Abstract: The effect of transition metal doping on Pt/Al2O3
catalyst used in propane dehydrogenation reaction at 500°C was
studied. The preparation methods investigated were sequential
impregnation (Pt followed by the 2nd metal or the 2nd metal followed
by Pt) and co-impregnation. The metal contents of these catalysts
were fixed as the weight ratio of Pt per the 2nd metal of around 0.075.
These catalysts were characterized by N2-physisorption, TPR, COchemisorption
and NH3-TPD. It was found that the impregnated 2nd
metal had an effect upon reducibility of Pt due to its interaction with
transition metal-containing structure. This was in agreement with the
CO-chemisorption result that the presence of Pt metal, which is a
result from Pt species reduction, was decreased. The total acidity of
bimetallic catalysts is decreased but the strong acidity is slightly
increased. It was found that the stability of bimetallic catalysts
prepared by co-impregnation and sequential impregnation where the
2nd metal was impregnated before Pt were better than that of
monometallic catalyst (undoped Pt one) due to the forming of Pt sites
located on the transition metal-oxide modified surface. Among all
preparation methods, the sequential impregnation method- having Pt
impregnated before the 2nd metal gave the worst stability because this
catalyst lacked the modified Pt sites and some fraction of Pt sites was
covered by the 2nd metal.
Abstract: The development of active and stable catalysts
without noble metals for low temperature oxidation of exhaust gases
remains a significant challenge. The purpose of this study is to
determine the influence of the preparation method on the catalytic
activity of the supported copper-manganese mixed oxides in terms of
VOCs oxidation. The catalysts were prepared by impregnation of γ-
Al2O3 with copper and manganese nitrates and acetates and the
possibilities for CO, CH3OH and dimethyl ether (DME) oxidation
were evaluated using continuous flow equipment with a four-channel
isothermal stainless steel reactor. Effect of the support, Cu/Mn mole
ratio, heat treatment of the precursor and active component loading
were investigated. Highly active alumina supported Cu-Mn catalysts
for CO and VOCs oxidation were synthesized. The effect of
preparation conditions on the activity behavior of the catalysts was
discussed.
The synergetic interaction between copper and manganese species
increases the activity for complete oxidation over mixed catalysts.
Type of support, calcination temperature and active component
loading along with catalyst composition are important factors,
determining catalytic activity. Cu/Mn molar ratio of 1:5, heat
treatment at 450oC and 20 % active component loading are the best
compromise for production of active catalyst for simultaneous
combustion of CO, CH3OH and DME.
Abstract: Considering palm oil as non-drying oil owing to its
low iodine value, an attempt was taken to increase the unsaturation in
the fatty acid chains of palm oil for the preparation of alkyds. To
increase the unsaturation in the palm oil, sulphuric acid (SA) and
para-toluene sulphonic acid (PTSA) was used prior to alcoholysis for
the dehydration process. The iodine number of the oil samples was
checked for the unsaturation measurement by Wijs method. Alkyd
resin was prepared using the dehydrated palm oil by following
alcoholysis and esterification reaction. To improve the film properties
0.5wt.% multi-wall carbon nano tubes (MWCNTs) were used to
manufacture polymeric film. The properties of the resins were
characterized by various physico-chemical properties such as density,
viscosity, iodine value, saponification value, etc. Structural
elucidation was confirmed by Fourier transform of infrared
spectroscopy and proton nuclear magnetic resonance; surfaces of the
films were examined by field-emission scanning electron microscope.
In addition, pencil hardness and chemical resistivity was also
measured by using standard methods. The effect of enhancement of
the unsaturation in the fatty acid chain found significant and
motivational. The resin prepared with dehydrated palm oil showed
improved properties regarding hardness and chemical resistivity
testing. The incorporation of MWCNTs enhanced the thermal
stability and hardness of the films as well.
Abstract: Information technology and information systems are
currently at a tipping point. The digital age fundamentally transforms
a large number of industries in the ways they work. Lines between
business and technology blur. Researchers have acknowledged that
this is the time in which the IT/IS organisation needs to re-strategize
itself. In this paper, the author provides a structured review of the IS
and organisation design literature addressing the question of how the
digital age changes the design categories of an IT/IS organisation
design. The findings show that most papers just analyse single
aspects of either IT/IS relevant information or generic organisation
design elements but miss a holistic ‘big-picture’ onto an IT/IS
organisation design. This paper creates a holistic IT/IS organisation
design framework bringing together the IS research strand, the digital
strand and the generic organisation design strand. The research
identified four IT/IS organisation design categories (strategy,
structure, processes and people) and discusses the importance of two
additional categories (sourcing and governance). The authors findings
point to a first anchor point from which further research needs to be
conducted to develop a holistic IT/IS organisation design framework.
Abstract: In this paper, we investigate the effect of friendly
jamming power allocation strategies on the achievable average
secrecy rate over a bank of parallel fading wiretap channels.
We investigate the achievable average secrecy rate in parallel
fading wiretap channels subject to Rayleigh and Rician fading.
The achievable average secrecy rate, due to the presence of a
line-of-sight component in the jammer channel is also evaluated.
Moreover, we study the detrimental effect of correlation across the
parallel sub-channels, and evaluate the corresponding decrease in the
achievable average secrecy rate for the various fading configurations.
We also investigate the tradeoff between the transmission power
and the jamming power for a fixed total power budget. Our
results, which are applicable to current orthogonal frequency division
multiplexing (OFDM) communications systems, shed further light on
the achievable average secrecy rates over a bank of parallel fading
channels in the presence of friendly jammers.
Abstract: The paper presents a thermodynamic cycle analysis
for three turboshaft engines. The first cycle is a Brayton cycle,
describing the evolution of a classical turboshaft, based on the
Klimov TV2 engine. The other four cycles aim at approaching an
Ericsson cycle, by replacing the Brayton cycle adiabatic expansion in
the turbine by quasi-isothermal expansion. The maximum quasi-
Ericsson cycles temperature is set to a lower value than the maximum
Brayton cycle temperature, equal to the Brayton cycle power turbine
inlet temperature, in order to decrease the engine NOx emissions.
Also, the power/expansion ratio distribution over the stages of the gas
generator turbine is maintained the same. In two of the considered
quasi-Ericsson cycles, the efficiencies of the gas generator turbine, as
well as the power/expansion ratio distribution over the stages of the
gas generator turbine are maintained the same as for the reference
case, while for the other two cases, the efficiencies are increased in
order to obtain the same shaft power as in the reference case. For the
two cases respecting the first condition, both the shaft power and the
thermodynamic efficiency of the engine decrease, while for the other
two, the power and efficiency are maintained, as a result of assuming
new, more efficient gas generator turbines.
Abstract: In this paper, we discuss the performance of applying
hybrid spiral dynamic bacterial chemotaxis (HSDBC) optimisation
algorithm on an intelligent controller for a differential drive robot. A
unicycle class of differential drive robot is utilised to serve as a basis
application to evaluate the performance of the HSDBC algorithm. A
hybrid fuzzy logic controller is developed and implemented for the
unicycle robot to follow a predefined trajectory. Trajectories of
various frictional profiles and levels were simulated to evaluate the
performance of the robot at different operating conditions. Controller
gains and scaling factors were optimised using HSDBC and the
performance is evaluated in comparison to previously adopted
optimisation algorithms. The HSDBC has proven its feasibility in
achieving a faster convergence toward the optimal gains and resulted
in a superior performance.
Abstract: In this paper, a new design of spherical robotic system
based on the concepts of gimbal structure and gyro dynamics is
presented. Robots equipped with multiple wheels and complex
steering mechanics may increase the weight and degrade the energy
transmission efficiency. In addition, the wheeled and legged robots are
relatively vulnerable to lateral impact and lack of lateral mobility.
Therefore, the proposed robotic design uses a spherical shell as the
main body for ground locomotion, instead of using wheel devices.
Three spherical shells are structured in a similar way to a gimbal
device and rotate like a gyro system. The design and mechanism of the
proposed robotic system is introduced. In addition, preliminary results
of the dynamic model based on the principles of planar rigid body
kinematics and Lagrangian equation are included. Simulation results
and rig construction are presented to verify the concepts.
Abstract: Interaction of Schiff base complexes of Iron and
Manganese: Iron [N, N’ Bis (5- (triphenyl phosphonium methyl)
salicylidene) -1, 2 ethanediamine) chloride, [Fe Salen]Cl; Manganese
[N, N’ Bis (5- (triphenyl phosphonium methyl) salicylidene) -1, 2
ethanediamine) acetate, were investigated by spectroscopic and
isothermal titration calorimetry techniques (ITC).
The absorbance spectra of complexes have shown hyper and
hypochromism in the presence of DNA that is indication of
interaction of complexes with DNA. The linear dichroism (LD)
measurements confirmed the bending of DNA in the presence of
complexes.
Furthermore, Isothermal titration calorimetry experiments
approved that complexes bound to DNA on the base of both
electrostatic and hydrophobic interactions. More, ITC profile exhibits
the existence of two binding phases for the complexes. Antibacterial
activity of ligand and complexes were tested in vitro to evaluate their
activity against the gram positive and negative bacteria.
Abstract: Catalytic combustion of methane is imperative due to
stability of methane at low temperature. Methane (CH4), therefore,
remains unconverted in vehicle exhausts thereby causing greenhouse
gas GHG emission problem. In this study, heterogeneous catalysts of
palladium with bio-char (2 wt% Pd/Bc) and Al2O3 (2wt% Pd/ Al2O3)
supports were prepared by incipient wetness impregnation and then
subsequently tested for catalytic combustion of CH4. Support-porous
heterogeneous catalytic combustion (HCC) material were selected
based on factors such as surface area, porosity, thermal stability,
thermal conductivity, reactivity with reactants or products, chemical
stability, catalytic activity, and catalyst life. Sustainable and
renewable support-material of bio-mass char derived from palm shell
waste material was compared with those from the conventional
support-porous materials. Kinetic rate of reaction was determined for
combustion of methane on Palladium (Pd) based catalyst with Al2O3
support and bio-char (Bc). Material characterization was done using
TGA, SEM, and BET surface area. The performance test was
accomplished using tubular quartz reactor with gas mixture ratio of
3% methane and 97% air. The methane porous-HCC conversion was
carried out using online gas analyzer connected to the reactor that
performed porous-HCC. BET surface area for prepared 2 wt% Pd/Bc
is smaller than prepared 2wt% Pd/ Al2O3 due to its low porosity
between particles. The order of catalyst activity based on kinetic rate
on reaction of catalysts in low temperature was 2wt%
Pd/Bc>calcined 2wt% Pd/ Al2O3> 2wt% Pd/ Al2O3>calcined 2wt%
Pd/Bc. Hence agro waste material can successfully be utilized as an
inexpensive catalyst support material for enhanced CH4 catalytic
combustion.
Abstract: Adolescents with Autism Spectrum Disorders (ASD)
often experience social-communication difficulties that negatively
impact their social interactions with typical peers. However, unlike
other age and disability groups, there is little intervention research to
inform best practice for these students. One evidence-based strategy
for younger students with ASD is peer-mediated intervention (PMI).
PMI may be particularly promising for use with adolescents, as peers
are readily available and are natural experts for encouraging authentic
high school conversations. This paper provides a review of previous
research that evaluated the use of PMI to improve the socialcommunication
skills of students with ASD. Specific intervention
features associated with positive student outcomes are identified and
recommendations for future research are provided. Adolescents with
ASD are targeted due the critical importance of social conversation at
the high school level.
Abstract: To determine the potential of a low cost Irish
engineered timber product to replace high cost solid timber for use in
bending active structures such as gridshells a single Irish engineered
timber product in the form of orientated strand board (OSB) was
selected. A comparative study of OSB and solid timber was carried
out to determine the optimum properties that make a material suitable
for use in gridshells. Three parameters were identified to be relevant
in the selection of a material for gridshells. These three parameters
are the strength to stiffness ratio, the flexural stiffness of
commercially available sections, and the variability of material and
section properties. It is shown that when comparing OSB against
solid timber, OSB is a more suitable material for use in gridshells that
are at the smaller end of the scale and that have tight radii of
curvature. Typically, for solid timber materials, stiffness is used as an
indicator for strength and engineered timber is no different. Thus, low
flexural stiffness would mean low flexural strength. However, when
it comes to bending active gridshells, OSB offers a significant
advantage. By the addition of multiple layers, an increased section
size is created, thus endowing the structure with higher stiffness and
higher strength from initial low stiffness and low strength materials
while still maintaining tight radii of curvature. This allows OSB to
compete with solid timber on large scale gridshells. Additionally, a
preliminary sustainability study using a set of sustainability indicators
was carried out to determine the relative sustainability of building a
large-scale gridshell in Ireland with a primary focus on economic
viability but a mention is also given to social and environmental
aspects. For this, the Savill garden gridshell in the UK was used as
the functional unit with the sustainability of the structural roof
skeleton constructed from UK larch solid timber being compared
with the same structure using Irish OSB. Albeit that the advantages of
using commercially available OSB in a bending active gridshell are
marginal and limited to specific gridshell applications, further study
into an optimised engineered timber product is merited.
Abstract: In the past few decades, the field of chemistry
education has grown tremendously and researches indicated that after
traditional chemistry instruction students often lacked deep
conceptual understanding and failed to integrate their ideas into
coherent conceptual framework. For several concepts in chemistry,
students at all levels have demonstrated difficulty in changing their
initial perceptions. Their perceptions are most often wrong and don't
agree with correct scientific concepts. This study explored the
effectiveness of intervention discussion sections for a college general
chemistry course designed to apply research on students
preconceptions, knowledge integration and student explanation.
Three interventions discussions lasting three hours on bond energy
and spontaneity were done tested and intervention (treatment)
students’ performances were compared with that of control group
which did not use the experimental pedagogy. Results indicated that
this instruction which was capable of identifying students'
misconceptions, initial conceptions and integrating those ideas into
class discussion led to enhanced conceptual understanding and better
achievement for the experimental group.
Abstract: Nitrogen fertilizer is the most used and often the most
mismanaged nutrient input. Nitrogen management has tremendous
implications on crop productivity, quality and environmental
stewardship. Sufficient nitrogen is needed to optimum yield and
quality. Soil and in-season plant tissue testing for nitrogen status are
a time consuming and expensive process. Real time sensing of plant
nitrogen status can be a useful tool in managing nitrogen inputs. The
objectives of this project were to assess the reliability of remotely
sensed non-destructive plant nitrogen measurements compared to wet
chemistry data from sampled plant tissue, develop in-season nitrogen
recommendations based on remotely sensed data for improved
nitrogen use efficiency and assess the potential for determining yield
and quality from remotely sensed data. Very good correlations were
observed between early-season remotely sensed crop nitrogen status
and plant nitrogen concentrations and subsequent in-season fertilizer
recommendations. The transmittance/absorbance type meters gave
the most accurate readings. Early in-season fertilizer recommendation
would be to apply 40 kg nitrogen per hectare plus 15 kg nitrogen per
hectare for each unit difference measured with the SPAD meter
between the crop and reference area or 25 kg plus 13 kg per hectare
for each unit difference measured with the CCM 200. Once the crop
was sufficiently fertilized meter readings became inconclusive and
were of no benefit for determining nitrogen status, silage yield and
quality and grain yield and protein.
Abstract: Solid waste management in steel industry is broadly
classified in “4 Rs” i.e. reduce, reuse, recycle and restore the
materials. Reuse and recycling the entire solid waste generated in the
process of steel making is a viable solution in targeting a clean, green
and zero waste technology leading to sustainable development of the
steel industry. Solid waste management has gained importance in
steel industry in view of its uncertainty, volatility and speculation due
to world competitive standards, rising input costs, scarcity of raw
materials and solid waste generated like in other sectors. The
challenges that the steel Industry faces today are the requirement of a
sustainable development by meeting the needs of our present
generation without compromising the ability of future generations.
Technologies are developed not only for gainful utilization of solid
wastes in manufacture of conventional products but also for
conversion of same in to completely new products.
Abstract: In this paper we present the efficient parallel
implementation of elastoplastic problems based on the TFETI (Total
Finite Element Tearing and Interconnecting) domain decomposition
method. This approach allow us to use parallel solution and compute
this nonlinear problem on the supercomputers and decrease the
solution time and compute problems with millions of DOFs. In
our approach we consider an associated elastoplastic model with
the von Mises plastic criterion and the combination of linear
isotropic-kinematic hardening law. This model is discretized by
the implicit Euler method in time and by the finite element
method in space. We consider the system of nonlinear equations
with a strongly semismooth and strongly monotone operator. The
semismooth Newton method is applied to solve this nonlinear
system. Corresponding linearized problems arising in the Newton
iterations are solved in parallel by the above mentioned TFETI. The
implementation of this problem is realized in our in-house MatSol
packages developed in MatLab.
Abstract: The present work describes the implementation of the
Enhanced Collaborative Optimization (ECO) multilevel architecture
with a gradient-based optimization algorithm with the aim of
performing a multidisciplinary design optimization of a generic
unmanned aerial vehicle with morphing technologies. The concepts
of weighting coefficient and dynamic compatibility parameter are
presented for the ECO architecture. A routine that calculates the
aircraft performance for the user defined mission profile and vehicle’s
performance requirements has been implemented using low fidelity
models for the aerodynamics, stability, propulsion, weight, balance
and flight performance. A benchmarking case study for evaluating
the advantage of using a variable span wing within the optimization
methodology developed is presented.
Abstract: The building sector is responsible, in many
industrialized countries, for about 40% of the total energy
requirements, so it seems necessary to devote some efforts in this
area in order to achieve a significant reduction of energy
consumption and of greenhouse gases emissions.
The paper presents a study aiming at providing a design
methodology able to identify the best configuration of the system
building/plant, from a technical, economic and environmentally point
of view.
Normally, the classical approach involves a building's energy
loads analysis under steady state conditions, and subsequent selection
of measures aimed at improving the energy performance, based on
previous experience made by architects and engineers in the design
team. Instead, the proposed approach uses a sequence of two wellknown
scientifically validated calculation methods (TRNSYS and
RETScreen), that allow quite a detailed feasibility analysis.
To assess the validity of the calculation model, an existing,
historical building in Central Italy, that will be the object of
restoration and preservative redevelopment, was selected as a casestudy.
The building is made of a basement and three floors, with a
total floor area of about 3,000 square meters.
The first step has been the determination of the heating and
cooling energy loads of the building in a dynamic regime by means,
which allows simulating the real energy needs of the building in
function of its use. Traditional methodologies, based as they are on
steady-state conditions, cannot faithfully reproduce the effects of
varying climatic conditions and of inertial properties of the structure.
With this model is possible to obtain quite accurate and reliable
results that allow identifying effective combinations building-HVAC
system.
The second step has consisted of using output data obtained as
input to the calculation model, which enables to compare different
system configurations from the energy, environmental and financial
point of view, with an analysis of investment, and operation and
maintenance costs, so allowing determining the economic benefit of
possible interventions.
The classical methodology often leads to the choice of
conventional plant systems, while our calculation model provides a
financial-economic assessment for innovative energy systems and
low environmental impact.
Computational analysis can help in the design phase, particularly
in the case of complex structures with centralized plant systems, by
comparing the data returned by the calculation model for different
design options.
Abstract: Comparing other methods of waste water treatment,
constructed wetlands are one of the most fascinating practices
because being a natural process they are eco-friendly have low
construction and maintenance cost and have considerable capability
of wastewater treatment. The current research was focused mainly on
comparison of Ranunculus muricatus and Typha latifolia as wetland
plants for domestic wastewater treatment by designing and
constructing efficient pilot scale horizontal subsurface flow
mesocosms. Parameters like chemical oxygen demand, biological
oxygen demand, phosphates, sulphates, nitrites, nitrates, and
pathogenic indicator microbes were studied continuously with
successive treatments. Treatment efficiency of the system increases
with passage of time and with increase in temperature. Efficiency of
T. latifolia planted setups in open environment was fairly good for
parameters like COD and BOD5 which was showing reduction up to
82.5% for COD and 82.6% for BOD5 while DO was increased up to
125%. Efficiency of R. muricatus vegetated setup was also good but
lowers than that of T. latifolia planted showing 80.95% removal of
COD and BOD5. Ranunculus muricatus was found effective in
reducing bacterial count in wastewater. Both macrophytes were
found promising in wastewater treatment.
Abstract: Knowledge is considered as an important asset which
can help organizations to create competitive advantage. The necessity
of taking care of these assets is more important in these days – in
days of turbulent changes in business environment. Knowledge could
facilitate adaption to constant changes. The aim of this paper is to
describe how the knowledge sharing can be supported in the
manufacturing companies. The methods of case studies and grounded
theory were used to present information gained by carrying out semistructured
interviews. Results show that knowledge sharing is
supported in very similar ways in respondent companies.