising way for the
immobilization of toxic elements like Cd or Pb since glass
ceramics are known to propose a “double barrier" protection
(metal-rich crystals embedded in a glass matrix) against metal
release in the environment.