Removal of Cibacron Brilliant Yellow 3G-P Dye from Aqueous Solutions Using Coffee Husks as Non-Conventional Low-Cost Sorbent

The purpose of this research is to establish the experimental conditions for removal of Cibacron Brilliant Yellow 3G-P dye (CBY) from aqueous solutions by sorption onto coffee husks as a low-cost sorbent. The effects of various experimental parameters (e.g. initial CBY dye concentration, sorbent mass, pH, temperature) were examined and the optimal experimental conditions were determined. The results indicated that the removal of the dye was pH dependent and at initial pH of 2, the dye was removed effectively. The CBY dye sorption data were fitted to Langmuir, Freundlich, Temkin and Dubinin-Radushkevich equilibrium models. The maximum sorption capacity of CBY dye ions onto coffee husks increased from 24.04 to 35.04 mg g-1 when the temperature was increased from 293 to 313 K. The calculated sorption thermodynamic parameters including ΔG°, ΔH°, and ΔS° indicated that the CBY dye sorption onto coffee husks is a spontaneous, endothermic and mainly physical in nature.





References:
[1] T. A. Khan, V. V. Singh, D. Kumar "Removal of some basic dyes from
artificial textile wastewater by adsorption on akash kinari coal," J. Sci.
Ind. Res., vol. 63, pp. 355-364, 2004.
[2] M. A. Ahmad, N. K. Rahman "Equilibrium, kinetics and thermodynamic
of remazol brilliant orange 3r dye adsorption on coffee husk-based
activated carbon," Chem. Eng. J., vol. 170, pp. 154-161, 2011.
[3] L. S. Oliveira, A. S. Franca, T. M. Alves, S. D. F. Rocha "Evaluation of
untreated coffee husks as potential biosorbents for treatment of dye
contaminated waters," J. Hazard. Mater., vol. 155, pp. 507-512, 2008.
[4] M. A. M. Salleh, D. K. Mahmoud, W. A. W. A. Karim, A. Idris
"Cationic and anionic dye adsorption by agricultural solid wastes: A
comprehensive review," Desalination, vol. 280, pp. 1-13, 2011.
[5] A. Bhatnagar, M. Sillanpää "Utilization of agro-industrial and municipal
waste materials as potential adsorbents for water treatment-A review,"
Chem. Eng. J., vol. 157, pp. 277-296, 2010.
[6] V. G├│mez, M. S. Larrechi, M. P. Callao "Kinetic and adsorption study of
acid dye removal using activated carbon," Chemosphere, vol. 69, pp.
1151-1158, 2007.
[7] M. F. R. Pereira, S. F. Soares, J. J. M. Órfão, J. L. Figueiredo
"Adsorption of dyes on activated carbons: Influence of surface chemical
groups," Carbon, vol. 41, pp. 811-821, 2003.
[8] M. Sanchez-Polo, J. Rivera-Utrilla "Adsorbent-adsorbate interactions in
the adsorption of Cd(II) and Hg(II) on ozonized activated carbons,"
Environ. Sci. Technol., vol. 36, pp. 3850-3854, 2002.
[9] K. Y. Foo, B. H. Hameed "Detoxification of pesticide waste via
activated carbon adsorption process," J. Hazard. Mater., vol. 175, pp. 1-
11, 2010.
[10] Sung Wook Won, Y.-S. Yun "Biosorptive removal of reactive yellow 2
using waste biomass from lysine fermentation process.," Dyes Pigm.,
vol. 76, pp. 502-507, 2008.
[11] W. E. Oliveira, A. S. Franca, L. S. Oliveira, S. D. Rocha "Untreated
coffee husks as biosorbents for the removal of heavy metals from
aqueous solutions," J. Hazard. Mater., vol. 152, pp. 1073-1081, 2008.
[12] H. P. Boehm "Surface oxides on carbon and their analysis: A critical
assessment," Carbon, vol. 40, pp. 145-149, 2002.
[13] H. Valdes, M. Sanchez-Polo, J. Rivera-Utrilla, C. A. Zaror "Effect of
ozone treatment on surface properties of activated carbon," Langmuir,
vol. 18, pp. 2111-2116, 2002.
[14] M.-S. Chiou, P.-Y. Ho, H.-Y. Li "Adsorption of anionic dyes in acid
solutions using chemically cross-linked chitosan beads," Dyes Pigm.,
vol. 60 pp. 69-84, 2004.
[15] A. Mittal, J. Mittal, L. Kurup "Batch and bulk removal of hazardous dye,
indigo carmine from wastewater through adsorption," J. Hazard. Mater.,
vol. 137, pp. 591-602, 2006.
[16] Z. m. Aksu, I. A. Isoglu "Use of agricultural waste sugar beet pulp for
the removal of gemazol turquoise blue-g reactive dye from aqueous
solution," J. Hazard. Mater., vol. 137, pp. 418-430, 2006.
[17] I. Langmuir "The adsorption of gases on plane surfaces of glass, mica
and platinum," J. Am. Chem. Soc., vol. 40, pp. 1361-1403, 1918.
[18] Y. Ho, J. Porter, G. McKay "Equilibrium isotherm studies for the
sorption of divalent metal ions onto peat: Copper, nickel and lead single
component systems," Water Air Soil Pollut., vol. 141, pp. 1-33, 2002.
[19] B. H. Hameed, J. M. Salman, A. L. Ahmad "Adsorption isotherm and
kinetic modeling of 2,4-d pesticide on activated carbon derived from
date stones," J. Hazard. Mater., vol. 163, pp. 121-126, 2009.
[20] H. Freundlich "├£ber die adsorption in lösungen (adsorption in
solution)," Z. Phys. Chem., vol. 57 pp. 384-470, 1906.
[21] V. I. Temkin, V. Pyzhev Acta Physicochim. URSS, vol. 12, pp. 217-222
1940.
[22] M. M. Dubinin, L. V. Radushkevich "Equation of the characteristic
curve of activated charcoal," Chem. Zentr., vol. 1 pp. 875-890, 1947.
[23] Y. Liu, Y.-J. Liu "Biosorption isotherms, kinetics and thermodynamics,"
Sep. Purif. Technol., vol. 61, pp. 229-242, 2008.
[24] K. R. Hall, L. C. Eagleton, A. Acrivos, T. Vermeulen "Pore- and soliddiffusion
kinetics in fixed-bed adsorption under constant-pattern
conditions," Ind. Eng. Chem. Fundam., vol. 5, pp. 212-223, 1966.
[25] R. E. Treybal, "Mass transfer operations". third ed. New York: McGraw
Hill. 1980.
[26] K. Vijayaraghavan, T. V. N. Padmesh, K. Palanivelu, M. Velan
"Biosorption of nickel(II) ions onto sargassum wightii: Application of
two-parameter and three-parameter isotherm models," J. Hazard. Mater.,
vol. 133, pp. 304-308, 2006.
[27] B. Canan Akmil "Applicability of the various adsorption models of three
dyes adsorption onto activated carbon prepared waste apricot," J.
Hazard. Mater., vol. 135, pp. 232-241, 2006.
[28] L. S. Oliveira, A. S. Franca, T. M. Alves, S. n. D. F. Rocha "Evaluation
of untreated coffee husks as potential biosorbents for treatment of dye
contaminated waters," J. Hazard. Mater., vol. 155, pp. 507-512, 2008.
[29] V. Dulman, S. M. Cucu-Man "Sorption of some textile dyes by beech
wood sawdust," J. Hazard. Mater., vol. 162, pp. 1457-1464, 2009.
[30] R. Sivaraj, C. Namasivayam, K. Kadirvelu "Orange peel as an adsorbent
in the removal of acid violet 17 (acid dye) from aqueous solutions,"
Waste Management, vol. 21, pp. 105-110, 2001.
[31] R. Gong, Y. Ding, M. Li, C. Yang, H. Liu, Y. Sun "Utilization of
powdered peanut hull as biosorbent for removal of anionic dyes from
aqueous solution," Dyes Pigm., vol. 64, pp. 187-192, 2005.
[32] C. Namasivayam, M. Dinesh Kumar, K. Selvi, R. Ashruffunissa Begum,
T. Vanathi, R. T. Yamuna "'waste' coir pith-a potential biomass for the
treatment of dyeing wastewaters," Biomass and Bioenergy, vol. 21, pp.
477-483, 2001.
[33] C. Namasivayam, D. Prabha, M. Kumutha "Removal of direct red and
acid brilliant blue by adsorption on to banana pith," Bioresour. Technol.,
vol. 64, pp. 77-79, 1998.
[34] J. F. Osma, V. n. Saravia, J. L. Toca-Herrera, S. R. g. Couto "Sunflower
seed shells: A novel and effective low-cost adsorbent for the removal of
the diazo dye reactive black 5 from aqueous solutions," J. Hazard.
Mater., vol. 147, pp. 900-905, 2007.
[35] Y. Liu "Is the free energy change of adsorption correctly calculated?," J.
Chem. Eng. Data, vol. 54, pp. 1981-1985, 2009.