Abstract: The paper presents a one-dimensional transient
mathematical model of compressible non-isothermal multicomponent
fluid mixture flow in a pipe. The set of the mass,
momentum and enthalpy conservation equations for gas phase is
solved in the model. Thermo-physical properties of multi-component
gas mixture are calculated by solving the Equation of State (EOS)
model. The Soave-Redlich-Kwong (SRK-EOS) model is chosen. Gas
mixture viscosity is calculated on the basis of the Lee-Gonzales-
Eakin (LGE) correlation. Numerical analysis of rapid gas
decompression process in rich and base natural gases is made on the
basis of the proposed mathematical model. The model is successfully
validated on the experimental data [1]. The proposed mathematical
model shows a very good agreement with the experimental data [1] in
a wide range of pressure values and predicts the decompression in
rich and base gas mixtures much better than analytical and
mathematical models, which are available from the open source
literature.
Abstract: The previous researches focused on the influence of
anthropogenic greenhouse gases exerting global warming, but not
consider whether desert sand may warm the planet, this could be
improved by accounting for sand's physical and geometric properties.
Here we show, sand particles (because of their geometry) at the desert
surface form an extended surface of up to 1 + π/4 times the planar area
of the desert that can contact sunlight, and at shallow depths of the
desert form another extended surface of at least 1 + π times the planar
area that can contact air. Based on this feature, an enhanced heat
exchange system between sunlight, desert sand, and air in the spaces
between sand particles could be built up automatically, which can
increase capture of solar energy, leading to rapid heating of the sand
particles, and then the heating of sand particles will dramatically heat
the air between sand particles. The thermodynamics of deserts may
thus have contributed to global warming, especially significant to
future global warming if the current desertification continues to
expand.
Abstract: The gases generated in oil filled transformers can be
used for qualitative determination of incipient faults. The Dissolved
Gas Analysis has been widely used by utilities throughout the world
as the primarily diagnostic tool for transformer maintenance. In this
paper, various Artificial Intelligence Techniques that have been used
by the researchers in the past have been reviewed, some conclusions
have been drawn and a sequential hybrid system has been proposed.
The synergy of ANN and FIS can be a good solution for reliable
results for predicting faults because one should not rely on a single
technology when dealing with real–life applications.
Abstract: In the gas refineries of Iran-s South Pars Gas
Complex, Sulfrex demercaptanization process is used to remove
volatile and corrosive mercaptans from liquefied petroleum gases by
caustic solution. This process consists of two steps. Removing low
molecular weight mercaptans and regeneration exhaust caustic. Some
parameters such as LPG feed temperature, caustic concentration and
feed-s mercaptan in extraction step and sodium mercaptide content in
caustic, catalyst concentration, caustic temperature, air injection rate
in regeneration step are effective factors. In this paper was focused on
temperature factor that play key role in mercaptans extraction and
caustic regeneration. The experimental results demonstrated by
optimization of temperature, sodium mercaptide content in caustic
because of good oxidation minimized and sulfur impurities in
product reduced.
Abstract: Fossil fuel-firing power plants dominate electric
power generation in Taiwan, which are also the major contributor to
Green House gases (GHG). CO2 is the most important greenhouse
gas that cause global warming. This paper penetrates the relationship
between carbon trading for GHG reduction and power generation
expansion planning (GEP) problem for the electrical utility. The
Particle Swarm Optimization (PSO) Algorithm is presented to deal
with the generation expansion planning strategy of the utility with
independent power providers (IPPs). The utility has to take both the
IPPs- participation and environment impact into account when a new
generation unit is considering expanded from view of supply side.
Abstract: Gas flaring is one of the most GHG emitting sources in the oil and gas industries. It is also a major way for wasting such an energy that could be better utilized and even generates revenue. Minimize flaring is an effective approach for reducing GHG emissions and also conserving energy in flaring systems. Integrating waste and flared gases into the fuel gas networks (FGN) of refineries is an efficient tool. A fuel gas network collects fuel gases from various source streams and mixes them in an optimal manner, and supplies them to different fuel sinks such as furnaces, boilers, turbines, etc. In this article we use fuel gas network model proposed by Hasan et al. as a base model and modify some of its features and add constraints on emission pollution by gas flaring to reduce GHG emissions as possible. Results for a refinery case study showed that integration of flare gas stream with waste and natural gas streams to construct an optimal FGN can significantly reduce total annualized cost and flaring emissions.
Abstract: To calculate the temperature distribution of the slab in
a hot rolled reheating furnace a mathematical model has been
developed by considering the thermal radiation in the furnace and
transient conduction in the slab. The furnace is modeled as radiating
medium with spatially varying temperature. Radiative heat flux within
the furnace including the effect of furnace walls, combustion gases,
skid beams and buttons is calculated using the FVM and is applied as
the boundary condition of the transient conduction equation of the
slab. After determining the slab emissivity by comparison between
simulation and experimental work, variation of heating characteristics
in the slab is investigated in the case of changing furnace temperature
with various time and the slab residence time is optimized with this
evaluation.
Abstract: Cogeneration may be defined as a system which
contains electricity production and regain of the thermo value of
exhaust gases simultaneously. The examination is based on the data-s
of an active cogeneration plant. This study, it is aimed to determine
which component of the system should be revised first to raise the
efficiency and decrease the loss of exergy. For this purpose, second
law analysis of thermodynamics is applied to each component due to
consider the effects of environmental conditions and take the quality
of energy into consideration as well as the quantity of it. The exergy
balance equations are produced and exergy loss is calculated for each
component. 44,44 % loss of exergy in heat exchanger, 29,59 % in
combustion chamber, 18,68 % in steam boiler, 5,25 % in gas turbine
and 2,03 % in compressor is calculated.
Abstract: Hydrogen sulfide (H2S) is a very toxic gas that is produced in very large quantities in the oil and gas industry. It cannot be flared to the atmosphere and Claus process based gas plants are used to recover the sulfur and convert the hydrogen to water. In this paper, we present optical characterization of an atmospheric pressure microwave plasma torch for H2S dissociation into hydrogen and sulfur. The torch is operated at 2.45 GHz with power up to 2 kW. Three different gases can simultaneously be injected in the plasma torch. Visual imaging and optical emission spectroscopy are used to characterize the plasma for varying gas flow rates and microwave power. The plasma length, emission spectra and temperature are presented. The obtained experimental results validate our earlier published simulation results of plasma torch.
Abstract: The scroll pump belongs to the category of positive
displacement pump can be used for continuous pumping of gases at
low pressure apart from general vacuum application. The shape of
volume occupied by the gas moves and deforms continuously as the
spiral orbits. To capture flow features in such domain where mesh
deformation varies with time in a complicated manner, mesh less
solver was found to be very useful. Least Squares Kinetic Upwind
Method (LSKUM) is a kinetic theory based mesh free Euler solver
working on arbitrary distribution of points. Here upwind is enforced
in molecular level based on kinetic flux vector splitting scheme
(KFVS). In the present study we extended the LSKUM to moving
node viscous flow application. This new code LSKUM-NS-MN for
moving node viscous flow is validated for standard airfoil pitching
test case. Simulation performed for flow through scroll pump using
LSKUM-NS-MN code agrees well with the experimental pumping
speed data.
Abstract: This paper contributes to the debate on the proximate
causes of climate change. Also, it discusses the impact of the global
temperature increases since the beginning of the twentieth century
and the effectiveness of climate change models in isolating the
primary cause (anthropogenic influences or natural variability in
temperature) of the observed temperature increases that occurred
within this period. The paper argues that if climate scientist and
policymakers ignore the anthropogenic influence (greenhouse gases)
on global warming on the pretense of lack of agreement among
various climate models and their inability to account for all the
necessary factors of global warming at all levels the current efforts of
greenhouse emissions control and global warming as a whole could
be exacerbated.
Abstract: This research is to study the performance of heat
pump dryer for drying of kaffir lime leaves under different media and
to compare the color values and essential oil content of final products
after drying. In the experiments, kaffir lime leaves were dried in the
closed-loop system at drying temperatures of 40, 50 and 60 oC. The
drying media used in this study were hot air, CO2 and N2 gases. The
velocity of drying media in the drying chamber was 0.4 m/s with
bypass ratio of 30%. The initial moisture content of kaffir lime leaves
was approximately 180-190 % d.b. It was dried until down to a final
moisture content of 10% d.b. From the experiments, the results
showed that drying rate, the coefficient of performance (COP) and
specific energy consumption (SEC) depended on drying temperature.
While drying media did not affect on drying rate. The time for kaffir
lime leaves drying at 40, 50 and 60 oC was 10, 5 and 3 hours,
respectively. The performance of the heat pump system decreased
with drying temperature in the range of 2.20-3.51. In the aspect of
final product color, the greenness and overall color had a great
change under drying temperature at 60 oC rather than drying at 40
and 50 oC. When compared among drying media, the greenness and
overall color of product dried with hot air at 60 oC had a great change
rather than dried with CO2 and N2.
Abstract: Pyrolysis of waste tire is one of alternative technique
to produce petrochemicals, such as light olefins, mixed C4, and monoaromatics.
Noble metals supported on acid zeolite catalysts were
reported as potential catalysts to produce the high valuable products
from waste tire pyrolysis. Especially, Pd supported on HBeta gave a
high yield of olefins, mixed C4, and mono-aromatics. Due to the high
prices of noble metals, the objective of this work was to investigate
whether or not a non-noble Ni metal can be used as a substitute of a
noble metal, Pd, supported on HBeta as a catalyst for waste tire pyrolysis.
Ni metal was selected in this work because Ni has high activity
in cracking, isomerization, hydrogenation and the ring opening of
hydrocarbons Moreover, Ni is an element in the same group as Pd
noble metal, which is VIIIB group, aiming to produce high valuable
products similarly obtained from Pd. The amount of Ni was varied as
5, 10, and 20% by weight, for comparison with a fixed 1 wt% Pd,
using incipient wetness impregnation. The results showed that as a
petrochemical-producing catalyst, 10%Ni/HBeta performed better
than 1%Pd/HBeta because it did not only produce the highest yield of
olefins and cooking gases, but the yields were also higher than
1%Pd/HBeta. 5%Ni/HBeta can be used as a substitute of
1%Pd/HBeta for similar crude production because its crude contains
the similar amounts of naphtha and saturated HCs, although it gave
no concentration of light mono-aromatics (C6-C11) in the oil. Additionally,
10%Ni/HBeta that gave high olefins and cooking gases was
found to give a fairly high concentration of the light mono-aromatics
in the oil.
Abstract: It is shown that a modified UNIFAC model can be
applied to predict solubility of hydrocarbon gases and vapors in
hydrocarbon solvents. Very good agreement with experimental data
has been achieved. In this work we try to find best way for predicting
dimethyl ether solubility in liquid paraffin by using group
contribution theory.
Abstract: Carbon dioxide is one of the major green house gases.
It is removed from different streams using amine absorption process.
Sterically hindered amines are suggested as good CO2 absorbers.
Solubility of carbon dioxide (CO2) was measured in aqueous
solutions of 2-Amino-2-methyl-1-propanol (AMP) at temperatures 30
oC, 40 oC and 60 oC. The effect of pressure and temperature was
studied over various concentrations of AMP. It has been found that
pressure has positive effect on CO2 solubility where as solubility
decreased with increasing temperature. Absorption performance of
AMP increased with increasing pressure. Solubility of aqueous AMP
was compared with mo-ethanolamine (MEA) and the absorption
capacity of aqueous solutions of AMP was found to be better.
Abstract: Fuel cells have become one of the major areas of
research in the academia and the industry. The goal of most fish
farmers is to maximize production and profits while holding labor
and management efforts to the minimum. Risk of fish kills, disease
outbreaks, poor water quality in most pond culture operations,
aeration offers the most immediate and practical solution to water
quality problems encountered at higher stocking and feeding rates.
Many units of aeration system are electrical units so using a
continuous, high reliability, affordable, and environmentally friendly
power sources is necessary. Aeration of water by using PEM fuel cell
power is not only a new application of the renewable energy, but
also, it provides an affordable method to promote biodiversity in
stagnant ponds and lakes. This paper presents a new design and
control of PEM fuel cell powered a diffused air aeration system for a
shrimp farm in Mersa Matruh in Egypt. Also Artificial intelligence
(AI) techniques control is used to control the fuel cell output power
by control input gases flow rate. Moreover the mathematical
modeling and simulation of PEM fuel cell is introduced. A
comparison study is applied between the performance of fuzzy logic
control (FLC) and neural network control (NNC). The results show
the effectiveness of NNC over FLC.
Abstract: We present an Electronic Nose (ENose), which is
aimed at identifying the presence of one out of two gases, possibly
detecting the presence of a mixture of the two. Estimation of the
concentrations of the components is also performed for a volatile
organic compound (VOC) constituted by methanol and acetone, for
the ranges 40-400 and 22-220 ppm (parts-per-million), respectively.
Our system contains 8 sensors, 5 of them being gas sensors (of the
class TGS from FIGARO USA, INC., whose sensing element is a tin
dioxide (SnO2) semiconductor), the remaining being a temperature
sensor (LM35 from National Semiconductor Corporation), a
humidity sensor (HIH–3610 from Honeywell), and a pressure sensor
(XFAM from Fujikura Ltd.).
Our integrated hardware–software system uses some machine
learning principles and least square regression principle to identify at
first a new gas sample, or a mixture, and then to estimate the
concentrations. In particular we adopt a training model using the
Support Vector Machine (SVM) approach with linear kernel to teach
the system how discriminate among different gases. Then we apply
another training model using the least square regression, to predict
the concentrations.
The experimental results demonstrate that the proposed
multiclassification and regression scheme is effective in the
identification of the tested VOCs of methanol and acetone with
96.61% correctness. The concentration prediction is obtained with
0.979 and 0.964 correlation coefficient for the predicted versus real
concentrations of methanol and acetone, respectively.
Abstract: In this communication a quantitative modeling
approach is applied to construct model for the exchange of gases
from open sewer channel to the atmosphere. The data for the
exchange of gases of the open sewer channel for the year January
1979 to December 2006 is utilized for the construction of the model.
The study reveals that stream flow of the open sewer channel
exchanges the toxic gases continuously with time varying scale. We
find that the quantitative modeling approach is more parsimonious
model for these exchanges. The usual diagnostic tests are applied for
the model adequacy. This model is beneficial for planner and
managerial bodies for the improvement of implemented policies to
overcome future environmental problems.
Abstract: Electric vehicle (EV) is one of the effective solutions to
control emission of greenhouses gases in the world. It is of interest
for future transportation due to its sustainability and efficiency by
automotive manufacturers. Various electrical motors have been used
for propulsion system of electric vehicles in last decades. In this
paper brushed DC motor, Induction motor (IM), switched reluctance
motor (SRM) and brushless DC motor (BLDC) are simulated and
compared. BLDC motor is recommended for high performance
electric vehicles. PWM switching technique is implemented for speed
control of BLDC motor. Behavior of different modes of PWM speed
controller of BLDC motor are simulated in MATLAB/SIMULINK.
BLDC motor characteristics are compared and discussed for various
PWM switching modes under normal and inverter fault conditions.
Comparisons and discussions are verified through simulation results.
Abstract: Despite of the preponderant role played by cement among the construction materials, it is today considered as a material destructing the environment due to the large quantities of carbon dioxide exhausted during its manufacture. Besides, global warming is now recognized worldwide as the new threat to the humankind against which advanced countries are investigating measures to reduce the current amount of exhausted gases to the half by 2050. Accordingly, efforts to reduce green gases are exerted in all industrial fields. Especially, the cement industry strives to reduce the consumption of cement through the development of alkali-activated geopolymer mortars using industrial byproducts like bottom ash. This study intends to gather basic data on the flowability and strength development characteristics of alkali-activated geopolymer mortar by examining its FT-IT features with respect to the effects and strength of the alkali-activator in order to develop bottom ash-based alkali-activated geopolymer mortar. The results show that the 35:65 mass ratio of sodium hydroxide to sodium silicate is appropriate and that a molarity of 9M for sodium hydroxide is advantageous. The ratio of the alkali-activators to bottom ash is seen to have poor effect on the strength. Moreover, the FT-IR analysis reveals that larger improvement of the strength shifts the peak from 1060 cm–1 (T-O, T=Si or Al) toward shorter wavenumber.