Abstract: Poly vinyl acetate (PVA)-based titania (TiO2)–carbon
nanotube composite nanofibers (PVA-TCCNs) with various
PVA-to-solvent ratios and PVA-based TiO2 composite nanofibers
(PVA-TN) were synthesized using an electrospinning process,
followed by thermal treatment. The photocatalytic activities of these
nanofibers in the degradation of airborne monocyclic aromatics under
visible-light irradiation were examined. This study focuses on the
application of these photocatalysts to the degradation of the target
compounds at sub-part-per-million indoor air concentrations. The
characteristics of the photocatalysts were examined using scanning
electron microscopy, X-ray diffraction, ultraviolet-visible
spectroscopy, and Fourier-transform infrared spectroscopy. For all the
target compounds, the PVA-TCCNs showed photocatalytic
degradation efficiencies superior to those of the reference PVA-TN.
Specifically, the average photocatalytic degradation efficiencies for
benzene, toluene, ethyl benzene, and o-xylene (BTEX) obtained using
the PVA-TCCNs with a PVA-to-solvent ratio of 0.3 (PVA-TCCN-0.3)
were 11%, 59%, 89%, and 92%, respectively, whereas those observed
using PVA-TNs were 5%, 9%, 28%, and 32%, respectively.
PVA-TCCN-0.3 displayed the highest photocatalytic degradation
efficiency for BTEX, suggesting the presence of an optimal
PVA-to-solvent ratio for the synthesis of PVA-TCCNs. The average
photocatalytic efficiencies for BTEX decreased from 11% to 4%, 59%
to 18%, 89% to 37%, and 92% to 53%, respectively, when the flow
rate was increased from 1.0 to 4.0 L min1. In addition, the average
photocatalytic efficiencies for BTEX increased 11% to ~0%, 59% to
3%, 89% to 7%, and 92% to 13%, respectively, when the input
concentration increased from 0.1 to 1.0 ppm. The prepared
PVA-TCCNs were effective for the purification of airborne aromatics
at indoor concentration levels, particularly when the operating
conditions were optimized.
Abstract: Today, the pollution due to non-degradable material
such as plastics, has led to studies about the development of
environmental-friendly material. Because of biodegradability
obtained from natural sources, polylactid acid (PLA) and ijuk fiber
are interesting to modify into a composite. This material is also
expected to reduce the impact of environmental pollution. Surface
modification of ijuk fiber through alkalinization with 0.25 M NaOH
solution for 30 minutes was aimed to enhance its compatibility to
PLA, in order to improve properties of the composite such as the
mechanical properties. Alkalinization of the ijuk fibers annihilates
some surface components such as lignin, wax and hemicelloluse, so
the pore on the surface clearly appeared, decreasing of the density
and diameter of the ijuk fibers. The change of the ijuk fiber properties
leads to increase the mechanical properties of PLA composites
reinforced the ijuk fibers through strengthening of the mechanical
interlocking with the PLA matrix. An addition to enhance the
distribution of the fibers in the PLA matrix, the stirring during DCM
solvent evaporation from the mixture of the ijuk fibers and the
dissolved-PLA can reduce amount of the trapped-voids and fibers
pull-out phenomena, which can decrease the mechanical properties of
the composite.
Abstract: Sustainability and eco-friendly requirement of
engineering materials are sort for in recent times, thus giving rise to
the development of bio-composites. However, the natural fibres to
matrix interface interactions remain a key issue in getting the desired
mechanical properties from such composites. Treatment of natural
fibres is essential in improving matrix to filler adhesion, hence
improving its mechanical properties. In this study, investigations
were carried out to determine the effect of sodium hydroxide
treatment on the tensile, flexural, impact and hardness properties of
crushed and uncrushed Luffa cylindrica fibre reinforced recycled low
density polyethylene composites. The LC (Luffa cylindrica) fibres
were treated with 0%, 2%, 4%, 6%, 8% and 10% wt. sodium
hydroxide (NaOH) concentrations for a period of 24 hours under
room temperature conditions. A formulation ratio of 80/20 g (matrix
to reinforcement) was maintained for all developed samples. Analysis
of the results showed that the uncrushed luffa fibre samples gave
better mechanical properties compared with the crushed luffa fibre
samples. The uncrushed luffa fibre composites had a maximum
tensile and flexural strength of 7.65 MPa and 17.08 Mpa respectively
corresponding to a young modulus and flexural modulus of 21.08
MPa and 232.22 MPa for the 8% and 4% wt. NaOH concentration
respectively. Results obtained in the research showed that NaOH
treatment with the 8% NaOH concentration improved the mechanical
properties of the LC fibre reinforced composites when compared with
other NaOH treatment concentration values.
Abstract: This study was developed to compare the behavior
and the ability of polymer foam composites towards sound absorption
test of Shorea leprosula wood (SL) of acid hydrolysis treatment with
particle size
Abstract: The development of Drugs Delivery System (DDS)
has been widely investigated in the last decades. In this paper, first a
general overview of traditional and modern wound dressing is
presented. This is followed by a review of what scientists have done
in the medical environment, focusing on the possibility to develop a
new alternative for DDS through transdermal pathway, aiming to
treat melanoma skin cancer.
Abstract: This study examines analytically the effect of tsunami loads on reinforced concrete (RC) frame buildings. The impact of tsunami wave loads and waterborne objects are analyzed using a typical substandard full-scale two-story RC frame building tested as part of the EU-funded Ecoleader project. The building was subjected to shake table tests in bare condition, and subsequently strengthened using Carbon Fiber Reinforced Polymers (CFRP) composites and retested. Numerical models of the building in both bare and CFRP-strengthened conditions are calibrated in DRAIN-3DX software to match the test results. To investigate the response of wave loads and impact forces, the numerical models are subjected to nonlinear dynamic analyses using force time-history input records. The analytical results are compared in terms of displacements at the floors and at the “impact point” of a boat. The results show that the roof displacement of the CFRP-strengthened building reduced by 63% when compared to the bare building. The results also indicate that strengthening only the mid-height of the impact column using CFRP is more effective at reducing damage when compared to strengthening other parts of the column. Alternative solutions to mitigate damage due to tsunami loads are suggested.
Abstract: Waste silicon carbide (waste SiC) filled high-density
polyethylene (HDPE) with and without surface modifiers were
studied. Two types of surface modifiers namely; high-density
polyethylene-grafted-maleic anhydride (HDPE-g-MA) and 3-aminopropyltriethoxysilane have been used in this study. The
composites were produced using a two roll mill, extruder and shaped
in a hydraulic compression molding machine. The mechanical
properties of polymer composites such as flexural strength and
modulus, impact strength, tensile strength, stiffness and hardness
were investigated over a range of compositions. It was found that,
flexural strength and modulus, tensile modulus and hardness
increased, whereas impact strength and tensile strength decreased
with the increasing in filler contents, compared to the neat HDPE. At
similar filler content, the effect of both surface modifiers increased
flexural modulus, impact strength, tensile strength and stiffness but
reduced the flexural strength. Morphological investigation using
SEM revealed that the improvement in mechanical properties was
due to enhancement of the interfacial adhesion between waste SiC
and HDPE.
Abstract: Sandwich structure composites produced by epoxy
core and aluminium skin were developed as potential building
materials. Interface bonding between core and skin was controlled by
varying kenaf content. Five different weight percentage of kenaf
loading ranging from 10 wt% to 50 wt% were employed in the core
manufacturing in order to study the mechanical properties of the
sandwich composite. Properties of skin aluminium with epoxy were
found to be affected by drying time of the adhesive. Mechanical
behavior of manufactured sandwich composites in relation with
properties of constituent materials was studied. It was found that 30
wt% of kenaf loading contributed to increase the flexural strength and
flexural modulus up to 102 MPa and 32 GPa, respectively. Analysis
were done on the flatwise and edgewise compression test. For
flatwise test, it was found that 30 wt% of fiber loading could
withstand maximum force until 250 kN, with compressive strength
results at 96.94 MPa. However, at edgewise compression test, the
sandwich composite with same fiber loading only can withstand 31
kN of the maximum load with 62 MPa of compressive strength
results.
Abstract: In this research the effects of adding silica and
alumina nanoparticles on flow ability and compressive strength of
cementitious composites based on Portland cement were investigated.
In the first stage, the rheological behavior of different samples
containing nanosilica, nanoalumina and polypropylene, polyvinyl
alcohol and polyethylene fibers were evaluated. With increasing of
nanoparticles in fresh samples, the slump flow diameter reduced.
Fibers reduced the flow ability of the samples and viscosity
increased. With increasing of the micro silica particles to cement
ratio from 2/1 to 2/2, the slump flow diameter increased. By adding
silica and alumina nanoparticles up to 3% and 2% respectively, the
compressive strength increased and after decreased. Samples
containing silica nanoparticles and fibers had the highest compressive
strength.
Abstract: Polysulfone (PSU) is a specialty engineering polymer
having various industrial applications. PSU is especially used in
waste water treatment membranes due to its good mechanical
properties, structural and chemical stability. But it is a hydrophobic
material and therefore its surface aim to pollute easily. In order to
resolve this problem and extend the properties of membrane, PSU
surface is rendered hydrophilic by addition of the sepiolite
nanofibers. Sepiolite is one of the natural clays, which is a hydrate
magnesium silicate fiber, also one of the well known layered clays of
the montmorillonites where has several unique channels and pores
within. It has also moisture durability, strength and low price.
Sepiolite channels give great capacity of absorption and good surface
properties. In this study, nanocomposites of commercial PSU and
Sepiolite were prepared by solvent mixing method. Different organic
solvents and their mixtures were used. Rheological characteristics of
PSU-Sepiolite solvent mixtures were analyzed, the solubility of
nanocomposite content in those mixtures were studied.
Abstract: Bio-composites derived from plant fiber and/or bioderived
polymer, are likely more ecofriendly and demonstrate
competitive performance with petroleum based composites. In this
research, the bio phenol-formaldehyde (bio-PF) was used as a matrix
and oil palm empty fruit bunch fiber (EFB) as reinforcement. The
matrix was synthesized via liquefaction and condensation to enhance
the combination of phenol and formaldehyde, during the process.
Then, the bio-PF was mixed with different percentage of EFB (5%,
10%, 15% and 20%) and molded at 180oC. The samples that viewed
under scanning electron microscopy (SEM) showed an excellent
wettability and interaction between EFB and matrix. Samples of 10%
EFB gave the optimum properties of impact and hardness meanwhile
sample 15% of EFB gave the highest reading of flexural modulus
(MOE) and flexural strength (MOR). For thermal stability analysis, it
was found that the weight loss and the activation energy (Ea) of the
bio-composites samples were decreased as the filler content
increased.
Abstract: Water contamination by toxic compound is one of the serious environmental problems today. These toxic compounds mostly originated from industrial effluents, agriculture, natural sources and human waste. These studies focus on modification of multiwalled carbon nanotube (MWCNTs) with nanoparticle of calixarene and explore the possibility of using this modification for the remediation of cadmium in water. The nanocomposites were prepared by dissolving calixarene in chloroform solution as solvent, followed by additional multiwalled carbon nanotube (MWCNTs) then sonication process for 3 hour and fabricated the nanocomposites on substrate by spin coating method. Finally, the nanocomposites were tested on cadmium ion (10 mg/ml). The morphology of nanocomposites was investigated by FESEM showing the formation of calixarene on the outer walls of carbon nanotube and cadmium ion also clearly seen from the micrograph. This formation was supported by using energy dispersive x-ray (EDX). The presence of cadmium ions in the films, leads to some changes in the surface potential and Fourier Transform Infrared spectroscopy (FTIR).The nanocomposites MWCNTs-calixarene have potential for development of sensor for pollutant monitoring and nanoelectronics devices applications.
Abstract: In this study, composites were fabricated from oil
palm empty fruit bunch fiber and poly(lactic) acid by extrusion
followed by injection moulding. Surface of the fiber was pre-treated
by ultrasound in an alkali medium and treatment efficiency was
investigated by scanning electron microscopy (SEM) analysis and
Fourier transforms infrared spectrometer (FTIR). Effect of fiber
treatment on composite was characterized by tensile strength (TS),
tensile modulus (TM) and impact strength (IS). Furthermore,
biostrong impact modifier was incorporated into the treated fiber
composite to improve its impact properties. Mechanical testing
showed an improvement of up to 23.5% and 33.6% respectively for
TS and TM of treated fiber composite above untreated fiber
composite. On the other hand incorporation of impact modifier led to
enhancement of about 20% above the initial IS of the treated fiber
composite.
Abstract: The prepreg process among the CFRP (Carbon Fiber
Reinforced Plastic) forming methods is the short term of
‘Pre-impregnation’, which is widely used for aerospace composites
that require a high quality property such as a fiber-reinforced woven
fabric, in which an epoxy hardening resin is impregnated the reality.
However, that this process requires continuous researches and
developments for its commercialization because the delamination
characteristically develops between the layers when a great weight is
loaded from outside to supplement such demerit, three lamination
methods among the prepreg lamination methods of CFRP were
designed to minimize the delamination between the layers due to
external impacts. Further, the newly designed methods and the
existing lamination methods were analyzed through a mechanical
characteristic test, Interlaminar Shear Strength test. The Interlaminar
Shear Strength test result confirmed that the newly proposed three
lamination methods, i.e. the Roll, Half and Zigzag laminations,
presented more excellent strengths compared to the conventional Ply
lamination. The interlaminar shear strength in the roll method with
relatively dense fiber distribution was approximately 1.75% higher
than that in the existing ply lamination method, and in the half method,
it was approximately 0.78% higher.
Abstract: Burnishing is increasingly used as a finishing operation to improve surface roughness and surface hardness. This can be achieved by applying a hard ball or roller onto metallic surfaces under pressure, in order to achieve many advantages in the metallic surface. In the present work, the feed rate, speed and force have been considered as the basic burnishing parameters to study the surface roughness and surface hardness of metallic matrix composites. The considered metal matrix composites were made from Aluminum-Magnesium-Graphite with five different weight percentage of graphite. Both effects of burnishing parameters mentioned above and the graphite percentage on the surface hardness and surface roughness of the metallic matrix composites were studied. The results of this investigation showed that the surface hardness of the metallic composites increases with the increase of the burnishing force and decreases with the increase in the burnishing feed rate and burnishing speed. The surface roughness of the metallic composites decreases with the increasing of the burnishing force, feed rate, and speed to certain values, then it starts to increase. On the other hand, the increase in the weight percentage of the graphite in the considered composites causes a decrease in the surface hardness and an increase in the surface roughness.
Abstract: Pipe failure and leakage is a problematic issue and the
traditional solution of replacing the pipes is costly and time
consuming. Rehabilitation by relining materials based on polymer
composites is an alternative solution towards the degradation problem
of the old piping. This paper provides a brief summary of advances in
technology, methods and materials for relining as well as a summary
of the degradation analyses of the two main composite materials used
for relining, rubber filled epoxy and reinforced polyester baltoflake
when they are exposed in deionized water and elevated temperature
up to 80°C for a duration of 2-14 months in the laboratory.
Abstract: Composite materials, due to their unique properties
such as high strength to weight ratio, corrosion resistance, and impact
resistance have huge potential as structural materials in automotive,
construction and transportation applications. However, these
properties often come at higher cost owing to complex design
methods, difficult manufacturing processes and raw material cost.
Traditionally, tapered laminated composite structures are
manufactured using autoclave manufacturing process by ply drop off
technique. Autoclave manufacturing though very powerful suffers
from high capital investment and higher energy consumption. As per
the current trends in composite manufacturing, Out of Autoclave
(OoA) processes are looked as emerging technologies for
manufacturing the structural composite components for aerospace
and defense applications. However, there is a need for improvement
among these processes to make them reliable and consistent. In this
paper, feasibility of using out of autoclave process to manufacture the
variable thickness cantilever beam is discussed. The minimum weight
design for the composite beam is obtained using constant stress beam
concept by tailoring the thickness of the beam. Ply drop off
techniques was used to fabricate the variable thickness beam from
glass/epoxy prepregs. Experiments were conducted to measure
bending stresses along the span of the cantilever beam at different
intervals by applying the concentrated load at the free end.
Experimental results showed that the stresses in the bean at different
intervals were constant. This proves the ability of OoA process to
manufacture the constant stress beam. Finite element model for the
constant stress beam was developed using commercial finite element
simulation software. It was observed that the simulation results
agreed very well with the experimental results and thus validated
design and manufacturing approach used.
Abstract: Lightweight design represents an important key to
successful implementation of energy-saving, fuel-efficient and
environmentally friendly means of transport in the aerospace and
automotive industry. In this context the use of carbon fibre reinforced
plastics (CFRP) which are distinguished by their outstanding
mechanical properties at relatively low weight, promise significant
improvements. Due to the reduction of the total mass, with the
resulting lowered fuel or energy consumption and CO2 emissions
during the operational phase, commercial aircraft will increasingly be
made of CFRP. An auspicious technology for the efficient and
economic production of high performance thermoset composites and
hybrid structures for future lightweight applications is the
combination of carbon fibre sheet moulding compound, tailored
continuous carbon fibre reinforcements and metallic components in a
one-shot pressing and curing process. This paper deals with a hybrid
composite technology for aerospace industries, which was developed
with the help of a special innovation and development system.
Abstract: Replacement of plastics used in the food industry
seems to be a serious issue to overcome mainly the environmental
problems in recent years. This study investigates the hydrophilicity
and permeability properties of starch biopolymer which ethylene
vinyl alcohol (EVOH) (0-10%) and nanocrystalline cellulose (NCC)
(1-15%) were used to enhance its properties. Starch -EVOH
nanocomposites were prepared by casting method in different
formulations. NCC production by acid hydrolysis was confirmed by
scanning electron microscopy. Solubility, water vapor permeability,
water vapor transmission rate and moisture absorbance were
measured on each of the nanocomposites. The results were analyzed
by SAS software. The lowest moisture absorbance was measured in
pure starch nanocomposite containing 8% NCC. The lowest
permeability to water vapor belongs to starch nanocomposite
containing 8% NCC and the sample containing 7.8% EVOH and 13%
NCC. Also the lowest solubility was observed in the composite
contains the highest amount of EVOH. Applied Process resulted in
production of bio films which have good resistance to water vapor
permeability and solubility in water. The use of NCC and EVOH
leads to reduced moisture absorbance property of the biofilms.
Abstract: In situ modified cyclohexanone-formaldehyde resins
were prepared by addition of alendronic acid during resin
preparation. Clay nanocomposites in ketonic resins were achieved by
adding clay into the flask at the beginning of the resin preparation.
The prepared resins were used for the synthesis of fire resistant
polyurethanes foam. Both phosphorous containing modifier
compound alendronic acid and nanoclay increases fire resistance of
the cyclohexanone-formaldehyde resin thus polyurethane produced
from these resins. The effect of the concentrations of alendronic acid
and clay on the fire resistance and physical properties of
polyurethanes was studied.