Abstract: A pilot plant for continuous flow microwave-assisted
chemical reaction combined with microreactors was developed and
water heating tests were conducted for evaluation of the developed
plant. We developed a microwave apparatus having a single
microwave generator that can heat reaction solutions in four reaction
fields simultaneously in order to increase throughput. We also
designed a four-branch waveguide using electromagnetic simulation,
and found that the transmission efficiency at 99%. Finally, we
developed the pilot plant using the developed microwave apparatus
and conducted water heating tests. The temperatures in the respective
reaction fields were controlled within ±1.1 K at 353.2 K. Moreover,
the energy absorption rates by the water were about 90% in the
respective reaction fields, whereas the energy absorption rate was
about 40% when 100 cm3 of water was heated by a commercially
available multimode microwave chemical reactor.
Abstract: Polymeric microreactors have emerged as a new
generation of carriers that hold tremendous promise in the areas of
cancer therapy, controlled delivery of drugs, for removal of
pollutants etc. Present work reports a simple and convenient
methodology for synthesis of polystyrene and poly caprolactone
microreactors. An aqueous suspension of carboxylated (1μm)
polystyrene latex particles was mixed with toluene solution followed
by freezing with liquid nitrogen. Freezed particles were incubated at
-20°C and characterized for formation of voids on the surface of
polymer microspheres by Field Emission Scanning Electron
Microscope. The hollow particles were then overnight incubated at
40ºC with unfunctionalized quantum dots (QDs) in 5:1 ratio. QDs
Encapsulated polystyrene microcapsules were characterized by
fluorescence microscopy.
Likewise Poly ε-caprolactone microreactors were prepared by
micro-volcanic rupture of freeze dried microspheres synthesized
using emulsification of polymer with aqueous Poly vinyl alcohol and
freezed with liquid nitrogen. Microreactors were examined with Field
Emission Scanning Electron Microscope for size and morphology.
Current study is an attempt to create hollow polymer particles which
can be employed for microencapsulation of nanoparticles and drug
molecules.