Abstract: In low permeability reservoirs, the reservoir pore throat is small and the micro heterogeneity is prominent. Conventional microsphere profile control agents generally have good injectability but poor plugging effect; however, profile control agents with good plugging effect generally have poor injectability, which makes it difficult for agent to realize deep profile control of reservoir. To solve this problem, styrene and acrylamide were used as monomers in the laboratory. Emulsion polymerization was used to prepare the Controllable Self-Aggregating Colloidal Particle (CSA), which was rich in amide group. The CSA microsphere dispersion solution with a particle diameter smaller than the pore throat diameter was injected into the reservoir to ensure that the profile control agent had good inject ability. After dispersing the CSA microsphere to the deep part of the reservoir, the CSA microspheres dispersed in static for a certain period of time will self-aggregate into large-sized particle clusters to achieve plugging of hypertonic channels. The CSA microsphere has the characteristics of low expansion and avoids shear fracture in the process of migration. It can be observed by transmission electron microscope that CSA microspheres still maintain regular and uniform spherical and core-shell heterogeneous structure after aging at 100 ºC for 35 days, and CSA microspheres have good thermal stability. The results of bottle test showed that with the increase of cation concentration, the aggregation time of CSA microspheres gradually shortened, and the influence of divalent cations was greater than that of monovalent ions. Physical simulation experiments show that CSA microspheres have good injectability, and the aggregated CSA particle clusters can produce effective plugging and migrate to the deep part of the reservoir for profile control.
Abstract: Sheet Molding Compounds (SMCs) with special microstructures are very attractive to use in automobile structures especially when they are accidentally subjected to collision type accidents because of their high energy absorption capacity. These are materials designated as standard SMC, Advanced Sheet Molding Compounds (A-SMC), Low-Density SMC (LD-SMC) and etc. In this study, testing methods have been performed to compare the mechanical responses and damage phenomena of SMC, LD-SMC, and A-SMC under quasi-static and high strain rate tensile tests. The paper also aims at investigating the effect of an initial pre-damage induced by fatigue on the tensile dynamic behavior of A-SMC. In the case of SMCs and A-SMCs, whatever the fibers orientation and applied strain rate are, the first observed phenomenon of damage corresponds to decohesion of the fiber-matrix interface which is followed by coalescence and multiplication of these micro-cracks and their propagations. For LD-SMCs, damage mechanisms depend on the presence of Hollow Glass Microspheres (HGM) and fibers orientation.
Abstract: This paper presents a model for a modified T-junction
device for microspheres generation. The numerical model is
developed using a commercial software package: COMSOL
Multiphysics. In order to test the accuracy of the numerical model,
multiple variables, such as the flow rate of cross-flow, fluid properties,
structure, and geometry of the microdevice are applied. The results
from the model are compared with the experimental results in the
diameter of the microsphere generated. The comparison shows a good
agreement. Therefore the model is useful in further optimization of the
device and feedback control of microsphere generation if any.
Abstract: The gel-supported precipitation (GSP) process can be
used to make spherical particles (spherules) of nuclear fuel,
particularly for very high temperature reactors (VHTR) and even for
implementing the process called SPHEREPAC. In these different
cases, the main characteristics are the sphericity of the particles to be
manufactured and the control over their grain size. Nonetheless,
depending on the specifications defined for these spherical particles,
the GSP process has intrinsic limits, particularly when fabricating
very small particles. This paper describes the use of secondary
fragmentation (water, water/PVA and uranyl nitrate) on solid
surfaces under varying temperature and vibration conditions to assess
the relevance of using this new technique to manufacture very small
spherical particles by means of a modified GSP process. The
fragmentation mechanisms are monitored and analysed, before the
trends for its subsequent optimised application are described.
Abstract: Using steelmaking slag as a raw material, aragonite superstructure product had been synthesized via an indirect CO2 mineral sequestration rout. It mainly involved two separate steps, in which the element of calcium is first selectively leached from steelmaking slag by a novel leaching media consisting of organic solvent Tributyl phosphate (TBP), acetic acid, and ultra-purity water, followed by enhanced carbonation in a separate step for aragonite superstructure production as well as efficiency recovery of leaching media. Based on the different leaching medium employed in the steelmaking slag leaching process, two typical products were collected from the enhanced carbonation step. The products were characterized by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM), respectively. It reveals that the needle-like aragonite crystals self-organized into aragonite superstructure particles including aragonite microspheres as well as dumbbell-like spherical particles, can be obtained from the steelmaking slag with the purity over 99%.
Abstract: Titanium oxide hollow microspheres were synthesized from organic precursor titanium tetraisopropoxide (TTIP) using continuous spray pyrolysis reactor. Effects of precursor concentration, applied voltage and annealing have been investigated. It was observed that the annealing of the as-synthesized TiO2 hollow microspheres at 2500C, which had an average external diameter of 200 nm, leads to an increase in the size and also more spherical shape. The precursor concentration was found to have a direct impact on the size of the microspheres, which is also evident in the absorption spectrum. The as-prepared TiO2 hollow microspheres exhibited good photocatalytic activity for the degradation of MO.
Abstract: The main aim of the presented experiments is to
improve behaviour of sandwich structures under dynamic loading,
such as crash or explosion. Several cellular materials are widely used
as core of the sandwich structures and their properties influence
the response of the entire element under impact load. To optimize
their performance requires the characterisation of the core material
behaviour at high strain rates and identification of the underlying
mechanism. This work presents the study of high strain-rate
characteristics of a specific porous lightweight blast energy absorbing
foam using a Split Hopkinson Pressure Bar (SHPB) technique
adapted to perform tests on low strength materials. Two different
velocities, 15 and 30 m.s-1 were used to determine the strain
sensitivity of the material. Foams were designed using two types of
porous lightweight spherical raw materials with diameters of 30-
100 *m, combined with polymer matrix. Cylindrical specimens with
diameter of 15 mm and length of 7 mm were prepared and loaded
using a Split Hopkinson Pressure Bar apparatus to assess the relation
between the composition of the material and its shock wave
attenuation capacity.
Abstract: Polymeric microreactors have emerged as a new
generation of carriers that hold tremendous promise in the areas of
cancer therapy, controlled delivery of drugs, for removal of
pollutants etc. Present work reports a simple and convenient
methodology for synthesis of polystyrene and poly caprolactone
microreactors. An aqueous suspension of carboxylated (1μm)
polystyrene latex particles was mixed with toluene solution followed
by freezing with liquid nitrogen. Freezed particles were incubated at
-20°C and characterized for formation of voids on the surface of
polymer microspheres by Field Emission Scanning Electron
Microscope. The hollow particles were then overnight incubated at
40ºC with unfunctionalized quantum dots (QDs) in 5:1 ratio. QDs
Encapsulated polystyrene microcapsules were characterized by
fluorescence microscopy.
Likewise Poly ε-caprolactone microreactors were prepared by
micro-volcanic rupture of freeze dried microspheres synthesized
using emulsification of polymer with aqueous Poly vinyl alcohol and
freezed with liquid nitrogen. Microreactors were examined with Field
Emission Scanning Electron Microscope for size and morphology.
Current study is an attempt to create hollow polymer particles which
can be employed for microencapsulation of nanoparticles and drug
molecules.