Abstract: A two-dimensional thin-walled capsule of a flexible
semi-permeable membrane is adhered onto a rigid planar substrate
under adhesive forces (derived from a potential function) in the
presence of osmosis across the membrane. The capsule is immersed
in a hypotonic and diluted binary solution of a non-electrolyte
solute. The Stokes flow problem is solved by the immersed interface
method (IIM) with equal viscosities for the enclosed and
surrounding fluid of the capsule. The numerical results obtained are
verified against two simplified theoretical solutions and the
agreements are good. The osmotic inflation of the adhered capsule is
studied as a function of the solute concentration field, hydraulic
conductivity, and the initial capsule shape. Our findings indicate that
the contact length shrinks in dimension as capsule inflates in the
hypotonic medium, and the equilibrium contact length does not
depend on the hydraulic conductivity of the membrane and the
initial shape of the capsule.
Abstract: Many commercial processes are available for the
removal of H2S from gaseous streams. The desulfurization of gas
streams using aqueous ferric sulfate solution as washing liquor is
studied. Apart from sulfur, only H2O is generated in the process, and
consequently, no waste treatment facilities are required. A distinct
advantage of the process is that the reaction of H2S with is so rapid
and complete that there remains no danger of discharging toxic waste
gas. In this study, the reactive absorption of hydrogen sulfide into
aqueous ferric sulfate solution has been studied and design
calculations for equipments have been done and effective operation
parameters on this process considered. Results show that high
temperature and low pressure are suitable for absorption reaction.
Variation of hydrogen sulfide concentration and Fe3+ concentration
with time in absorption reaction shown that the reaction of ferric
sulfate and hydrogen sulfide is first order with respect to the both
reactant. At low Fe2(SO4)3 concentration the absorption rate of H2S
increase with increasing the Fe2(SO4)3 concentration. At higher
concentration a decrease in the absorption rate was found. At higher
concentration of Fe2(SO4)3, the ionic strength and viscosity of
solution increase remarkably resulting in a decrease of solubility,
diffusivity and hence absorption rate.
Abstract: Among the technologies available to reduce methane
emitted from the pig industry, biofiltration seems to be an effective
and inexpensive solution. In methane (CH4) biofiltration, nitrogen is
an important macronutrient for the microorganisms growth. The
objective of this research project was to study the effect of
ammonium (NH4
+) on the performance, the biomass production and
the nitrogen conversion of a biofilter treating methane. For NH4
+
concentrations ranging from 0.05 to 0.5 gN-NH4
+/L, the CH4 removal
efficiency and the dioxide carbon production rate decreased linearly
from 68 to 11.8 % and from 7.1 to 0.5 g/(m3-h), respectively. The dry
biomass content varied from 4.1 to 5.8 kg/(m3 filter bed). For the
same range of concentrations, the ammonium conversion decreased
while the specific nitrate production rate increased. The specific
nitrate production rate presented negative values indicating
denitrification in the biofilter.
Abstract: In this study the integration of an absorption heat
pump (AHP) with the concentration section of an industrial pulp and
paper process is investigated using pinch technology. The optimum
design of the proposed water-lithium bromide AHP is then achieved
by minimizing the total annual cost. A comprehensive optimization is
carried out by relaxation of all stream pressure drops as well as heat
exchanger areas involving in AHP structure. It is shown that by
applying genetic algorithm optimizer, the total annual cost of the
proposed AHP is decreased by 18% compared to one resulted from
simulation.
Abstract: This study investigated the relationship between urban
and rural ozone concentrations and quantified the extent to which
ambient rural conditions and the concentrations of other pollutants
can be used to predict urban ozone concentrations. The study
describes the variations of ozone in weekday and weekends as well as
the daily maximum recorded at selected monitoring stations. The
results showed that Putrajaya station had the highest concentrations
of O3 on weekend due the titration of NO during the weekday.
Additionally, Jerantut had the lowest average concentration with a
reading value high on Wednesdays. The comparisons of average and
maximum concentrations of ozone for the three stations showed that
the strongest significant correlation is recorded in Jerantut station
with the value R2= 0.769. Ozone concentrations originating from a
neighbouring urban site form a better predictor to the urban ozone
concentrations than widespread rural ozone at some levels of
temporal averaging. It is found that in urban and rural of Malaysian
peninsular, the concentration of ozone depends on the concentration
of NOx and seasonal meteorological factors. The HYSPLIT Model
(the northeast monsoon) showed that the wind direction can also
influence the concentration of ozone in the atmosphere in the studied
areas.
Abstract: The aim of this studywas toinvestigate the effect
ofrunning classification (sprint, middle, and long distance)and two
distances on blood lactate (BLa), heart rate (HR), and rating of
perceived exertion (RPE) Borg scale ratings in collegiate athletes. On
different days, runners (n = 15) ran 400m and 1600m at a five min
mile pace, followed by a two min 6mph jog, and a two min 3mph
walk as part of the cool down. BLa, HR, and RPE were taken at
baseline, post-run, plus 2 and 4 min recovery times. The middle and
long distance runners exhibited lower BLa concentrations than sprint
runners after two min of recovery post 400 m runs, immediately after,
and two and four min recovery periods post 1600 m runs. When
compared to sprint runners, distance runners may have exhibited the
ability to clear BLa more quickly, particularly after running 1600 m.
Abstract: The present study was performed in Musa bay (northern part of the Persian Gulf) around the coastal area of Bandare-Imam Khomeini and Razi Petrochemical Companies. Sediment samples and effluent samples were collected from the selected stations, from June 2009 to June 2010. The samples were analyzed to determine the degree of hydrocarbon contamination. The average level of TPH concentration in the study area was more than the natural background value at all of the stations, especially at station BI1 which was the main effluent outlet of Bandar-e- Imam Khomeini petrochemical company. Also the concentration of total petroleum hydrocarbon was monitored in the effluents of aforementioned petrochemical companies and the results showed that the concentration of TPH in the effluents of Bandar-e- Imam Khomeini petrochemical company was greater than Razi petrochemical company which is may be related to the products of Bandar-e- Imam Khomeini petrochemical company (aromatics, polymers, chemicals, fuel).
Abstract: In this paper 2D Simulation of catalytic Fixed Bed Reactor in Fischer-Tropsch Synthesis of GTL technology has been performed utilizing computational fluid dynamics (CFD). Synthesis gas (a mixture of carbon monoxide and hydrogen) has been used as feedstock. The reactor was modeled and the model equations were solved employing finite volume method. The model was validated against the experimental data reported in literature. The comparison showed a good agreement between simulation results and the experimental data. In addition, the model was applied to predict the concentration contours of the reactants and products along the length of reactor.
Abstract: A vast array of biological materials, especially algae have received increasing attention for heavy metal removal. Algae have been proven to be cheaper, more effective for the removal of metallic elements in aqueous solutions. A fresh water algal strain was isolated from Zoo Lake, Johannesburg, South Africa and identified as Desmodesmus sp. This paper investigates the efficacy of Desmodesmus sp.in removing heavy metals contaminating the Wonderfonteinspruit Catchment Area (WCA) water bodies. The biosorption data fitted the pseudo-second order and Langmuir isotherm models. The Langmuir maximum uptakes gave the sequence: Mn2+>Ni2+>Fe2+. The best results for kinetic study was obtained in concentration 120 ppm for Fe3+ and Mn2+, whilst for Ni2+ was at 20 ppm, which is about the same concentrations found in contaminated water in the WCA (Fe3+115 ppm, Mn2+ 121 ppm and Ni2+ 26.5 ppm).
Abstract: Alcohol and water extracts of Cymbopogon citratus
was investigated for anti-bacterial properties and phytochemical
constituents. The extract was screened against four gram-negative
bacteria Escherichia coli, Klebsiella pneumoniae, Pseudomonas
aeruginosa, Proteus vulgaris) and two grampositive bacteria Bacillus
subtilis and Staphylococcus aureus at four different concentrations
(1:1, 1:5, 1:10 and 1:20) using disc diffusion method. The antibacterial
examination was by disc diffusion techniques, while the
photochemical constituents were investigated using standard
chemical methods. Results showed that the extracts inhibited the
growth of standard and local strains of the organisms used. The
treatments were significantly different (P = 0.05). The minimum
inhibitory concentration of the extracts against the tested
microorganisms ranged between 150mg/ml and 50mg/ml. The
alcohol extracts were found to be generally more effective than the
water extract. The photochemical analysis revealed the presence of
alkaloids and phenol but absence of cardiac and cyanogenic
glycosides. The presence of alkaloid and phenols were inferred as
being responsible for the anti-bacterial properties of the extracts.
Abstract: This article is dedicated to development of
mathematical models for determining the dynamics of
concentration of hazardous substances in urban turbulent
atmosphere. Development of the mathematical models implied
taking into account the time-space variability of the fields of
meteorological items and such turbulent atmosphere data as vortex
nature, nonlinear nature, dissipativity and diffusivity. Knowing the
turbulent airflow velocity is not assumed when developing the
model. However, a simplified model implies that the turbulent and
molecular diffusion ratio is a piecewise constant function that
changes depending on vertical distance from the earth surface.
Thereby an important assumption of vertical stratification of urban
air due to atmospheric accumulation of hazardous substances
emitted by motor vehicles is introduced into the mathematical
model. The suggested simplified non-linear mathematical model of
determining the sought exhaust concentration at a priori unknown
turbulent flow velocity through non-degenerate transformation is
reduced to the model which is subsequently solved analytically.
Abstract: In this study, lipase production has been investigated
using submerge fermentation by Aspergillus niger in Kilka fish oil as
main substrate. The Taguchi method with an L9 orthogonal array
design was used to investigate the effect of parameters and their
levels on lipase productivity. The optimum conditions for Kilka fish
oil concentration, incubation temperature and pH were obtained 3
gr./ml 35°C and 7, respectively. The amount of lipase activity in
optimum condition was obtained 4.59IU/ml. By comparing this
amount with the amount of productivity in the olive oil medium
based on the cost of each medium, it was that using Kilka fish oil is
84% economical. Therefore Kilka fish oil can be used as an
economical and suitable substrate in the lipase production and
industrial usages.
Abstract: Trace element speciation of an integrated soil
amendment matrix was studied with a modified BCR sequential
extraction procedure. The analysis included pseudo-total
concentration determinations according to USEPA 3051A and
relevant physicochemical properties by standardized methods. Based
on the results, the soil amendment matrix possessed neutralization
capacity comparable to commercial fertilizers. Additionally, the
pseudo-total concentrations of all trace elements included in the
Finnish regulation for agricultural fertilizers were lower than the
respective statutory limit values. According to chemical speciation,
the lability of trace elements increased in the following order: Hg <
Cr < Co < Cu < As < Zn < Ni < Pb < Cd < V < Mo < Ba. The
validity of the BCR approach as a tool for chemical speciation was
confirmed by the additional acid digestion phase. Recovery of trace
elements during the procedure assured the validity of the approach
and indicated good quality of the analytical work.
Abstract: The effect of gamma irradiation on micro-hardness of polymer blends of poly (ethyl methacrylate)(PEMA) and poly (ethylene oxide) (PEO) has been investigated to detect the radiation induced crosslinking. The blend system comprises a noncrystallizable polymer, PEMA and a crystallizable polymer, PEO. On irradiation, the overall hardness of the blend specimens for different dose levels infers occurrence of a crosslinking process. The radiation-induced crosslinking was greater for blends having lower concentration of PEO. However, increase in radiation dose causes softening of blend system due to radiation induced scissioning of the chains
Abstract: Recent studies demonstrated that high-fat diet increases oxidative stress in plasma and in a variety of tissues. Many researchers have been looking for natural products, which can reverse the effect of high fat diet. Recently, buckwheat is becoming common ingredient in functional food because of it properties. In study on buckwheat, it is known that, this plant plays roles as anti-oxidative, anti-inflammatory and anti-hypertensive. Nevertheless still little is known about buckwheat groats. The aim of this study was to investigate the effects of addition of buckwheat groats to the fat diet (30% lard), on some antioxidant and oxidant stress parameters in plasma and selected tissues in Wistar rats. The experiment was carried out with three months old male Wistar rats ca. 250g of body weight fed for 5 weeks with either a high-fat (30% of lard) diet or control diet, with or without addition of buckwheat groats. In plasma biochemistry and the activities of the antioxidant enzymes were measured selected tissues: glutathione peroxidase (GPX), catalase (CAT) and the levels of total and reduced glutathione (GSH), free thiol groups (pSH), antioxidant potential of plasma (FRAP) and oxidant stress indices - proteins carbonyl groups (CO) and malonyldialdehyde concentration (MDA). Activity of catalase (CAT) in plasma of rats was significantly increased in buckwheat groats groups and activity of GPx3 in plasma of rats was decreased in buckwheat groups as compared to control group. The reduced glutathione (GSH) in plasma of rats was significantly increased and protein CO was significantly decreased in buckwheat groups as compared to controls. The lowered concentration of GSH was found in serum of rats fed buckwheat groats addition but it accompanied in 7-fold increase in reduced-to-oxidized glutatione ratio, significant increase in HDL and decrease in nonHDL concentration. Conclusions: Buckwheat groats indicate a beneficial effect in inhibiting protein and lipid peroxidation in rats and improved lipid profile. These results suggest that buckwheat groats exert a significant antioxidant potential and may be used as normal food constituent to ameliorate the oxidant-induced damage in organism.
Abstract: Durian husk (DH), a fruit waste, was studied for its ability to remove Basic blue 3 (BB3) from aqueous solutions. Batch kinetic studies were carried out to study the sorption characteristics under various experimental conditions. The optimum pH for the dye removal occurred in the pH range of 3-10. Sorption was found to be concentration and agitation dependent. The kinetics of dye sorption fitted a pseudo-second order rate expression. Both Langmuir and Freundlich models appeared to provide reasonable fittings for the sorption data of BB3 on durian husk. Maximum sorption capacity calculated from the Langmuir model is 49.50 mg g-1.
Abstract: The Iranian bentonite was first characterized by
Scanning Electron Microscopy (SEM), Inductively Coupled Plasma
mass spectrometry (ICP-MS), X-ray fluorescence (XRF), X-ray
Diffraction (XRD) and BET. The bentonite was then treated
thermally between 150°C-250°C at 15min, 45min and 90min and
also was activated chemically with different concentration of
sulphuric acid (3N, 5N and 10N). Although the results of thermal
activated-bentonite didn-t show any considerable changes in specific
surface area and Cation Exchange Capacity (CEC), but the results of
chemical treated bentonite demonstrated that such properties have
been improved by acid activation process.
Abstract: Isobaric and cooling zone of iron ore reactor have been
simulated. In this paper, heat and mass transfer equation are
formulated to perform the temperature and concentration of gas and
solid phase respectively. Temperature profile for isobaric zone is
simulated on the range temperature of 873-1163K while cooling zone
is simulated on the range temperature of 733-1139K. The simulation
results have a good agreement with the plant data. Total carbon
formation in the isobaric zone is only 30% of total carbon contained in
the sponge iron product. The formation of Fe3C in isobaric zone
reduces metallization degree up to 0.58% whereas reduction of
metallization degree in cooling zone up to 1.139%. The decreasing of
sponge iron temperature in the isobaric and cooling zone is around 300
K and 600 K respectively.
Abstract: Macrophomina phaseolina is a devastating soil-borne
fungal plant pathogen that causes charcoal rot disease in many
economically important crops worldwide. So far, no registered
fungicide is available against this plant pathogen. This study was
planned to examine the antifungal activity of an allelopathic grass
Cenchrus pennisetiformis (Hochst. & Steud.) Wipff. for the
management of M. phaseolina isolated from cowpea [Vigna
unguiculata (L.) Walp.] plants suffering from charcoal rot disease.
Different parts of the plants viz. inflorescence, shoot and root were
extracted in methanol. Laboratory bioassays were carried out using
different concentrations (0, 0.5, 1.0, …, 3.0 g mL-1) of methanolic
extracts of the test allelopathic grass species to assess the antifungal
activity against the pathogen. In general, extracts of all parts of the
grass exhibited antifungal activity. All the concentrations of
methanolic extracts of shoot and root significantly reduced fungal
biomass by 20–73% and 40–80%, respectively. Methanolic shoot
extract was fractionated using n-hexane, chloroform, ethyl acetate
and n-butanol. Different concentrations of these fractions (3.125,
6.25, …, 200 mg mL-1) were analyzed for their antifungal activity.
All the concentrations of n-hexane fraction significantly reduced
fungal biomass by 15–96% over corresponding control treatments.
Higher concentrations (12.5–200 mg mL-1) of chloroform, ethyl
acetate and n-butanol also reduced the fungal biomass significantly
by 29–100%, 46–100% and 24–100%, respectively.
Abstract: The morphology, mineralogical and chemical
composition of a low-grade nickel ore from Mpumalanga, South
Africa, were studied by scanning electron microscope (SEM), X-ray
diffraction (XRD) and X-ray fluorescence (XRF), respectively. The
ore was subjected to atmospheric agitation leaching using sulphuric
acid to investigate the effects of acid concentration, leaching
temperature, leaching time and particle size on extraction of nickel
and cobalt. Analyses results indicated the ore to be a saprolitic nickel
laterite belonging to the serpentine group of minerals. Sulphuric acid
was found to be able to extract nickel from the ore. Increased acid
concentration and temperature only produced low amounts of nickel
but improved cobalt extraction. As high as 77.44% Ni was achieved
when leaching a -106+75μm fraction with 4.0M acid concentration at
25oC. The kinetics of nickel leaching from the saprolitic ore were
studied and the activation energy was determined to be 18.16kJ/mol.
This indicated that nickel leaching reaction was diffusion controlled.