Abstract: In this investigation Salicylic acid, Sulfosalicylic acid
and Acetyl salicylic acid were chosen as a sample for thin layer
chromatography (TLC) on silica gel plates. Bicarbonate buffer at
different pH containing different amounts of boric acid was applied
as mobile phase. Specific interaction of these substances with boric
acid has effect on Rf in thin layer chromatography. Regular and
similar trend was observed in variations of Rf for mentioned
compounds in TLC by altering of percentages of boric acid in mobile
phase in pH range of 8-10. Also effect of organic solvent, mixture of
water/ organic solvent and organic solvent containing boric acid as
mobile phase was studied.
Abstract: Series of tellurite glass of the system 78TeO2-10PbO-
10Li2O-(2-x)Nd2O3-xEr2O3, where x = 0.5, 1.0, 1.5 and 2.0 was
successfully been made. A study of upconversion luminescence of
the Nd3+/Er3+ co-doped tellurite glass has been carried out. From
Judd-Ofelt analysis, the experimental lifetime, exp. τ of the glass
serie are found higher in the visible region as they varies from
65.17ms to 114.63ms, whereas in the near infrared region (NIR) the
lifetime are varies from 2.133ms to 2.270ms. Meanwhile, the
emission cross section,σ results are found varies from 0.004 x 1020
cm2 to 1.007 x 1020 cm2 with respect to composition. The emission
spectra of the glass are found been contributed from Nd3+ and Er3+
ions by which nine significant transition peaks are observed. The
upconversion mechanism of the co-doped tellurite glass has been
shown in the schematic energy diagrams. In this works, it is found
that the excited state-absorption (ESA) is still dominant in the
upconversion excitation process as the upconversion excitation
mechanism of the Nd3+ excited-state levels is accomplished through a
stepwise multiphonon process. An efficient excitation energy transfer
(ET) has been observed between Nd3+ as a donor and Er3+ as the
acceptor. As a result, respective emission spectra had been observed.
Abstract: A new chelating resin is prepared by coupling Amberlite XAD-4 with 1-amino-2-naphthole through an azo spacer. The resulting sorbent has been characterized by FT-IR, elemental analysis and thermogravimetric analysis (TGA) and studied for preconcentrating of Fe (II) using flame atomic absorption spectrometry (FAAS) for metal monitoring. The optimum pH value for sorption of the iron ions was 6.5. The resin was subjected to evaluation through batch binding of mentioned metal ion. Quantitative desorption occurs instantaneously with 0.5 M HNO3. The sorption capacity was found 4.1 mmol.g-1 of resin for Fe (II) in the aqueous solution. The chelating resin can be reused for 10 cycles of sorption-desorption without any significant change in sorption capacity. A recovery of 97% was obtained the metal ions with 0.5 M HNO3 as eluting agent. The method was applied for metal ions determination from industrial waste water sample.
Abstract: In this study spatial-temporal speckle correlation techniques have been applied for the quality evaluation of three different Indian fruits namely apple, pear and tomato for the first time. The method is based on the analysis of variations of laser light scattered from biological samples. The results showed that crosscorrelation coefficients of biospeckle patterns change subject to their freshness and the storage conditions. The biospeckle activity was determined by means of the cross-correlation functions of the intensity fluctuations. Significant changes in biospeckle activity were observed during their shelf lives. From the study, it is found that the biospeckle activity decreases with the shelf-life storage time. Further it has been shown that biospeckle activity changes according to their respiration rates.
Abstract: Deformable active contours are widely used in
computer vision and image processing applications for image
segmentation, especially in biomedical image analysis. The active
contour or “snake" deforms towards a target object by controlling the
internal, image and constraint forces. However, if the contour
initialized with a lesser number of control points, there is a high
probability of surpassing the sharp corners of the object during
deformation of the contour. In this paper, a new technique is
proposed to construct the initial contour by incorporating prior
knowledge of significant corners of the object detected using the
Harris operator. This new reconstructed contour begins to deform, by
attracting the snake towards the targeted object, without missing the
corners. Experimental results with several synthetic images show the
ability of the new technique to deal with sharp corners with a high
accuracy than traditional methods.