Abstract: In a pilot plant scale of a fluidized bed reactor, a
reduction reaction of sodium sulfate by natural gas has been
investigated. Natural gas is applied in this study as a reductant. Feed
density, feed mass flow rate, natural gas and air flow rate
(independent parameters)and temperature of bed and CO
concentration in inlet and outlet of reactor (dependent parameters)
were monitored and recorded at steady state. The residence time was
adjusted close to value of traditional reaction [1]. An artificial neural
network (ANN) was established to study dependency of yield and
carbon gradient on operating parameters. Resultant 97% accuracy of
applied ANN is a good prove that natural gas can be used as a
reducing agent. Predicted ANN model for relation between other
sources carbon gradient (accuracy 74%) indicates there is not a
meaningful relation between other sources carbon variation and
reduction process which means carbon in granule does not have
significant effect on the reaction yield.
Abstract: High purity hydrogen and the valuable by-product of carbon nanotubes (CNTs) can be produced by the methane catalytic decomposition. The methane conversion and the performance of CNTs were determined by the choices of catalysts and the condition of decomposition reaction. In this paper, Ni/MgO and Ni/O-D (oxidized diamond) catalysts were prepared by wetness impregnation method. The effects of reaction temperature and space velocity of methane on the methane conversion were investigated in a fixed-bed. The surface area, structure and micrography were characterized with BET, XPS, SEM, EDS technology. The results showed that the conversion of methane was above 8% within 150 min (T=500) for 33Ni/O-D catalyst and higher than 25% within 120 min (T=650) for 41Ni/MgO catalyst. The initial conversion increased with the increasing temperature of the decomposition reaction, but their catalytic activities decreased rapidly while at too higher temperature. To decrease the space velocity of methane was propitious to promote the methane conversion, but not favor of the hydrogen yields. The appearance of carbon resulted from the methane decomposition lied on the support type and the condition of catalytic reaction. It presented as fiber shape on the surface of Ni/O-D at the relatively lower temperature such as 500 and 550, but as grain shape stacked on and overlayed on the surface of the metal nickel while at 650. The carbon fiber can form on the Ni/MgO surface at 650 and the diameter of the carbon fiber increased with the decreasing space velocity.
Abstract: CO2 is the primary anthropogenic greenhouse gas,
accounting for 77% of the human contribution to the greenhouse
effect in 2004. In the recent years, global concentration of CO2 in the
atmosphere is increasing rapidly. CO2 emissions have an impact on
global climate change. Anthropogenic CO2 is emitted primarily from
fossil fuel combustion. Carbon capture and storage (CCS) is one
option for reducing CO2 emissions. There are three major approaches
for CCS: post-combustion capture, pre-combustion capture and
oxyfuel process. Post-combustion capture offers some advantages as
existing combustion technologies can still be used without radical
changes on them.
There are several post combustion gas separation and capture
technologies being investigated, namely; (a) absorption, (b)
cryogenic separation, (c) membrane separation (d) micro algal biofixation
and (e) adsorption. Apart from establishing new techniques,
the exploration of capture materials with high separation performance
and low capital cost are paramount importance. However, the
application of adsorption from either technology, require easily
regenerable and durable adsorbents with a high CO2 adsorption
capacity. It has recently been reported that the cost of the CO2
capture can be reduced by using this technology. In this paper, the
research progress (from experimental results) in adsorbents for CO2
adsorption, storage, and separations were reviewed and future
research directions were suggested as well.
Abstract: IFP Group Technology “Sulfrex process" was used in
Iran-s South Pars Gas Complex Refineries for removing sulfur
compounds such as mercaptans, carbonyl sulfide and hydrogen
sulfide, which uses sulfonated cobalt phthalocyanine dispersed in
alkaline solution as catalyst. In this technology, catalyst and alkaline
solution were used circularly. However the stability of catalyst due to
effect of some parameters would reduce with the running of the unit
and therefore sweetening efficiency would be decreased. Hence, the
aim of this research is study the factors effecting on the stability of
catalyst.
Abstract: Geopolymer cement was evaluated as wellbore sealing material for carbon dioxide geosequestration application. Curing of cement system in saline water and strength testing in triaxial stress state condition under lateral confinement is relevant to primary cementing in CO2 geosequestration wellbore in saline aquifer. Geopolymer cement was cured in saline water (both at ambient conditions for 28 days and heated (60°C) conditions for 12 hours) and tested for triaxial strength at different levels of lateral confinement. Normal water and few other curing techniques were also studied both for geopolymer and API ‘G’ cement. Results reported were compared to evaluate the suitability of saline water for curing of geopolymer cement. Unconfined compression test results showed higher strength for curing in saline water than normal water. Besides, testing strength under lateral confinement demonstrated the material failure behavior from brittle to plastic.
Abstract: In the present work, an attempt has been made to
understand the feasibility of using UHF technique for identification
of any corona discharges/ arcing in insulating material due to water
droplets. The sensors of broadband type are useful for identification
of such discharges. It is realised that arcing initiated by liquid droplet
radiates UHF signals in the entire bandwidth up to 2 GHz. The
frequency content of the UHF signal generated due to corona/arcing
is not much varied in epoxy nanocomposites with different weight
percentage of clay content. The exfoliated/intercalated properties
were analysed through TEM studies. It is realized that corona
initiated discharges are of intermittent process. The hydrophobicity
of the material characterized through contact angle measurement. It
is realized that low Wt % of nanoclay content in epoxy resin reduces
the surface carbonization due to arcing/corona discharges. The results
of the study with gamma irradiated specimen indicates that contact
angle, discharge inception time and evaporation time of the liquid are
much lower than the virgin epoxy nanocomposite material.
Abstract: The purpose of the study was to determine the amount of Palm Kernel Oil (PKO) extracted from a packed bed of palm kernels in a supercritical fluid extractor using supercritical carbon dioxide (SC-CO2) as an environmental friendly solvent. Further, the study sought to ascertain the values of the overall mass transfer coefficient (K) of PKO evaluation through a mass transfer model, at constant temperature of 50 °C, 60 °C, and 70 °C and pressures range from 27.6 MPa, 34.5 MPa, 41.4 MPa and 48.3 MPa respectively. Finally, the study also seeks to demonstrate the application of the overall mass transfer coefficient values in relation to temperature and pressure. The overall mass transfer coefficient was found to be dependent pressure at each constant temperature of 50 °C, 60 °C and 70 °C. The overall mass transfer coefficient for PKO in a packed bed of palm kernels was found to be in the range of 1.21X 10-4 m min-1 to 1.72 X 10-4 m min-1 for a constant temperature of 50 °C and in the range of 2.02 X 10-4 m min-1 to 2.43 X 10-4 m min-1 for a constant temperature of 60 °C. Similar increasing trend of the overall mass transfer coefficient from 1.77 X 10-4 m min-1 to 3.64 X 10-4 m min-1 was also observed at constant temperature of 70 °C within the same pressure range from 27.6 MPa to 48.3 MPa.
Abstract: Low carbon deep drawing steel DC 01 according to EN 10130-91 was nitrooxidized in dissociated ammonia at 580°C/45 min and consequently oxidised at 380°C/5 min in vapour of distilled water. Material after nitrooxidation had 54 % increase of yield point, 34 % increase of strength and 10-times increased resistance to atmospheric corrosion in comparison to the material before nitrooxidation. The microstructure of treated material consisted of thin ε-phase layer connected to layer containing precipitated massive needle shaped Fe4N - γ' nitrides. This layer passed to a diffusion layer consisting of fine irregular shaped Fe16N2 - α'' nitrides regularly dispersed in ferritic matrix. Fatigue properties were examined under bending load with frequency of 20 kHz and sinusoidal symmetric cycle. The results confirmed positive influence of nitrooxidation on fatigue properties as fatigue limit of treated material was double in comparison to untreated material.
Abstract: Despite of the preponderant role played by cement among the construction materials, it is today considered as a material destructing the environment due to the large quantities of carbon dioxide exhausted during its manufacture. Besides, global warming is now recognized worldwide as the new threat to the humankind against which advanced countries are investigating measures to reduce the current amount of exhausted gases to the half by 2050. Accordingly, efforts to reduce green gases are exerted in all industrial fields. Especially, the cement industry strives to reduce the consumption of cement through the development of alkali-activated geopolymer mortars using industrial byproducts like bottom ash. This study intends to gather basic data on the flowability and strength development characteristics of alkali-activated geopolymer mortar by examining its FT-IT features with respect to the effects and strength of the alkali-activator in order to develop bottom ash-based alkali-activated geopolymer mortar. The results show that the 35:65 mass ratio of sodium hydroxide to sodium silicate is appropriate and that a molarity of 9M for sodium hydroxide is advantageous. The ratio of the alkali-activators to bottom ash is seen to have poor effect on the strength. Moreover, the FT-IR analysis reveals that larger improvement of the strength shifts the peak from 1060 cm–1 (T-O, T=Si or Al) toward shorter wavenumber.
Abstract: In this study acoustic emission (AE) signals obtained during deformation and fracture of two types of ferrite-martensite dual phase steels (DPS) specimens have been analyzed in frequency domain. For this reason two low carbon steels with various amounts of carbon were chosen, and intercritically heat treated. In the introduced method, identifying the mechanisms of failure in the various phases of DPS is done. For this aim, AE monitoring has been used during tensile test of several DPS with various volume fraction of the martensite (VM) and attempted to relate the AE signals and failure mechanisms in these steels. Different signals, which referred to 2-3 micro-mechanisms of failure due to amount of carbon and also VM have been seen. By Fast Fourier Transformation (FFT) of signals in distinct locations, an excellent relationship between peak frequencies in these areas and micro-mechanisms of failure were seen. The results were verified by microscopic observations (SEM).
Abstract: This study investigated the use of modified
atmosphere packaging (MAP) and different packaging to extend the
shelf life of Barbari flat bread. Three atmospheres including 70%CO2
and 30%N2, 50% CO2 and 50%N2 and a normal air as control were
used. The bread samples were packaged in three type pouches. The
shelf life was determined by appearance of mold and yeast (M +Y) in
Barbari bread samples stored at 25 ± 1°C and 38 ± 2% relative
humidity. The results showed that it is possible to prolong the shelf
life of Barbari bread from four days to about 21 days by using
modified atmosphere packaging with high carbon dioxide
concentration and high-barrier laminated and vacuum bags packages.
However, the hardness of samples kept in MAP increase significantly
by increase of carbon dioxide concentration. The correlation
coefficient (r) between headspace CO2 concentration and hardness
was 0.997, 0.997 and 0.599 for A, B and C packaging respectively.
High negative correlation coefficients were found between the crumb
moisture and the hardness values in various packaging. There were
significant negative correlation coefficients between sensory
parameters and hardness of texture.
Abstract: Regarding previous research studies it was concluded
that thin-walled fiber-cement composites are able to conduct electric
current under specific conditions. This property is ensured by using
of various kinds of carbon materials. Though carbon fibers are less
conductive than metal fibers, composites with carbon fibers were
evaluated as better current conductors than the composites with metal
fibers. The level of electric conductivity is monitored by the means of
impedance measurement of designed samples. These composites
could be used for a range of applications such as heating of
trafficable surfaces or shielding of electro-magnetic fields.
The aim of the present research was to design an element with the
ability to monitor internal processes in building structures and
prevent them from collapsing. As a typical element for laboratory
testing there was chosen a concrete column, which was repeatedly
subjected to load by simple pressure with continual monitoring of
changes in electrical properties.
Abstract: This paper discusses on the use of Spline Interpolation
and Mean Square Error (MSE) as tools to process data acquired from
the developed simulator that shall replicate sea bed logging environment.
Sea bed logging (SBL) is a new technique that uses marine
controlled source electromagnetic (CSEM) sounding technique and is
proven to be very successful in detecting and characterizing hydrocarbon
reservoirs in deep water area by using resistivity contrasts. It uses
very low frequency of 0.1Hz to 10 Hz to obtain greater wavelength.
In this work the in house built simulator was used and was provided
with predefined parameters and the transmitted frequency was varied
for sediment thickness of 1000m to 4000m for environment with and
without hydrocarbon. From series of simulations, synthetics data were
generated. These data were interpolated using Spline interpolation
technique (degree of three) and mean square error (MSE) were
calculated between original data and interpolated data. Comparisons
were made by studying the trends and relationship between frequency
and sediment thickness based on the MSE calculated. It was found
that the MSE was on increasing trends in the set up that has the
presence of hydrocarbon in the setting than the one without. The MSE
was also on decreasing trends as sediment thickness was increased
and with higher transmitted frequency.
Abstract: Air infiltration in mass scale industrial applications of
bio char production is inevitable. The presence of oxygen during the
carbonization process is detrimental to the production of biochar yield
and properties. The experiment was carried out on several wood
species in a fixed-bed pyrolyser under various fractions of oxygen
ranging from 0% to 11% by varying nitrogen and oxygen composition
in the pyrolysing gas mixtures at desired compositions. The bed
temperature and holding time were also varied. Process optimization
was carried out by Response Surface Methodology (RSM) by
employing Central Composite Design (CCD) using Design Expert 6.0
Software. The effect of oxygen ratio and holding time on biochar yield
within the range studied were statistically significant. From the
analysis result, optimum condition of 15.2% biochar yield of
mangrove wood was predicted at pyrolysis temperature of 403 oC,
oxygen percentage of 2.3% and holding time of two hours. This
prediction agreed well with the experiment finding of 15.1% biochar
yield.
Abstract: This work presents the experimental results obtained
at a pilot plant which works with a slow, wet and catalytic pyrolysis
process of dry fowl manure. This kind of process mainly consists in
the cracking of the organic matrix and in the following reaction of
carbon with water, which is either already contained in the organic
feed or added, to produce carbon monoxide and hydrogen. Reactions
are conducted in a rotating reactor maintained at a temperature of
500°C; the required amount of water is about 30% of the dry organic
feed. This operation yields a gas containing about 59% (on a volume
basis) of hydrogen, 17% of carbon monoxide and other products such
as light hydrocarbons (methane, ethane, propane) and carbon
monoxide in lesser amounts. The gas coming from the reactor can be
used to produce not only electricity, through internal combustion
engines, but also heat, through direct combustion in industrial
boilers. Furthermore, as the produced gas is devoid of both solid
particles and pollutant species (such as dioxins and furans), the
process (in this case applied to fowl manure) can be considered as an
optimal way for the disposal and the contemporary energetic
valorization of organic materials, in such a way that is not damaging
to the environment.
Abstract: Cashew nut shells were converted into activated carbon powders using KOH activation plus CO2 gasification at 1027 K. The increase both of impregnation ratio and activation time, there was swiftly the development of mesoporous structure with increasing of mesopore volume ratio from 20-28% and 27-45% for activated carbon with ratio of KOH per char equal to 1 and 4, respectively. Activated carbon derived from KOH/char ratio equal to 1 and CO2 gasification time from 20 to 150 minutes were exhibited the BET surface area increasing from 222 to 627 m2.g-1. And those were derived from KOH/char ratio of 4 with activation time from 20 to 150 minutes exhibited high BET surface area from 682 to 1026 m2.g-1. The adsorption of Lead(II) and Cadmium(II) ion was investigated. This adsorbent exhibited excellent adsorption for Lead(II) and Cadmium(II) ion. Maximum adsorption presented at 99.61% at pH 6.5 and 98.87% at optimum conditions. The experimental data was calculated from Freundlich isotherm and Langmuir isotherm model. The maximum capacity of Pb2+ and Cd2+ ions was found to be 28.90 m2.g-1 and 14.29 m2.g-1, respectively.
Abstract: This study addresses the effect of impurities on the
crystallization of Na2CO3 produced within a strategy for capturing
CO2 from flue gases by alkaline absorption. A novel technology -
membrane assisted crystallization - is proposed for Na2CO3
crystallization from mother liquors containing impurities. High purity
of Na2CO3•10H2O crystals was obtained without impacting the
performance of the mass transfer of water vapor through membranes
during crystallization.
Abstract: Cement, the most widely used construction material
is very brittle and characterized by low tensile strength and strain
capacity. Macro to nano fibers are added to cement to provide
tensile strength and ductility to it. Carbon Nanotube (CNT), one of
the nanofibers, has proven to be a promising reinforcing material in
the cement composites because of its outstanding mechanical
properties and its ability to close cracks at the nano level. The
experimental investigations for CNT reinforced cement is costly,
time consuming and involves huge number of trials. Mathematical
modeling of CNT reinforced cement can be done effectively and
efficiently to arrive at the mechanical properties and to reduce the
number of trials in the experiments. Hence, an attempt is made to
numerically study the effective mechanical properties of CNT
reinforced cement numerically using Representative Volume
Element (RVE) method. The enhancement in its mechanical
properties for different percentage of CNTs is studied in detail.
Abstract: The overall objective of this research is a strain
improvement technology for efficient pectinase production. A novel
cells cultivation technology by immobilization of fungal cells has
been studied in long time continuous fermentations. Immobilization
was achieved by using of new material for absorption of stores of
immobilized cultures which was for the first time used for
immobilization of microorganisms. Effects of various conditions of
nitrogen and carbon nutrition on the biosynthesis of pectolytic
enzymes in Aspergillus awamori 1-8 strain were studied. Proposed
cultivation technology along with optimization of media components
for pectinase overproduction led to increased pectinase productivity
in Aspergillus awamori 1-8 from 7 to 8 times. Proposed technology
can be applied successfully for production of major industrial
enzymes such as α-amylase, protease, collagenase etc.
Abstract: Natural organic matter (NOM) is heterogeneous
mixture of organic compounds that enter the water media from
animal and plant remains, domestic and industrial wastes.
Researches showed that NOM is likely precursor material for
disinfection by products (DBPs). Chlorine very commenly used for
disinfection purposes and NOM and chlorine reacts then
Trihalomethane (THM) and Haloacetic acids (HAAs) which are
cancerogenics for human health are produced. The aim of the study is
to search NOM removal by enhanced coagulation from drinking
water source of Eskisehir which is supplied from Porsuk Dam.
Recently, Porsuk dam water is getting highly polluted and therefore
NOM concentration is increasing. Enhanced coagulation studies were
evaluated by measurement of Dissolved Organic Carbon (DOC), UV
absorbance at 254 nm (UV254), and different trihalomethane
formation potential (THMFP) tests. Results of jar test experiments
showed that NOM can be removed from water about 40-50 % of
efficiency by enhanced coagulation. Optimum coagulant type and
coagulant dosages were determined using FeCl3 and Alum.