Abstract: Ultraviolet (UV) disinfection causes damage to the DNA or RNA of microorganisms, but many microorganisms can repair this damage after exposure to near-UV or visible wavelengths (310–480 nm) by a mechanism called photoreactivation. Photoreactivation is gaining more attention because it can reduce the efficiency of UV disinfection of wastewater several hours after treatment. The focus of many photoreactivation research activities on the single species has caused a considerable lack in knowledge about complex natural communities of microorganisms and their response to UV treatment. In this research, photoreactivation experiments were carried out on the influent of the UV disinfection unit at a municipal wastewater treatment plant (WWTP) in Edmonton, Alberta after exposure to a Medium-Pressure (MP) UV lamp system to evaluate the effect of environmental factors on photoreactivation of microorganisms in the actual municipal wastewater. The effect of reactivation fluence, temperature, and river water on photoreactivation of total coliforms was examined under indoor conditions. The results showed that higher effective reactivation fluence values (up to 20 J/cm2) and higher temperatures (up to 25 °C) increased the photoreactivation of total coliforms. However, increasing the percentage of river in the mixtures of the effluent and river water decreased the photoreactivation of the mixtures. The results of this research can help the municipal wastewater treatment industry to examine the environmental effects of discharging their effluents into receiving waters.
Abstract: During the past two decades, photoinitiated polymerization has been attracting a great interest in terms of scientific and industrial activity. The wide recognition of UV treatment in the polymer industry results not only from its many practical applications but also from its advantage for low-cost processes. Unlike most thermal curing systems, radiation-curable systems can polymerize at room temperature without additional heat, and the curing is completed in a very short time. The advantage of cationic UV technology is that post-cure can continue in the ‘dark’ after radiation. In this study, bio-based acrylated epoxidized soybean oil (AESO) was cured with UV radiation using radicalic photoinitiator Irgacure 184. Triarylsulphonium hexafluoroantimonate was used as cationic photoinitiator for curing of 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexanecarboxylate. The effect of curing time and the amount of initiators on the curing degree and thermal properties were investigated. The thermal properties of the coating were analyzed after crosslinking UV irradiation. The level of crosslinking in the coating was evaluated by FTIR analysis. Cationic UV-cured coatings demonstrated excellent adhesion and corrosion resistance properties. Therefore, our study holds a great potential with its simple and low-cost applications.
Abstract: Photo-crosslinked rice starch-based biodegradable
films were prepared by casting film-solution on leveled trays and
ultra violet (UV) irradiation was applied for 10 minute. The effect of
the content (3%, 6% and 9 wt. %)of photosensitiser (sodium
benzoate) on mechanical properties, water vapor permeability (WVP)
and structural properties of rice starch films were investigated. The
tensile strength increased while elongation at break and water
resistance properties of rice starch films decreased with addition and
increasing content of photosensitiser. The % crystallinity of rice
starch films were decreased when the content of photosensitiser
increased and UV were applied. The results showed that the
carboxylate group band of sodium benzoate was found in the FTIR
spectrum of rice starch films and found that incorporation of 6% of
photosensitiser into the films showed a higher absorption band of
resulted films. This result pointed out the highest interaction between
starch molecules was occurred.
Abstract: Indium-tin oxide films are deposited by low plasma
temperature RF sputtering on highly flexible modification of glycol
polyethyleneterephtalate substrates. The produced layers are
characterized with transparency over 82 % and sheet resistance of
86.9 Ω/square. The film’s conductivity was further improved by
additional UV illumination from light source (365 nm), having power
of 250 W. The influence of the UV exposure dose on the structural
and electro-optical properties of ITO was investigated. It was
established that the optimum time of illumination is 10 minutes and
further UV treatment leads to polymer substrates degradation.
Structural and bonds type analysis show that at longer treatment
carbon atoms release and diffuse into ITO films, which worsen their
electrical behavior. For the optimum UV dose the minimum sheet
resistance was measured to be 19.2 Ω/square, and the maximum
transparency remained almost unchanged – above 82 %.
Abstract: The removal efficiency of 4-chlorophenol with
different advanced oxidation processes have been studied. Oxidation
experiments were carried out using two 4-chlorophenol
concentrations: 100 mg L-1 and 250 mg L-1 and UV generated from a
KrCl excilamp with (molar ratio H2O2: 4-chlorophenol = 25:1) and
without H2O2, and, with Fenton process (molar ratio H2O2:4-
chlorophenol of 25:1 and Fe2+ concentration of 5 mg L-1).
The results show that there is no significant difference in the 4-
chlorophenol conversion when using one of the three assayed
methods. However, significant concentrations of the photoproductos
still remained in the media when the chosen treatment involves UV
without hydrogen peroxide. Fenton process removed all the
intermediate photoproducts except for the hydroquinone and the
1,2,4-trihydroxybenzene. In the case of UV and hydrogen peroxide
all the intermediate photoproducts are removed.
Microbial bioassays were carried out utilising the naturally
luminescent bacterium Vibrio fischeri and a genetically modified
Pseudomonas putida isolated from a waste treatment plant receiving
phenolic waste. The results using V. fischeri show that with samples
after degradation, only the UV treatment showed toxicity (IC50 =38)
whereas with H2O2 and Fenton reactions the samples exhibited no
toxicity after treatment in the range of concentrations studied. Using
the Pseudomonas putida biosensor no toxicity could be detected for
all the samples following treatment due to the higher tolerance of the
organism to phenol concentrations encountered.