Effect of UV-Treatment on Properties of Biodegradable Film From Rice Starch
Photo-crosslinked rice starch-based biodegradable
films were prepared by casting film-solution on leveled trays and
ultra violet (UV) irradiation was applied for 10 minute. The effect of
the content (3%, 6% and 9 wt. %)of photosensitiser (sodium
benzoate) on mechanical properties, water vapor permeability (WVP)
and structural properties of rice starch films were investigated. The
tensile strength increased while elongation at break and water
resistance properties of rice starch films decreased with addition and
increasing content of photosensitiser. The % crystallinity of rice
starch films were decreased when the content of photosensitiser
increased and UV were applied. The results showed that the
carboxylate group band of sodium benzoate was found in the FTIR
spectrum of rice starch films and found that incorporation of 6% of
photosensitiser into the films showed a higher absorption band of
resulted films. This result pointed out the highest interaction between
starch molecules was occurred.
[1] S. Mali, M. V. E. Grossmann, M. A. Garcia, M. N. Martino, and N. E.
Zaritzky, "Microstructural characterization of yam starch films"
Carbohyd. Polym. J. vol. 50, pp. 379-386, 2002.
[2] G. Carvalho, P. C. Lemos, A. Oehmen, and M. A. M. Reis, "enitrifying
phosphorus removal: linking the process performance with the microbial
community structure" Water Res. J. vol. 41, pp. 4383-4396, 2007.
[3] P. H. Mu├▒oz, R. Villalobos, and A. Chiralt, "Effect of cross-linking
using aldehydes on properties of glutenin-rich films" Food
Hydrocolloids J. vol. 18, pp. 403-411, 2003.
[4] M. A. Garcia, M. N. Martino, and N. E. Zaritzky, "Microstructural
characterization of plasticized starch-based films" Starch/Starke J. vol.
52, pp. 118-124, 2000.
[5] J. M. Krochta, and C. De Mulder-Johnston, "Edible and biodegradable
polymer films: challenges and opportunities" Food Technology J. vol.
51, pp. 61-74, 1997.
[6] J.E. Cohen, K. Schoenly, K.L. Heong, H. Justo, G. Arida, A.T. Barrion,
and J.A. Litsinger, "A Food Web Approach to Evaluating the Effect of
Insecticide Spraying on Insect Pest Population Dynamics in a Philippine
Irrigated Rice Ecosystem" Applied Ecology J. vol. 31, no. 4, pp. 747-
763, 1994.
[7] X.Y. Xu, K.M. Kim, M.A. Hanna, and D. Nag, "Chitosan-starch
composite film: preparation and characterization. Industrial Crops and
Products" Industrial Crops and Products J. vol. 21, pp. 185-192, 2005.
[8] C. C. Seow, P. B. Cheah, and Y. P. Chang, "Antiplasticization by water
in reduced-moisture food systems" Food Sci J. vol. 64, pp. 576-581,
1999.
[9] K. Woo, and A. S. Paul, "Cross-linking of wheat starch and
hydroxypropylated wheat starch in alkaline slurry with sodium
trimetaphosphate" Carbohyd. Polym. J. vol. 33, pp. 263-271, 1997.
[10] L. Kuniak, and R. H. Marchessault, "Study of the crosslinking reaction
between epichlorohydrin and starch" Die stärke J. vol. 24,pp. 110-116,
1973.
[11] J. Gehring, "With radiation crosslinking of engineering plastics into the
next millennium. Radiation Physics and Chemistry" vol. 57, no. 3-6,
pp. 361-365, 2000.
[12] K. Takakura, G. Takayama, and J. Ukida, "Ultraviolet-induced
crosslinking of poly(vinylalcohol) in the presence of sensitizers" Applied
Polym. Sci. J. vol. 9, pp. 3217-3224, 1965.
[13] P. Ghosp, and R. Gangopadhay, "Photofunctionalisation of cellulose and
lignocelluloses fibres using photoactive organic acids" European Polym.
J. vol. 36, pp. 625-634, 2000.
[14] C. H. J. Wells, "Photochemical reactions-II: introduction to molecular
photochemistry" London: Chapman & Hall Textbook series, 1972.
[15] M. Zhai, F. Yoshii, and T. Kume, "Radiation modification of starch-base
plastic sheets" Carbohyd. Polym. J. vol. 52, pp. 311-317, 2003.
[16] J. Delville, C. Joly, P. Dole, and C. Bliard, "Solid state photocrosslinked
starch based films: a new family of homogeneous modified starches"
Carbohyd. Polym. J. vol. 49, pp. 71-81, 2002.
[17] ASTM. (1993), "Standard practice for conditioning plastics and
electrical insulating materials for testing: D618-61 (reproved 1990)" In
ASTM. Annual book of American standard testing methods, vol. 8.01,
pp. 146-148. Philadelphia, PA.
[18] T. H. McHugh, R. Avena-Bustillos, and J. M. Krochta, "Hydrophilic
edible films: modified procedure for water vapor permeability and
explanation of thickness effects" Food Science J. vol. 58, pp. 899-903,
1993.
[19] J. Zhou, J. Zhang, Y. Ma, and J. Tong, "Surface photo-crosslinking of
corn starch sheets" Carbohyd. Polym. J. vol. 74, pp. 405-410, 2008.
[20] V. Morillon, F. Debeaufort, G. Blond, and A. Voilley, "Temperature
influence on moisture transfer through synthetic films" Membrane
Science J. vol. 168, pp. 223-231, 2000.
[21] M.A. Bertuzzi, E.F. Castro Vidaurre, M. Armada, and J.C. Gottifredi,
"Water vapor permeability of edible starch based films" Food
Engineering J. vol. 80, no. 3, pp. 972-978, 2007.
[22] C. Decker, and K. Moussa, "Photopolymérisation de monomers
multifonctionnels-III. Analyse cinétique par spectroscopie Infrarouge
résolue dans le temps (RTIR)" European Polymer J. vol. 26, pp. 393-
401, 1990.
[23] ASTM. (1995) "Standard test methods for tensile properties of thin
plastics sheeting D882-91" In ASTM. Annual Book of American
Standard Testing Methods, vol 8.01, pp. 182-190. West Conshohochem,
PA.
[24] N. Gontard, S. Guilbert, and J. L. Cuq, "Edible wheat gluten films:
influence of the main process variables on film properties using response
surface methodology" Food Science J. vol. 57, no. 1, pp. 190-195, 1992.
[25] J. Bao, and C.J. Bergman, "The functionality of rice starch. In: Starch in
food: Structure, function and applications" A.-C. Eliasson (Ed.),
Woodhead Publishing Ltd. and CRC Press LLC: Boca Raton, Fl. pp.
258-294.
[26] T. Bourtoom, and M. S. Chinnan, "and properties of rice starch-chitosan
blend biodegradable film" LWT-Food Science and Technology J. vol.
41, pp. 1633-1641, 2008.
[27] Q. Yu, Z. Zhang, X. Xie, K. Naito, and Y. Kagawa, "Preparation and
crystalline morphology of biodegradable starch/clay nanocomposites"
Polym. J. vol. 48, pp. 7193-7200, 2007.
[28] K. Das, D. Ray, N.R. Bandyopahyay, A. Gupta, S. Sengupta, S. Sahoo,
A. Mohanty, and M. Misra, "Preparation and Characterization of Cross-
Linked Starch/Poly(vinylalcohol) Green Films with Low Moisture
Absorption" Ind. Eng. Chem. Res. J. vol. 49, pp. 2176-2185, 2010.
[29] C. J. Chen and G. S. Y. Yeh. "Radiation-induced crosslinking: III. Effect
on the crystalline and amorphous density fluctuations of polyethylene"
Colloid and Polymer Science J. vol. 269, no. 4, pp. 353-363, 1991.
[30] C. Mestres, and X. Rouau, "Influence of natural fermentation and drying
conditions on the Physicochemical characteristics of cassava starch" Sci
Food Agric. J. vol. 74, pp. 147-55, 1997.
[31] M. I. T(Tejedor).- Tejedor, E. C. Yost., and M. A. Anderson,
"Characterization of Benzoic and Phenolic Complexes at the
Goethite/Aqueous Solution Interface Using Cylindrical Internal
Reflection Fourier Transform Infrared Spectroscopy. Part 1.
Methodology" Langmuir J. vol. 6, pp. 979-987, 1990.
[32] R. Bhat, and A. A. Karim, "Ultraviolet irradiation improves gel strength
of fish gelatin" Food Chemistry J. vol. 113, pp. 1160-1164, 2009.
[1] S. Mali, M. V. E. Grossmann, M. A. Garcia, M. N. Martino, and N. E.
Zaritzky, "Microstructural characterization of yam starch films"
Carbohyd. Polym. J. vol. 50, pp. 379-386, 2002.
[2] G. Carvalho, P. C. Lemos, A. Oehmen, and M. A. M. Reis, "enitrifying
phosphorus removal: linking the process performance with the microbial
community structure" Water Res. J. vol. 41, pp. 4383-4396, 2007.
[3] P. H. Mu├▒oz, R. Villalobos, and A. Chiralt, "Effect of cross-linking
using aldehydes on properties of glutenin-rich films" Food
Hydrocolloids J. vol. 18, pp. 403-411, 2003.
[4] M. A. Garcia, M. N. Martino, and N. E. Zaritzky, "Microstructural
characterization of plasticized starch-based films" Starch/Starke J. vol.
52, pp. 118-124, 2000.
[5] J. M. Krochta, and C. De Mulder-Johnston, "Edible and biodegradable
polymer films: challenges and opportunities" Food Technology J. vol.
51, pp. 61-74, 1997.
[6] J.E. Cohen, K. Schoenly, K.L. Heong, H. Justo, G. Arida, A.T. Barrion,
and J.A. Litsinger, "A Food Web Approach to Evaluating the Effect of
Insecticide Spraying on Insect Pest Population Dynamics in a Philippine
Irrigated Rice Ecosystem" Applied Ecology J. vol. 31, no. 4, pp. 747-
763, 1994.
[7] X.Y. Xu, K.M. Kim, M.A. Hanna, and D. Nag, "Chitosan-starch
composite film: preparation and characterization. Industrial Crops and
Products" Industrial Crops and Products J. vol. 21, pp. 185-192, 2005.
[8] C. C. Seow, P. B. Cheah, and Y. P. Chang, "Antiplasticization by water
in reduced-moisture food systems" Food Sci J. vol. 64, pp. 576-581,
1999.
[9] K. Woo, and A. S. Paul, "Cross-linking of wheat starch and
hydroxypropylated wheat starch in alkaline slurry with sodium
trimetaphosphate" Carbohyd. Polym. J. vol. 33, pp. 263-271, 1997.
[10] L. Kuniak, and R. H. Marchessault, "Study of the crosslinking reaction
between epichlorohydrin and starch" Die stärke J. vol. 24,pp. 110-116,
1973.
[11] J. Gehring, "With radiation crosslinking of engineering plastics into the
next millennium. Radiation Physics and Chemistry" vol. 57, no. 3-6,
pp. 361-365, 2000.
[12] K. Takakura, G. Takayama, and J. Ukida, "Ultraviolet-induced
crosslinking of poly(vinylalcohol) in the presence of sensitizers" Applied
Polym. Sci. J. vol. 9, pp. 3217-3224, 1965.
[13] P. Ghosp, and R. Gangopadhay, "Photofunctionalisation of cellulose and
lignocelluloses fibres using photoactive organic acids" European Polym.
J. vol. 36, pp. 625-634, 2000.
[14] C. H. J. Wells, "Photochemical reactions-II: introduction to molecular
photochemistry" London: Chapman & Hall Textbook series, 1972.
[15] M. Zhai, F. Yoshii, and T. Kume, "Radiation modification of starch-base
plastic sheets" Carbohyd. Polym. J. vol. 52, pp. 311-317, 2003.
[16] J. Delville, C. Joly, P. Dole, and C. Bliard, "Solid state photocrosslinked
starch based films: a new family of homogeneous modified starches"
Carbohyd. Polym. J. vol. 49, pp. 71-81, 2002.
[17] ASTM. (1993), "Standard practice for conditioning plastics and
electrical insulating materials for testing: D618-61 (reproved 1990)" In
ASTM. Annual book of American standard testing methods, vol. 8.01,
pp. 146-148. Philadelphia, PA.
[18] T. H. McHugh, R. Avena-Bustillos, and J. M. Krochta, "Hydrophilic
edible films: modified procedure for water vapor permeability and
explanation of thickness effects" Food Science J. vol. 58, pp. 899-903,
1993.
[19] J. Zhou, J. Zhang, Y. Ma, and J. Tong, "Surface photo-crosslinking of
corn starch sheets" Carbohyd. Polym. J. vol. 74, pp. 405-410, 2008.
[20] V. Morillon, F. Debeaufort, G. Blond, and A. Voilley, "Temperature
influence on moisture transfer through synthetic films" Membrane
Science J. vol. 168, pp. 223-231, 2000.
[21] M.A. Bertuzzi, E.F. Castro Vidaurre, M. Armada, and J.C. Gottifredi,
"Water vapor permeability of edible starch based films" Food
Engineering J. vol. 80, no. 3, pp. 972-978, 2007.
[22] C. Decker, and K. Moussa, "Photopolymérisation de monomers
multifonctionnels-III. Analyse cinétique par spectroscopie Infrarouge
résolue dans le temps (RTIR)" European Polymer J. vol. 26, pp. 393-
401, 1990.
[23] ASTM. (1995) "Standard test methods for tensile properties of thin
plastics sheeting D882-91" In ASTM. Annual Book of American
Standard Testing Methods, vol 8.01, pp. 182-190. West Conshohochem,
PA.
[24] N. Gontard, S. Guilbert, and J. L. Cuq, "Edible wheat gluten films:
influence of the main process variables on film properties using response
surface methodology" Food Science J. vol. 57, no. 1, pp. 190-195, 1992.
[25] J. Bao, and C.J. Bergman, "The functionality of rice starch. In: Starch in
food: Structure, function and applications" A.-C. Eliasson (Ed.),
Woodhead Publishing Ltd. and CRC Press LLC: Boca Raton, Fl. pp.
258-294.
[26] T. Bourtoom, and M. S. Chinnan, "and properties of rice starch-chitosan
blend biodegradable film" LWT-Food Science and Technology J. vol.
41, pp. 1633-1641, 2008.
[27] Q. Yu, Z. Zhang, X. Xie, K. Naito, and Y. Kagawa, "Preparation and
crystalline morphology of biodegradable starch/clay nanocomposites"
Polym. J. vol. 48, pp. 7193-7200, 2007.
[28] K. Das, D. Ray, N.R. Bandyopahyay, A. Gupta, S. Sengupta, S. Sahoo,
A. Mohanty, and M. Misra, "Preparation and Characterization of Cross-
Linked Starch/Poly(vinylalcohol) Green Films with Low Moisture
Absorption" Ind. Eng. Chem. Res. J. vol. 49, pp. 2176-2185, 2010.
[29] C. J. Chen and G. S. Y. Yeh. "Radiation-induced crosslinking: III. Effect
on the crystalline and amorphous density fluctuations of polyethylene"
Colloid and Polymer Science J. vol. 269, no. 4, pp. 353-363, 1991.
[30] C. Mestres, and X. Rouau, "Influence of natural fermentation and drying
conditions on the Physicochemical characteristics of cassava starch" Sci
Food Agric. J. vol. 74, pp. 147-55, 1997.
[31] M. I. T(Tejedor).- Tejedor, E. C. Yost., and M. A. Anderson,
"Characterization of Benzoic and Phenolic Complexes at the
Goethite/Aqueous Solution Interface Using Cylindrical Internal
Reflection Fourier Transform Infrared Spectroscopy. Part 1.
Methodology" Langmuir J. vol. 6, pp. 979-987, 1990.
[32] R. Bhat, and A. A. Karim, "Ultraviolet irradiation improves gel strength
of fish gelatin" Food Chemistry J. vol. 113, pp. 1160-1164, 2009.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:62442", author = "Nawapat Detduangchan and Thawien Wittaya", title = "Effect of UV-Treatment on Properties of Biodegradable Film From Rice Starch", abstract = "Photo-crosslinked rice starch-based biodegradable
films were prepared by casting film-solution on leveled trays and
ultra violet (UV) irradiation was applied for 10 minute. The effect of
the content (3%, 6% and 9 wt. %)of photosensitiser (sodium
benzoate) on mechanical properties, water vapor permeability (WVP)
and structural properties of rice starch films were investigated. The
tensile strength increased while elongation at break and water
resistance properties of rice starch films decreased with addition and
increasing content of photosensitiser. The % crystallinity of rice
starch films were decreased when the content of photosensitiser
increased and UV were applied. The results showed that the
carboxylate group band of sodium benzoate was found in the FTIR
spectrum of rice starch films and found that incorporation of 6% of
photosensitiser into the films showed a higher absorption band of
resulted films. This result pointed out the highest interaction between
starch molecules was occurred.", keywords = "Biodegradable film, Rice starch, UV treatment, Photosensitiser, Photo-crosslink", volume = "5", number = "9", pages = "798-6", }
