Equilibrium Modeling of Carbon Dioxide Adsorption on Zeolites
High pressure adsorption of carbon dioxide on zeolite
13X was investigated in the pressure range (0 to 4) Mpa and
temperatures 298, 308 and 323K. The data fitting is accomplished
with the Toth, UNILAN, Dubinin-Astakhov and virial adsorption
models which are generally used for micro porous adsorbents such as
zeolites. Comparison with experimental data from the literature
indicated that the virial model would best determine results. These
results may be partly attributed to the flexibility of the virial model
which can accommodate as many constants as the data warrants.
[1] I. Langmuir, J. Am. Chem. Soc. 40 (1918) 1361-1403
[2] R. Sips, J. Chem. Phys. 16 (1948) 490-495.
[3] J. Toth, Acta chim. Acad. Sci. Hung. 69 (1971) 311-328.
[4] R. Sips, J. Chem. Phys. 18 (1950) 1024-1026.
[5] J.M. Honig, L.H. Reyerson, J. Phys. Chem. 56 (1952) 140-144.
[6] M.M. Dubinin, V. A. Astakhov, Russ. Chem. Bull. 20 (1971) 8-12.
[7] V.A. Astakhov, M.M. Dubinin, Russ. Chem. Bull. 20 (1971) 13-16.
[8] M.M. Dubinin, V.A. Astakhov, Adv. Chem. Ser. 102 (1971) 69-85.
[9] R.M. Barrer, D.E.W. Vaughan, J. Phys. Chem. Solids. 32 (1971) 731-
734.
[10] D. M. Ruthven, B.K. Kaul, Lnd, Eng. Chem. Res. 32 (1993) 2047-2052.
[11] C.L. Cavalcante, D.M. Ruthven, Ind. Eng. Chem. Res. 34 (1995) 177-
184.
[12] G.W. Miller, K.S. Knaebel, K.G. Ikels, AIChE J. 33 (1987) 194-201.
[13] A. Khelifa, L. Benchehida, Z. Derriche, J. Colloid Interface Sci. 278
(2004) 9-17.
[14] D.P. Valenzuela, A.L. Mayers, Adsorption Equilibrium Data Handbook,
Prentic¬e Hall, Englewood Cliffs, New Jersey, 1989 (Chapters 1 and 2).
[15] S.G. Chen, R.T. Yang, Langmuir 10 (1994) 4244-4249.
[16] S. Cavenati, C. A. Grande, and A.E. Rodrigues, J. Chem. Eng. Data (
2004) 49, 1095-1101.
[1] I. Langmuir, J. Am. Chem. Soc. 40 (1918) 1361-1403
[2] R. Sips, J. Chem. Phys. 16 (1948) 490-495.
[3] J. Toth, Acta chim. Acad. Sci. Hung. 69 (1971) 311-328.
[4] R. Sips, J. Chem. Phys. 18 (1950) 1024-1026.
[5] J.M. Honig, L.H. Reyerson, J. Phys. Chem. 56 (1952) 140-144.
[6] M.M. Dubinin, V. A. Astakhov, Russ. Chem. Bull. 20 (1971) 8-12.
[7] V.A. Astakhov, M.M. Dubinin, Russ. Chem. Bull. 20 (1971) 13-16.
[8] M.M. Dubinin, V.A. Astakhov, Adv. Chem. Ser. 102 (1971) 69-85.
[9] R.M. Barrer, D.E.W. Vaughan, J. Phys. Chem. Solids. 32 (1971) 731-
734.
[10] D. M. Ruthven, B.K. Kaul, Lnd, Eng. Chem. Res. 32 (1993) 2047-2052.
[11] C.L. Cavalcante, D.M. Ruthven, Ind. Eng. Chem. Res. 34 (1995) 177-
184.
[12] G.W. Miller, K.S. Knaebel, K.G. Ikels, AIChE J. 33 (1987) 194-201.
[13] A. Khelifa, L. Benchehida, Z. Derriche, J. Colloid Interface Sci. 278
(2004) 9-17.
[14] D.P. Valenzuela, A.L. Mayers, Adsorption Equilibrium Data Handbook,
Prentic¬e Hall, Englewood Cliffs, New Jersey, 1989 (Chapters 1 and 2).
[15] S.G. Chen, R.T. Yang, Langmuir 10 (1994) 4244-4249.
[16] S. Cavenati, C. A. Grande, and A.E. Rodrigues, J. Chem. Eng. Data (
2004) 49, 1095-1101.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:55271", author = "Alireza Behvandi and Somayeh Tourani", title = "Equilibrium Modeling of Carbon Dioxide Adsorption on Zeolites", abstract = "High pressure adsorption of carbon dioxide on zeolite
13X was investigated in the pressure range (0 to 4) Mpa and
temperatures 298, 308 and 323K. The data fitting is accomplished
with the Toth, UNILAN, Dubinin-Astakhov and virial adsorption
models which are generally used for micro porous adsorbents such as
zeolites. Comparison with experimental data from the literature
indicated that the virial model would best determine results. These
results may be partly attributed to the flexibility of the virial model
which can accommodate as many constants as the data warrants.", keywords = "adsorption models, zeolite, carbon dioxide", volume = "5", number = "4", pages = "324-3", }