Abstract: In this study, we sought to investigate the mercury
removal efficiency of manganese oxides from natural gas. The
fundamental studies on mercury removal with manganese oxides
sorbents were carried out in a laboratory scale fixed bed reactor at 30
°C with a mixture of methane (20%) and nitrogen gas laden with 4.8
ppb of elemental mercury. Manganese oxides with varying surface
area and crystalline phase were prepared by conventional precipitation
method in this study. The effects of surface area, crystallinity and
other metal oxides on mercury removal efficiency were investigated.
Effect of Ag impregnation on mercury removal efficiency was also
investigated. Ag supported on metal oxide such titania and zirconia as
reference materials were also used in this study for comparison. The
characteristics of mercury removal reaction with manganese oxide
was investigated using a temperature programmed desorption (TPD)
technique.
Manganese oxides showed very high Hg removal activity (about
73-93% Hg removal) for first time use. Surface area of the manganese
oxide samples decreased after heat-treatment and resulted in complete
loss of Hg removal ability for repeated use after Hg desorption in the
case of amorphous MnO2, and 75% loss of the initial Hg removal
activity for the crystalline MnO2. Mercury desorption efficiency of
crystalline MnO2 was very low (37%) for first time use and high (98%)
after second time use. Residual potassium content in MnO2 may have
some effect on the thermal stability of the adsorbed Hg species.
Desorption of Hg from manganese oxides occurs at much higher
temperatures (with a peak at 400 °C) than Ag/TiO2 or Ag/ZrO2.
Mercury may be captured on manganese oxides in the form of mercury
manganese oxide.
Abstract: The aim of our research was to evaluate the effects of
physical exercise on lipid profile and anthropometric characteristics
in young subjects, diagnosed with metabolic syndrome (MS). The
study has been developed during 28 weeks on 20 young obese
patients which have undertaken an intermittent submaximal exercise
program. After 28 weeks of physical activity, the results show
significant effects on anthropometric characteristics and serum lipid
profile of research subjects. Additionally, the results of this study
confirms the major correlation between the variations of
intraabdominal adiposity, determined ultrasonographycally,
and the changes of serum lipid concentrations, a better
correlation than it is used abdominal circumference or body
weight index.
Abstract: Charging and discharging phenomenon on the surface
of materials can be found in plasma display panel, spacecraft
charging, high voltage insulator, etc. This report gives a simple
explanation on this phenomenon. A scanning electron microscope
was used not only as a tool to produce energetic electron beam to
charge an insulator without metallic coating and to produce a surface
discharging (surface breakdown/flashover) but also to observe the
visible charging and discharging on the sample surface. A model of
electric field distribution on the surface was developed in order to
explain charging and discharging phenomena. Since charging and
discharging process involves incubation time, therefore this process
can be used to evaluate the insulation property of materials under
electron bombardment.
Abstract: In this paper, a simple microfluidic device for monitoring algal cell behavior is proposed. An array of algal microwells is fabricated by PDMS soft-lithography using X-ray LIGA mold, placed on a glass substrate. Two layers of replicated PDMS and substrate are attached by oxygen plasma bonding, creating a microchannel for the microfluidic system. Algal cell are loaded into the microfluidic device, which provides positive charge on the bottom surface of wells. Algal cells, which are negative charged, can be attracted to the bottom of the wells via electrostatic interaction. By varying the concentration of algal cells in the loading suspension, it is possible to obtain wells with a single cell. Liquid medium for cells monitoring are flown continuously over the wells, providing nutrient and waste exchange between the well and the main flow. This device could lead to the uncovering of the quantitative biology of the algae, which is a key to effective and extensive algal utilizations in the field of biotechnology, food industry and bioenergy research and developments.
Abstract: As the material used for fuselage structure must
possess low density, high strength to weight ratio, the selection of
appropriate materials for fuselage structure is one of the most
important tasks. Aluminum metal itself is soft and low in strength. It
can be made stronger by giving proper combination of suitable alloy
addition, mechanical treatment and thermal treatment. The usual
thermal treatment given to aluminum alloys is called age-hardening
or precipitation hardening. In this paper, the studies are carried out on
7075 aluminum alloy which is how to improve strength level for
fuselage structure. The marked effect of the strength on the ternary
alloy is clearly demonstrated at several ageing times and
temperatures. It is concluded that aluminum-zinc-magnesium alloy
can get the highest strength level in natural ageing.
Abstract: A suitable e-learning system management needs to
carry out a web-information system in order to allow integrated
fruition of data and metadata concerning the activities typical of elearning
environment. The definition of a “web information system"
for e-learning takes advantage of the potentialities of Web
technologies both as for the access to metadata present on the several
platforms, and as for the implementation of courseware which make
up the relative didactic environment. What information systems have
in common is the technological environment on which they are
generally implemented and the use of metadata in order to structure
information at all cognitive and organization levels. In this work we
are going to define a methodology for the implementation of a
specific web information system for an e-learning environment.
Abstract: The authors of this work indicate by means of a concrete example that it is possible to apply efficaciously the method of multiple criteria programming in dealing with the problem of determining the optimal production plan for a certain period of time. The work presents: (1) the selection of optimization criteria, (2) the setting of the problem of determining an optimal production plan, (3) the setting of the model of multiple criteria programming in finding a solution to a given problem, (4) the revised surrogate trade-off method, (5) generalized multicriteria model for solving production planning problem and problem of choosing technological variants in the metal manufacturing industry. In the final part of this work the authors reflect on the application of the method of multiple criteria programming while determining the optimal production plan in manufacturing enterprises.
Abstract: Global approximation using metamodel for complex
mathematical function or computer model over a large variable
domain is often needed in sensibility analysis, computer simulation,
optimal control, and global design optimization of complex, multiphysics
systems. To overcome the limitations of the existing
response surface (RS), surrogate or metamodel modeling methods for
complex models over large variable domain, a new adaptive and
regressive RS modeling method using quadratic functions and local
area model improvement schemes is introduced. The method applies
an iterative and Latin hypercube sampling based RS update process,
divides the entire domain of design variables into multiple cells,
identifies rougher cells with large modeling error, and further divides
these cells along the roughest dimension direction. A small number
of additional sampling points from the original, expensive model are
added over the small and isolated rough cells to improve the RS
model locally until the model accuracy criteria are satisfied. The
method then combines local RS cells to regenerate the global RS
model with satisfactory accuracy. An effective RS cells sorting
algorithm is also introduced to improve the efficiency of model
evaluation. Benchmark tests are presented and use of the new
metamodeling method to replace complex hybrid electrical vehicle
powertrain performance model in vehicle design optimization and
optimal control are discussed.
Abstract: The treatment of the industrial wastewater can be
particularly difficult in the presence of toxic compounds. Excessive
concentration of Chromium in soluble form is toxic to a wide variety
of living organisms. Biological removal of heavy metals using natural
and genetically engineered microorganisms has aroused great interest
because of its lower impact on the environment. Ralston
metallidurans, formerly known as Alcaligenes eutrophus is a LProteobacterium
colonizing industrial wastewater with a high content
of heavy metals. Tris-buffered mineral salt medium was used for
growing Alcaligenes eutrophus AE104 (pEBZ141). The cells were
cultivated for 18 h at 30 oC in Tris-buffered mineral salt medium
containing 3 mM disodium sulphate and 46 mM sodium gluconate as
the carbon source. The cells were harvested by centrifugation,
washed, and suspended in 10 mM Tris HCl, pH 7.0, containing 46
mM sodium gluconate, and 5 mM Chromium. Interaction among
induction of chr resistance determinant, and chromate reduction have
been demonstrated. Results of this study show that the above bacteria
can be very useful for bioremediation of chromium from industrial
wastewater.
Abstract: Metal matrix composites have been increasingly used
as materials for components in automotive and aerospace industries
because of their improved properties compared with non-reinforced
alloys. During machining the selection of appropriate machining
parameters to produce job for desired surface roughness is of great
concern considering the economy of manufacturing process. In this
study, a surface roughness prediction model using fuzzy logic is
developed for end milling of Al-SiCp metal matrix composite
component using carbide end mill cutter. The surface roughness is
modeled as a function of spindle speed (N), feed rate (f), depth of cut
(d) and the SiCp percentage (S). The predicted values surface
roughness is compared with experimental result. The model predicts
average percentage error as 4.56% and mean square error as 0.0729.
It is observed that surface roughness is most influenced by feed rate,
spindle speed and SiC percentage. Depth of cut has least influence.
Abstract: This research aimed at investigating the Cr (III), Cd
(II) and Pb (II) removal efficiencies by using the newly synthesized
metal oxides/ polyethersulfone (PES), Al2O3/PES and ZrO2/PES,
membranes from synthetic wastewater and exploring fouling
mechanisms. A Comparative study between the removal efficiencies
of Cr (III), Cd (II) and Pb (II) from synthetic and natural wastewater
by using adsorption onto agricultural by products and the newly
synthesized Al2O3/PES and ZrO2/PES membranes was conducted to
assess the advantages and limitations of using the metal oxides/PES
membranes for heavy metals removal. The results showed that about
99 % and 88 % removal efficiencies were achieved by the tested
membranes for Pb (II) and Cr (III), respectively.
Abstract: Machining is an important manufacturing process used to produce a wide variety of metallic parts. Among various machining processes, turning is one of the most important one which is employed to shape cylindrical parts. In turning, the quality of finished product is measured in terms of surface roughness. In turn, surface quality is determined by machining parameters and tool geometry specifications. The main objective of this study is to simultaneously model and optimize machining parameters and tool geometry in order to improve the surface roughness for AISI1045 steel. Several levels of machining parameters and tool geometry specifications are considered as input parameters. The surface roughness is selected as process output measure of performance. A Taguchi approach is employed to gather experimental data. Then, based on signal-to-noise (S/N) ratio, the best sets of cutting parameters and tool geometry specifications have been determined. Using these parameters values, the surface roughness of AISI1045 steel parts may be minimized. Experimental results are provided to illustrate the effectiveness of the proposed approach.
Abstract: The aim of this paper is to experimentally discover the workability coefficient of the Inconel 718 material by using a slide turning machining. Two different types of cutting inserts, one made of carbide and the other one made of ceramic, are being used. The purpose is to compare measured results and recommend the appropriate materials and cutting parameters for a machining of the Inconel 718. Furthermore, the durability of inserts with the chosen wear criterion is being compared for different cutting speeds. Machinability of these materials is a crucial characteristic as it allows us to shorten the technological cycle time and increase the machining productivity. And this is of great importance from an economic point of view.
Abstract: Face recognition in the infrared spectrum has attracted a lot of interest in recent years. Many of the techniques used in infrared are based on their visible counterpart, especially linear techniques like PCA and LDA. In this work, we introduce a probabilistic Bayesian framework for face recognition in the infrared spectrum. In the infrared spectrum, variations can occur between face images of the same individual due to pose, metabolic, time changes, etc. Bayesian approaches permit to reduce intrapersonal variation, thus making them very interesting for infrared face recognition. This framework is compared with classical linear techniques. Non linear techniques we developed recently for infrared face recognition are also presented and compared to the Bayesian face recognition framework. A new approach for infrared face extraction based on SVM is introduced. Experimental results show that the Bayesian technique is promising and lead to interesting results in the infrared spectrum when a sufficient number of face images is used in an intrapersonal learning process.
Abstract: In this work, effects of catalysts (TiO2, and Nb2O5) were investigated on the hydrogen desorption of Mg(BH4)2. LiBH4 and MgCl2 with 2:1 molar ratio were mixed by using ball milling to prepare Mg(BH4)2. The desorption behaviors were measured by thermo-volumetric apparatus. The hydrogen desorption capacity of the mixed sample milled for 2 h was 4.78 wt% with a 2-step released. The first step occurred at 214 °C and the second step appeared at 374 °C. The addition of 16 wt% Nb2O5 decreased the desorption temperature in the second step about 66 °C and increased the hydrogen desorption capacity to 4.86 wt% hydrogen. The addition of TiO2 also improved the desorption temperature in the second step and the hydrogen desorption capacity. It decreased the desorption temperature about 71°C and showed a high amount of hydrogen, 5.27 wt%, released from the mixed sample. The hydrogen absorption after desorption of Mg(BH4)2 was also studied under 9.5 MPa and 350 °C for 12 h.
Abstract: Based on the thermodynamic theory, the dependence of
sublimation energy of metal on temperature and pressure is discussed,
and the results indicate that the sublimation energy decreases linearly
with the increase of temperature and pressure. Combined with this
result, the blow-off impulse of aluminum induced by pulsed X-ray is
simulated by smoothed particle hydrodynamics (SPH) method. The
numerical results show that, while the change of sublimation energy
with temperature and pressure is considered, the blow-off impulse of
aluminum is larger than the case that the sublimation energy is
assumed to be a constant.
Abstract: Cast metal inlays can be used on molars requiring a
class II restoration instead amalgam and offer a durable alternative.
Because it is known that class II inlays may increase the
susceptibility to fracture, it is important to ensure optimal
performance in selection of the adequate preparation design to reduce
stresses in teeth structures and also in the restorations. The aim of the
study was to investigate the influence of preparation design on stress
distribution in molars with different class II preparations and in cast
metal inlays. The first step of the study was to achieve 3D models in
order to analyze teeth and cast metal class II inlays. The geometry of
the intact tooth was obtained by 3D scanning using a manufactured
device. With a NURBS modeling program the preparations and the
appropriately inlays were designed. 3D models of first upper molars
of the same shape and size were created. Inlay cavities designs were
created using literature data. The geometrical model was exported
and the mesh structure of the solid 3D model was created for
structural simulations. Stresses were located around the occlusal
contact areas. For the studied cases, the stress values were not
significant influenced by the taper of the preparation. it was
demonstrated stresses are higher in the cast metal restorations and
therefore the strength of the teeth is not affected.
Abstract: This study investigated possible ways to improve the
efficiency of the platinum precipitation process using ammonium
chloride by reducing the platinum content reporting to the effluent.
The ore treated consist of five platinum group metals namely,
ruthenium, rhodium, iridium, platinum, palladium and a precious
metal gold. Gold, ruthenium, rhodium and iridium were extracted
prior the platinum precipitation process. Temperature, reducing
agent, flow rate and potential difference were the variables controlled
to determine the operation conditions for optimum platinum
precipitation efficiency. Hydrogen peroxide was added as the
oxidizing agent at the temperature of 85-90oC and potential
difference of 700-850mV was the variable used to check the
oxidizing state of platinum. The platinum was further purified at
temperature between 60-65oC, potential difference above 700 mV,
ammonium chloride of 200 l, and at these conditions the platinum
content reporting to the effluent was reduced to less than 300ppm,
resulting in optimum platinum precipitation efficiency and purity of
99.9%.
Abstract: This paper presents the design, development and characterization of contractile water jet thruster (CWJT) for mini underwater robot. Instead of electric motor, this CWJT utilizes the Ionic Polymer Metal Composite (IPMC) as the actuator to generate the water jet. The main focus of this paper is to analyze the conceptual design of the proposed CWJT which would determine the thrust force value, jet flow behavior and actuator’s stress. Those thrust force and jet flow studies were carried out using Matlab/Simscape simulation software. The actuator stress had been analyzed using COSMOS simulation software. The results showed that there was no significant change for jet velocity at variable cross sectional nozzle area. However, a significant change was detected for jet velocity at different nozzle cross sectional area ratio which was up to 37%. The generated thrust force has proportional relation to the nozzle cross sectional area.
Abstract: The direct sewage sludge application is a relative
cheap method for their liquidation. In the past heavy metal contents
increase in soils treated with sewage sludge was observed. In 2003
there was acceptance on act n.188/2003 about sewage sludge
application on soils. The basic philosophy of act is a safety of the
environmental proof of sludge application on soils. The samples of
soils from wastewater treatment plant (WTP) Poprad (35) and WTP
Michalovce (33 samples) were analyzed which were chosen for
sludge application on soils. According to the results only 14 areas for
Poprad and 25 areas for Michalovce are suitable for sludge
application according to act No. 188/2003. The application dose of
sludge was calculated 50 t.ha-1 or 75 t. ha-1 once in 5 years to ensure
that heavy metal contents in treated soils will be kept.