Abstract: A vast array of biological materials, especially algae have received increasing attention for heavy metal removal. Algae have been proven to be cheaper, more effective for the removal of metallic elements in aqueous solutions. A fresh water algal strain was isolated from Zoo Lake, Johannesburg, South Africa and identified as Desmodesmus sp. This paper investigates the efficacy of Desmodesmus sp.in removing heavy metals contaminating the Wonderfonteinspruit Catchment Area (WCA) water bodies. The biosorption data fitted the pseudo-second order and Langmuir isotherm models. The Langmuir maximum uptakes gave the sequence: Mn2+>Ni2+>Fe2+. The best results for kinetic study was obtained in concentration 120 ppm for Fe3+ and Mn2+, whilst for Ni2+ was at 20 ppm, which is about the same concentrations found in contaminated water in the WCA (Fe3+115 ppm, Mn2+ 121 ppm and Ni2+ 26.5 ppm).
Abstract: Group contribution methods such as the UNIFAC are
of major interest to researchers and engineers involved synthesis,
feasibility studies, design and optimization of separation processes as
well as other applications of industrial use. Reliable knowledge of
the phase equilibrium behavior is crucial for the prediction of the fate
of the chemical in the environment and other applications. The
objective of this study was to predict the solubility of selected
volatile organic compounds (VOCs) in glycol polymers and
biodiesel. Measurements can be expensive and time consuming,
hence the need for thermodynamic models. The results obtained in
this study for the infinite dilution activity coefficients compare very
well those published in literature obtained through measurements. It
is suggested that in preliminary design or feasibility studies of
absorption systems for the abatement of volatile organic compounds,
prediction procedures should be implemented while accurate fluid
phase equilibrium data should be obtained from experiment.
Abstract: For more than 120 years, gold mining formed the
backbone the South Africa-s economy. The consequence of mine
closure was observed in large-scale land degradation and widespread
pollution of surface water and groundwater. This paper investigates
the feasibility of using natural zeolite in removing heavy metals
contaminating the Wonderfonteinspruit Catchment Area (WCA), a
water stream with high levels of heavy metals and radionuclide
pollution. Batch experiments were conducted to study the adsorption
behavior of natural zeolite with respect to Fe2+, Mn2+, Ni2+, and Zn2+.
The data was analysed using the Langmuir and Freudlich isotherms.
Langmuir was found to correlate the adsorption of Fe2+, Mn2+, Ni2+,
and Zn2+ better, with the adsorption capacity of 11.9 mg/g, 1.2 mg/g,
1.3 mg/g, and 14.7 mg/g, respectively. Two kinetic models namely,
pseudo-first order and pseudo second order were also tested to fit the
data. Pseudo-second order equation was found to be the best fit for
the adsorption of heavy metals by natural zeolite. Zeolite
functionalization with humic acid increased its uptake ability.