Abstract: The aim of this study was to compare the solubility of selected volatile organic compounds in water and silicon oil using the simple static headspace method. The experimental design allowed equilibrium achievement within 30 – 60 minutes. Infinite dilution activity coefficients and Henry-s law constants for various organics representing esters, ketones, alkanes, aromatics, cycloalkanes and amines were measured at 303K. The measurements were reproducible with a relative standard deviation and coefficient of variation of 1.3x10-3 and 1.3 respectively. The static determined activity coefficients using shaker flasks were reasonably comparable to those obtained using the gas liquid - chromatographic technique and those predicted using the group contribution methods mainly the UNIFAC. Silicon oil chemically known as polydimethysiloxane was found to be better absorbent for VOCs than water which quickly becomes saturated. For example the infinite dilution mole fraction based activity coefficients of hexane is 0.503 and 277 000 in silicon oil and water respectively. Thus silicon oil gives a superior factor of 550 696. Henry-s law constants and activity coefficients at infinite dilution play a significant role in the design of scrubbers for abatement of volatile organic compounds from contaminated air streams. This paper presents the phase equilibrium of volatile organic compounds in very dilute aqueous and polymeric solutions indicating the movement and fate of chemical in air and solvent. The successful comparison of the results obtained here and those obtained using other methods by the same authors and in literature, means that the results obtained here are reliable.
Abstract: Intermetallic Ni3Al – based alloys belong to a group
of advanced materials characterized by good chemical and physical
properties (such as structural stability, corrosion resistance) which
offer advenced technological applications. The paper presents the
study of catalytic properties of Ni3Al foils (thickness approximately
50 &m) in the methanol and hexane decomposition. The egzamined
material posses microcrystalline structure without any additional
catalysts on the surface. The better catalytic activity of Ni3Al foils
with respect to quartz plates in both methanol and hexane
decomposition was confirmed. On thin Ni3Al foils the methanol
conversion reaches approximately 100% above 480 oC while the
hexane conversion reaches approximately 100% (98,5%) at 500 oC.
Deposit formed during the methanol decomposition is built up of
carbon nanofibers decorated with metal-like nanoparticles.
Abstract: The characteristics of fluid flow and phase separation
in an oil-water separator were numerically analysed as part of the
work presented herein. Simulations were performed for different
velocities and droplet diameters, and the way this parameters can
influence the separator geometry was studied.
The simulations were carried out using the software package
Fluent 6.2, which is designed for numerical simulation of fluid flow
and mass transfer. The model consisted of a cylindrical horizontal
separator. A tetrahedral mesh was employed in the computational
domain. The condition of two-phase flow was simulated with the
two-fluid model, taking into consideration turbulence effects using
the k-ε model.
The results showed that there is a strong dependency of phase
separation on mixture velocity and droplet diameter. An increase in
mixture velocity will bring about a slow down in phase separation
and as a consequence will require a weir of greater height. An
increase in droplet diameter will produce a better phase separation.
The simulations are in agreement with results reported in literature
and show that CFD can be a useful tool in studying a horizontal oilwater
separator.
Abstract: This paper shows a simple and effective approach to
the design and implementation of Industrial Information Systems
(IIS) oriented to control the characteristics of each individual product manufactured in a production line and also their manufacturing conditions. The particular products considered in this work are large steel strips that are coiled just after their manufacturing. However, the approach is directly applicable to coiled strips in other industries, like
paper, textile, aluminum, etc. These IIS provide very detailed information of each manufactured product, which complement the general information managed by the ERP system of the production line. In spite of the high importance of this type of IIS to guarantee and improve the quality of the products manufactured in many industries, there are very few works about them in the technical literature. For this reason, this paper represents an important contribution to the development of this type of IIS, providing guidelines for their design, implementation and exploitation.
Abstract: The hydrogen peroxide treatment was able to
remediate chlorophenols, polycyclic aromatic hydrocarbons, diesel
and transformer oil contaminated soil. Chemical treatment of
contaminants adsorbed in peat resulted in lower contaminants-
removal and required higher addition of chemicals than the treatment
of contaminants in sand. The hydrogen peroxide treatment was found
to be feasible for soil remediation at natural soil pH. Contaminants in
soil could degrade with the addition of hydrogen peroxide only
indicating the ability of transition metals ions and minerals of these
metals presented in soil to catalyse the reaction of hydrogen peroxide
decomposition.
Abstract: Flows over a harmonically oscillating NACA 0012
airfoil are simulated here using a two-dimensional, unsteady,
incompressibleNavier-Stokes solver.Both pure-plunging and
pitching-plunging combined oscillations are considered at a Reynolds
number of 5000. Special attention is paid to the vortex shedding and
interaction mechanism of the motions. For all the simulations
presented here, the reduced frequency (k) is fixed at a value of 2.5
and plunging amplitude (h) is selected to be in the range of 0.2-0.5.
The simulation results show that the interaction mechanism between
the leading and trailing edge vortices has a decisive effect on the
values of the resulting thrust and propulsive efficiency.
Abstract: Transesterification of candlenut (aleurites moluccana)
oil with methanol using potassium hydroxide as catalyst was
studied. The objective of the present investigation was to produce
the methyl ester for use as biodiesel. The operation variables
employed were methanol to oil molar ratio (3:1 – 9:1), catalyst
concentration (0.50 – 1.5 %) and temperature (303 – 343K). Oil
volume of 150 mL, reaction time of 75 min were fixed as common
parameters in all the experiments. The concentration of methyl ester
was evaluated by mass balance of free glycerol formed which was
analyzed by using periodic acid. The optimal triglyceride conversion
was attained by using methanol to oil ratio of 6:1, potassium
hydroxide as catalyst was of 1%, at room temperature. Methyl ester
formed was characterized by its density, viscosity, cloud and pour
points. The biodiesel properties had properties similar to those of
diesel oil, except for the viscosity that was higher.
Abstract: Empty Fruit Bunches (EFB) and Palm Oil Mill
Effluent (POME) are two main wastes from oil palm industries which
contain rich lignocellulose. Degradation of EFB and POME by
microorganisms will produce hydrolytic enzyme which will degrade
cellulose and hemicellulose during composting process. However,
normal composting takes about four to six months to reach maturity.
Hence, application of fungi into compost can shorten the period of
composting. This study identifies the effect of xylanase and cellulase
produced by Aspergillus niger and Trichoderma virens on
composting process using EFB and POME. The degradation of EFB
and POME indicates the lignocellulolytic capacity of Aspergillus
niger and Trichoderma virens with more than 7% decrease in
hemicellulose and more than 25% decrease in cellulose for both
inoculated compost. Inoculation of Aspergillus niger and
Trichoderma virens also increased the enzyme activities during the
composting period compared to the control compost by 21% for both
xylanase and cellulase. Rapid rise in the activities of cellulase and
xylanase was observed by Aspergillus niger with the highest
activities of 14.41 FPU/mg and 3.89 IU/mg, respectively. Increased
activities of cellulase and xylanase also occurred in inoculation of
Trichoderma virens with the highest activities obtained at 13.21
FPU/mg and 4.43 IU/mg, respectively. Therefore, it is evident that
the inoculation of fungi can increase the enzyme activities hence
effectively degrading the EFB and POME.
Abstract: This study presents a systematic analysis of the
dynamic behaviors of a gear-bearing system with porous squeeze film
damper (PSFD) under nonlinear suspension, nonlinear oil-film force
and nonlinear gear meshing force effect. It can be found that the
system exhibits very rich forms of sub-harmonic and even the chaotic
vibrations. The bifurcation diagrams also reveal that greater values of
permeability may not only improve non-periodic motions effectively,
but also suppress dynamic amplitudes of the system. Therefore, porous
effect plays an important role to improve dynamic stability of
gear-bearing systems or other mechanical systems. The results
presented in this study provide some useful insights into the design
and development of a gear-bearing system for rotating machinery that
operates in highly rotational speed and highly nonlinear regimes.
Abstract: The chemical degradation of dieldrin in ferric
sulfide and iron powder aqueous suspension was investigated
in laboratory batch type experiments. To identify the reaction
mechanism, reduced copper was used as reductant. More than
90% of dieldrin was degraded using both reaction systems after
29 days. Initial degradation rate of the pesticide using ferric
sulfide was superior to that using iron powder. The reaction
schemes were completely dissimilar even though the ferric ion
plays an important role in both reaction systems. In the case of
metallic iron powder, dieldrin undergoes partial dechlorination.
This reaction proceeded by reductive hydrodechlorination with
the generation of H+, which arise by oxidation of ferric iron.
This reductive reaction was accelerated by reductant but
mono-dechlorination intermediates were accumulated. On the
other hand, oxidative degradation was observed in the reaction
with ferric sulfide, and the stable chemical structure of dieldrin
was decomposed into water-soluble intermediates. These
reaction intermediates have no chemical structure of drin class.
This dehalogenation reaction assumes to occur via the adsorbed
hydroxyl radial generated on the surface of ferric sulfide.
Abstract: This study was conducted Ismailoglu grape type (Vitis
vinifera L.) and its vine which was aged 15 was grown on its own
root in a vegetation period of 2013 in Nevşehir province in Turkey.
In this research, it was investigated whether the applications of
Control (C), 1/3 cluster tip reduction (1/3 CTR), shoot tip reduction
(STR), 1/3 CTR + STR, TKI-HUMAS (TKI-HM) (Soil) (S), TKIHM
(Foliar) (F), TKI-HM (S + F), 1/3 CTR + TKI-HM (S), 1/3 CTR
+ TKI-HM (F), 1/3 CTR + TKI-HM (S+F), STR + TKI-HM (S), STR
+ TKI-HM (F), STR + TKI-HM (S + F), 1/3 CTR + STR+TKI-HM
(S), 1/3 CTR + STR + TKI-HM (F), 1/3 CTR + STR + TKI-HM (S +
F) on yield and yield components of Ismailoglu grape type. The
results were obtained as the highest fresh grape yield (16.15 kg/vine)
with TKI-HM (S), as the highest cluster weight (652.39 g) with 1/3
CTR + STR, as the highest 100 berry weight (419.07 g) with 1/3
CTR + STR + TKI-HM (F), as the highest maturity index (44.06)
with 1/3 CTR, as the highest must yield (810.00 ml) with STR +
TKI-HM (F), as the highest intensity of L* color (42.04) with TKIHM
(S + F), as the highest intensity of a* color (2.60) with 1/3 CTR
+ TKI-HM (S), as the highest intensity of b* color (7.16) with 1/3
CTR + TKI-HM (S) applications. To increase the fresh grape yield of
Ismailoglu grape type can be recommended TKI-HM (S) application.
Abstract: The incidence of mechanical fracture of an
automobile piston rings prompted development of fracture analysis
method on this case. The three rings (two compression rings and one
oil ring) were smashed into several parts during the power-test (after
manufacturing the engine) causing piston and liner to be damaged.
The radial and oblique cracking happened on the failed piston rings.
The aim of the fracture mechanics simulations presented in this paper
was the calculation of particular effective fracture mechanics
parameters, such as J-integrals and stress intensity factors. Crack
propagation angles were calculated as well. Two-dimensional
fracture analysis of the first compression ring has been developed in
this paper using ABAQUS CAE6.5-1 software. Moreover, SEM
fractography was developed on fracture surfaces and is discussed in
this paper. Results of numerical calculations constitute the basis for
further research on real object.
Abstract: In the other to Study of drought stress and Selenium
spraying effect on superoxide dismotase (SOD) activity of rapeseed
(Brassica napus L.) cultivars in Shahr-e-Rey region, an experiment
carried out in Split factorial design in the basis of randomized
complete blocks with 4 replications in 2006. Irrigation in two levels:
Normal irrigation and irrigation with drought stress when the soil
electrical conductivity reached to 60 as main factor and rapeseed
cultivars in 3 levels Zarfam, Okapi, Opera and selenium spraying at
the beginning of flowering stage in 3 levels: 0, 16 and 21 g/ha as sub
factor.
The results showed that the simple and interaction effect of
irrigation, selenium and cultivars on SOD activity had significant
difference. In this case Zarfam cultivar with 2010 u.mg-1 protein and
Opera with 1454 u.mg-1 protein produced maximum and minimum
amounts of SOD activitiy. Interaction effect of irrigation and variety
showed that, normal irrigation in Opera with 1115 u.mg-1 protein
and drought stress in Zarfam with 2784 u.mg-1 protein conducted to
and minimum and maximum amounts of SOD activity.
Interaction effect of irrigation, cultivar and selenium on SOD
indicated that drought stress condition and 21 gr/ha selenium
spraying in Zarfam variety with 3146 u.mg-1 protein gained to
highest activities of SOD.
Abstract: This paper presents a model for the evaluation of
energy performance and aerodynamic forces acting on a three-bladed
small vertical axis Darrieus wind turbine depending on blade chord
curvature with respect to rotor axis.
The adopted survey methodology is based on an analytical code
coupled to a solid modeling software, capable of generating the
desired blade geometry depending on the blade design geometric
parameters, which is linked to a finite volume CFD code for the
calculation of rotor performance.
After describing and validating the model with experimental data,
the results of numerical simulations are proposed on the bases of two
different blade profile architectures, which are respectively
characterized by a straight chord and by a curved one, having a chord
radius equal to rotor external circumference. A CFD campaign of
analysis is completed for three blade-candidate airfoil sections, that is
the recently-developed DU 06-W-200 cambered blade profile, a
classical symmetrical NACA 0021 and its derived cambered airfoil,
characterized by a curved chord, having a chord radius equal to rotor
external circumference.
The effects of blade chord curvature on angle of attack, blade
tangential and normal forces are first investigated and then the
overall rotor torque and power are analyzed as a function of blade
azimuthal position, achieving a numerical quantification of the
influence of blade camber on overall rotor performance.
Abstract: Biodiesel production with used frying by
transesterification reaction with methanol, using a commercial
kaolinite thermally-activated solid acid catalyst was investigated.
The surface area, the average pore diameter and pore volume of the
kaolinite catalyst were 10 m2/g, 13.0 nm and 30 mm3/g, respectively.
The optimal conditions for the transesterification reaction were
determined to be oil/methanol, in a molar ratio 1:31, temperature 160
ºC and catalyst concentration of 3% (w/w). The yield of fatty acids
methyl esters (FAME) was 92.4% after 2 h of reaction. This method
of preparation of biodiesel can be a positive alternative for utilizing
used frying corn oil for feedstock of biodiesel combined with the
inexpensive catalyst.
Abstract: Subgrade moisture content varies with environmental and soil conditions and has significant influence on pavement performance. Therefore, it is important to establish realistic estimates of expected subgrade moisture contents to account for the effects of this variable on predicted pavement performance during the design stage properly. The initial boundary soil suction profile for a given pavement is a critical factor in determining expected moisture variations in the subgrade for given pavement and climatic and soil conditions. Several numerical models have been developed for predicting water and solute transport in saturated and unsaturated subgrade soils. Soil hydraulic properties are required for quantitatively describing water and chemical transport processes in soils by the numerical models. The required hydraulic properties are hydraulic conductivity, water diffusivity, and specific water capacity. The objective of this paper was to determine isothermal moisture profiles in a soil fill and predict the soil moisture movement above the ground water table using a simple one-dimensional finite difference model.
Abstract: Simplified coupled engine block-crankshaft models
based on beam theory provide an efficient substitute to engine
simulation in the design process. These models require accurate
definition of the main bearing stiffness. In this paper, an investigation
of this stiffness is presented. The clearance effect is studied using a
smooth bearing model. It is manifested for low shaft displacement.
The hydrodynamic assessment model shows that the oil film has no
stiffness for low loads and it is infinitely rigid for important loads.
The deformation stiffness is determined using a suitable finite
elements model based on real CADs. As a result, a main bearing
behaviour law is proposed. This behaviour law takes into account the
clearance, the hydrodynamic sustention and the deformation stiffness.
It ensures properly the transition from the configuration low rigidity
to the configuration high rigidity.
Abstract: The aim of this study was to investigate the effects of
supplementing the diluent of roosters' semen with different levels of
olive oil on motility, viability, morphology and acrosome integrity of
chicken spermatozoa after in vitro storage for up to 72 h. Semen was
collected from 60 White Layer males (62 wk of age) kept in
separated floor pens and randomly divided into six treatment groups
(10 males in each group). Experimental groups were as follows: T1
:fresh semen, T2 : semen extended 1:1 with Al – Daraji 2 diluent
(AD2D) alone, T3 – T6 :semen samples extended 1:1 with AD2D
supplemented with 2 ml, 4 ml, 6 ml or 8 ml of olive oil / 100 ml of
diluent, respectively. Semen samples were then stored at 5 °C for 24
h, 48 h or 72 h. There was a clear influence of diluent
supplementation with olive oil on the spermatozoa motility profile;
olive oil groups (T3, T4, T5 and T6) recorded the highest scores of
mass activity and individual motility during all storage periods
compared to T1 and T2 groups. In addition, the inclusion of olive oil
into semen diluent (T3, T4, T5 and T6) gave significantly higher
percentages of viable spermatozoa, normal morphologically
spermatozoa and intact acrosomes irrespective of storage period.
These results clearly show that supplementation the diluent of
roosters' semen with olive oil can improve semen quality when
semen samples in vitro stored at 5 °C for up to 72 h.
Abstract: Hydrogenated biodiesel is one of the most promising
renewable fuels. It has many advantages over conventional biodiesel,
including higher cetane number, higher heating value, lower
viscosity, and lower corrosiveness due to its absence of oxygen.
From previous work, Pd/TiO2 gave high conversion and selectivity in
hydrogenated biodiesel. In this work, the effect of biomass feedstocks
(i.e. beef fat, chicken fat, pork fat, and jatropha oil) on the production
of hydrogenated biodiesel over Pd/TiO2 has been studied. Biomass
feedstocks were analyzed by ICP-OES (inductively coupled plasma
optical emission spectrometry) to identify the content of impurities
(i.e. P, K, Ca, Na, and Mg). The deoxygenation catalyst, Pd/TiO2,
was prepared by incipient wetness impregnation (IWI) and tested in a
continuous flow packed-bed reactor at 500 psig, 325°C, H2/feed
molar ratio of 30, and LHSV of 4 h-1 for its catalytic activity and
selectivity in hydrodeoxygenation. All feedstocks gave high
selectivity in diesel specification range hydrocarbons and the main
hydrocarbons were n-pentadecane (n-C15) and n-heptadecane (n-
C17), resulting from the decarbonylation/decarboxylation reaction.
Intermediates such as oleic acid, stearic acid, palmitic acid, and esters
were also detected in minor amount. The conversion of triglycerides
in jatropha oil is higher than those of chicken fat, pork fat, and beef
fat, respectively. The higher concentration of metal impurities in
feedstock, the lower conversion of feedstock.
Abstract: The unsteady wake of an EPPLER 361 airfoil in
pitching motion has been investigated in a subsonic wind tunnel by
hot-wire anemometry. The airfoil was given the pitching motion
about the one-quarter chord axis at reduced frequency of 0182.
Streamwise mean velocity profiles (wake profiles) were investigated
at several vertically aligned points behind the airfoil at one-quarter
chord downstream distance from trailing edge. Oscillation amplitude
and mean angle of attack were varied to determine the effects on
wake profiles. When the maximum dynamic angle of attack was
below the static stall angle of attack, weak effects on wake were
found by increasing oscillation amplitude and mean angle of attack.
But, for higher angles of attack strong unsteady effects were
appeared on the wake.