Removal of Hydrogen Sulphide from Air by Means of Fibrous Ion Exchangers
The removal of hydrogen sulphide is required for reasons of health, odour problems, safety and corrosivity problems. The means of removing hydrogen sulphide mainly depend on its concentration and kind of medium to be purified. The paper deals with a method of hydrogen sulphide removal from the air by its catalytic oxidation to elemental sulphur with the use of Fe-EDTA complex. The possibility of obtaining fibrous filtering materials able to remove small concentrations of H2S from the air were described. The base of these materials is fibrous ion exchanger with Fe(III)- EDTA complex immobilized on their functional groups. The complex of trivalent iron converts hydrogen sulphide to elemental sulphur. Bivalent iron formed in the reaction is oxidized by the atmospheric oxygen, so complex of trivalent iron is continuously regenerated and the overall process can be accounted as pseudocatalytic. In the present paper properties of several fibrous catalysts based on ion exchangers with different chemical nature (weak acid,weak base and strong base) were described. It was shown that the main parameters affecting the process of catalytic oxidation are:concentration of hydrogen sulphide in the air, relative humidity of the purified air, the process time and the content of Fe-EDTA complex in the fibres. The data presented show that the filtering layers with anion exchange package are much more active in the catalytic processes of hydrogen sulphide removal than cation exchanger and inert materials. In the addition to the nature of the fibres relative air humidity is a critical factor determining efficiency of the material in the air purification from H2S. It was proved that the most promising carrier of the Fe-EDTA catalyst for hydrogen sulphide oxidation are Fiban A-6 and Fiban AK-22 fibres.
[1] G. Busca, C. Pistarino, "Technologies for the abatement of sulphide
compounds from gaseous streams: a comparative overview", Journal of
Loss Prevention in the Process Industry, vol. 16, pp. 363 - 371, 2003.
[2] V. Meeyoo, J. H. Lee, D. L. Trimm, N. W. Cant, "Hydrogen sulphide emission control by combined adsorption and catalytic combustion",
Catalysis Today, vol. 44, pp. 67 - 72, 1998.
[3] M. Schlegelmilch, J. Streese, R. Stegmann, "Odour management and
treatment technologies: An overview", Waste Management, vol. 25, pp.
928-939, 2005.
[4] N. Rakmak, W. Wiyaratn, C. Bunyakan, J. Chungsiriporn, "Synthesis of
Fe/MgO nano-crystal catalyst by sol-gel method for hydrogen sulfide
removal", Chemical Engineering Journal, vol. 162, pp. 84-90, 2010.
[5] L. Deng, H. Chen, Z. Chen, X. Liu, X. Pu, L. Song, "Process of
simultaneous hydrogen sulfide removal from biogas and nitrogen
removal from swine wastewater", Bioresource Technology, vol. 100, pp.
5600-5608, 2010.
[6] D. Panza, V. Belgiorno, "Hydrogen sulphide removal from landfill gas",
Process Safety and Environmental Protection, vol. 88, pp. 420-424,
2010.
[7] M.D. Soriano, J. Jimenez-Jimenez, P. Concepcion, A. Jimenez-Lopez,
E. Rodriguez-Castellon, J.M. Lopez Nieto, "Selective oxidation of H2S
to sulphur over vanadium supported on mesoporous zirconium
phosphate heterostructure", Applied Catalysis B: Environmental, vol.
92, pp. 271-279, 2009.
[8] X. Wu, A.K. Kerchief, V. Schwartz, H.S. Overbuy, R. T. Armstrong,
"Activated carbons for selective catalytic oxidation of hydrogen sulfide
to sulfur", Carbon vol. 43, pp. 1084-1114, 2005.
[9] A. J. H. Janssen, G. Lettinga, A. Keizer, "Removal of hydrogen sulphide
from wastewater and waste gases by biological conversion to elemental
sulphur: Colloidal and interfacial aspects of biologically produced
sulphur particles", Colloids and Surfaces A: Physicochemical and
Engineering Aspects, vol. 151, pp. 389-397, 1999.
[10] J. E. Burgess, S. A. Parsons, R. M. Stuetz, "Developments in odour
control and waste gas treatment biotechnology: a review",
Biotechnology Advances, vol. 19, pp. 35-63, 2001.
[11] V. S. Soldatov, E. G. Kosandrovich, "Ion exchangers for air
purification", in Ion Exchange and Solvent Extraction, A Series of Advances, vol. 20, K Arup, M. Sengupta Eds. New York, CRC Press,
2011, pp. 45-117.
[12] S. Piche, F. Larachi, Dynamics of pH on the oxidation of HS- with
iron(III) chelates in anoxic conditions, Chemical Engineering Science
vol. 61, pp. 7673-7683, 2006.
[13] S. Piche, N. Ribeiro, A. Bacaoui, F. Larachi, "Assessment of a redox
alkaline/iron-chelate absorption process for the removal of dilute
hydrogen sulfide in air emissions", Chemical Engineering Science, vol.
60, pp. 6452-6461, 2005.
[14] A. Karimi, A. Tavassoli, B. Nassernejad, "Kinetic studies and reactor
modeling of single step H2S removal using chelated iron solution",
Chemical Engineering Research and Design, vol. 88, pp. 748-756, 2010.
[15] J. F. Demmink, A. Mehra, A. A. C. M. Beenackers, "Absorption of
hydrogen sulfide into aqueous solutions of ferric nitrilotriacetic acid:
local auto-catalytic effects", Chemical Engineering Science, vol. 57, pp.
1723-1734, 2002.
[16] H. Wasag, V. Soldatov, E. Kosandrovich, H. Sobczuk, "Odour control by fibrous ion exchangers", Chemical Engineering Transactions, vol.
15, pp. 387-394, 2008.
[17] V.S. Soldatov, L. Pawlowski, H. Wasag, A. Schunkevich, "New
materials and technologies for environmental engineering. Part I -
Synthesis and structure of ion exchange fibres, Lublin, Poland,
(Published Conference Proceedings style)," in. Monographs of the
Polish Academy of Sciences, Lublin, 2004, vol. 21, pp. 1-127.
[18] V. S. Soldatov, L. Pawlowski, H. Wasag, I. Elinson, A. Shunkievich,
"Air pollution control with fibrous ion exchangers", in. Chemistry for
the Protection of the Environment, 2, Plenum Press, New York, 1996,
pp. 55-66.
[19] A.A. Shunkevich, G.V. Med-jak, R.V. Martsinkevich, V.I. Grachek,
V.S. Soldatov, "Fibrous chelating carboxylic acid ion exchangers",
Sorption & Chromatography Processes, vol. 1, pp. 741-748, 2001.
[1] G. Busca, C. Pistarino, "Technologies for the abatement of sulphide
compounds from gaseous streams: a comparative overview", Journal of
Loss Prevention in the Process Industry, vol. 16, pp. 363 - 371, 2003.
[2] V. Meeyoo, J. H. Lee, D. L. Trimm, N. W. Cant, "Hydrogen sulphide emission control by combined adsorption and catalytic combustion",
Catalysis Today, vol. 44, pp. 67 - 72, 1998.
[3] M. Schlegelmilch, J. Streese, R. Stegmann, "Odour management and
treatment technologies: An overview", Waste Management, vol. 25, pp.
928-939, 2005.
[4] N. Rakmak, W. Wiyaratn, C. Bunyakan, J. Chungsiriporn, "Synthesis of
Fe/MgO nano-crystal catalyst by sol-gel method for hydrogen sulfide
removal", Chemical Engineering Journal, vol. 162, pp. 84-90, 2010.
[5] L. Deng, H. Chen, Z. Chen, X. Liu, X. Pu, L. Song, "Process of
simultaneous hydrogen sulfide removal from biogas and nitrogen
removal from swine wastewater", Bioresource Technology, vol. 100, pp.
5600-5608, 2010.
[6] D. Panza, V. Belgiorno, "Hydrogen sulphide removal from landfill gas",
Process Safety and Environmental Protection, vol. 88, pp. 420-424,
2010.
[7] M.D. Soriano, J. Jimenez-Jimenez, P. Concepcion, A. Jimenez-Lopez,
E. Rodriguez-Castellon, J.M. Lopez Nieto, "Selective oxidation of H2S
to sulphur over vanadium supported on mesoporous zirconium
phosphate heterostructure", Applied Catalysis B: Environmental, vol.
92, pp. 271-279, 2009.
[8] X. Wu, A.K. Kerchief, V. Schwartz, H.S. Overbuy, R. T. Armstrong,
"Activated carbons for selective catalytic oxidation of hydrogen sulfide
to sulfur", Carbon vol. 43, pp. 1084-1114, 2005.
[9] A. J. H. Janssen, G. Lettinga, A. Keizer, "Removal of hydrogen sulphide
from wastewater and waste gases by biological conversion to elemental
sulphur: Colloidal and interfacial aspects of biologically produced
sulphur particles", Colloids and Surfaces A: Physicochemical and
Engineering Aspects, vol. 151, pp. 389-397, 1999.
[10] J. E. Burgess, S. A. Parsons, R. M. Stuetz, "Developments in odour
control and waste gas treatment biotechnology: a review",
Biotechnology Advances, vol. 19, pp. 35-63, 2001.
[11] V. S. Soldatov, E. G. Kosandrovich, "Ion exchangers for air
purification", in Ion Exchange and Solvent Extraction, A Series of Advances, vol. 20, K Arup, M. Sengupta Eds. New York, CRC Press,
2011, pp. 45-117.
[12] S. Piche, F. Larachi, Dynamics of pH on the oxidation of HS- with
iron(III) chelates in anoxic conditions, Chemical Engineering Science
vol. 61, pp. 7673-7683, 2006.
[13] S. Piche, N. Ribeiro, A. Bacaoui, F. Larachi, "Assessment of a redox
alkaline/iron-chelate absorption process for the removal of dilute
hydrogen sulfide in air emissions", Chemical Engineering Science, vol.
60, pp. 6452-6461, 2005.
[14] A. Karimi, A. Tavassoli, B. Nassernejad, "Kinetic studies and reactor
modeling of single step H2S removal using chelated iron solution",
Chemical Engineering Research and Design, vol. 88, pp. 748-756, 2010.
[15] J. F. Demmink, A. Mehra, A. A. C. M. Beenackers, "Absorption of
hydrogen sulfide into aqueous solutions of ferric nitrilotriacetic acid:
local auto-catalytic effects", Chemical Engineering Science, vol. 57, pp.
1723-1734, 2002.
[16] H. Wasag, V. Soldatov, E. Kosandrovich, H. Sobczuk, "Odour control by fibrous ion exchangers", Chemical Engineering Transactions, vol.
15, pp. 387-394, 2008.
[17] V.S. Soldatov, L. Pawlowski, H. Wasag, A. Schunkevich, "New
materials and technologies for environmental engineering. Part I -
Synthesis and structure of ion exchange fibres, Lublin, Poland,
(Published Conference Proceedings style)," in. Monographs of the
Polish Academy of Sciences, Lublin, 2004, vol. 21, pp. 1-127.
[18] V. S. Soldatov, L. Pawlowski, H. Wasag, I. Elinson, A. Shunkievich,
"Air pollution control with fibrous ion exchangers", in. Chemistry for
the Protection of the Environment, 2, Plenum Press, New York, 1996,
pp. 55-66.
[19] A.A. Shunkevich, G.V. Med-jak, R.V. Martsinkevich, V.I. Grachek,
V.S. Soldatov, "Fibrous chelating carboxylic acid ion exchangers",
Sorption & Chromatography Processes, vol. 1, pp. 741-748, 2001.
@article{"International Journal of Earth, Energy and Environmental Sciences:57572", author = "H. Wasag", title = "Removal of Hydrogen Sulphide from Air by Means of Fibrous Ion Exchangers", abstract = "The removal of hydrogen sulphide is required for reasons of health, odour problems, safety and corrosivity problems. The means of removing hydrogen sulphide mainly depend on its concentration and kind of medium to be purified. The paper deals with a method of hydrogen sulphide removal from the air by its catalytic oxidation to elemental sulphur with the use of Fe-EDTA complex. The possibility of obtaining fibrous filtering materials able to remove small concentrations of H2S from the air were described. The base of these materials is fibrous ion exchanger with Fe(III)- EDTA complex immobilized on their functional groups. The complex of trivalent iron converts hydrogen sulphide to elemental sulphur. Bivalent iron formed in the reaction is oxidized by the atmospheric oxygen, so complex of trivalent iron is continuously regenerated and the overall process can be accounted as pseudocatalytic. In the present paper properties of several fibrous catalysts based on ion exchangers with different chemical nature (weak acid,weak base and strong base) were described. It was shown that the main parameters affecting the process of catalytic oxidation are:concentration of hydrogen sulphide in the air, relative humidity of the purified air, the process time and the content of Fe-EDTA complex in the fibres. The data presented show that the filtering layers with anion exchange package are much more active in the catalytic processes of hydrogen sulphide removal than cation exchanger and inert materials. In the addition to the nature of the fibres relative air humidity is a critical factor determining efficiency of the material in the air purification from H2S. It was proved that the most promising carrier of the Fe-EDTA catalyst for hydrogen sulphide oxidation are Fiban A-6 and Fiban AK-22 fibres.
", keywords = "hydrogen sulphide, catalytic oxidation, odour control, ion exchange, fibrous ion exchangers, air deodorization", volume = "6", number = "4", pages = "197-5", }
