Abstract: Based on activity method, this paper focuses on morning commuting behavior when commuters travel with autonomous vehicles (AVs). Firstly, a net utility function of commuters is constructed by the activity utility of commuters at home, in car and at workplace, and the disutility of travel time cost and that of schedule delay cost. Then, this net utility function is applied to build an equilibrium model. Finally, under the assumption of constant marginal activity utility, the properties of equilibrium are analyzed. The results show that, in autonomous driving, the starting and ending time of morning peak and the number of commuters who arrive early and late at workplace are the same as those in manual driving. In automatic driving, however, the departure rate of arriving early at workplace is higher than that of manual driving, while the departure rate of arriving late is just the opposite. In addition, compared with manual driving, the departure time of arriving at workplace on time is earlier and the number of people queuing at the bottleneck is larger in automatic driving. However, the net utility of commuters and the total net utility of system in automatic driving are greater than those in manual driving.
Abstract: In this study, the calculations of proton emission spectra produced by 63Cu(n,xp) and 65Cu(n,xp) reactions are used in the framework of preequilibrium models using the EMPIRE code and TALYS code. Exciton Model predidtions combined with the Kalbach angular distribution systematics and the Hybrid Monte Carlo Simulation (HMS) were used. The effects of levels densities and those of a-parameter have been investigated for our calculations. The comparison with experimental data shows clear improvement over the Exciton Model and HMS calculations.
Abstract: This study investigated the biosorption of the azo dye reactive Black B (RBB) from aqueous solution using the nonviable biomass of Cladosporium cladosporioides LM1. The biosorption systems were carried out in batch mode considering different conditions of initial pH, contact time, temperature, initial dye concentration and biosorbent dosage. Higher removal rate of RBB was obtained at pH 2. Biosorption data were successfully described by pseudo-second-order kinetic model and Langmuir isotherm model with the maximum monolayer biosorption capacity estimated at 71.43 mg/g. The values of thermodynamic parameters such as ∆G°, ∆H° and ∆S° indicated that the biosorption of RBB onto fungal biomass was spontaneous and exothermic in nature. It can be concluded that nonviable biomass of Cladosporium cladosporioides LM1 may be an attractive low-cost biosorbent for the removal of azo dye RBB from aqueous solution.
Abstract: Current literature about trade liberalization of
environmental goods and services (EGS) raises doubts about the
extent of the triple win-win situation for trade, development and the
environment. However, much of this literature does not consider the
possibility that this agreement carries technological transmissions,
either through trade or foreign direct investment. This paper presents
a computable general equilibrium model calibrated for Argentina,
where there are alternative technologies (one dirty and one clean
according to carbon emissions) to produce the same goods. In this
context, the trade liberalization of EGS allows to increase GDP,
trade, reduce unemployment and improve the households welfare.
However, the capital mobility appears as the key assumption to
jointly reach the environmental target, when the positive scale effect
generated by the increase in trade is offset by the change in the
composition of production (composition and technical effects by
the use of the clean alternative technology) and of consumption
(composition effect by substitution of relatively lesspolluting
imported goods).
Abstract: This work consists of a numerical simulation of
convective heat transfer in a vertical plane channel filled with a heat
generating porous medium, in the absence of local thermal
equilibrium. The walls are maintained to a constant temperature and
the inlet velocity is uniform. The dynamic range is described by the
Darcy-Brinkman model and the thermal field by two energy
equations model. A dimensionless formulation is developed for
performing a parametric study based on certain dimensionless groups
such as, the Biot interstitial number, the thermal conductivity ratio
and the volumetric heat generation, q '''. The governing equations are
solved using the finite volume method, gave rise to a multitude of
results concerning in particular the thermal field in the porous
channel and the existence or not of the local thermal equilibrium.
Abstract: In the present study, two distinctly different approaches are followed for modeling of reactive distillation column, the equilibrium stage model and the nonequilibrium stage model. These models are simulated with a computer code developed in the present
study using MATLAB programming. In the equilibrium stage models, the vapor and liquid phases are assumed to be in equilibrium and allowance is made for finite reaction rates, where as in the nonequilibrium stage models simultaneous mass transfer and reaction rates are considered. These simulated model results are validated from the experimental data reported in the literature. The simulated results of equilibrium and nonequilibrium models are compared for concentration, temperature and reaction rate profiles in a reactive distillation column for Methyl Tert Butyle Ether (MTBE) production. Both the models show similar trend for the concentration, temperature and reaction rate profiles but the nonequilibrium model predictions are higher and closer to the experimental values reported in the literature.
Abstract: Non-premixed turbulent combustion Computational Fluid Dynamics (CFD) has been carried out in a simplified methanefuelled coaxial jet combustor employing Large Eddy Simulation (LES). The objective of this study is to evaluate the performance of LES in modelling non-premixed combustion using a commercial software, FLUENT, and investigate the effects of the grid density and chemistry models employed on the accuracy of the simulation results. A comparison has also been made between LES and Reynolds Averaged Navier-Stokes (RANS) predictions. For LES grid sensitivity test, 2.3 and 6.2 million cell grids are employed with the equilibrium model. The chemistry model sensitivity analysis is achieved by comparing the simulation results from the equilibrium chemistry and steady flamelet models. The predictions of the mixture fraction, axial velocity, species mass fraction and temperature by LES are in good agreement with the experimental data. The LES results are similar for the two chemistry models but influenced considerably by the grid resolution in the inner flame and near-wall regions.
Abstract: Unsteady natural convection and heat transfer in a square cavity partially filled with porous media using a thermal
non-equilibrium model is studied in this paper. The left vertical wall is
maintained at a constant hot temperature Th and the right vertical wall
is maintained at a constant cold temperature Tc, while the horizontal
walls are adiabatic. The governing equations are obtained by applying
the Darcy model and Boussinesq approximation. COMSOL’s finite
element method is used to solve the non-dimensional governing
equations together with specified boundary conditions. The governing
parameters of this study are the Rayleigh number (Ra = 10^5, and Ra = 10^6 ), Darcy namber (Da = 10^−2, and Da = 10^−3),
the modified thermal conductivity ratio (10^−1 ≤ γ ≤ 10^4), the inter-phase heat transfer coefficien (10^−1 ≤ H ≤ 10^3) and the
time dependent (0.001 ≤ τ ≤ 0.2). The results presented for
values of the governing parameters in terms of streamlines in both
fluid/porous-layer, isotherms of fluid in fluid/porous-layer, isotherms
of solid in porous layer, and average Nusselt number.
Abstract: This article presents a numerical study of the doublediffusive
mixed convection in a vertical channel filled with porous
medium by using non-equilibrium model. The flow is assumed
fully developed, uni-directional and steady state. The controlling
parameters are thermal Rayleigh number (RaT ), Darcy number (Da),
Forchheimer number (F), buoyancy ratio (N), inter phase heat transfer
coefficient (H), and porosity scaled thermal conductivity ratio
(γ). The Brinkman-extended non-Darcy model is considered. The
governing equations are solved by spectral collocation method. The
main emphasize is given on flow profiles as well as heat and solute
transfer rates, when two diffusive components in terms of buoyancy
ratio are in favor (against) of each other and solid matrix and fluid
are thermally non-equilibrium. The results show that, for aiding flow
(RaT = 1000), the heat transfer rate of fluid (Nuf ) increases upto a
certain value of H, beyond that decreases smoothly and converges
to a constant, whereas in case of opposing flow (RaT = -1000),
the result is same for N = 0 and 1. The variation of Nuf in (N,
Nuf )-plane shows sinusoidal pattern for RaT = -1000. For both cases
(aiding and opposing) the flow destabilize on increasing N by inviting
point of inflection or flow separation on the velocity profile. Overall,
the buoyancy force have significant impact on the non-Darcy mixed
convection under LTNE conditions.
Abstract: High pressure adsorption of carbon dioxide on zeolite
13X was investigated in the pressure range (0 to 4) Mpa and
temperatures 298, 308 and 323K. The data fitting is accomplished
with the Toth, UNILAN, Dubinin-Astakhov and virial adsorption
models which are generally used for micro porous adsorbents such as
zeolites. Comparison with experimental data from the literature
indicated that the virial model would best determine results. These
results may be partly attributed to the flexibility of the virial model
which can accommodate as many constants as the data warrants.
Abstract: Optimization plays an important role in most real
world applications that support decision makers to take the right
decision regarding the strategic directions and operations of the
system they manage. Solutions for traffic management and traffic
congestion problems are considered major problems that most
decision making authorities for cities around the world are looking
for. This review paper gives a full description of the traffic problem
as part of the transportation planning process and present a view as a
framework of urban transportation system analysis where the core of
the system is a transportation network equilibrium model that is
based on optimization techniques and that can also be used for
evaluating an alternative solution or a combination of alternative
solutions for the traffic congestion. Different transportation network
equilibrium models are reviewed from the sequential approach to the
multiclass combining trip generation, trip distribution, modal split,
trip assignment and departure time model. A GIS-Based intelligent
decision support system framework for urban transportation system
analysis is suggested for implementation where the selection of
optimized alternative solutions, single or packages, will be based on
an intelligent agent rather than human being which would lead to
reduction in time, cost and the elimination of the difficulty, by
human being, for finding the best solution to the traffic congestion
problem.
Abstract: This paper proposes a simple model of economic geography within the Dixit-Stiglitz-Iceberg framework that may be used to analyze migration patterns among three cities. The cost–benefit tradeoffs affecting incentives for three types of migration, including echelon migration, are discussed. This paper develops a tractable, heterogeneous-agent, general equilibrium model, where agents share constant human capital, and explores the relationship between the benefits of echelon migration and gross human capital. Using Chinese numerical solutions, we study the manifestation of echelon migration and how it responds to changes in transportation cost and elasticity of substitution. Numerical results demonstrate that (i) there are positive relationships between a migration-s benefit-and-wage ratio, (ii) there are positive relationships between gross human capital ratios and wage ratios as to origin and destination, and (iii) we identify 13 varieties of human capital convergence among cities. In particular, this model predicts population shock resulting from the processes of migration choice and echelon migration.
Abstract: The purpose of this research is to establish the experimental conditions for removal of Cibacron Brilliant Yellow 3G-P dye (CBY) from aqueous solutions by sorption onto coffee husks as a low-cost sorbent. The effects of various experimental parameters (e.g. initial CBY dye concentration, sorbent mass, pH, temperature) were examined and the optimal experimental conditions were determined. The results indicated that the removal of the dye was pH dependent and at initial pH of 2, the dye was removed effectively. The CBY dye sorption data were fitted to Langmuir, Freundlich, Temkin and Dubinin-Radushkevich equilibrium models. The maximum sorption capacity of CBY dye ions onto coffee husks increased from 24.04 to 35.04 mg g-1 when the temperature was increased from 293 to 313 K. The calculated sorption thermodynamic parameters including ΔG°, ΔH°, and ΔS° indicated that the CBY dye sorption onto coffee husks is a spontaneous, endothermic and mainly physical in nature.
Abstract: Equilibrium and rate based models have been applied
in the simulation of methyl tertiary-butyl ether (MTBE) synthesis
through reactive distillation. Temperature and composition profiles
were compared for both the models and found that both the profiles
trends, though qualitatively similar are significantly different
quantitatively. In the rate based method (RBM), multicomponent
mass transfer coefficients have been incorporated to describe
interphase mass transfer. MTBE mole fraction in the bottom stream is
found to be 0.9914 in the Equilibrium Model (EQM) and only 0.9904
for RBM when the same column configuration was preserved. The
individual tray efficiencies were incorporated in the EQM and
simulations were carried out. Dynamic simulation have been also
carried out for the two column configurations and compared.
Abstract: This study deals with evaluation of influence of salinity (NaCl) onto equilibrium of Cu and Ni removal from aqueous solutions by natural sorbent – zeolite. Equilibrium data were obtained by batch experiments. The salinity of the aqueous solution was influenced by dissolving NaCl in distilled water. It was studied in the range of NaCl concentrations from 1 g.l-1 to 100g.l-1. For Cu sorption there is a significant influence of salinity. The maximum capacity of zeolite for Cu was decreasing with growing concentration of NaCl. For Ni sorption there is not so significant influence of salinity as for Cu. The maximum capacity of zeolite for Ni was slightly decreasing with growing concentration of NaCl.