Abstract: This paper present some preliminary work on the
preparation and physicochemical caracterization of nanocomposite
MFI-alumina structures based on alumina hollow fibres. The fibers
are manufactured by a wet spinning process. α-alumina particles were
dispersed in a solution of polysulfone in NMP. The resulting slurry is
pressed through the annular gap of a spinneret into a precipitation
bath. The resulting green fibres are sintered. The mechanical strength
of the alumina hollow fibres is determined by a three-point-bending
test while the pore size is characterized by bubble-point testing. The
bending strength is in the range of 110 MPa while the average pore
size is 450 nm for an internal diameter of 1 mm and external diameter
of 1.7 mm. To characterize the MFI membranes various techniques
were used for physicochemical characterization of MFI–ceramic
hollow fibres membranes: The nitrogen adsorption, X-ray
diffractometry, scanning electron microscopy combined with X
emission microanalysis. Scanning Electron Microscopy (SEM) and
Energy Dispersive Microanalysis by the X-ray were used to observe
the morphology of the hollow fibre membranes (thickness,
infiltration into the carrier, defects, homogeneity). No surface film,
has been obtained, as observed by SEM and EDX analysis and
confirmed by high temperature variation of N2 and CO2 gas
permeances before cation exchange. Local analysis and characterise
(SEM and EDX) and overall (by ICP elemental analysis) were
conducted on two samples exchanged to determine the quantity and
distribution of the cation of cesium on the cross section fibre of the
zeolite between the cavities.
Abstract: Renewable natural fibres such as oil palm, flax, and
pineapple leaf can be utilized to obtain new high performance
polymer materials. The reuse of waste natural fibres as reinforcement
for polymer is a sustainable option to the environment. However, due
to its high hydroxyl content of cellulose, natural fibres are
susceptible to absorb water that affects the composite mechanical
properties adversely. Research found that Nano materials such as
Nano Silica Carbide (n-SiC) and Nano Clay can be added into the
polymer composite to overcome this problem by enhancing its
mechanical properties in wet condition. The addition of Nano
material improves the tensile and wear properties, flexural stressstrain
behaviour, fracture toughness, and fracture strength of polymer
natural composites in wet and dry conditions.
Abstract: Two different superhydrophobic surfaces were
elaborated and their oil repellency behavior was evaluated using
several liquid with different surface tension. A silicone rubber/SiO2
nanocomposite coated (A) on aluminum substrate by “spin-coating"
and the sample B was an anodized aluminum surface covered by
Teflon-like coating. A high static contact angle about ∼162° was
measured for two prepared surfaces on which the water droplet rolloff.
Scanning electron microscopy (SEM) showed the presence of
micro/nanostructures for both sample A and B similar to that of lotus
leaf.
However the sample A presented significantly different behaviour
of wettability against the low surface tension liquid. Sample A has
been wetted totally by oil (dodecan) droplet while sample B showed
oleophobic behaviour. Oleophobic property of Teflon like coating
can be contributed to the presence of CF2 and CF3 functional group
which was shown by XPS analysis.
Abstract: Large scale climate signals and their teleconnections can influence hydro-meteorological variables on a local scale. Several extreme flow and timing measures, including high flow and low flow measures, from 62 hydrometric stations in Canada are investigated to detect possible linkages with several large scale climate indices. The streamflow data used in this study are derived from the Canadian Reference Hydrometric Basin Network and are characterized by relatively pristine and stable land-use conditions with a minimum of 40 years of record. A composite analysis approach was used to identify linkages between extreme flow and timing measures and climate indices. The approach involves determining the 10 highest and 10 lowest values of various climate indices from the data record. Extreme flow and timing measures for each station were examined for the years associated with the 10 largest values and the years associated with the 10 smallest values. In each case, a re-sampling approach was applied to determine if the 10 values of extreme flow measures differed significantly from the series mean. Results indicate that several stations are impacted by the large scale climate indices considered in this study. The results allow the determination of any relationship between stations that exhibit a statistically significant trend and stations for which the extreme measures exhibit a linkage with the climate indices.
Abstract: This paper investigates experimental studies on
vibration suppression for a cantilever beam using an
Electro-Rheological (ER) sandwich shock absorber. ER fluid (ERF) is a
class of smart materials that can undergo significant reversible changes
immediately in its rheological and mechanical properties under the
influence of an applied electric field. Firstly, an ER sandwich beam is
fabricated by inserting a starch-based ERF into a hollow composite
beam. At the same time, experimental investigations are focused on the
frequency response of the ERF sandwich beam. Second, the ERF
sandwich beam is attached to a cantilever beam to become as a shock
absorber. Finally, a fuzzy semi-active vibration control is designed to
suppress the vibration of the cantilever beam via the ERF sandwich
shock absorber. To check the consistency of the proposed fuzzy
controller, the real-time implementation validated the performance of
the controller.
Abstract: An adaptive neural network controller for
autonomous underwater vehicles (AUVs) is presented in this paper.
The AUV model is highly nonlinear because of many factors, such as
hydrodynamic drag, damping, and lift forces, Coriolis and centripetal
forces, gravity and buoyancy forces, as well as forces from thruster.
In this regards, a nonlinear neural network is used to approximate the
nonlinear uncertainties of AUV dynamics, thus overcoming some
limitations of conventional controllers and ensure good performance.
The uniform ultimate boundedness of AUV tracking errors and the
stability of the proposed control system are guaranteed based on
Lyapunov theory. Numerical simulation studies for motion control of
an AUV are performed to demonstrate the effectiveness of the
proposed controller.
Abstract: Delamination between layers in composite materials is a major structural failure. The delamination resistance is quantified by the critical strain energy release rate (SERR). The present investigation deals with the strain energy release rate of two woven fabric composites. Materials used are made of two types of glass fiber (360 gsm and 600 gsm) of plain weave and epoxy as matrix. The fracture behavior is studied using the mode I, double cantilever beam test and the mode II, end notched flexure test, in order to determine the energy required for the initiation and growth of an artificial crack. The delamination energy of these two materials is compared in order to study the effect of weave and reinforcement on mechanical properties. The fracture mechanism is also analyzed by means of scanning electron microscopy (SEM). It is observed that the plain weave fabric composite with lesser strand width has higher inter laminar fracture properties compared to the plain weave fabric composite with more strand width.
Abstract: This research study the application of the immobilized
TiO2 layer and Cu-TiO2 layer on graphite substrate as a negative
electrode or anode for Li-ion battery. The titania layer was produced
through chemical bath deposition method, meanwhile Cu particles
were deposited electrochemically. A material can be used as an
electrode as it has capability to intercalates Li ions into its crystal
structure. The Li intercalation into TiO2/Graphite and Cu-
TiO2/Graphite were analyzed from the changes of its XRD pattern
after it was used as electrode during discharging process. The XRD
patterns were refined by Le Bail method in order to determine the
crystal structure of the prepared materials. A specific capacity and the
cycle ability measurement were carried out to study the performance
of the prepared materials as negative electrode of the Li-ion battery.
The specific capacity was measured during discharging process from
fully charged until the cut off voltage. A 300 was used as a load.
The result shows that the specific capacity of Li-ion battery with
TiO2/Graphite as negative electrode is 230.87 ± 1.70mAh.g-1 which is
higher than the specific capacity of Li-ion battery with pure graphite
as negative electrode, i.e 140.75 ±0.46mAh.g-1. Meanwhile
deposition of Cu onto TiO2 layer does not increase the specific
capacity, and the value even lower than the battery with
TiO2/Graphite as electrode. The cycle ability of the prepared battery
is only two cycles, due to the Li ribbon which was used as cathode
became fragile and easily broken.
Abstract: New nondestructive technique, namely an inverse technique based on vibration tests, to characterize nonlinear mechanical properties of adhesive layers in sandwich composites is developed. An adhesive layer is described as a viscoelastic isotropic material with storage and loss moduli which are both frequency dependent values in wide frequency range. An optimization based on the planning of experiments and response surface technique to minimize the error functional is applied to decrease considerably the computational expenses. The developed identification technique has been tested on aluminum panels and successfully applied to characterize viscoelastic material properties of 3M damping polymer ISD-112 used as a core material in sandwich panels.
Abstract: Plastics occupy wide place in the applications of
automotive, electronics and house goods. Especially reinforced
plastics become popular because of their high strength besides their
advantages of low weight and easy manufacturability. In this study,
mechanical and morphological properties of polypropylene (PP) and
high density polyethylene (HDPE) matrix composites reinforced with
surface modified nano titan dioxide (TiO2) particles were
investigated. Surface modification was made by coating the nano
powders with maleic anhydride grafted styrene ethylene butylene
styrene (SEBS-g-MA) and silane, respectively. After surface
modification, PP/TiO2 and HDPE/TiO2 composites were obtained by
using twin screw extruder at titan dioxide loading of 1 wt.%, 3 wt.%
and 5 wt.%. Effects of surface modification were determined by
thermal and morphological analysis. SEBS-g-MA provided bridging
effect between TiO2 particles and polymer matrix while silane was
effective as a dispersant. Depending on that, homogenous structures
without agglomeration were obtained. Mechanical tests were
performed on the injection moldings of the composites for obtaining
the impact strength, tensile strength, stress at break, elongation and
elastic modulus. Reinforced HDPE and PP moldings gave higher
tensile strength and elastic modulus due to the rigid structure of TiO2.
Slight increment was seen in stress at break. Elongation and impact
strength decreased due to the stiffness of the nano titan dioxide.
Abstract: Polyurethanes (PURs) are very versatile polymeric
materials with a wide range of physical and chemical properties.
PURs have desirable properties such as high abrasion resistance, tear
strength, shock absorption, flexibility and elasticity. Although they
have relatively poor thermal stability, this can be improved by using
treated clay. Polyurethane/clay nanocomposites have been
synthesized from renewable sources. A polyol for the production of
polyurethane by reaction with an isocyanate was obtained by the
synthesis of palm oil-based oleic acid with glycerol. Dodecylbenzene
sulfonic acid (DBSA) was used as catalyst and emulsifier. The
unmodified clay (kunipia-F) was treated with cetyltrimethyl
ammonium bromide (CTAB-mont) and octadodecylamine (ODAmont).
The d-spacing in CTAB-mont and ODA-mont were 1.571 nm
and 1.798 nm respectively and larger than that of the pure-mont
(1.142 nm). The organoclay was completely intercalated in the
polyurethane, as confirmed by a wide angle x-ray diffraction
(WAXD) pattern.
The results showed that adding clay demonstrated better thermal
stability in comparison with the virgin polyurethane. Onset
degradation of pure PU is at 200oC, and is lower than that of the
CTAB-mont PU and ODA-mont PU which takes place at about
318oC and 330oC, respectively. The mechanical properties (including
the dynamic mechanical properties) of pure polyurethane (PU) and
PU/clay nanocomposites, were measured. The modified organoclay
had a remarkably beneficial effect on the strength and elongation at
break of the nanocomposites, which both increased with increasing
clay content with the increase of the tensile strength of more than
214% and 267% by the addition of only 5 wt% of the
montmorillonite CTAB-mont PU and ODA-mont PU, respectively.
Abstract: Object: Review recent publications of patient safety
culture to investigate the relationship between leadership behavior,
safety culture, and safety performance in the healthcare industry.
Method: This study is a cross-sectional study, 350 questionnaires were
mailed to hospital workers with 195 valid responses obtained, and a
55.7% valid response rate. Confirmatory factor analysis (CFA) was
carried out to test the factor structure and determine if the composite
reliability was significant with a factor loading of >0.5, resulting in an
acceptable model fit. Results: Through the analysis of One-way
ANOVA, the results showed that physicians significantly have more
negative patient safety culture perceptions and safety performance
perceptions than non- physicians. Conclusions: The path analysis
results show that leadership behavior affects safety culture and safety
performance in the health care industry. Safety performance was
affected and improved with contingency leadership and a positive
patient safety organization culture. The study suggests improving
safety performance by providing a well-managed system that
includes: consideration of leadership, hospital worker training
courses, and a solid safety reporting system.
Abstract: Stress analysis of functionally graded composite plates
composed of ceramic, functionally graded material and metal layers is
investigated using 3-D finite element method. In FGM layer, material
properties are assumed to be varied continuously in the thickness
direction according to a simple power law distribution in terms of the
volume fraction of a ceramic and metal. The 3-D finite element model
is adopted by using an 18-node solid element to analyze more
accurately the variation of material properties in the thickness
direction. Numerical results are compared for three types of materials.
In the analysis, the tensile and the compressive stresses are
summarized for various FGM thickness ratios, volume fraction
distributions, geometric parameters and mechanical loads.
Abstract: This paper deals with analysis of flexural stiffness,
indentation and their energies in three point loading of sandwich
beams with composite faces from Eglass/epoxy and cores from
Polyurethane or PVC. Energy is consumed in three stages of
indentation in laminated beam, indentation of sandwich beam and
bending of sandwich beam. Theory of elasticity is chosen to present
equations for indentation of laminated beam, then these equations
have been corrected to offer better results. An analytical model has
been used assuming an elastic-perfectly plastic compressive behavior
of the foam core. Classical theory of beam is used to describe three
point bending. Finite element (FE) analysis of static indentation
sandwich beams is performed using the FE code ABAQUS. The
foam core is modeled using the crushable foam material model and
response of the foam core is experimentally characterized in uniaxial
compression.
Three point bending and indentation have been done
experimentally in two cases of low velocity and higher velocity
(quasi-impact) of loading. Results can describe response of beam in
terms of core and faces thicknesses, core material, indentor diameter,
energy absorbed, and length of plastic area in the testing. The
experimental results are in good agreement with the analytical and
FE analyses. These results can be used as an introduction for impact
loading and energy absorbing of sandwich structures.
Abstract: In this study, Friction Stir Processing (FSP) a recent grain refinement technique was employed to disperse micron-sized (2 *m) SiCp particles into aluminum alloy AA6063. The feasibility to fabricate bulk composites through FSP was analyzed and experiments were conducted at different traverse speeds and wider volumes of the specimens. Micro structural observation were carried out by employing optical microscopy test of the cross sections in both parallel and perpendicular to the tool traverse direction. Mechanical property including micro hardness was evaluated in detail at various regions on the specimen. The composites had an excellent bonding with aluminum alloy substrate and a significant increase of 30% in the micro hardness value of metal matrix composite (MMC) as to that of the base metal has observed. The observations clearly indicate that SiC particles were uniformly distributed within the aluminum matrix.
Abstract: The stab resistance performance of newly developed
fabric composites composed of hexagonal paper honeycombs, filled
with shear thickening fluid (STF), and woven Kevlar® fabric or
UHMPE was investigated in this study. The STF was prepared by
dispersing submicron SiO2 particles into polyethylene glycol (PEG).
Our results indicate that the STF-Kevlar composite possessed lower
penetration depth than that of neat Kevlar. In other words, the
STF-Kevlar composite can attain the same energy level in
stab-resistance test with fewer layers of Kevlar fabrics than that of the
neat Kevlar fabrics. It also indicates that STF can be used for the
fabrication of flexible body armors and can provide improved
protection against stab threats. We found that the stab resistance of the
STF-Kevlar composite increases with the increase of SiO2
concentration in STF. Moreover, the silica particles functionalized
with silane coupling agent can further improve the stab resistance.
Abstract: In the present work we investigate both the elastic and
electric properties of a chiral material. We consider a composite
structure made from a polymer matrix and anisotropic inclusions of
GaAs taking into account piezoelectric and dielectric properties of
the composite material. The principal task of the work is the
estimation of the functional properties of the composite material.
Abstract: Researchers investigate arious strategies to develop composite beams and maximize the structural advantages. This study
attempted to conduct experiments and analysis of changes in the
neutral axis of positive moments of a Green Beam. Strain
compatibility analysis was used, and its efficiency was demonstrated
by comparing experimental and analytical values. In the comparison of
neutral axis, the difference between experimental and analytical values
was found to range from 8.8~26.2%. It was determined that strain
compatibility analysis can be useful for predicting the behaviors of
composite beams, with the ability to predict the behavior of not only
the elastic location of the composite member, but also of the plastic
location
Abstract: The friction between two metal surfaces results in a
high frequency noise (squealing) which also occurs during the
braking of wagons with rail brakes in the process of shunting at a
marshalling yard with a hump. At that point the noise level may
exceed 130dB, which is extremely unpleasant for workers and
inhabitants. In our research we developed a new composite material
which does not change braking properties, is capable of taking
extremely high pressure loads, reduces noise and is environmentally
friendly. The noise reduction results had been very good and had
shown a decrease of the high frequency noise almost completely (by
99%) at its source. With our technology we had also reduced general
noise by more than 30dBA.
Abstract: Within this work High Temperature Single Impact
Studies were performed to evaluate deformation mechanisms at
different energy and momentum levels. To show the influence of
different microstructures and hardness levels and their response to
single impacts four different materials were tested at various
temperatures up to 700°C. One carbide reinforced NiCrBSi based
Metal Matrix Composite and three different steels were tested. The
aim of this work is to determine critical energies for fracture
appearance and the materials response at different energy and
momenta levels. Critical impact loadings were examined at elevated
temperatures to limit operating conditions in impact dominated
regimes at elevated temperatures. The investigations on the
mechanisms were performed using different means of microscopy at
the surface and in metallographic cross sections. Results indicate
temperature dependence of the occurrence of cracks in hardphase
rich materials, such as Metal Matrix Composites High Speed Steels
and the influence of different impact momenta at constant energies
on the deformation of different steels.