Abstract: An experimental and analytical research on shear
buckling of a comparably large polymer composite I-section is
presented. It is known that shear buckling load of a large span
composite beam is difficult to determine experimentally. In order to
sensitively detect shear buckling of the tested I-section, twenty strain
rosettes and eight displacement sensors were applied and attached on
the web and flange surfaces. The tested specimen was a pultruded
composite beam made of vinylester resin, E-glass, carbon fibers and
micro-fillers. Various coupon tests were performed before the shear
buckling test to obtain fundamental material properties of the Isection.
An asymmetric four-point bending loading scheme was
utilized for the shear test. The loading scheme resulted in a high shear
and almost zero moment condition at the center of the web panel. The
shear buckling load was successfully determined after analyzing the
obtained test data from strain rosettes and displacement sensors. An
analytical approach was also performed to verify the experimental
results and to support the discussed experimental program.
Abstract: Fly ash (FA) thanks to the significant presence of SiO2
and Al2O3 as the main components is a potential raw material for
geopolymers production. Mechanical activation is a method for
improving FA reactivity and also the porosity of final mixture; those
parameters can be analysed through sorption properties. They have
direct impact on the durability of fly ash based geopolymer mortars.
In the paper, effect of FA fineness on sorption properties of
geopolymers based on sodium silicate, as well as relationship
between fly ash fineness and apparent density, compressive and
flexural strength of geopolymers are presented. The best results in the
evaluated area reached the sample H1, which contents the highest
portion of particle under 20μm (100% of GFA). The interdependence
of individual tested properties was confirmed for geopolymer
mixtures corresponding to those in the cement based mixtures: higher
is portion of fine particles < 20μm, higher is strength, density and
lower are sorption properties. The compressive strength as well as
sorption parameters of the geopolymer can be reasonably controlled
by grinding process and also ensured by the higher share of fine
particle (to 20μm) in total mass of the material.
Abstract: An Australian manufacturer has fabricated an
innovative GFRP sandwich panel made from E-glass fiber skin and a
modified phenolic core for structural applications. Debonding, which
refers to separation of skin from the core material in composite
sandwiches, is one of the most common types of damage in
composites. The presence of debonding is of great concern because it
not only severely affects the stiffness but also modifies the dynamic
behaviour of the structure. Generally it is seen that the majority of
research carried out has been concerned about the delamination of
laminated structures whereas skin-core debonding has received
relatively minor attention. Furthermore it is observed that research
done on composite slabs having multiple skin-core debonding is very
limited. To address this gap, a comprehensive research investigating
dynamic behaviour of composite panels with single and multiple
debonding is presented. The study uses finite-element modelling and
analyses for investigating the influence of debonding on free
vibration behaviour of single and multilayer composite sandwich
panels. A broad parametric investigation has been carried out by
varying debonding locations, debonding sizes and support conditions
of the panels in view of both single and multiple debonding.
Numerical models were developed with Strand7 finite element
package by innovatively selecting the suitable elements to diligently
represent their actual behavior. Three-dimensional finite element
models were employed to simulate the physically real situation as
close as possible, with the use of an experimentally and numerically
validated finite element model. Comparative results and conclusions
based on the analyses are presented. For similar extents and locations
of debonding, the effect of debonding on natural frequencies appears
greatly dependent on the end conditions of the panel, giving greater
decrease in natural frequency when the panels are more restrained.
Some modes are more sensitive to debonding and this sensitivity
seems to be related to their vibration mode shapes. The fundamental
mode seems generally the least sensitive mode to debonding with
respect to the variation in free vibration characteristics. The results
indicate the effectiveness of the developed three dimensional finite
element models in assessing debonding damage in composite
sandwich panels.
Abstract: In this study, ultrasonic assisted machining (UAM) technique is applied in side-surface milling experiment for glass-ceramic workpiece material. The tungsten carbide cutting-tool with diamond coating is used in conjunction with two kinds of cooling/lubrication mediums such as water-soluble (WS) cutting fluid and minimum quantity lubricant (MQL). Full factorial process parameter combinations on the milling experiments are planned to investigate the effect of process parameters on cutting performance. From the experimental results, it tries to search for the better process parameter combination which the edge-indentation and the surface roughness are acceptable. In the machining experiments, ultrasonic oscillator was used to excite a cutting-tool along the radial direction producing a very small amplitude of vibration frequency of 20KHz to assist the machining process. After processing, toolmaker microscope was used to detect the side-surface morphology, edge-indentation and cutting tool wear under different combination of cutting parameters, and analysis and discussion were also conducted for experimental results. The results show that the main leading parameters to edge-indentation of glass ceramic are cutting depth and feed rate. In order to reduce edge-indentation, it needs to use lower cutting depth and feed rate. Water-soluble cutting fluid provides a better cooling effect in the primary cutting area; it may effectively reduce the edge-indentation and improve the surface morphology of the glass ceramic. The use of ultrasonic assisted technique can effectively enhance the surface finish cleanness and reduce cutting tool wear and edge-indentation.
Abstract: A chromium-loaded ash originating from incineration of tannery sludge under anoxic conditions was mixed with low grade soda-lime glass powder coming from commercial glass bottles. The relative weight proportions of ash over glass powder tested were 30/70, 40/60 and 50/50. The solid mixtures, formed in green state compacts, were sintered at the temperature range of 800o C up to 1200o C. The resulting products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDXS) and micro-indentation. The above methods were employed to characterize the various phases, microstructure and hardness of the produced materials. Thermal treatment at 800o C and 1000o C produced opaque ceramic products composed of a variety of chromium-containing and chromium-free crystalline phases. Thermal treatment at 1200o C gave rise to composite products, where only chromium-containing crystalline phases were detected. Hardness results suggest that specific products are serious candidates for structural applications.
Abstract: The thermal performance of a solar water heating with
1.00 m2 flat plate collectors in Cascavel - PR, is which presented in
this article, paper presents the solution to leverage the marketing of
solar heating systems through detailed constituent materials of the
solar collector studies, these abundant materials in construction, such
as expanded polyethylene, PVC, aluminum and glass tubes, mixing
them with new materials to minimize loss of efficiency while
decreasing its cost. The system was tested during months and the
collector obtained maximum recorded temperature of outlet fluid of
55°C, while the maximum temperature of the water at the bottom of
the hot water tank was 35°C. The average daily energy collected was
19.6 MJ/d; the energy supplied by the solar plate was 16.2 MJ/d; the
loss in the feed pipe was 3.2 MJ/d; the solar fraction was 32.2%, the
efficiency of the collector was 45.6% and the efficiency of the system
was 37.8%.
Abstract: The material selection in the design of the sandwich
structures is very crucial aspect because of the positive or negative
influences of the base materials to the mechanical properties of the
entire panel. In the literature, it was presented that the selection of the
skin and core materials plays very important role on the behavior of
the sandwich. Beside this, the use of the correct adhesive can make
the whole structure to show better mechanical results and behavior.
In the present work, the static three-point bending tests were
performed on the sandwiches having an aluminum alloy foam core,
the skins made of three different types of fabrics and two different
commercial adhesives (flexible polyurethane and toughened epoxy
based) at different values of support span distances by aiming the
analyses of their flexural performance in terms of absorbed energy,
peak force values and collapse mechanisms. The main results of the
flexural loading are: force-displacement curves obtained after the
bending tests, peak force and absorbed energy values, collapse
mechanisms and adhesion quality. The experimental results presented
that the sandwiches with epoxy based toughened adhesive and the
skins made of S-Glass Woven fabrics indicated the best adhesion
quality and mechanical properties. The sandwiches with toughened
adhesive exhibited higher peak force and energy absorption values
compared to the sandwiches with flexible adhesive. The use of these
sandwich structures can lead to a weight reduction of the transport
vehicles, providing an adequate structural strength under operating
conditions.
Abstract: The textile industry plays a major role in the economy
of India and on the other side of the coin it is the major source for
water pollution. As azo dyes is the largest dye class they are
extensively used in many fields such as textile industry, leather
tanning industry, paper production, food, color photography,
pharmaceuticals and medicine, cosmetic, hair colorings, wood
staining, agricultural, biological and chemical research etc. In
addition to these, they can have acute and/or chronic effects on
organisms depending on their concentration and length of exposure
when they discharged as effluent in the environment. The aim of this
study was to assess the genotoxic and histotoxic potentials of
environmentally relevant concentrations of C. I. Reactive Red 120
(RR 120) on Catla catla, important edible freshwater fingerlings. For
this, healthy Catla catla fingerlings were procured from the
Government Fish Farm and acclimatized in 100 L capacity and
continuously aerated glass aquarium in laboratory for 15 days.
According to APHA some physic-chemical parameters were
measured and maintained such as temperature, pH, dissolve oxygen,
alkalinity, total hardness. Water along with excreta had been changed
every 24 hrs. All fingerlings were fed artificial food palates once a
day @ body weight. After 15 days fingerlings were grouped in 5 (10
in each) and exposed to various concentrations of RR 120 (Control,
10, 20, 30 and 40 mg.l-1) and samples (peripheral blood and gills,
kidney) were collected and analyzed at 96 hrs. All results were
compared with the control. Micronuclei (MN), nuclear buds (NB),
fragmented-apoptotic (FA) and bi-nucleated (BN) cells in blood
smears and in tissues (gills and kidney cells) were observed.
Prominent histopathological alterations were noticed in gills such as
aneurism, hyperplasia, degenerated central axis, lifting of gill
epithelium, curved secondary gill lamellae etc. Similarly kidney
showed some detrimental changes like shrunken glomeruli with
increased periglomerular space, degenerated renal tubules etc. Both
haematological and histopathological changes clearly reveal the toxic
potential of RR 120. This work concludes that water pollution
assessment can be done by these two biomarkers which provide
baseline to the further chromosomal or molecular work.
Abstract: This paper presents effects of distilled water, seawater
and sustained bending strains of 30% and 50% ultimate strain at
room temperature, on the durability of unidirectional pultruded
carbon fiber reinforced polymer (CFRP) plates. In this study,
dynamic mechanical analyzer (DMA) was used to investigate the
synergic effects of the immersions and bending strains on the viscoelastic
properties of (CFRP) such as storage modulus, tan delta and
glass transition temperature. The study reveals that the storage
modulus and glass transition temperature increase while tan delta
peak decreases in the initial stage of both immersions due to the
progression of curing. The storage modulus and Tg subsequently
decrease and tan delta increases due to the matrix plasticization. The
blister induced damages in the unstrained seawater samples enhance
water uptake and cause more serious degradation of Tg and storage
modulus than in water immersion. Increasing sustained bending
decreases Tg and storage modulus in a long run for both immersions
due to resin matrix cracking and debonding. The combined effects of
immersions and strains are not clearly reflected due to the statistical
effects of DMA sample sizes and competing processes of molecular
reorientation and postcuring.
Abstract: In this study, the Compressive strength of concretes
made with Ground Granulated Blast furnace Slag (GGBS),
Pulverised Fuel Ash (PFA), Rice Husk Ash (RHA) and Waste Glass
Powder (WGP) after they were exposed 7800C (exposure duration of
around 60 minutes) and then allowed to cool down gradually in the
furnace for about 280 minutes at water binder ratio of 0.50 was
investigated. GGBS, PFA, RHA and WGP were used to replace up to
20% Portland cement in the control concrete. Test for the
determination of workability, compressive strength and tensile
splitting strength of the concretes were carried out and the results
were compared with control concrete. The test results showed that the
compressive strength decreased by an average of around 30% after
the concretes were exposed to the heating and cooling scenario.
Abstract: The Al-MoO3-P-CdTe-Al MOS sandwich structures
were fabricated by vacuum deposition method on cleaned glass
substrates. Capacitance versus voltage measurements were performed
at different frequencies and sweep rates of applied voltages for oxide
and semiconductor films of different thicknesses. In the negative
voltage region of the C-V curve a high differential capacitance of the
semiconductor was observed and at high frequencies (
Abstract: The main aim of the presented experiments is to
improve behaviour of sandwich structures under dynamic loading,
such as crash or explosion. This paper describes experimental
investigation on the response of new advanced materials to low and
high velocity load. Blast wave energy absorbers were designed using
two types of porous lightweight raw particle materials based on
expanded glass and ceramics with dimensions of 0.5-1 mm,
combined with polymeric binder. The effect of binder amount on the
static and dynamic properties of designed materials was observed.
Prism shaped specimens were prepared and loaded to obtain physicomechanical
parameters – bulk density, compressive and flexural
strength under quasistatic load, the dynamic response was determined
using Split Hopkinson Pressure bar apparatus. Numerical
investigation of the material behaviour in sandwich structure was
performed using implicit/explicit solver LS-Dyna. As the last step,
the developed material was used as the interlayer of blast resistant
litter bin, and it´s functionality was verified by real field blast tests.
Abstract: Thin-walled elements with a matrix set on a base of
high-valuable Portland cement with dispersed reinforcement from
alkali-resistant glass fibres are used in a range of applications as
claddings of buildings and infrastructure constructions as well as
various architectural elements of residential buildings.
Even though their elementary thickness and therefore total weight
is quite low, architects and building companies demand on even
further decreasing of the bulk density of these fibre-cement elements
for the reason of loading elimination of connected superstructures
and easier assembling in demand conditions.
By the means of various kinds of light-weight aggregates it is
possible to achieve light-weighing of these composite elements.
From the range of possible fillers with different material properties
granulated expanded glass worked the best.
By the means of laboratory testing an effect of two fillers based on
expanded glass on the fibre reinforced cement composite was
verified.
Practical applicability was tested in the production of commonly
manufactured glass fibre reinforced concrete elements, such as
channels for electrical cable deposition, products for urban equipment
and especially various cladding elements.
Even though these are not structural elements, it is necessary to
evaluate also strength characteristics and resistance to environment
for their durability in certain applications.
Abstract: The borate glasses are known by their structural
characterized by existence of unit’s structural composed by triangles
and tetrahedrons boron in different configurations depending on the
percentage of B2O3 in the glass chemical composition. In this paper,
effect of lithium oxide addition on the thermal and physical
properties of an alumina borate glass, was investigated. It was found
that the boron abnormality has a significant effect in the change of
glass properties according to the addition rate of lithium oxide.
Abstract: Thin ZnO films are deposited on glass substrates via
sol–gel method and dip-coating. The films are prepared from zinc
acetate dehydrate as a starting reagent. After that the as-prepared
ZnO sol is aged for different periods (0, 1, 3, 5, 10, 15 and 30 days).
Nanocrystalline thin films are deposited from various sols. The
effect ZnO sols aging time on the structural and photocatalytic
properties of the films is studied. The films surface is studied by
Scanning Electron Microscopy. The effect of the aging time of the
starting solution is studied in the photocatalytic degradation of
Reactive Black 5 (RB5) by UV-vis spectroscopy. The experiments
are conducted upon UV-light illumination and in complete darkness.
The variation of the absorption spectra shows the degradation of RB5
dissolved in water, as a result of the reaction, occurring on the surface
of the films and promoted by UV irradiation. The initial
concentrations of dye (5, 10 and 20 ppm) and the effect of the aging
time are varied during the experiments. The results show, that the
increasing aging time of starting solution with respect to ZnO
generally promotes photocatalytic activity. The thin films obtained
from ZnO sol, which is aged 30 days have best photocatalytic
degradation of the dye (97,22%) in comparison with the freshly
prepared ones (65,92%). The samples and photocatalytic
experimental results are reproducible. Nevertheless, all films exhibit
a substantial activity in both UV light and darkness, which is
promising for the development of new ZnO photocatalysts by sol-gel
method.
Abstract: In this paper, the electromagnetic shielding
characteristics of an up-to-date typical carbon filler material, carbon
fiber used with a metal mesh were investigated. Carbon fiber
12k-prepregs, where carbon fibers were impregnated with epoxy, were
laminated with wire meshes, vacuum bag-molded and hardened to
manufacture hybrid-type specimens, with which an electromagnetic
shield test was performed in accordance with ASTM D4935-10,
through which was known as the most excellent reproducibility is
obtainable among electromagnetic shield tests. In addition, glass fiber
prepregs whose electromagnetic shielding effect were known as
insignificant were laminated and formed with wire meshes to verify
the validity of the electromagnetic shield effect of wire meshes in
order to confirm the electromagnetic shielding effect of metal meshes
corresponding existing carbon fiber 12k-prepregs. By grafting carbon
fibers, on which studies are being actively underway in the
environmental aspects and electromagnetic shielding effect, with
hybrid-type wire meshes that were analysed through the tests, in this
study, the applicability and possibility are proposed.
Abstract: Composite materials, due to their unique properties
such as high strength to weight ratio, corrosion resistance, and impact
resistance have huge potential as structural materials in automotive,
construction and transportation applications. However, these
properties often come at higher cost owing to complex design
methods, difficult manufacturing processes and raw material cost.
Traditionally, tapered laminated composite structures are
manufactured using autoclave manufacturing process by ply drop off
technique. Autoclave manufacturing though very powerful suffers
from high capital investment and higher energy consumption. As per
the current trends in composite manufacturing, Out of Autoclave
(OoA) processes are looked as emerging technologies for
manufacturing the structural composite components for aerospace
and defense applications. However, there is a need for improvement
among these processes to make them reliable and consistent. In this
paper, feasibility of using out of autoclave process to manufacture the
variable thickness cantilever beam is discussed. The minimum weight
design for the composite beam is obtained using constant stress beam
concept by tailoring the thickness of the beam. Ply drop off
techniques was used to fabricate the variable thickness beam from
glass/epoxy prepregs. Experiments were conducted to measure
bending stresses along the span of the cantilever beam at different
intervals by applying the concentrated load at the free end.
Experimental results showed that the stresses in the bean at different
intervals were constant. This proves the ability of OoA process to
manufacture the constant stress beam. Finite element model for the
constant stress beam was developed using commercial finite element
simulation software. It was observed that the simulation results
agreed very well with the experimental results and thus validated
design and manufacturing approach used.
Abstract: The design, manufacture, and operation of thin-walled
pressure vessels must be based on maximum safe operating pressure
and an adequate factor of safety (FoS). This research paper first
reports experimental evaluation of longitudinal and hoops stresses
based on working pressure as well as maximum pressure; and then
includes a critical study of factor of safety (FoS) in the design of a
glass fiber pressure vessel. Experimental work involved the use of
measuring instruments and the readings from pressure gauges.
Design calculations involved the computations of design stress and
FoS; the latter was based on breaking strength of 55 MPa for the
glass fiber (pressure-vessel material). The experimentally determined
FoS value has been critically compared with the general FoS allowed
in the design of glass fiber pressure vessels.
Abstract: In this paper, extract of papaya leaves are used as a
natural dye and combined by variations of solvent concentration
applied on DSSC (Dye-Sensitized Solar Cell). Indonesian geographic
located on the equator line occasions the magnitude of the potential
to develop organic solar cells made from extracts of chlorophyll as a
substitute for inorganic materials or synthetic dye on DSSC material.
Dye serves as absorbing photons which are then converted into
electrical energy. A conductive coated glass layer called TCO
(Transparent Conductive Oxide) is used as a substrate of electrode.
TiO2 nanoparticles as binding dye molecules, redox couple iodide/
tri-iodide as the electrolyte and carbon as the counter electrode in the
DSSC are used. TiO2 nanoparticles, organic dyes, electrolytes, and
counter electrode are arranged and combined with the layered
structure of the photo-catalyst absorption layer. Dye absorption
measurements using a spectrophotometer at 400-800 nm light
spectrum produces a total amount of chlorophyll 80.076 mg/l. The
test cell at 7 watt LED light with 5000 lux luminescence was
obtained Voc and Isc of 235.5 mV and 14 μA, respectively.
Abstract: TiO2 thin films have been prepared by the sol-gel dipcoating
technique in order to elaborate antireflective thin films for
monocrystalline silicon (mono-Si). The titanium isopropoxyde was
chosen as a precursor with hydrochloric acid as a catalyser for
preparing a stable solution. The optical properties have been tailored
with varying the solution concentration, the withdrawn speed, and the
heat-treatment. We showed that using a TiO2 single layer with 64.5
nm in thickness, heat-treated at 450°C or 300°C reduces the mono-Si
reflection at a level lower than 3% over the broadband spectral
domains [669-834] nm and [786-1006] nm respectively. Those latter
performances are similar to the ones obtained with double layers of
low and high refractive index glasses respectively.