Abstract: Environmental decision making, particularly about
hazardous waste management, is inherently exposed to a high
potential conflict, principally because of the trade-off between sociopolitical,
environmental, health and economic factors. The need to
plan complex contexts has led to an increasing request for decision
analytic techniques as support for the decision process. In this work,
alternative systems of asbestos-containing waste management
(ACW) in Puglia (Southern Italy) were explored by a multi-criteria
decision analysis. In particular, through Analytic Hierarchy Process
five alternatives management have been compared and ranked
according to their performance and efficiency, taking into account
environmental, health and socio-economic aspects. A separated
valuation has been performed for different temporal scale. For short
period results showed a narrow deviation between the disposal
alternatives “mono-material landfill in public quarry" and “dedicate
cells in existing landfill", with the best performance of the first one.
While for long period “treatment plant to eliminate hazard from
asbestos-containing waste" was prevalent, although high energy
demand required to achieve the change of crystalline structure. A
comparison with results from a participative approach in valuation
process might be considered as future development of method
application to ACW management.
Abstract: In this paper, the application of the Mode Matching
(MM) method in the case of photonic crystal waveguide
discontinuities is presented. The structure under consideration is
divided into a number of cells, which supports a number of guided
and evanescent modes. These modes can be calculated numerically
by an alternative formulation of the plane wave expansion method
for each frequency. A matrix equation is then formed relating the
modal amplitudes at the beginning and at the end of the structure.
The theory is highly efficient and accurate and can be applied to
study the transmission sensitivity of photonic crystal devices due to
fabrication tolerances. The accuracy of the MM method is compared
to the Finite Difference Frequency Domain (FDFD) and the Adjoint
Variable Method (AVM) and good agreement is observed.
Abstract: In this paper, the absorption and fluorescence
emission spectra of Yb:Y3Al5O12 (YAG)(25 at%) crystal as a disk
laser medium are measured at high temperature (300-450K). The
absorption and emission cross sections of Yb:YAG crystal are
determined using Reciprocity method. Temperature dependence of
941nm absorption cross section and 1031nm emission cross section
is extracted in the range of 300-450K. According to our experimental
results, an exponential temperature dependence between 300K and
450K is acquired for the 1031nm peak emission cross section and
also for 941nm peak absorption cross section of Yb:YAG crystal.
These results could be used for simulation and design of high power
highly doped Yb:YAG thin disk lasers.
Abstract: In the Fe-3%Si sheets, grade Hi-B, with AlN and MnS
as inhibitors, the Goss grains which abnormally grow do not have a
size greater than the average size of the primary matrix. In this
heterogeneous microstructure, the size factor is not a required
condition for the secondary recrystallization. The onset of the small
Goss grain abnormal growth appears to be related to a particular
behavior of their grain boundaries, to the local texture and to the
distribution of the inhibitors. The presence and the evolution of
oriented clusters ensure to the small Goss grains a favorable
neighborhood to grow. The modified Monte-Carlo approach, which
is applied, considers the local environment of each grain. The grain
growth is dependent of its real spatial position; the matrix
heterogeneity is then taken into account. The grain growth conditions
are considered in the global matrix and in different matrixes
corresponding to A component clusters. The grain growth behaviour
is considered with introduction of energy only, energy and mobility,
energy and mobility and precipitates.
Abstract: Single crystals of Magnesium alloys such as Mg-1Al,
Mg-1Zn-0.5Y, Mg-3Li, and AZ31 alloys were successfully fabricated in this study by employing the modified Bridgman method. Single
crystals of pure Mg were also made in this study. To determine the exact orientation of crystals, Laue back-reflection method and pole figure measurement were carried out on each single crystal. Dimensions of single crystals were 10 mm in diameter and 120 mm in
length. Hardness and compression tests were conducted and the results
revealed that hardness and the strength strongly depended on the
orientation. The closer to basal one the orientation was, the higher hardness and compressive strength were. The effect of alloying was
not higher than that of orientation. After compressive deformation of single crystals, the orientation of the crystals was found to rotate and to be parallel to the basal orientation.
Abstract: Zinc oxide thin films with various microstructures
were grown on substrates by using HCOOH-sols. The reaction
mechanism of the sol system was investigated by performing an XPS
analysis of as-synthesized films, due to the products of hydrolysis
and condensation in the sol system contributing to the chemical state
of the as-synthesized films. The chemical structures of the assynthesized
films related to the microstructures of the final annealed
films were also studied. The results of the Zn 2p3/2, C 1s and O1s
XPS patterns indicate that the hydrolysis reaction in the sol system is
strongly influenced by the HCOOH agent. The results of XRD and
FE-SEM demonstrated the microstructures of the annealed films are
related to the content of hydrolyzed zinc hydrate (Zn-OH) species
present, and that content of the Zn-OH species in the sol system
increases the HCOOH adding, and these Zn-OH species existing in
the sol phase are responsible for large ZnO crystallites in the final
annealed films.
Abstract: Pyritisation halos are identified in weathering crusts and unconsolidated formations at five locations within large fault structure of the Urals’ eastern slope. Electron microscopy reveals the presence of inclusions and growths on pyrite faces – normally on cubic pyrite with striations, or combinations of cubes and other forms. Following neogenesis types are established: native elements and intermetallic compounds (including gold and silver), halogenides, sulphides, sulfosalts, tellurides, sulphotellurides,
selenides, tungstates, sulphates, phosphates, carbon-based substances. Direct relationship is noted between amount and diversity of such mineral phases, and proximity to and scale of ore-grade mineralization. Gold and silver, both in native form and within tellurides, presence of lead (galena, native lead), native tungsten, and, possibly, molybdenite and sulfosalts can indicate gold-bearing formations. First find of native tungsten in the Urals is for the first time – in crystallised and druse-like form. Link is suggested between unusual mineralization and “reducing” hydrothermal fluids from deep-seated faults at later stages of Urals’ reactivation.
Abstract: We investigated a modified thermal evaporation
method in the growth process of ZnO nanowires. ZnO nanowires
were fabricated on p-type silicon substrates without using a metal
catalyst. A simple horizontal double-tube system along with
chemical vapor diffusion of the precursor was used to grow the ZnO
nanowires. The substrates were placed in different temperature
zones, and ZnO nanowires with different diameters were obtained for
the different substrate temperatures. In addition to the nanowires,
ZnO microdiscs with different diameters were obtained on another
substrate, which was placed at a lower temperature than the other
substrates. The optical properties and crystalline quality of the ZnO
nanowires and microdiscs were characterized by room temperature
photoluminescence (PL) and Raman spectrometers. The PL and
Raman studies demonstrated that the ZnO nanowires and microdiscs
grown using such set-up had good crystallinity with excellent optical
properties. Rectifying behavior of ZnO/Si heterostructures was
characterized by a simple DC circuit.
Abstract: The worldwide prevalence of H3N2 influenza virus
and its increasing resistance to the existing drugs necessitates for the
development of an improved/better targeting anti-influenza drug.
H3N2 influenza neuraminidase is one of the two membrane-bound
proteins belonging to group-2 neuraminidases. It acts as key player
involved in viral pathogenicity and hence, is an important target of
anti-influenza drugs. Oseltamivir is one of the potent drugs targeting
this neuraminidase. In the present work, we have taken subtype N2
neuraminidase as the receptor and probable analogs of oseltamivir as
drug molecules to study the protein-drug interaction in anticipation of
finding efficient modified candidate compound. Oseltamivir analogs
were made by modifying the functional groups using Marvin Sketch
software and were docked using Schrodinger-s Glide. Oseltamivir
analog 10 was detected to have significant energy value (16% less
compared to Oseltamivir) and could be the probable lead molecule. It
infers that some of the modified compounds can interact in a novel
manner with increased hydrogen bonding at the active site of
neuraminidase and it might be better than the original drug. Further
work can be carried out such as enzymatic inhibition studies;
synthesis and crystallizing the drug-target complex to analyze the
interactions biologically.
Abstract: In this study, structural, mechanical, thermal and
electrical properties of poly (lactic acid) (PLA) nanocomposites with
low-loaded (0-1.5 wt%) untreated, heat and nitric acid treated multiwalled
carbon nanotubes (MWCNTs) were studied. Among the
composites, untreated 0.5 wt % MWCNTs and acid-treated 1.0 wt%
MWCNTs reinforced PLA show the tensile strength and modulus
values higher than the others. These two samples along with pure
PLA exhibit the stable orthorhombic α-form, whilst other samples
reveal the less stable orthorhombic β-form, as demonstrated by X-ray
diffraction study. Differential scanning calorimetry reveals the
evolution of the mentioned different phases by controlled cooling and
discloses an enhancement of PLA crystallization by nanotubes
incorporation. Thermogravimetric analysis shows that the MWCNTs
loaded sample degraded faster than PLA. Surface resistivity of the
nanocomposites is found to be dropped drastically by a factor of 1013
with a low loading of MWCNTs (1.5 wt%).
Abstract: The nanotechnology based on epitaxial systems
includes single or arranged misfit dislocations. In general, whatever
is the type of dislocation or the geometry of the array formed by the
dislocations; it is important for experimental studies to know exactly
the stress distribution for which there is no analytical expression [1,
2]. This work, using a numerical analysis, deals with relaxation of
epitaxial layers having at their interface a periodic network of edge
misfit dislocations. The stress distribution is estimated by using
isotropic elasticity. The results show that the thickness of the two
sheets is a crucial parameter in the stress distributions and then in the
profile of the two sheets.
A comparative study between the case of single dislocation and
the case of parallel network shows that the layers relaxed better when
the interface is covered by a parallel arrangement of misfit.
Consequently, a single dislocation at the interface produces an
important stress field which can be reduced by inserting a parallel
network of dislocations with suitable periodicity.
Abstract: In this paper, the effect of addition the dune sand powder (DSP) on development of compressive strength and hydration of cement pastes was investigated as a function of water/binder ratio, was varied, on the one hand, the percentage of DSP and on the other, the fineness of DSP. In order to understand better the pozzolanic effect of dune sand powder in cement pastes, we followed the mixtures hydration (50% Pure Lime + 50% DSP) by X-ray diffraction. These mixtures the pastes present a hydraulic setting which is due to the formation of a C-S-H phase (calcium silicate hydrate). The latter is semi-crystallized. This study is a simplified approach to that of the mixtures (80% ordinary Portland cement + 20% DSP), in which the main reaction is the fixing of the lime coming from the cement hydration in the presence of DSP, to form calcium silicate hydrate semi-crystallized of second generation. The results proved that up to (20% DSP) as Portland cement replacement could be used with a fineness of 4000 cm²/g without affecting adversely the compressive strength. After 28 days, the compressive strength at 5, 10 and 15% DSP is superior to Portland cement, with an optimum effect for a percentage of the order of 5% to 10% irrespective of the w/b ratio and fineness of DSP.
Abstract: Copper based composites reinforced with WC and Ti
particles were prepared using planetary ball-mill. The experiment
was designed by using Taguchi technique and milling was carried out
in an air for several hours. The powder was characterized before and
after milling using the SEM, TEM and X-ray for microstructure and
for possible new phases. Microstructures show that milled particles
size and reduction in particle size depend on many parameters. The
distance d between planes of atoms estimated from X-ray powder
diffraction data and TEM image. X-ray diffraction patterns of the
milled powder did not show clearly any new peak or energy shift, but
the TEM images show a significant change in crystalline structure of
corporate on titanium in the composites.
Abstract: The effect of gamma irradiation on micro-hardness of polymer blends of poly (ethyl methacrylate)(PEMA) and poly (ethylene oxide) (PEO) has been investigated to detect the radiation induced crosslinking. The blend system comprises a noncrystallizable polymer, PEMA and a crystallizable polymer, PEO. On irradiation, the overall hardness of the blend specimens for different dose levels infers occurrence of a crosslinking process. The radiation-induced crosslinking was greater for blends having lower concentration of PEO. However, increase in radiation dose causes softening of blend system due to radiation induced scissioning of the chains
Abstract: This study deals with the experimental investigation
and theoretical modeling of Semi crystalline polymeric materials with
a rubbery amorphous phase (HDPE) subjected to a uniaxial cyclic
tests with various maximum strain levels, even at large deformation.
Each cycle is loaded in tension up to certain maximum strain and
then unloaded down to zero stress with N number of cycles. This
work is focuses on the measure of the volume strain due to the
phenomena of damage during this kind of tests. On the basis of
thermodynamics of relaxation processes, a constitutive model for
large strain deformation has been developed, taking into account the
damage effect, to predict the complex elasto-viscoelastic-viscoplastic
behavior of material. A direct comparison between the model
predictions and the experimental data show that the model accurately
captures the material response. The model is also capable of
predicting the influence damage causing volume variation.
Abstract: Photo-crosslinked rice starch-based biodegradable
films were prepared by casting film-solution on leveled trays and
ultra violet (UV) irradiation was applied for 10 minute. The effect of
the content (3%, 6% and 9 wt. %)of photosensitiser (sodium
benzoate) on mechanical properties, water vapor permeability (WVP)
and structural properties of rice starch films were investigated. The
tensile strength increased while elongation at break and water
resistance properties of rice starch films decreased with addition and
increasing content of photosensitiser. The % crystallinity of rice
starch films were decreased when the content of photosensitiser
increased and UV were applied. The results showed that the
carboxylate group band of sodium benzoate was found in the FTIR
spectrum of rice starch films and found that incorporation of 6% of
photosensitiser into the films showed a higher absorption band of
resulted films. This result pointed out the highest interaction between
starch molecules was occurred.
Abstract: As application of re-activation of backside on power
device Insulated Gate Bipolar Transistor (IGBT), laser annealing was
employed to irradiate amorphous silicon substrate, and resistivities
were measured using four point probe measurement. For annealing
the amorphous silicon two lasers were used at wavelength of visible
green (532 nm) together with Infrared (793 nm). While the green
laser efficiently increased temperature at top surface the Infrared
laser reached more deep inside and was effective for melting the
top surface. A finite element method was employed to evaluate time
dependent thermal distribution in silicon substrate.
Abstract: In this paper, a new method of controlling position of AC Servomotor using Field Programmable Gate Array (FPGA). FPGA controller is used to generate direction and the number of pulses required to rotate for a given angle. Pulses are sent as a square wave, the number of pulses determines the angle of rotation and frequency of square wave determines the speed of rotation. The proposed control scheme has been realized using XILINX FPGA SPARTAN XC3S400 and tested using MUMA012PIS model Alternating Current (AC) servomotor. Experimental results show that the position of the AC Servo motor can be controlled effectively. KeywordsAlternating Current (AC), Field Programmable Gate Array (FPGA), Liquid Crystal Display (LCD).
Abstract: Noble metal participation in nanostructured
semiconductor catalysts has drawn much interest because of their
improved properties. Recently, it has been discussed by many
researchers that Ag participation in TiO2, CuO, ZnO semiconductors
showed improved photocatalytic and optical properties. In this
research, Ag/ZnO nanocomposite particles were prepared by
Ultrasonic Spray Pyrolysis(USP) Method. 0.1M silver and zinc
nitrate aqueous solutions were used as precursor solutions. The
Ag:Zn atomic ratio of the solution was selected 1:1. Experiments
were taken place under constant air flow of 400 mL/min at 800°C
furnace temperature. Particles were characterized by X-Ray
Diffraction (XRD), Scanning Electron Microscope (SEM) and
Energy Dispersive Spectroscopy (EDS). The crystallite sizes of Ag
and ZnO in composite particles are 24.6 nm, 19.7 nm respectively.
Although, spherical nanocomposite particles are in a range of 300-
800 nm, these particles are formed by the aggregation of primary
particles which are in a range of 20-60 nm.
Abstract: In this study, we sought to investigate the mercury
removal efficiency of manganese oxides from natural gas. The
fundamental studies on mercury removal with manganese oxides
sorbents were carried out in a laboratory scale fixed bed reactor at 30
°C with a mixture of methane (20%) and nitrogen gas laden with 4.8
ppb of elemental mercury. Manganese oxides with varying surface
area and crystalline phase were prepared by conventional precipitation
method in this study. The effects of surface area, crystallinity and
other metal oxides on mercury removal efficiency were investigated.
Effect of Ag impregnation on mercury removal efficiency was also
investigated. Ag supported on metal oxide such titania and zirconia as
reference materials were also used in this study for comparison. The
characteristics of mercury removal reaction with manganese oxide
was investigated using a temperature programmed desorption (TPD)
technique.
Manganese oxides showed very high Hg removal activity (about
73-93% Hg removal) for first time use. Surface area of the manganese
oxide samples decreased after heat-treatment and resulted in complete
loss of Hg removal ability for repeated use after Hg desorption in the
case of amorphous MnO2, and 75% loss of the initial Hg removal
activity for the crystalline MnO2. Mercury desorption efficiency of
crystalline MnO2 was very low (37%) for first time use and high (98%)
after second time use. Residual potassium content in MnO2 may have
some effect on the thermal stability of the adsorbed Hg species.
Desorption of Hg from manganese oxides occurs at much higher
temperatures (with a peak at 400 °C) than Ag/TiO2 or Ag/ZrO2.
Mercury may be captured on manganese oxides in the form of mercury
manganese oxide.