Abstract: This study addresses the effect of impurities on the
crystallization of Na2CO3 produced within a strategy for capturing
CO2 from flue gases by alkaline absorption. A novel technology -
membrane assisted crystallization - is proposed for Na2CO3
crystallization from mother liquors containing impurities. High purity
of Na2CO3•10H2O crystals was obtained without impacting the
performance of the mass transfer of water vapor through membranes
during crystallization.