Abstract: Agricultural residue such as oil palm fronds (OPF) is
cheap, widespread and available throughout the year. Hemicelluloses
extracted from OPF can be hydrolyzed to their monomers and used in
production of xylooligosaccharides (XOs). The objective of the
present study was to optimize the enzymatic hydrolysis process of
OPF hemicellulose by varying pH, temperature, enzyme and substrate
concentration for production of XOs. Hemicelluloses was extracted
from OPF by using 3 M potassium hydroxide (KOH) at temperature of
40°C for 4 hrs and stirred at 400 rpm. The hemicellulose was then
hydrolyzed using Trichoderma longibrachiatum xylanase at different
pH, temperature, enzyme and substrate concentration. XOs were
characterized based on reducing sugar determination. The optimum
conditions to produced XOs from OPF hemicellulose was obtained at
pH 4.6, temperature of 40°C , enzyme concentration of 2 U/mL and
2% substrate concentration. The results established the suitability of
oil palm fronds as raw material for production of XOs.
Abstract: The coastal sediments of West Port of Malaysia was monitored from Nov. 2009 to Oct. 2010 to assess spatial distribution of heavy metals As, Cu, Cd, Cr, Hg, Ni, Zn and Pb. Sediment samples were collected from 10 stations in dry and rainy season in West Port. The range concentrations measured (Mg/g dry weight ) were from 23.4 to 98.3 for Zn, 22.3 to 80 for Pb, 7.4 to 27.6 Cu, 0.244 to 3.53 for Cd, 7.2 to 22.2 for Ni, 20.2 to 162 for As, 0.11 to 0.409 for Hg and 11.5 to 61.5 for Cr. The geochemical indexes used in this study were Geoaccumulation (Igeo), Contamination Factor (CF) and Pollution Load Index (PLI); these indexes were used to evaluate the levels of sediment contaminations. The results of these indexes show that, the status of West Port sediment quality are moderately polluted by heavy metals except in arsenic which shows the high level of pollution.
Abstract: Simultaneous effects of temperature, immersion time, salt concentration, sucrose concentration, pressure and convective dryer temperature on the combined osmotic dehydration - convective drying of edible button mushrooms were investigated. Experiments were designed according to Central Composite Design with six factors each at five different levels. Response Surface Methodology (RSM) was used to determine the optimum processing conditions that yield maximum water loss and rehydration ratio and minimum solid gain and shrinkage in osmotic-convective drying of edible button mushrooms. Applying surfaces profiler and contour plots optimum operation conditions were found to be temperature of 39 °C, immersion time of 164 min, salt concentration of 14%, sucrose concentration of 53%, pressure of 600 mbar and drying temperature of 40 °C. At these optimum conditions, water loss, solid gain, rehydration ratio and shrinkage were found to be 63.38 (g/100 g initial sample), 3.17 (g/100 g initial sample), 2.26 and 7.15%, respectively.
Abstract: The photochemical and photo-Fenton oxidation of 1,3-dichloro-2-propanol was performed in a batch reactor, at room temperature, using UV radiation, H2O2 as oxidant, and Fenton-s reagent. The effect of the oxidative agent-s initial concentration was investigated as well as the effect of the initial concentration of Fe(II) by following the target compound degradation, the total organic carbon removal and the chloride ion production. Also, from the kinetic analysis conducted and proposed reaction scheme it was deduced that the addition of Fe(II) significantly increases the production and the further oxidation of the chlorinated intermediates.
Abstract: The objectives were to identify cyanide-degrading
bacteria and study cyanide removal efficiency. Agrobacterium
tumefaciens SUTS 1 was isolated. This is a new strain of
microorganisms for cyanide degradation. The maximum growth rate
of SUTS 1 obtained 4.7 × 108 CFU/ml within 4 days. The cyanide
removal efficiency was studied at 25, 50, and 150 mg/L cyanide. The
residual cyanide, ammonia, nitrate, nitrite, pH, and cell counts were
analyzed. At 25 and 50 mg/L cyanide, SUTS 1 obtained similar
removal efficiency approximately 87.50%. At 150 mg/L cyanide,
SUTS 1 enhanced the cyanide removal efficiency up to 97.90%. Cell
counts of SUTS 1 increased when the cyanide concentration was set
at lower. The ammonia increased when the removal efficiency
increased. The nitrate increased when the ammonia decreased but the
nitrite did not detect in all experiments. pH values also increased
when the cyanide concentrations were set at higher.
Abstract: Three dimensional simulations are carried out to estimate the effect of wind direction, wind speed and geometry on the flow and dispersion of vehicular pollutant in a street canyon. The pollutant sources are motor vehicles passing between the two buildings. Suitable emission factors for petrol and diesel vehicles at varying vehicle speed are used for the estimation of the rate of emission from the streets. The dispersion of automobile pollutant released from the street is simulated by introducing vehicular emission source term as a fixed-flux boundary condition at the ground level over the road. The emission source term is suitably calculated by adopting emission factors from literature for varying conditions of street traffic. It is observed that increase in wind angle disturbs the symmetric pattern of pollution distribution along the street length. The concentration increases in the far end of the street as compared to the near end.
Abstract: The increasing interest in plant sterol enriched foods
is due to the fact that they reduce blood cholesterol concentrations
without adverse side effects. In this context, enriched foods with
phytosterols may be helpful in protecting population against
atherosclerosis and cardiovascular diseases. The aim of the present
work was to evaluate in a population of Viseu, Portugal, the
consumption habits low-fat, plant sterol-enriched yoghurt. For this
study, 577 inquiries were made and the sample was randomly
selected for people shopping in various supermarkets. The
preliminary results showed that the biggest consumers of these
products were women aged 45 to 65 years old. Most of the people
who claimed to buy these products consumed them once a day. Also,
most of the consumers under antidyslipidemic therapeutics noticed
positive effects on hypercholesterolemia.
Abstract: The nanosized polymeric micelles release the drug
due to acoustic cavitation, which is enhanced in dual frequency
ultrasonic fields. In this study, adult female Balb/C mice were
transplanted with spontaneous breast adenocarcinoma tumors and
were injected with a dose of 1.3 mg/kg doxorubicin in one of three
forms: free doxorubicin, micellar doxorubicin without sonication and
micellar doxorubicin with sonication. To increase cavitation yield,
the tumor region was sonicated with low level dual frequency of 3
MHz and 28 kHz. The animals were sacrificed 24 h after injection,
and their tumor, heart, spleen, liver, kidneys and plasma were
separated and homogenized. The drug content in their tumor, heart,
spleen, liver, kidneys and plasma was determined using tissue
fluorimetry. The results show that in the group that received micellar
doxorubicin with sonication, the drug concentration in the tumor
tissue was nine and three times higher than in the free doxorubicin
group and the micellar doxorubicin without sonication group,
respectively. In the micellar doxorubicin with sonication group, the
drug concentration in other tissues was lower than other groups
(p
Abstract: The removal of hydrogen sulphide is required for reasons of health, odour problems, safety and corrosivity problems. The means of removing hydrogen sulphide mainly depend on its concentration and kind of medium to be purified. The paper deals with a method of hydrogen sulphide removal from the air by its catalytic oxidation to elemental sulphur with the use of Fe-EDTA complex. The possibility of obtaining fibrous filtering materials able to remove small concentrations of H2S from the air were described. The base of these materials is fibrous ion exchanger with Fe(III)- EDTA complex immobilized on their functional groups. The complex of trivalent iron converts hydrogen sulphide to elemental sulphur. Bivalent iron formed in the reaction is oxidized by the atmospheric oxygen, so complex of trivalent iron is continuously regenerated and the overall process can be accounted as pseudocatalytic. In the present paper properties of several fibrous catalysts based on ion exchangers with different chemical nature (weak acid,weak base and strong base) were described. It was shown that the main parameters affecting the process of catalytic oxidation are:concentration of hydrogen sulphide in the air, relative humidity of the purified air, the process time and the content of Fe-EDTA complex in the fibres. The data presented show that the filtering layers with anion exchange package are much more active in the catalytic processes of hydrogen sulphide removal than cation exchanger and inert materials. In the addition to the nature of the fibres relative air humidity is a critical factor determining efficiency of the material in the air purification from H2S. It was proved that the most promising carrier of the Fe-EDTA catalyst for hydrogen sulphide oxidation are Fiban A-6 and Fiban AK-22 fibres.
Abstract: In this study, aerobic digestion of tannery industry
wastewater was carried out using mixed culture obtained from
common effluent treatment plant treating tannery wastewater. The
effect of pH, temperature, inoculum concentration, agitation speed
and initial substrate concentration on the reduction of organic matters
were found. The optimum conditions for COD reduction was found
to be pH - 7 (60%), temperature - 30ÔùªC (61%), inoculum
concentration - 2% (61%), agitation speed - 150rpm (65%) and initial
substrate concentration - 1560 mg COD/L (74%). Kinetics studies
were carried by using Monod model, First order, Diffusional model
and Singh model. From the results it was found that the Monod
model suits well for the degradation of tannery wastewater using
mixed microbial consortium.
Abstract: In the present study Schwertmannite (an iron oxide
hydroxide) is selected as an adsorbent for defluoridation of water.
The adsorbent was prepared by wet chemical process and was
characterized by SEM, XRD and BET. The fluoride adsorption
efficiency of the prepared adsorbent was determined with respect to
contact time, initial fluoride concentration, adsorbent dose and pH of
the solution. The batch adsorption data revealed that the fluoride
adsorption efficiency was highly influenced by the studied factors.
Equilibrium was attained within one hour of contact time indicating
fast kinetics and the adsorption data followed pseudo second order
kinetic model. Equilibrium isotherm data fitted to both Langmuir and
Freundlich isotherm models for a concentration range of 5-30 mg/L.
The adsorption system followed Langmuir isotherm model with
maximum adsorption capacity of 11.3 mg/g. The high adsorption
capacity of Schwertmannite points towards the potential of this
adsorbent for fluoride removal from aqueous medium.
Abstract: In this research, CaO-ZnO catalysts (with various
Ca:Zn atomic ratios of 1:5, 1:3, 1:1, and 3:1) prepared by incipientwetness
impregnation (IWI) and co-precipitation (CP) methods were
used as a catalyst in the transesterification of palm oil with methanol
for biodiesel production. The catalysts were characterized by several
techniques, including BET method, CO2-TPD, and Hemmett
Indicator. The effects of precursor concentration, and calcination
temperature on the catalytic performance were studied under reaction
conditions of a 15:1 methanol to oil molar ratio, 6 wt% catalyst,
reaction temperature of 60°C, and reaction time of 8 h. At Ca:Zn
atomic ratio of 1:3 gave the highest FAME value owing to a basic
properties and surface area of the prepared catalyst.
Abstract: This study was conducted to evaluate factors
regulating groundwater quality in an area with agriculture as main
use. Under this study twelve groundwater samples have been
collected from Padra taluka, Dabhoi taluka and Savli taluka of
Vadodara district. Groundwater samples were chemically analyzed
for major physicochemical parameter in order to understand the
different geochemical processes affecting the groundwater quality.
The analytical results shows higher concentration of total dissolved
solids (16.67%), electrical conductivity (25%) and magnesium
(8.33%) for pre monsoon and total dissolved solids (16.67%),
electrical conductivity (33.3%) and magnesium (8.33%) for post
monsoon which indicates signs of deterioration as per WHO and BIS
standards. On the other hand, 50% groundwater sample is unsuitable
for irrigation purposes based on irrigation quality parameters. The
study revealed that application of fertilizer for agricultural
contributing the higher concentration of ions in aquifer of Vadodara
district.
Abstract: Fecal coliform bacteria are widely used as indicators of
sewage contamination in surface water. However, there are some
disadvantages in these microbial techniques including time consuming
(18-48h) and inability in discriminating between human and animal
fecal material sources. Therefore, it is necessary to seek a more
specific indicator of human sanitary waste. In this study, the feasibility
was investigated to apply caffeine and human pharmaceutical
compounds to identify the human-source contamination. The
correlation between caffeine and fecal coliform was also explored.
Surface water samples were collected from upstream, middle-stream
and downstream points respectively, along Rochor Canal, as well as 8
locations of Marina Bay. Results indicate that caffeine is a suitable
chemical tracer in Singapore because of its easy detection (in the range
of 0.30-2.0 ng/mL), compared with other chemicals monitored.
Relative low concentrations of human pharmaceutical compounds (<
0.07 ng/mL) in Rochor Canal and Marina Bay water samples make
them hard to be detected and difficult to be chemical tracer. However,
their existence can help to validate sewage contamination. In addition,
it was discovered the high correlation exists between caffeine
concentration and fecal coliform density in the Rochor Canal water
samples, demonstrating that caffeine is highly related to the
human-source contamination.
Abstract: The halophilic proteinase showed a maximal activity
at 50°C and pH 9~10, in 20% NaCl and was highly stabilized by
NaCl. It was able to hydrolyse natural actomyosin (NAM), collagen
and anchovy protein. For NAM hydrolysis, the myosin heavy chain
was completely digested by halophilic proteinase as evidenced by the
lowest band intensity remaining, but partially hydrolysed actin. The
SR5-3 proteinase was also capable hydrolyzing two major
components of collagen, β- and α-compounds, effectively. The
degree of hydrolysis (DH) of the halophilic proteinase and
commercial proteinases (Novozyme, Neutrase, chymotrypsin and
Flavourzyme) on the anchovy protein, were compared, and it was
found that the proteinase showed a greater degree of hydrolysis
towards anchovy protein than that from commercial proteinases. DH
of halophilic proteinase was sharply enhanced according to the
increase in the concentration of enzyme from 0.035 U to 0.105 U.
The results warranting that the acceleration of the production of fish
sauce with higher quality, may be achieved by adding of the
halophilic proteinase from this bacterium.
Abstract: Traffic Density provides an indication of the level of
service being provided to the road users. Hence, there is a need to
study the traffic flow characteristics with specific reference to
density in detail. When the length and speed of the vehicles in a
traffic stream vary significantly, the concept of occupancy, rather
than density, is more appropriate to describe traffic concentration.
When the concept of occupancy is applied to heterogeneous traffic
condition, it is necessary to consider the area of the road space and
the area of the vehicles as the bases. Hence, a new concept named,
'area-occupancy' is proposed here. It has been found that the
estimated area-occupancy gives consistent values irrespective of
change in traffic composition.
Abstract: Simultaneous effects of temperature, immersion time, salt concentration, sucrose concentration, pressure and convective dryer temperature on the combined osmotic dehydration - convective drying of edible button mushrooms were investigated. Experiments were designed according to Central Composite Design with six factors each at five different levels. Response Surface Methodology (RSM) was used to determine the optimum processing conditions that yield maximum water loss and rehydration ratio and minimum solid gain and shrinkage in osmotic-convective drying of edible button mushrooms. Applying surfaces profiler and contour plots optimum operation conditions were found to be temperature of 39 °C, immersion time of 164 min, salt concentration of 14%, sucrose concentration of 53%, pressure of 600 mbar and drying temperature of 40 °C. At these optimum conditions, water loss, solid gain, rehydration ratio and shrinkage were found to be 63.38 (g/100 g initial sample), 3.17 (g/100 g initial sample), 2.26 and 7.15%, respectively.
Abstract: Article devoted to the development of technologies
for medicine and agroecology by using plant organelle – spherosome.
Technological method of purification and isolation of this organelle
by using novel nanostructured carbon sorbent – “nanocarbosorb"
ARK type are presented. Also the methods of preparation of
nanocontainers based on using of spherosome with loaded isosorbide
dinitrate, piroxicam or diclofenak are exhibited. We found that the
spherosome could be applied for ecological aims as bioregulator and
also as biosensor for determination of ammonia ions in water
reservoirs at concentration range 1mM to 100mM.
Abstract: Dispersions of casein micelles (CM) were studied at a
constant protein concentration of 5 wt % in high NaCl environment
ranging from 0% to 12% by Dynamic light scattering (DLS) and
Fourier Transform Infrared (FTIR). The rehydration profiles obtained
were interpreted in term of wetting, swelling and dispersion stages by
using a turbidity method. Two behaviours were observed depending
on the salt concentration. The first behaviour (low salt concentration)
presents a typical rehydration profile with a significant change
between 3 and 6% NaCl indicating quick wetting, swelling and long
dispersion stage. On the opposite, the dispersion stage of the second
behaviour (high salt concentration) was significantly shortened
indicating a strong modification of the protein backbone. A salt
increase result to a destabilization of the micelle and the formation of
mini-micelles more or less aggregated indicating an average micelles
size ranging from 100 to 200 nm. For the first time, the estimations
of secondary structural elements (irregular, ß-sheet, α-helix and turn)
by the Amide III assignments were correlated with results from
Amide I.
Abstract: Excilamps are new UV sources with great potential
for application in wastewater treatment. In the present work, a XeBr
excilamp emitting radiation at 283 nm has been used for the
photodegradation of 4-chlorophenol within a range of concentrations
from 50 to 500 mg L-1. Total removal of 4-chlorophenol was
achieved for all concentrations assayed. The two main photoproduct
intermediates formed along the photodegradation process,
benzoquinone and hydroquinone, although not being completely
removed, remain at very low residual concentrations. Such
concentrations are insignificant compared to the 4-chlorophenol
initial ones and non-toxic. In order to simulate the process and scaleup,
a kinetic model has been developed and validated from the
experimental data.