Abstract: Portugal is an important wine and olive oil producer, activities which generate a high quantity of residues commonly called grape stalks and olive cake, respectively. In this work grape stalks and olive cake were used as lignocellulosic adsorbents for wastewater containing lead treatment. To attain a better knowledge of the factors that could influence the quality of the treated wastewater, a chemical characterization of the materials used in the treatment was done. To access the ecotoxicological safety of the treated wastewater, several tests were performed.
The results of the toxicity test show that the samples leachate has a mild effect on the living models tested. The tests performed in lemna and bacteria were the most sensible to toxicity effects of the samples. The results obtained in this work evidenced the importance of use of simple and fast toxicity tests to predict impacts in the environment.
Abstract: Activated carbons were produced from olive stones by a chemical process. The activated carbon (AC) were modified by nitric acid and used as adsorbents for the removal of methylene blue dye from aqueous solution. The activated carbons were characterized by nitrogen adsorption and enthalpy of immersion. Batch adsorption experiments were carried out to study the effect of initial different concentrations solution on dye adsorption properties. Isotherms were fitted to Langmuir model, and corresponding parameters were determined. The results showed that the increase of ration of ZnCl2 leads to increase in apparent surface areas and produces activated carbons with pore structure more developed. However, the maximum MB uptakes for all carbons were determined and correlated with activated carbons characteristics.
Abstract: One of the causes of water pollution is the presence of heavy metals in water. In the present study, an adsorbent prepared from the raw bark of the Pongamia pinnata tree is used for the removal of ferrous or ferric ions from aqueous and waste water containing heavy metals. Adsorption studies were conducted at different pH, concentration of metal ion, amount of adsorbent, contact time, agitation and temperature. The Langmuir and Freundlich adsorption isotherm models were applied for the results. The Langmuir isotherms were best fitted by the equilibrium data. The maximum adsorption was found to 146mg/g in waste water at a temperature of 30°C which is in agreement as comparable to the adsorption capacity of different adsorbents reported in literature. Pseudo second order model best fitted the adsorption of both ferrous and ferric ions.
Abstract: A water treatment technology employing the adsorption of dissolved organic contaminants from water and their electrochemical regeneration has been commercialized by Arvia Technology Ltd, UK. This technology focuses the adsorption of pollutants onto the surface of low surface area graphite based adsorbents followed by the anodic oxidation of adsorbed species in an electrochemical cell. However, some of the adsorbed species may lead to the formation of intermediate breakdown products due to incomplete oxidation. The information regarding the formation of breakdown products during electrochemical regeneration of these adsorbents is important for the effective application of this process to water treatment. In the present paper, the formation of the break down products during electrochemical regeneration of various graphite based adsorbents has been demonstrated.
Abstract: Fly ash is a waste material of coal firing thermal
plants that is released from thermal power plants. It was defined as
very fine particles that are drifted upward which are taken up by the
flue gases. The emerging amount of fly ash in the world is
approximately 600 million tons per year. In our country, it is
expected that will be occurred 50 million tons of waste ash per year
until 2020. The fly ashes can be evaluated by using as adsorbent
material. The purpose of this study is to investigate the possibility of
use of various fly ashes (Tuncbilek, Catalagzi, Orhaneli) like lowcost
adsorbents for heavy metal adsorption. First of all, fly ashes
were characterized. For this purpose; analyses such as XRD, XRF,
SEM and FT-IR were performed.
Abstract: Intercalation imparts interesting features to the host graphite material. Two different types of intercalated compounds called (GIC-bisulphate or Nyex 1000 and GIC-nitrate or Nyex 3000) were tested for their adsorption capacity and ability to undergo electrochemical regeneration. It was found that Nyex 3000 showed comparatively slow kinetics along with reduced adsorption capacity to one half for acid violet 17 as adsorbate. Acid violet 17 was selected as model organic pollutant for evaluating comparative performance of said adsorbents. Both adsorbent materials showed 100% regeneration efficiency as achieved by passing a charge of 36 C g-1 at a current density of 12 mA cm-2 and a treatment time of 60 min.
Abstract: In this project cadmium ions were adsorbed from
aqueous solutions onto either date pits; a cheap agricultural and nontoxic
material, or chemically activated carbon prepared from date pits
using phosphoric acid. A series of experiments were conducted in a
batch adsorption technique to assess the feasibility of using the
prepared adsorbents. The effects of the process variables such as
initial cadmium ions concentration, contact time, solution pH and
adsorbent dose on the adsorption capacity of both adsorbents were
studied. The experimental data were tested using different isotherm
models such as Langmuir, Freundlich, Tempkin and Dubinin-
Radushkevich. The results showed that although the equilibrium data
could be described by all models used, Langmuir model gave slightly
better results when using activated carbon while Freundlich model,
gave better results with date pits.
Abstract: As the fossil fuels kept on depleting, intense research in developing hydrogen (H2) as the alternative fuel has been done to cater our tremendous demand for fuel. The potential of H2 as the ultimate clean fuel differs with the fossil fuel that releases significant amounts of carbon dioxide (CO2) into the surrounding and leads to the global warming. The experimental work was carried out to study the production of H2 from palm kernel shell steam gasification at different variables such as heating rate, steam to biomass ratio and adsorbent to biomass ratio. Maximum H2 composition which is 61% (volume basis) was obtained at heating rate of 100oCmin-1, steam/biomass of 2:1 ratio, and adsorbent/biomass of 1:1 ratio. The commercial adsorbent had been modified by utilizing the alcoholwater mixture. Characteristics of both adsorbents were investigated and it is concluded that flowability and floodability of modified CaO is significantly improved.
Abstract: Sol-gel immobilization of enzymes, which can improve considerably their properties, is now one of the most used techniques. By deposition of the entrapped lipase on a solid support, a new and improved biocatalyst was obtained, which can be used with excellent results in acylation reactions. In this paper, lipase B from Candida antarctica was double immobilized on different adsorbents. These biocatalysts were employed in the kinetic resolution of several aliphatic secondary alcohols in organic medium. High total recovery yields of enzymatic activity, up to 560%, were obtained. For all the studied alcohols the enantiomeric ratios E were over 200. The influence of the reaction medium was studied for the kinetic resolution of 2-pentanol.
Abstract: CO2 is the primary anthropogenic greenhouse gas,
accounting for 77% of the human contribution to the greenhouse
effect in 2004. In the recent years, global concentration of CO2 in the
atmosphere is increasing rapidly. CO2 emissions have an impact on
global climate change. Anthropogenic CO2 is emitted primarily from
fossil fuel combustion. Carbon capture and storage (CCS) is one
option for reducing CO2 emissions. There are three major approaches
for CCS: post-combustion capture, pre-combustion capture and
oxyfuel process. Post-combustion capture offers some advantages as
existing combustion technologies can still be used without radical
changes on them.
There are several post combustion gas separation and capture
technologies being investigated, namely; (a) absorption, (b)
cryogenic separation, (c) membrane separation (d) micro algal biofixation
and (e) adsorption. Apart from establishing new techniques,
the exploration of capture materials with high separation performance
and low capital cost are paramount importance. However, the
application of adsorption from either technology, require easily
regenerable and durable adsorbents with a high CO2 adsorption
capacity. It has recently been reported that the cost of the CO2
capture can be reduced by using this technology. In this paper, the
research progress (from experimental results) in adsorbents for CO2
adsorption, storage, and separations were reviewed and future
research directions were suggested as well.
Abstract: Waste lubricating oil re-refining adsorption process by
different adsorbent materials was investigated. Adsorbent materials
such as oil adsorbent, egg shale powder, date palm kernel powder,
and acid activated date palm kernel powder were used. The
adsorption process over fixed amount of adsorbent at ambient
conditions was investigated. The adsorption/extraction process was
able to deposit the asphaltenic and metallic contaminants from the
waste oil to lower values. It was found that the date palm kernel
powder with contact time of 4 h was able to give the best conditions
for treating the waste oil. The recovered solvent could be also reused.
It was also found that the activated bentonite gave the best
physical properties followed by the date palm kernel powder.
Abstract: The implementation of Super-Ultra Low Emission
Vehicle standards requires more efficient exhaust gas purification. To
increase the efficiency of exhaust gas purification, an the adsorbent
capable of holding hydrocarbons up to 250-300 ОС should be
developed. The possibility to design such adsorbents by modification
of zeolites of mordenite type, ZSM-5 and NaY, using different
metals cations has been studied.
It has been shown that introducing Cr, Cs, Zn, Ni, Co, Li, Mn in
zeolites results in modification of the toluene TPD and toluene
sorption capacity.
5%LiZSM-5 zeolite exhibits the most attractive TPD curve, with
toluene desorption temperature ranging from 250 to 350ОС. The
sorption capacity of 5%Li-ZSM-5 is 0.4 mmol/g. NaY zeolite has the
highest sorption capacity, up to 2 mmol/g, and holds toluene up to
350ОС, but at 120ОС toluene desorption starts, which is not desirable,
since the adsorbent of cold start hydrocarbons should retain them
until 250-300ОС. Therefore 5%LiZSM-5 zeolite was found to be the
most promising to control the cold-start hydrocarbon emissions
among the samples studied.
Abstract: Fly ash is one of the residues generated in
combustion, and comprises the fine particles that rise with the flue
gases. Ash which does not rise is termed bottom ash [1]. In our
country, it is expected that will be occurred 50 million tons of waste
ash per year until 2020. Released waste from the thermal power
plants is caused very significant problems as known. The fly ashes
can be evaluated by using as adsorbent material.
The purpose of this study is to investigate the possibility of use of
Tuncbilek fly ash like low-cost adsorbents for heavy metal
adsorption. First of all, Tuncbilek fly ash was characterized. For this
purpose; analysis such as sieve analysis, XRD, XRF, SEM and FT-IR
were performed.
Abstract: Ciprofloxacin (CIP) and Carbamazepine (CBZ), nonbiodegradable pharmaceutical residues, were become emerging pollutants in several aquatic environments. The objectives of this research were to study the possibility to recover these pharmaceuticals residues from pharmaceutical wastewater by increasing the selective adsorption on synthesized functionalized porous silicate, comparing with powdered activated carbon (PAC). Hexagonal mesoporous silicate (HMS), functionalized HMSs (3- aminopropyltriethoxy, 3- mercaptopropyltrimethoxy and noctyldimethyl) were synthesized and characterized physico-chemical characteristics. Obtained adsorption kinetics and isotherms showed that 3-mercaptopropyltrimethoxy functional groups grafted on HMS provided highest CIP and CBZ adsorption capacities; however, it was still lower than that of PAC. The kinetic results were compatible with pseudo-second order. The hydrophobicity and hydrogen bonding might play a key role on the adsorption. Furthermore, the capacities were affected by varying pH values due to the strength of hydrogen bonding between targeted compounds and adsorbents. Electrostatic interaction might not affect the adsorption capacities.
Abstract: High pressure adsorption of carbon dioxide on zeolite
13X was investigated in the pressure range (0 to 4) Mpa and
temperatures 298, 308 and 323K. The data fitting is accomplished
with the Toth, UNILAN, Dubinin-Astakhov and virial adsorption
models which are generally used for micro porous adsorbents such as
zeolites. Comparison with experimental data from the literature
indicated that the virial model would best determine results. These
results may be partly attributed to the flexibility of the virial model
which can accommodate as many constants as the data warrants.
Abstract: In this study, we used a two-stage process and
potassium hydroxide (KOH) to transform waste biomass (rice straw)
into activated carbon and then evaluated the adsorption capacity of the
waste for removing carbofuran from an aqueous solution. Activated
carbon was fast and effective for the removal of carbofuran because of
its high surface area. The native and carbofuran-loaded adsorbents
were characterized by elemental analysis. Different adsorption
parameters, such as the initial carbofuran concentration, contact time,
temperature and pH for carbofuran adsorption, were studied using a
batch system. This study demonstrates that rice straw can be very
effective in the adsorption of carbofuran from bodies of water.
Abstract: Zeolite A and MCM-41 have extensive applications in basic science, petrochemical science, energy conservation/storage, medicine, chemical sensor, air purification, environmentally benign composite structure and waste remediation. However, the use of zeolite A and MCM-41 in these areas, especially environmental remediation, are restricted due to prohibitive production cost. Efficient recycling of and resource recovery from coal fly ash has been a major topic of current international research interest, aimed at achieving sustainable development of human society from the viewpoints of energy, economy, and environmental strategy. This project reported an original, novel, green and fast methods to produce nano-porous zeolite A and MCM-41 materials from coal fly ash. For zeolite A, this novel production method allows a reduction by half of the total production time while maintaining a high degree of crystallinity of zeolite A which exists in a narrower particle size distribution. For MCM-41, this remarkably green approach, being an environmentally friendly process and reducing generation of toxic waste, can produce pure and long-range ordered MCM-41 materials from coal fly ash. This approach took 24 h at 25 oC to produce 9 g of MCM-41 materials from 30 g of the coal fly ash, which is the shortest time and lowest reaction temperature required to produce pure and ordered MCM-41 materials (having the largest internal surface area) compared to the values reported in the literature. Performance evaluation of the produced zeolite A and MCM-41 materials in wastewater treatment and air pollution control were reported. The residual fly ash was also converted to zeolite Na-P1 which showed good performance in removal of multi-metal ions in wastewater. In wastewater treatment, compared to commercial-grade zeolite A, adsorbents produced from coal fly ash were effective in removing multi heavy metal ions in water and could be an alternative material for treatment of wastewater. In methane emission abatement, the zeolite A (produced from coal fly ash) achieved similar methane removal efficiency compared to the zeolite A prepared from pure chemicals. This report provides the guidance for production of zeolite A and MCM-41 from coal fly ash by a cost-effective approach which opens potential applications of these materials in environmental industry. Finally, environmental and economic aspects of production of zeolite A and MCM-41 from coal fly ash were discussed.
Abstract: Arvia®, a spin-out company of University of Manchester, UK is commercialising a water treatment technology for the removal of low concentrations of organics from water. This technology is based on the adsorption of organics onto graphite based adsorbents coupled with their electrochemical regeneration in a simple electrochemical cell. In this paper, the potential of the process to adsorb microorganisms and electrochemically disinfect them present in water has been demonstrated. Bench scale experiments have indicated that the process of adsorption using graphite adsorbents with electrochemical regeneration can be used for water disinfection effectively. The most likely mechanisms of disinfection of water through this process include direct electrochemical oxidation and electrochemical chlorination.
Abstract: To reduce the carbon dioxide emission into the
atmosphere, adsorption is believed to be one of the most attractive
methods for post-combustion treatment of flue gas. In this work,
activated carbon (AC) was modified by polyethylenimine (PEI) via
impregnation in order to enhance CO2 adsorption capacity. The
adsorbents were produced at 0.04, 0.16, 0.22, 0.25, and 0.28 wt%
PEI/AC. The adsorption was carried out at a temperature range from
30 °C to 75 °C and five different gas pressures up to 1 atm. TG-DTA,
FT-IR, UV-visible spectrometer, and BET were used to characterize
the adsorbents. Effects of PEI loading on the AC for the CO2
adsorption were investigated. Effectiveness of the adsorbents on the
CO2 adsorption including CO2 adsorption capacity and adsorption
temperature was also investigated. Adsorption capacities of CO2 were
enhanced with the increase in the amount of PEI from 0.04 to 0.22
wt% PEI before the capacities decreased onwards from0.25 wt% PEI
at 30 °C. The 0.22 wt% PEI/AC showed higher adsorption capacity
than the AC for adsorption at 50 °C to 75 °C.
Abstract: Contamination of aromatic compounds in water can
cause severe long-lasting effects not only for biotic organism but also
on human health. Several alternative technologies for remediation of
polluted water have been attempted. One of these is adsorption
process of aromatic compounds by using organic modified clay
mineral. Porous structure of clay is potential properties for molecular
adsorptivity and it can be increased by immobilizing hydrophobic
structure to attract organic compounds. In this work natural
montmorillonite were modified with cetyltrimethylammonium
(CTMA+) and was evaluated for use as adsorbents of aromatic
compounds: benzene, toluene, and 2-chloro phenol in its single and
multicomponent solution by ethanol:water solvent. Preparation of
CTMA-montmorillonite was conducted by simple ion exchange
procedure and characterization was conducted by using x-day
diffraction (XRD), Fourier-transform infra red (FTIR) and gas
sorption analysis. The influence of structural modification of
montmorillonite on its adsorption capacity and adsorption affinity of
organic compound were studied. It was shown that adsorptivity of
montmorillonite was increased by modification associated with
arrangements of CTMA+ in the structure even the specific surface
area of modified montmorillonite was lower than raw
montmorillonite. Adsorption rate indicated that material has affinity
to adsorb compound by following order: benzene> toluene > 2-chloro
phenol. The adsorption isotherms of benzene and toluene showed 1st
order adsorption kinetic indicating a partition phenomenon of
compounds between the aqueous and organophilic CTMAmontmorillonite.