Abstract: During the last few years, several sheet hydroforming
processes have been introduced. Despite the advantages of these
methods, they have some limitations. Of the processes, the two main
ones are the standard hydroforming and hydromechanical deep
drawing. A new sheet hydroforming die set was proposed that has the
advantages of both processes and eliminates their limitations. In this
method, a polyurethane plate was used as a part of the die-set to
control the blank holder force. This paper outlines the Taguchi
optimization methodology, which is applied to optimize the effective
parameters in forming cylindrical cups by the new die set of sheet
hydroforming process. The process parameters evaluated in this
research are polyurethane hardness, polyurethane thickness, forming
pressure path and polyurethane hole diameter. The design of
experiments based upon L9 orthogonal arrays by Taguchi was used
and analysis of variance (ANOVA) was employed to analyze the
effect of these parameters on the forming pressure. The analysis of
the results showed that the optimal combination for low forming
pressure is harder polyurethane, bigger diameter of polyurethane hole
and thinner polyurethane. Finally, the confirmation test was derived
based on the optimal combination of parameters and it was shown
that the Taguchi method is suitable to examine the optimization
process.
Abstract: The production and consumption of natural gas is on
the rise throughout the world as a result of its wide availability, ease
of transportation, use and clean-burning characteristics. The chief use
of ethane is in the chemical industry in the production of Ethene
(ethylene) by steam cracking. In this simulation, obtained ethane
recovery percent based on Gas sub-cooled process (GSP) is 99.9 by
mole that is included 32.1% by using de-methanizer column and
67.8% by de-ethanizer tower. The outstanding feature of this process
is the novel split-vapor concept that employs to generate reflux for
de-methanizer column. Remain amount of ethane in export gas cause
rise in gross heating value up to 36.66 MJ/Nm3 in order to use in
industrial and household consumptions.
Abstract: Anaerobic digestion process is one of the alternative
methods to convert organic waste into methane gas which is a fuel
and energy source. Activities of various kinds of microorganisms are
the main factor for anaerobic digestion which produces methane gas.
Therefore, in this study a modified Anaerobic Baffled Reactor (ABR)
with working volume of 50 liters was designed to identify the
microorganisms through biogas production. The mixture of 75%
kitchen waste and 25% sewage sludge was used as substrate.
Observations on microorganisms in the ABR showed that there exists
a small amount of protozoa (5%) and fungi (2%) in the system, but
almost 93% of the microorganism population consists of bacteria. It
is definitely clear that bacteria are responsible for anaerobic
biodegradation of kitchen waste. Results show that in the
acidification zone of the ABR (front compartments of reactor) fast
growing bacteria capable of growth at high substrate levels and
reduced pH was dominant. A shift to slower growing scavenging
bacteria that grow better at higher pH was occurring towards the end
of the reactor. Due to the ability of activity in acetate environment the
percentages of Methanococcus, Methanosarcina and Methanotrix
were higher than other kinds of methane former in the system.
Abstract: Production of biogas from bakery waste was enhanced
by additional bacterial cell. This study was divided into 2 steps. First
step, grease waste from bakery industry-s grease trap was initially
degraded by Pseudomonas aeruginosa. The concentration of byproduct,
especially glycerol, was determined and found that glycerol
concentration increased from 12.83% to 48.10%. Secondary step, 3
biodigesters were set up in 3 different substrates: non-degraded waste
as substrate in first biodigester, degraded waste as substrate in
secondary biodigester, and degraded waste mixed with swine manure
in ratio 1:1 as substrate in third biodigester. The highest
concentration of biogas was found in third biodigester that was
44.33% of methane and 63.71% of carbon dioxide. The lower
concentration at 24.90% of methane and 18.98% of carbon dioxide
was exhibited in secondary biodigester whereas the lowest was found
in non-degraded waste biodigester. It was demonstrated that the
biogas production was greatly increased with the initial grease waste
degradation by Pseudomonas aeruginosa.
Abstract: Fecal sterol has been proposed as a chemical indicator
of human fecal pollution even when fecal coliform populations have
diminished due to water chlorination or toxic effects of industrial
effluents. This paper describes an improved derivatization procedure
for simultaneous determination of four fecal sterols including
coprostanol, epicholestanol, cholesterol and cholestanol using gas
chromatography-mass spectrometry (GC-MS), via optimization study
on silylation procedures using N-O-bis
(trimethylsilyl)-trifluoroacetamide (BSTFA), and
N-(tert-butyldimethylsilyl)-N-methyltrifluoroacetamide
(MTBSTFA), which lead to the formation of trimethylsilyl (TMS) and
tert-butyldimethylsilyl (TBS) derivatives, respectively. Two
derivatization processes of injection-port derivatization and water bath
derivatization (60 oC, 1h) were inspected and compared. Furthermore,
the methylation procedure at 25 oC for 2h with
trimethylsilydiazomethane (TMSD) for fecal sterols analysis was also
studied. It was found that most of TMS derivatives demonstrated the
highest sensitivities, followed by methylated derivatives. For BSTFA
or MTBSTFA derivatization processes, the simple injection-port
derivatization process could achieve the same efficiency as that in the
tedious water bath derivatization procedure.
Abstract: Soy polyol obtained from hydroxylation of soy
epoxide with ethylene glycol were prepared as pre-polyurethane. The
two step process method were applied in the polyurethane synthesis.
The blending of soy polyol with synthetic polyol then simultaneously
carried out to TDI (2,4): MDI (4,4-) (80:20), blowing agent, and
surfactant. Ethylene glycol were not taking part in the polyurethane
synthesis. The inclusion of ethylene glycol were used as a control.
Characterization of polyurethane foam through impact resillience,
indentation deflection, and density can visualize the polyurethane
classifications.
Abstract: This paper describes analysis of low velocity transverse impact on fully backed sandwich beams with composite faces from Eglass/epoxy and cores from Polyurethane or PVC. Indentation on sandwich beams has been analyzed with the existing theories and modeled with the FE code ABAQUS, also loadings have been done experimentally to verify theoretical results. Impact on fully backed has been modeled in two cases of impactor energy with SDOF model (single-degree-of-freedom) and indentation stiffness: lower energy for elastic indentation of sandwich beams and higher energy for plastic area in indentation. Impacts have been modeled by ABAQUS. Impact results can describe response of beam in terms of core and faces thicknesses, core material, indentor energy and energy absorbed. The foam core is modeled using the crushable foam material model and response of the foam core is experimentally characterized in uniaxial compression with higher velocity loading to define quasi impact behaviour.
Abstract: Transpedicular screw fixation in spinal fractures,
degenerative changes, or deformities is a well-established procedure.
However, important rate of fixation failure due to screw bending,
loosening, or pullout are still reported particularly in weak bone stock
in osteoporosis. To overcome the problem, mechanism of failure has
to be fully investigated in vitro. Post-mortem human subjects are less
accessible and animal cadavers comprise limitations due to different
geometry and mechanical properties. Therefore, the development of a
synthetic model mimicking the realistic human vertebra is highly
demanded. A bone surrogate, composed of Polyurethane (PU) foam
analogous to cancellous bone porous structure, was tested for 3
different densities in this study. The mechanical properties were
investigated under uniaxial compression test by minimizing the end
artifacts on specimens. The results indicated that PU foam of 0.32
g.cm-3 density has comparable mechanical properties to human
cancellous bone in terms of young-s modulus and yield strength.
Therefore, the obtained information can be considered as primary
step for developing a realistic cancellous bone of human vertebral
body. Further evaluations are also recommended for other density
groups.
Abstract: The present investigation was undertaken to explore the biogas potentiality of Jatropha (Jatropha curcas, Euphorbiaceae) Fruit Coat (JFC) alone and in combination with cattle dung (CD) in various proportions at 15 per cent total solids by batch phase anaerobic digestion for a period of ten weeks HRT (Hydraulic Retention Time) under a temperature of 35°C+1°C. The maximum biogas production was noticed in Cattle dung and Jatropha Fruit Coat in 2:1 ratio with 403.84 L/kg dry matter followed by 3:1,1:2, 1:1 and 1:3 having 329.66, 219.77, 217.79, 203.64 L /kg dm respectively as compared to 178.49 L/kg dm in CD alone. The JFC alone found to produce 91 per cent of total biogas that obtained from Cattle dung. The per cent methane content of the biogas in all the treatments was found on par with Cattle dung.
Abstract: Trihalogenmethanes are the most significant byproducts of the reaction of disinfection agent with organic precursors naturally present in ground and surface waters.Their incidence negatively affects the quality of drinking water in relation to their nephrotoxic, hepatotoxic and genotoxic effects on human health. Taking into consideration the considerable volatility of monitored contaminants it could be assumed that their incidence in drinking water would depend on the distance of sampling from the area of disinfection. Based on the concentration of trihalogenmethanes determined with the help of gas chromatography with mass detector and the analysis of variance (ANOVA) such dependence has been proved as statistically significant. The acquired outcomes will be used for assessing the non-carcinogenic and genotoxic risks to consumers.
Abstract: Polyurethane foams (PUF) has been prepared from
vegetable; soybean based polyols. They were characterized into
flexible and semi rigid polyurethane foam. This work is directed to
production of flexible polyurethane foams by a process involving the
reaction of mixture of 2,4- and 2,6-Toluene di Isocyanate isomers,
with portion of to blends of soy polyols with petroleum polyol in the
presence of other ingredients such as blowing agents, silicone
surfactants and accelerating agents. Additon of chain extender
improves the property then further decreases the properties on further
addition of the same. The objective of this work was to study the
effect of chain extender and role of phosphoric acid catalyst to the
final properties and correlate the morphology image with mechanical
properties of these foams.
Abstract: High purity hydrogen and the valuable by-product of carbon nanotubes (CNTs) can be produced by the methane catalytic decomposition. The methane conversion and the performance of CNTs were determined by the choices of catalysts and the condition of decomposition reaction. In this paper, Ni/MgO and Ni/O-D (oxidized diamond) catalysts were prepared by wetness impregnation method. The effects of reaction temperature and space velocity of methane on the methane conversion were investigated in a fixed-bed. The surface area, structure and micrography were characterized with BET, XPS, SEM, EDS technology. The results showed that the conversion of methane was above 8% within 150 min (T=500) for 33Ni/O-D catalyst and higher than 25% within 120 min (T=650) for 41Ni/MgO catalyst. The initial conversion increased with the increasing temperature of the decomposition reaction, but their catalytic activities decreased rapidly while at too higher temperature. To decrease the space velocity of methane was propitious to promote the methane conversion, but not favor of the hydrogen yields. The appearance of carbon resulted from the methane decomposition lied on the support type and the condition of catalytic reaction. It presented as fiber shape on the surface of Ni/O-D at the relatively lower temperature such as 500 and 550, but as grain shape stacked on and overlayed on the surface of the metal nickel while at 650. The carbon fiber can form on the Ni/MgO surface at 650 and the diameter of the carbon fiber increased with the decreasing space velocity.
Abstract: A research study was conducted with an objective to propose a collaborative business strategy of a oil and gas trading company, representing PPT Energy Trading Co., Ltd., with its shareholder, especially electricity and power supply companies for LNG Form of Coal Bed Methane in B2B Transaction. Collaborative business strategy is a strategy to collaborate with other organizations due to have future benefits in both parties, or achieve the business objective through the collaboration of business, its strategy and partners. A structured interview was established to collect the required primary data from the company. Not only interview, but also company’s business plan and annual report were collected and analyzed for the company’s current condition. As the result, this research shows a recommendation to propose a new collaborative strategy with limiting its target market, diversifying product, conducting new business model, and considering other stakeholders.
Abstract: In this study, we illustrated the performance and
microbial community of single- and two-phase systems anaerobically
co-digesting cassava pulp and pig manure. The results showed that
the volatile solid reduction and biogas productivity of two-phase
CSTR were 66 ± 4% and 2000 ± 210 ml l-1 d-1, while those of singlephase
CSTR were 59 ± 1% and 1670 ± 60 ml l-1 d-1, respectively. Codigestion
in two-phase CSTR gave higher 12% solid degradation and
25% methane production than single-phase CSTR. Phylogenetic
analysis of 16S rDNA clone library revealed that the Bacteroidetes
were the most abundant group, followed by the Clostridia in singlephase
CSTR. In hydrolysis/acidification reactor of two-phase system,
the bacteria within the phylum Firmicutes, especially Clostridium,
Eubacteriaceae and Lactobacillus were the dominant phylogenetic
groups. Among the Archaea, Methanosaeta sp. was the exclusive
predominant in both digesters while the relative abundance of
Methanosaeta sp. and Methanospirillum hungatei differed between
the two systems.
Abstract: Landfill gas, particularly methane is one of the
greenhouse gases which contributes to global warming. This paper presents the findings of a study on methane gas production from
simulated landfill reactor under saturated conditions. A reactor was constructed to represent a landfill cell of 2.5 m thickness on sandy
soil. The reactor was 0.2 m in diameter and 4 m in height. One meter of sand and pebble layer was packed at the bottom of the reactor
followed by 2.5 m of solid waste layer and 0.4 m of sand layer as the cover soil. Degradation of waste in the solid waste layer was at
acidification stage as indicated by the leachate quality with COD as
high as 55,511 mg/L and pH as low as 5.1. However, methanogenic
environment was established at the bottom sand layer after one year of operation indicated by pH of 7.2 and methane gas generation.
Leachate degradation took place as the leachate moved through the
sand layer at an infiltration of rate 0.7 cm/day. This resulted in landfill gas production of 77 mL/day/kg containing 55 to 65% methane. The application of sand layer contributed to the gas
production from landfill by an in-situ degradation of leachate in the
sand at the bottom of the landfill.
Abstract: Two-interconnected fluidized bed systems are widely used in various processes such as Fisher-Tropsch, hot gas desulfurization, CO2 capture-regeneration with dry sorbent, chemical-looping combustion, sorption enhanced steam methane reforming, chemical-looping hydrogen generation system, and so on. However, most of two-interconnected fluidized beds systems require riser and/or pneumatic transport line for solid conveying and loopseals or seal-pots for gas sealing, recirculation of solids to the riser, and maintaining of pressure balance. The riser (transport bed) is operated at the high velocity fluidization condition and residence times of gas and solid in the riser are very short. If the reaction rate of catalyst or sorbent is slow, the riser can not ensure sufficient contact time between gas and solid and we have to use two bubbling beds for each reaction to ensure sufficient contact time. In this case, additional riser must be installed for solid circulation. Consequently, conventional two-interconnected fluidized bed systems are very complex, large, and difficult to operate. To solve these problems, a novel two-interconnected fluidized bed system has been developed. This system has two bubbling beds, solid injection nozzles, solid conveying lines, and downcomers. In this study, effects of operating variables on solid circulation rate, gas leakage between two beds have been investigated in a cold mode two-interconnected fluidized bed system. Moreover, long-term operation of continuous solid circulation up to 60 hours has been performed to check feasibility of stable operation.
Abstract: This work presents the experimental results obtained
at a pilot plant which works with a slow, wet and catalytic pyrolysis
process of dry fowl manure. This kind of process mainly consists in
the cracking of the organic matrix and in the following reaction of
carbon with water, which is either already contained in the organic
feed or added, to produce carbon monoxide and hydrogen. Reactions
are conducted in a rotating reactor maintained at a temperature of
500°C; the required amount of water is about 30% of the dry organic
feed. This operation yields a gas containing about 59% (on a volume
basis) of hydrogen, 17% of carbon monoxide and other products such
as light hydrocarbons (methane, ethane, propane) and carbon
monoxide in lesser amounts. The gas coming from the reactor can be
used to produce not only electricity, through internal combustion
engines, but also heat, through direct combustion in industrial
boilers. Furthermore, as the produced gas is devoid of both solid
particles and pollutant species (such as dioxins and furans), the
process (in this case applied to fowl manure) can be considered as an
optimal way for the disposal and the contemporary energetic
valorization of organic materials, in such a way that is not damaging
to the environment.
Abstract: Natural organic matter (NOM) is heterogeneous
mixture of organic compounds that enter the water media from
animal and plant remains, domestic and industrial wastes.
Researches showed that NOM is likely precursor material for
disinfection by products (DBPs). Chlorine very commenly used for
disinfection purposes and NOM and chlorine reacts then
Trihalomethane (THM) and Haloacetic acids (HAAs) which are
cancerogenics for human health are produced. The aim of the study is
to search NOM removal by enhanced coagulation from drinking
water source of Eskisehir which is supplied from Porsuk Dam.
Recently, Porsuk dam water is getting highly polluted and therefore
NOM concentration is increasing. Enhanced coagulation studies were
evaluated by measurement of Dissolved Organic Carbon (DOC), UV
absorbance at 254 nm (UV254), and different trihalomethane
formation potential (THMFP) tests. Results of jar test experiments
showed that NOM can be removed from water about 40-50 % of
efficiency by enhanced coagulation. Optimum coagulant type and
coagulant dosages were determined using FeCl3 and Alum.
Abstract: The upgrading of low quality crude natural gas (NG) is attracting interest due to high demand of pipeline-grade gas in recent years. Membrane processes are commercially proven technology for the removal of impurities like carbon dioxide from NG. In this work, cross flow mathematical model has been suggested to be incorporated with ASPEN HYSYS as a user defined unit operation in order to design the membrane system for CO2/CH4 separation. The effect of operating conditions (such as feed composition and pressure) and membrane selectivity on the design parameters (methane recovery and total membrane area required for the separation) has been studied for different design configurations. These configurations include single stage (with and without recycle) and double stage membrane systems (with and without permeate or retentate recycle). It is shown that methane recovery can be improved by recycling permeate or retentate stream as well as by using double stage membrane systems. The ASPEN HYSYS user defined unit operation proposed in the study has potential to be applied for complex membrane system design and optimization.
Abstract: This study investigates CO2 mitigation by methanol
synthesis from flue gas CO2 and H2 generation through water
electrolysis. Electrolytic hydrogen generation is viable provided that
the required electrical power is supplied from renewable energy
resources; whereby power generation from renewable resources is yet
commercial challenging. This approach contribute to zero-emission,
moreover it produce oxygen which could be used as feedstock for
chemical process. At ZPC, however, oxygen would be utilized
through partial oxidation of methane in autothermal reactor (ATR);
this makes ease the difficulties of O2 delivery and marketing. On the
other hand, onboard hydrogen storage and consumption; in methanol
plant; make the project economically more competitive.