Abstract: A pilot plant for continuous flow microwave-assisted
chemical reaction combined with microreactors was developed and
water heating tests were conducted for evaluation of the developed
plant. We developed a microwave apparatus having a single
microwave generator that can heat reaction solutions in four reaction
fields simultaneously in order to increase throughput. We also
designed a four-branch waveguide using electromagnetic simulation,
and found that the transmission efficiency at 99%. Finally, we
developed the pilot plant using the developed microwave apparatus
and conducted water heating tests. The temperatures in the respective
reaction fields were controlled within ±1.1 K at 353.2 K. Moreover,
the energy absorption rates by the water were about 90% in the
respective reaction fields, whereas the energy absorption rate was
about 40% when 100 cm3 of water was heated by a commercially
available multimode microwave chemical reactor.
Abstract: We have developed a microfluidic device system for the continuous producting of nanoparticles, and we have clarified the relationship between the mixing performance of reactors and the particle size. First, we evaluated the mixing performance of reactors by carring out the Villermaux–Dushman reaction and determined the experimental conditions for producing AgCl nanoparticles. Next, we produced AgCl nanoparticles and evaluated the mixing performance and the particle size. We found that as the mixing performance improves the size of produced particles decreases and the particle size distribution becomes sharper. We produced AgCl nanoparticles with a size of 86 nm using the microfluidic device that had the best mixing performance among the three reactors we tested in this study; the coefficient of variation (Cv) of the size distribution of the produced nanoparticles was 26.1%.