Abstract: Contamination of aromatic compounds in water can
cause severe long-lasting effects not only for biotic organism but also
on human health. Several alternative technologies for remediation of
polluted water have been attempted. One of these is adsorption
process of aromatic compounds by using organic modified clay
mineral. Porous structure of clay is potential properties for molecular
adsorptivity and it can be increased by immobilizing hydrophobic
structure to attract organic compounds. In this work natural
montmorillonite were modified with cetyltrimethylammonium
(CTMA+) and was evaluated for use as adsorbents of aromatic
compounds: benzene, toluene, and 2-chloro phenol in its single and
multicomponent solution by ethanol:water solvent. Preparation of
CTMA-montmorillonite was conducted by simple ion exchange
procedure and characterization was conducted by using x-day
diffraction (XRD), Fourier-transform infra red (FTIR) and gas
sorption analysis. The influence of structural modification of
montmorillonite on its adsorption capacity and adsorption affinity of
organic compound were studied. It was shown that adsorptivity of
montmorillonite was increased by modification associated with
arrangements of CTMA+ in the structure even the specific surface
area of modified montmorillonite was lower than raw
montmorillonite. Adsorption rate indicated that material has affinity
to adsorb compound by following order: benzene> toluene > 2-chloro
phenol. The adsorption isotherms of benzene and toluene showed 1st
order adsorption kinetic indicating a partition phenomenon of
compounds between the aqueous and organophilic CTMAmontmorillonite.
Abstract: The pavement constructions on soft and expansive soils are not durable and unable to sustain heavy traffic loading. As a result, pavement failures and settlement problems will occur very often even under light traffic loading due to cyclic and rolling effects. Geotechnical engineers have dwelled deeply into this matter, and adopt various methods to improve the engineering characteristics of soft fine-grained soils and expansive soils. The problematic soils are either replaced by good and better quality material or treated by using chemical stabilization with various binding materials. Increased the strength and durability are also the part of the sustainability drive to reduce the environment footprint of the built environment by the efficient use of resources and waste recycle materials. This paper presents a series of laboratory tests and evaluates the effect of cement and fly ash on the strength and drainage characteristics of soil in Miri. The tests were performed at different percentages of cement and fly ash by dry weight of soil. Additional tests were also performed on soils treated with the combinations of fly ash with cement and lime. The results of this study indicate an increase in unconfined compression strength and a decrease in hydraulic conductivity of the treated soil.
Abstract: In this paper, we propose a novel time-frequency distribution (TFD) for the analysis of multi-component signals. In particular, we use synthetic as well as real-life speech signals to prove the superiority of the proposed TFD in comparison to some existing ones. In the comparison, we consider the cross-terms suppression and the high energy concentration of the signal around its instantaneous frequency (IF).
Abstract: A piston cylinder based high pressure differential
thermal analyzer system is developed to investigate phase
transformations, melting, glass transitions, crystallization behavior of
inorganic materials, glassy systems etc., at ambient to 4 GPa and at
room temperature to 1073 K. The pressure is calibrated by the phase
transition of bismuth and ytterbium and temperature is calibrated
by using thermocouple data chart. The system developed is
calibrated using benzoic acid, ammonium nitrate and it has a
pressure and temperature control of ± 8.9 x 10 -4 GPa , ± 2 K
respectively. The phase transition of Asx Te100-x chalcogenides,
ferrous oxide and strontium boride are studied using the
indigenously developed system.
Abstract: Monitoring of ecological systems is one of the major
issues in ecosystem research. The concepts and methodology of
mathematical systems theory provide useful tools to face this
problem. In many cases, state monitoring of a complex ecological
system consists in observation (measurement) of certain state
variables, and the whole state process has to be determined from the
observed data. The solution proposed in the paper is the design of an
observer system, which makes it possible to approximately recover
the state process from its partial observation. The method is
illustrated with a trophic chain of resource – producer – primary
consumer type and a numerical example is also presented.
Abstract: Cerium-doped lanthanum bromide LaBr3:Ce(5%)
crystals are considered to be one of the most advanced scintillator
materials used in PET scanning, combining a high light yield, fast
decay time and excellent energy resolution. Apart from the correct
choice of scintillator, it is also important to optimise the detector
geometry, not least in terms of source-to-detector distance in order to
obtain reliable measurements and efficiency. In this study a
commercially available 25 mm x 25 mm BrilLanCeTM 380 LaBr3: Ce
(5%) detector was characterised in terms of its efficiency at varying
source-to-detector distances. Gamma-ray spectra of 22Na, 60Co, and
137Cs were separately acquired at distances of 5, 10, 15, and 20cm. As
a result of the change in solid angle subtended by the detector, the
geometric efficiency reduced in efficiency with increasing distance.
High efficiencies at low distances can cause pulse pile-up when
subsequent photons are detected before previously detected events
have decayed. To reduce this systematic error the source-to-detector
distance should be balanced between efficiency and pulse pile-up
suppression as otherwise pile-up corrections would need to be
necessary at short distances. In addition to the experimental
measurements Monte Carlo simulations have been carried out for the
same setup, allowing a comparison of results. The advantages and
disadvantages of each approach have been highlighted.
Abstract: It is well known that the phraseology of a language - the phenomenon of identity. This uniqueness is due to the fact that "there are idioms image-based views of reality that shows mainly of everyday empirical, historical and spiritual experience of a language community, associated with its cultural traditions. The article says that the phraseological units very clearly show the image of the people and give us a great view of the national identity. With the phraseology of the Kazakh and Korean language can understand the mentality of the nation, identity, perception of people. It is in the phraseological units can surprise the culture and customs of the people. Phraseological units store and transmit information about the level of material and spiritual culture of the people, his life, past and present, the development of society in general. And in Korean and Kazakh languages idioms occupy a particularly important role.
Abstract: Quality of 2D and 3D cross-sectional images produce
by Computed Tomography primarily depend upon the degree of
precision of primary and secondary X-Ray intensity detection.
Traditional method of primary intensity detection is apt to errors.
Recently the X-Ray intensity measurement system along with smart
X-Ray sensors is developed by our group which is able to detect
primary X-Ray intensity unerringly. In this study a new smart X-Ray
sensor is developed using Light-to-Frequency converter TSL230
from Texas Instruments which has numerous advantages in terms of
noiseless data acquisition and transmission. TSL230 construction is
based on a silicon photodiode which converts incoming X-Ray
radiation into the proportional current signal. A current to frequency
converter is attached to this photodiode on a single monolithic CMOS
integrated circuit which provides proportional frequency count to
incoming current signal in the form of the pulse train. The frequency
count is delivered to the center of PICDEM FS USB board with
PIC18F4550 microcontroller mounted on it. With highly compact
electronic hardware, this Demo Board efficiently read the smart
sensor output data. The frequency output approaches overcome
nonlinear behavior of sensors with analog output thus un-attenuated
X-Ray intensities could be measured precisely and better
normalization could be acquired in order to attain high resolution.
Abstract: Concrete performance is strongly affected by the
particle packing degree since it determines the distribution of the
cementitious component and the interaction of mineral particles. By
using packing theory designers will be able to select optimal
aggregate materials for preparing concrete with low cement content,
which is beneficial from the point of cost. Optimum particle packing
implies minimizing porosity and thereby reducing the amount of
cement paste needed to fill the voids between the aggregate particles,
taking also the rheology of the concrete into consideration. For
reaching good fluidity superplasticizers are required. The results from
pilot tests at Luleå University of Technology (LTU) show various
forms of the proposed theoretical models, and the empirical approach
taken in the study seems to provide a safer basis for developing new,
improved packing models.
Abstract: This paper deals with a new way for designing
external fixators applied in traumatology and orthopaedics. These
fixators can be applied in the treatment of open and unstable
fractures or for lengthening human or animal bones etc. The new
design is based on the development of Ilizarov and other techniques
(i.e. shape and weight optimalization based on composite materials,
application of smart materials, nanotechnology, low x-ray absorption,
antibacterial protection, patient's comfort, reduction in the duration
of the surgical treatment, and cost).
Abstract: The state-of-the-art Bag of Words model in Content-
Based Image Retrieval has been used for years but the relevance
feedback strategies for this model are not fully investigated. Inspired
from text retrieval, the Bag of Words model has the ability to use the
wealth of knowledge and practices available in text retrieval. We
study and experiment the relevance feedback model in text retrieval
for adapting it to image retrieval. The experiments show that the
techniques from text retrieval give good results for image retrieval
and that further improvements is possible.
Abstract: Larval survey was carried out in 6 localities in the
urban areas (Putrajaya) and suburban areas (Kuala Selangor) from
January until December 2010. A total of 520 representative
households in 6 localities were selected. Breeding habitats were
sampled outdoors in the surroundings of housing areas. The study
indicated that the most predominant species found in both areas was
Aedes albopictus with the gardening utensil as a preferred breeding
microhabitat for Putrajaya, in contrast to the artificial containers for
Kuala Selangor. From a total of 1083 mosquito larvae species, 984
were Aedes albopictus larvae, 67 positive larvae of Aedes aegypti
and 32 of Culex larvae. Aedes Index and Container Index were
elevated in Putrajaya with 13% and 11% respectively which is higher
than the standard given by the Ministry of Health, Malaysia. This
results implicating dengue-sensitive skewed to the urban areas.
Breteau Index result also above the standard in both study locations.
Abstract: Lipases are enzymes particularly amenable for
immobilization by entrapment methods, as they can work equally
well in aqueous or non-conventional media and long-time stability of
enzyme activity and enantioselectivity is needed to elaborate more
efficient bioprocesses. The improvement of Pseudomonas
fluorescens (Amano AK) lipase characteristics was investigated by
optimizing the immobilization procedure in hybrid organic-inorganic
matrices using ionic liquids as additives. Ionic liquids containing a
more hydrophobic alkyl group in the cationic moiety are beneficial
for the activity of immobilized lipase. Silanes with alkyl- or aryl
nonhydrolizable groups used as precursors in combination with
tetramethoxysilane could generate composites with higher
enantioselectivity compared to the native enzyme in acylation
reactions of secondary alcohols. The optimal effect on both activity
and enantioselectivity was achieved for the composite made from
octyltrimethoxysilane and tetramethoxysilane at 1:1 molar ratio (60%
increase of total activity following immobilization and enantiomeric
ratio of 30). Ionic liquids also demonstrated valuable properties as
reaction media for the studied reactions, comparable with the usual
organic solvent, hexane.
Abstract: An efficient architecture for low jitter All Digital
Phase Locked Loop (ADPLL) suitable for high speed SoC
applications is presented in this paper. The ADPLL is designed using
standard cells and described by Hardware Description Language
(HDL). The ADPLL implemented in a 90 nm CMOS process can
operate from 10 to 200 MHz and achieve worst case frequency
acquisition in 14 reference clock cycles. The simulation result shows
that PLL has cycle to cycle jitter of 164 ps and period jitter of 100 ps
at 100MHz. Since the digitally controlled oscillator (DCO) can
achieve both high resolution and wide frequency range, it can meet
the demands of system-level integration. The proposed ADPLL can
easily be ported to different processes in a short time. Thus, it can
reduce the design time and design complexity of the ADPLL, making
it very suitable for System-on-Chip (SoC) applications.
Abstract: The past decade has witnessed a good opportunities
for city development schemes in UK. The government encouraged
restoration of city centers to comprise mixed use developments with
high density residential apartments. Investments in regeneration areas
were doing well according to the analyses of Property Databank
(IPD). However, more recent analysis by IPD has shown that since
2007, property in regeneration areas has been more vulnerable to the
market downturn than other types of investment property. The early
stages of a property market downturn may be felt most in
regeneration where funding, investor confidence and occupier
demand would dissipate because the sector was considered more
marginal or risky when development costs rise. Moreover, the Bank
of England survey shows that lenders have sequentially tightened the
availability of credit for commercial real estate since mid-2007. A
sharp reduction in the willingness of banks to lend on commercial
property was recorded. The credit crunch has already affected
commercial property but its impact has been particularly severe in
certain kinds of properties where residential developments are
extremely difficult, in particular city centre apartments and buy-to-let
markets. Commercial property – retail, industrial leisure and mixed
use were also pressed, in Birmingham; tens of mixed use plots were
built to replace old factories in the heart of the city. The purpose of
these developments was to enable young professionals to work and
live in same place. Thousands of people lost their jobs during the
recession, moreover lending was more difficult and the future of
many developments is unknown. The recession casts its shadow upon
the society due to cuts in public spending by government, Inflation,
rising tuition fees and high rise in unemployment generated anger and
hatred was spreading among youth causing vandalism and riots in
many cities. Recent riots targeted many mixed used development in
the UK where banks, shops, restaurants and big stores were robbed
and set into fire leaving residents with horror and shock. This paper
examines the impact of the recession and riots on mixed use
development in UK.
Abstract: An iterative definition of any n variable mean function is given in this article, which iteratively uses the two-variable form of the corresponding two-variable mean function. This extension method omits recursivity which is an important improvement compared with certain recursive formulas given before by Ando-Li-Mathias, Petz- Temesi. Furthermore it is conjectured here that this iterative algorithm coincides with the solution of the Riemann centroid minimization problem. Certain simulations are given here to compare the convergence rate of the different algorithms given in the literature. These algorithms will be the gradient and the Newton mehod for the Riemann centroid computation.
Abstract: Bones are dynamic and responsive organs, they
regulate their strength and mass according to the loads which they are subjected. Because, the Wnt/β-catenin pathway has profound
effects on the regulation of bone mass, we hypothesized that mechanical loading of bone cells stimulates Wnt/β-catenin signaling, which results in the generation of new bone mass.
Mechanical loading triggers the secretion of the Wnt molecule, which after binding to transmembrane proteins, causes GSK-3β (Glycogen synthase kinase 3 beta) to cease the phosphorylation of β-catenin. β-catenin accumulation in the cytoplasm, followed by its
transport into the nucleus, binding to transcription factors (TCF/LEF)
that initiate transcription of genes related to bone formation. To test this hypothesis, we used TOPGAL (Tcf Optimal Promoter
β-galactosidase) mice in an experiment in which cyclic loads were
applied to the forearm. TOPGAL mice are reporters for cells effected
by the Wnt/β-catenin signaling pathway. TOPGAL mice are genetically engineered mice in which transcriptional activation of β-
catenin, results in the production of an enzyme, β-galactosidase. The
presence of this enzyme allows us to localize transcriptional
activation of β-catenin to individual cells, thereby, allowing us to quantify the effects that mechanical loading has on the Wnt/β-catenin pathway and new bone formation. The ulnae of loaded TOPGAL
mice were excised and transverse slices along different parts of the
ulnar shaft were assayed for the presence of β-galactosidase.
Our results indicate that loading increases β-catenin transcriptional
activity in regions where this pathway is already primed (i.e. where basal activity is already higher) in a load magnitude dependent
manner. Further experiments are needed to determine the temporal and spatial activation of this signaling in relation to bone formation.
Abstract: This paper argues that networks, such as the ECN and the American network, are affected by certain small events which are inherent to path dependence and preclude the full evolution towards efficiency. It is advocated that the American network is superior to the ECN in many respects due to its greater flexibility and longer history. This stems in particular from the creation of the American network, which was based on a small number of cases. Such a structure encourages further changes and modifications which are not necessarily radical. The ECN, by contrast, was established by legislative action, which explains its rigid structure and resistance to change. This paper is an attempt to transpose the superiority of the American network on to the ECN. It looks at concepts such as judicial cooperation, harmonisation of procedure, peer review and regulatory impact assessments (RIAs), and dispute resolution procedures.
Abstract: The possibility of using cassava residue containing
49.66% starch, 21.47% cellulose, 12.97% hemicellulose, and 21.86%
lignin as a raw material to produce glucose using enzymatic
hydrolysis was investigated. In the experiment, each reactor
contained the cassava residue, bacteria cells, and production medium.
The effects of particles size (40 mesh and 60 mesh) and strains of
bacteria (A002 and M015) isolated from Thai higher termites,
Microcerotermes sp., on the glucose concentration at 37°C were
focused. High performance liquid chromatography (HPLC) with a
refractive index detector was used to determine the quantity of
glucose. The maximum glucose concentration obtained at 37°C using
strain A002 and 60 mesh of the cassava residue was 1.51 g/L at 10 h.