Abstract: This work presents the experimental results obtained
at a pilot plant which works with a slow, wet and catalytic pyrolysis
process of dry fowl manure. This kind of process mainly consists in
the cracking of the organic matrix and in the following reaction of
carbon with water, which is either already contained in the organic
feed or added, to produce carbon monoxide and hydrogen. Reactions
are conducted in a rotating reactor maintained at a temperature of
500°C; the required amount of water is about 30% of the dry organic
feed. This operation yields a gas containing about 59% (on a volume
basis) of hydrogen, 17% of carbon monoxide and other products such
as light hydrocarbons (methane, ethane, propane) and carbon
monoxide in lesser amounts. The gas coming from the reactor can be
used to produce not only electricity, through internal combustion
engines, but also heat, through direct combustion in industrial
boilers. Furthermore, as the produced gas is devoid of both solid
particles and pollutant species (such as dioxins and furans), the
process (in this case applied to fowl manure) can be considered as an
optimal way for the disposal and the contemporary energetic
valorization of organic materials, in such a way that is not damaging
to the environment.
Abstract: In metal cutting industries, mathematical/statistical
models are typically used to predict tool replacement time. These
off-line methods usually result in less than optimum replacement
time thereby either wasting resources or causing quality problems.
The few online real-time methods proposed use indirect measurement
techniques and are prone to similar errors. Our idea is based on
identifying the optimal replacement time using an electronic nose to
detect the airborne compounds released when the tool wear reaches
to a chemical substrate doped into tool material during the
fabrication. The study investigates the feasibility of the idea, possible
doping materials and methods along with data stream mining
techniques for detection and monitoring different phases of tool
wear.
Abstract: The composite materials were prepared by sawdust, cassava starch and natural rubber latex (NR). The mixtures of 15%w/v gelatinized cassava starch and 15%w/v PVOH were used as the binder of these composite materials. The concentrated rubber latex was added to the mixtures. They were mixed rigorously to the treated sawdust in the ratio of 70:30 until achive uniform dispersion. The batters were subjected to the hot compression moulding at the temperature of 160°C and 3,000 psi pressure for 5 min. The experimental results showed that the mechanical properties of composite materials, which contained the gelatinized cassava starch and PVOH in the ratio of 2:1, 20% NR latex by weight of the dry starch and treated sawdust with 5%NaOH or 1% BPO, were the best. It contributed the maximal compression strength (341.10 + 26.11 N), puncture resistance (8.79 + 0.98 N/mm2) and flexural strength (3.99 + 0.72N/mm2). It is also found that the physicochemical and mechanical properties of composites strongly depends on the interface quality of sawdust, cassava starch and NR latex.
Abstract: A judicious choice of insert material, tool geometry and
cutting conditions can make hard turning produce better surfaces than
grinding. In the present study, an attempt has been made to
investigate the effect of cutting tool materials on cutting forces (feed
force, thrust force and cutting force) in finish hard turning of AISI
D2 cold work tool steel. In conclusion of the results obtained with a
constant depth of cut and feed rate, it is important to note that cutting
force is directly affected by cutting tool material.
Abstract: One of the main problems of suspended cable structures is initial shape change under the action of non uniform load. The problem can be solved by increasing of weight of construction or by using of prestressing. But this methods cause increasing of materials consumption of suspended cable structure. The cable truss usage is another way how the problem of shape change under the action of non uniform load can be fixed. The cable trusses with the vertical and inclined suspensions, cross web and single cable were analyzed as the main load-bearing structures of suspension bridge. It was shown, that usage of cable truss allows to reduce the vertical displacements up to 32% in comparison with the single cable in case of non uniformly distributed load. In case of uniformly distributed load single cable is preferable.
Abstract: The present investigation was aimed to develop methodology for the standardization of Marichyadi Vati and its raw materials. Standardization was carried using systematic Pharmacognostical and physicochemical parameters as per WHO guidelines. The detailed standardization of Marichyadi Vati, it is concluded that there are no major differences prevailed in the quality of marketed products and laboratory samples of Marichyadi Vati. However, market samples showed slightly better amount of Piperine than the laboratory sample by both methods. This is the first attempt to generate complete set of standards required for the Marichyadi Vati.
Abstract: Chitosan is an attractive polysaccharide obtained by
deacetylation of an abundant natural biopolymer called chitin. Chitin
and chitosan are excellent materials. To improve the potential of
chitin and chitosan modification is needed. In the present study,
grafting of maleic acid on to chitosan by cerium ammonium nitrate in
acetic acid solution was investigated with use of a microwave and
reflux system. The grafted chitosan was characterized by using a
Fourier-transform infrared spectrometry. The solubility and swelling
behavior of grafted chitosans were determined in acetate buffer (pH
3.6), citrophosphate buffer (pH 5.6 and pH 7.0), and boric buffer (pH
9.2) solutions. The sample obtained by microwave system with use of
a chitosan/maleic anhydride/ceric ammonium nitrate 0.2/3.922/0.99
gram of raw material within 30 minute showed the maximum
swelling ratio (13.6) in boric buffer solution.
Abstract: Reinforced Concrete (RC) structures strengthened
with fiber reinforced polymer (FRP) lack in thermal resistance under
elevated temperatures in the event of fire. This phenomenon led to
the lining of strengthened concrete with thin high performance
cementitious composites (THPCC) to protect the substrate against
elevated temperature. Elevated temperature effects on THPCC, based
on different cementitious materials have been studied in the past but
high-alumina cement (HAC)-based THPCC have not been well
characterized. This research study will focus on the THPCC based on
HAC replaced by 60%, 70%, 80% and 85% of ground granulated
blast furnace slag (GGBS). Samples were evaluated by the
measurement of their mechanical strength (28 & 56 days of curing)
after exposed to 400°C, 600°C and 28°C of room temperature for
comparison and corroborated by their microstructure study. Results
showed that among all mixtures, the mix containing only HAC
showed the highest compressive strength after exposed to 600°C as
compared to other mixtures. However, the tensile strength of THPCC
made of HAC and 60% GGBS content was comparable to the
THPCC with HAC only after exposed to 600°C. Field emission
scanning electron microscopy (FESEM) images of THPCC
accompanying Energy Dispersive X-ray (EDX) microanalysis
revealed that the microstructure deteriorated considerably after
exposure to elevated temperatures which led to the decrease in
mechanical strength.
Abstract: In this paper authors presented the research of textile electroconductive materials, which can be used to construction
sensory textronic shirt to breath frequency measurement.
The full paper also will present results of measurements carried
out on unique measurement stands.
Abstract: In modern agriculture, polymeric hydrogels are
known as a component able to hold an amount of water due to their
3-dimensional network structure and their tendency to absorb water
in humid environments. In addition, these hydrogels are able to
controllably release the fertilisers and pesticides loaded in them.
Therefore, they deliver these materials to the plants' roots and help
them with growing. These hydrogels also reduce the pollution of
underground water sources by preventing the active components
from leaching. In this study, sIPN acrylamide based hydrogels are
synthesised by using acrylamide free radical, potassium acrylate, and
linear polyvinyl alcohol. Ammonium nitrate is loaded in the hydrogel
as the fertiliser. The effect of various amounts of monomers and
linear polymer, measured in molar ratio, on the swelling rate,
equilibrium swelling, and release of ammonium nitrate is studied.
Abstract: We measured the major and trace element contents
and Rb-Sr isotopic compositions of 12 tektites from the Maoming
area, Guandong province (south China). All the samples studied are
splash-form tektites which show pitted or grooved surfaces with
schlieren structures on some surfaces. The trace element ratios Ba/Rb
(avg. 4.33), Th/Sm (avg. 2.31), Sm/Sc (avg. 0.44), Th/Sc (avg. 1.01) ,
La/Sc (avg. 2.86), Th/U (avg. 7.47), Zr/Hf (avg. 46.01) and the rare
earth elements (REE) contents of tektites of this study are similar to the
average upper continental crust. From the chemical composition, it is
suggested that tektites in this study are derived from similar parental
terrestrial sedimentary deposit which may be related to post-Archean
upper crustal rocks. The tektites from the Maoming area have high
positive εSr(0) values-ranging from 176.9~190.5 which indicate that
the parental material for these tektites have similar Sr isotopic
compositions to old terrestrial sedimentary rocks and they were not
dominantly derived from recent young sediments (such as soil or
loess). The Sr isotopic data obtained by the present study support the
conclusion proposed by Blum et al. (1992)[1] that the depositional age
of sedimentary target materials is close to 170Ma (Jurassic). Mixing
calculations based on the model proposed by Ho and Chen (1996)[2]
for various amounts and combinations of target rocks indicate that the
best fit for tektites from the Maoming area is a mixture of 40% shale,
30% greywacke, 30% quartzite.
Abstract: New lead-free ferroelectric relaxor ceramics were
prepared by conventional solid-state synthesis in the BaTiO3-Bi2O3-
Y2O3 systems. Some of these ceramics present a ferroelectric relaxor
with transition temperature close to room temperature. These new
materials are very interesting for applications and can replace leadbased
ceramic to prevent the toxic pollutions during the preparation
state. In the other hand, the energy band diagram shows the
potentiality of these compounds for the solar energy conversion.
Thus, some compositions have been tested successfully for H2
production upon visible light. The best activity occurs in alkaline
media with a rate evolution of about 0.15 mL g-1 mn-1 and a quantum
yield of 1% under polychromatic light.
Abstract: In this paper, a study on the modes of collapse of
compress- expand members are presented. Compress- expand member
is a compact, multiple-combined cylinders, to be proposed as energy
absorbers. Previous studies on the compress- expand member have
clarified its energy absorption efficiency, proposed an approximate
equation to describe its deformation characteristics and also
highlighted the improvement that it has brought. However, for the
member to be practical, the actual range of geometrical dimension that
it can maintain its applicability must be investigated. In this study,
using a virtualized materials that comply the bilinear hardening law,
Finite element Method (FEM) analysis on the collapse modes of
compress- expand member have been conducted. Deformation maps
that plotted the member's collapse modes with regards to the member's
geometric and material parameters were then presented in order to
determine the dimensional range of each collapse modes.
Abstract: The polyfunctional and highly reactive bio-polymer,
the chitosan was first regioselectively converted into dialkylated
chitosan using dimsyl anionic solution(NaH in DMSO) and
bromodecane after protecting amino groups by phthalic anhydride.
The dibenzo-18-crown-6-ether, on the other hand, was converted into
its carbonyl derivatives via Duff reaction prior to incorporate into
chitosan by Schiff base formation. Thus formed diformylated
dibenzo-18-crown-6-ether was condensed with lipophilic chitosan to
prepare the novel solvent extraction reagent. The products were
characterized mainly by IR and 1H-NMR. Hence, the multidentate
crown ether-embedded polyfunctional bio-material was tested for
extraction of Pd(II) and Pt(IV) in aqueous solution.
Abstract: We report the electronic structure and optical
properties of NdF3 compound. Our calculations are based on density
functional theory (DFT) using the full potential linearized augmented
plane wave (FPLAPW) method with the inclusion of spin orbit
coupling. We employed the local spin density approximation (LSDA)
and Coulomb-corrected local spin density approximation, known for
treating the highly correlated 4f electrons properly, is able to
reproduce the correct insulating ground state. We find that the
standard LSDA approach is incapable of correctly describing the
electronic properties of such materials since it positions the f-bands
incorrectly resulting in an incorrect metallic ground state. On the
other hand, LSDA + U approximation, known for treating the highly
correlated 4f electrons properly, is able to reproduce the correct
insulating ground state. Interestingly, however, we do not find any
significant differences in the optical properties calculated using
LSDA, and LSDA + U suggesting that the 4f electrons do not play a
decisive role in the optical properties of these compounds. The
reflectivity for NdF3 compound stays low till 7 eV which is
consistent with their large energy gaps. The calculated energy gaps
are in good agreement with experiments. Our calculated reflectivity
compares well with the experimental data and the results are analyzed
in the light of band to band transitions.
Abstract: Topology Optimization is a defined as the method of
determining optimal distribution of material for the assumed design
space with functionality, loads and boundary conditions [1].
Topology optimization can be used to optimize shape for the
purposes of weight reduction, minimizing material requirements or
selecting cost effective materials [2]. Topology optimization has been
implemented through the use of finite element methods for the
analysis, and optimization techniques based on the method of moving
asymptotes, genetic algorithms, optimality criteria method, level sets
and topological derivatives. Case study of Typical “Fuselage design"
is considered for this paper to explain the benefits of Topology
Optimization in the design cycle. A cylindrical shell is assumed as
the design space and aerospace standard pay loads were applied on
the fuselage with wing attachments as constraints. Then topological
optimization is done using Finite Element (FE) based software. This
optimization results in the structural concept design which satisfies
all the design constraints using minimum material.
Abstract: Waste lubricating oil re-refining adsorption process by
different adsorbent materials was investigated. Adsorbent materials
such as oil adsorbent, egg shale powder, date palm kernel powder,
and acid activated date palm kernel powder were used. The
adsorption process over fixed amount of adsorbent at ambient
conditions was investigated. The adsorption/extraction process was
able to deposit the asphaltenic and metallic contaminants from the
waste oil to lower values. It was found that the date palm kernel
powder with contact time of 4 h was able to give the best conditions
for treating the waste oil. The recovered solvent could be also reused.
It was also found that the activated bentonite gave the best
physical properties followed by the date palm kernel powder.
Abstract: These Nowadays the explosion of bombs or explosive
materials such as gas and oil near or inside the buildings cause some
losses in installations and building components. This has made the
engineers to make the buildings and their components resistance
against the effects of explosion. These activities lead to provide
regulations and different methods. The above regulations are mostly
focused on the explosion effects resulting from the vehicles around
the buildings. Therefore, the explosion resulting from the vehicles
outside the buildings will be studied in this research.
In the present study, the main goals are to investigate the
explosion load effects on the structures located on the piles with the
specific quantity of plasticity and observing the permissible response
of these structures. The concentrated mass system and the spring with
two degree of freedom will be used to study the structural system.
Abstract: The 20th century has brought much development to the practice of Architecture worldwide, and technology has bridged inhabitation limits in many regions of the world with high levels of comfort and conveniences, most times at high costs to the environment. Throughout the globe, the tropical countries are being urbanized at an unprecedented rate and housing has become a major issue worldwide, in light of increased demand and lack of appropriate infra-structure and planning. Buildings and urban spaces designed in tropical cities have mainly adopted external concepts that in most cases do not fit the needs of the inhabitants living in such harsh climatic environment, and when they do, do so at high financial, environmental and cultural costs. Traditional architectural practices can provide valuable understanding on how self-reliance and autonomy of construction can be reinforced in rural-urban tropical environments. From traditional housing knowledge, it is possible to derive lessons for the development of new construction materials that are affordable, environmentally friendly, culturally acceptable and accesible to all.Specifically to the urban context, such solutions are of outmost importance, given the needs to a more democratic society, where access to housing is considered high in the agenda for development. Traditional or rural constructions are also ongoing through extensive changes eventhough they have mostly adopted climate-responsive building practices relying on local resources (with minimum embodied energy) and energy (for comfort and quality of life). It is important to note that many of these buildings can actually be called zero-energy, and hold potential answers to enable transition from high energy, high cost, low comfort urban habitations to zero/low energy habitations with high quality urban livelihood. Increasing access to modern urban lifestyels have also an effect on the aspirations from people in terms of performance, comfort and convenience in terms of their housing and the way it is produced and used. These aspirations are resulting in transitions from localresource dependent habitations- to non-local resource based highenergy urban style habitations. And such transitions are resulting in the habitations becoming increasingly unsuited to the local climatic conditions with increasing discomfort, ill-health, and increased CO2 emissions and local environmental disruption. This research studies one specific transition group in the context of 'water communities' in tropical-equatorial regions: Ribeirinhos housing typology (Amazonas, Brazil). The paper presents the results of a qualitative sustainability assessment of the housing typologies under transition, found at the Ribeirinhos communities.
Abstract: Nanostructured materials have attracted many
researchers due to their outstanding mechanical and physical
properties. For example, carbon nanotubes (CNTs) or carbon
nanofibres (CNFs) are considered to be attractive reinforcement
materials for light weight and high strength metal matrix composites.
These composites are being projected for use in structural
applications for their high specific strength as well as functional
materials for their exciting thermal and electrical characteristics. The
critical issues of CNT-reinforced MMCs include processing
techniques, nanotube dispersion, interface, strengthening mechanisms
and mechanical properties. One of the major obstacles to the effective
use of carbon nanotubes as reinforcements in metal matrix
composites is their agglomeration and poor distribution/dispersion
within the metallic matrix. In order to tap into the advantages of the
properties of CNTs (or CNFs) in composites, the high dispersion of
CNTs (or CNFs) and strong interfacial bonding are the key issues
which are still challenging. Processing techniques used for synthesis
of the composites have been studied with an objective to achieve
homogeneous distribution of carbon nanotubes in the matrix.
Modified mechanical alloying (ball milling) techniques have emerged
as promising routes for the fabrication of carbon nanotube (CNT)
reinforced metal matrix composites. In order to obtain a
homogeneous product, good control of the milling process, in
particular control of the ball movement, is essential. The control of
the ball motion during the milling leads to a reduction in grinding
energy and a more homogeneous product. Also, the critical inner
diameter of the milling container at a particular rotational speed can
be calculated. In the present work, we use conventional and modified
mechanical alloying to generate a homogenous distribution of 2 wt.
% CNT within Al powders. 99% purity Aluminium powder (Acros,
200mesh) was used along with two different types of multiwall
carbon nanotube (MWCNTs) having different aspect ratios to
produce Al-CNT composites. The composite powders were processed
into bulk material by compaction, and sintering using a cylindrical
compaction and tube furnace. Field Emission Scanning electron
microscopy (FESEM), X-Ray diffraction (XRD), Raman
spectroscopy and Vickers macro hardness tester were used to
evaluate CNT dispersion, powder morphology, CNT damage, phase
analysis, mechanical properties and crystal size determination.
Despite the success of ball milling in dispersing CNTs in Al powder,
it is often accompanied with considerable strain hardening of the Al
powder, which may have implications on the final properties of the
composite. The results show that particle size and morphology vary
with milling time. Also, by using the mixing process and sonication
before mechanical alloying and modified ball mill, dispersion of the
CNTs in Al matrix improves.