Abstract: Carbon nanotube is one of the most attractive materials
for the potential applications of nanotechnology due to its excellent
mechanical, thermal, electrical and optical properties. In this paper we
report a supercapacitor made of nickel foil electrodes, coated with
multiwall carbon nanotubes (MWCNTs) thin film using
electrophoretic deposition (EPD) method. Chemical vapor deposition
method was used for the growth of MWCNTs and ethanol was used as
a hydrocarbon source. High graphitic multiwall carbon nanotube was
found at 750oC analyzing by Raman spectroscopy. We observed the
electrochemical performance of supercapacitor by cyclic
voltammetry. The electrodes of supercapacitor fabricated from
MWCNTs exhibit considerably small equivalent series resistance
(ESR), and a high specific power density. Electrophoretic deposition
is an easy method in fabricating MWCNT electrodes for high
performance supercapacitor.
Abstract: Nanocrystalline powders of the lead-free piezoelectric
material, tantalum-substituted potassium sodium niobate
(K0.5Na0.5)(Nb0.9Ta0.1)O3 (KNNT), were produced using a Retsch
PM100 planetary ball mill by setting the milling time to 15h, 20h,
25h, 30h, 35h and 40h, at a fixed speed of 250rpm. The average
particle size of the milled powders was found to decrease from 12nm
to 3nm as the milling time increases from 15h to 25h, which is in
agreement with the existing theoretical model. An anomalous
increase to 98nm and then a drop to 3nm in the particle size were
observed as the milling time further increases to 30h and 40h
respectively. Various sizes of these starting KNNT powders were
used to investigate the effect of milling time on the microstructure,
dielectric properties, phase transitions and piezoelectric properties of
the resulting KNNT ceramics. The particle size of starting KNNT
was somewhat proportional to the grain size. As the milling time
increases from 15h to 25h, the resulting ceramics exhibit
enhancement in the values of relative density from 94.8% to 95.8%,
room temperature dielectric constant (εRT) from 878 to 1213, and
piezoelectric charge coefficient (d33) from 108pC/N to 128pC/N. For
this range of ceramic samples, grain size refinement suppresses the
maximum dielectric constant (εmax), shifts the Curie temperature (Tc)
to a lower temperature and the orthorhombic-tetragonal phase
transition (Tot) to a higher temperature. Further increase of milling
time from 25h to 40h produces a gradual degradation in the values of
relative density, εRT, and d33 of the resulting ceramics.
Abstract: The hydrogenated amorphous carbon films (α-C:H)
were deposited on p-type Si (100) substrates at different thicknesses by
radio frequency plasma enhanced chemical vapor deposition
technique (rf-PECVD). Raman spectra display asymmetric
diamond-like carbon (DLC) peaks, representative of the α-C:H films.
The decrease of intensity ID/IG ratios revealed the sp3 content arise at
different thicknesses of the α-C:H films. In terms of mechanical
properties, the high hardness and elastic modulus values showed the
elastic and plastic deformation behaviors related to sp3 content in
amorphous carbon films. Electrochemical properties showed that the
α-C:H films exhibited excellent corrosion resistance in air-saturated
3.5 wt.% NaCl solution for pH 2 at room temperature. Thickness
increasing affected the small sp2 clusters in matrix, restricting the
velocity transfer and exchange of electrons. The deposited α-C:H films
exhibited excellent mechanical properties and corrosion resistance.
Abstract: Hydrogenated amorphous carbon (a-C:H) films have
been synthesized by a radio frequency plasma enhanced chemical
vapor deposition (rf-PECVD) technique with different bias voltage
from 0.0 to -0.5 kV. The Raman spectra displayed the polymer-like
hydrogenated amorphous carbon (PLCH) film with 0.0 to -0.1 and
a-C:H films with -0.2 to -0.5 kV of bias voltages. The surface chemical
information of all films were studied by X-ray photoelectron
spectroscopy (XPS) technique, presented to C-C (sp2 and sp3) and C-O
bonds, and relative carbon (C) and oxygen (O) atomics contents. The
O contamination had affected on structure and optical properties. The
true density of PLCH and a-C:H films were characterized by X-ray
refractivity (XRR) method, showed the result as in the range of
1.16-1.73 g/cm3 that depending on an increasing of bias voltage. The
hardness was proportional to the true density of films. In addition, the
optical properties i.e. refractive index (n) and extinction coefficient (k)
of these films were determined by a spectroscopic ellipsometry (SE)
method that give formation to in 1.62-2.10 (n) and 0.04-0.15 (k)
respectively. These results indicated that the optical properties
confirmed the Raman results as presenting the structure changed with
applied bias voltage increased.
Abstract: In this paper family of multilevel inverter topology
with reduced number of power switches is presented. The proposed
inverter can generate both even and odd level. The proposed topology
is suitable for symmetric structure. The proposed symmetric inverter
results in reduction of power switches, power diode and gate driver
circuits and also it may further minimize the installation area and
cost. To prove the superiority of proposed topology is compared with
conventional topologies. The performance of this symmetric
multilevel inverter has been tested by computer based simulation and
prototype based experimental setup for nine-level inverter is
developed and results are verified.
Abstract: Multiwall carbon nanotubes, prepared by chemical
vapor deposition, have an average diameter of 60-100 nm as shown
by High Resolution Transmittance Electron Microscope, HR-TEM.
The Multiwall carbon nanotubes (MWCNTs) were further
characterized using X-ray Diffraction and Raman Spectroscopy.
Mercury uptake capacity of MWCNTs was studied using batch
adsorption method at different concentration ranges up to 150 ppm.
Mercury concentration (before and after the treatment) was measured
using cold vapor atomic absorption spectroscopy. The effect of time,
concentration, pH and adsorbent dose were studied. MWCNT were
found to perform complete absorption in the sub-ppm concentrations
(parts per billion levels) while for high concentrations, the adsorption
efficiency was 92% at the optimum conditions; 0.1 g of the adsorbent
at 150 ppm mercury (II) solution. The adsorption of mercury on
MWCNTs was found to follow the Freundlich adsorption isotherm
and the pseudo-second order kinetic model.
Abstract: The purpose of this project is to carry out an analysis
and determine the profile of actual lean manufacturing processes in
the Metropolitan Area of Bucaramanga. Through the analysis of
qualitative and quantitative variables it was possible to establish how
these manufacturers develop production practices that ensure their
competitiveness and productivity in the market.
In this study, a random sample of metallurgic and wrought iron
companies was applied, following which a quantitative focus and
analysis was used to formulate a qualitative methodology for
measuring the level of lean manufacturing procedures in the industry.
A qualitative evaluation was also carried out through a multivariate
analysis using the Numerical Taxonomy System (NTSYS) program
which should allow for the determination of Lean Manufacturing
profiles.
Through the results it was possible to observe how the companies
in the sector are doing with respect to Lean Manufacturing Practices,
as well as identify the level of management that these companies
practice with respect to this topic. In addition, it was possible to
ascertain that there is no one dominant profile in the sector when it
comes to Lean Manufacturing.
It was established that the companies in the metallurgic and
wrought iron industry show low levels of Lean Manufacturing
implementation. Each one carries out diverse actions that are
insufficient to consolidate a sectoral strategy for developing a
competitive advantage which enables them to tie together a
production strategy.
Abstract: One- and two-dimensional carbon nanostructures with
sp2 hybridization of carbon atoms (single walled carbon nanotubes
and graphene) are promising materials in future electronic and
spintronics devices due to specific character of their electronic
structure. In this paper we present a comparative study of graphene
and single-wall carbon nanotubes by Raman spectro-microscopy in
strong magnetic field. This unique method allows to study changes in
electronic band structure of the two types of carbon nanostructures
induced by a strong magnetic field.
Abstract: This article presents summary on preparation and
characterization of zinc, copper, cadmium and cobalt chromite
nanocrystals, embedded in an amorphous silica matrix. The
ZnCr2O4/SiO2, CuCr2O4/SiO2, CdCr2O4/SiO2 and CoCr2O4/SiO2
nanocomposites were prepared by a conventional sol-gel method
under acid catalysis. Final heat treatment of the samples was carried
out at temperatures in the range of 900−1200 ◦C to adjust the
phase composition and the crystallite size, respectively. The resulting
samples were characterized by Powder X-ray diffraction (PXRD),
High Resolution Transmission Electron Microscopy (HRTEM),
Raman/FTIR spectroscopy and magnetic measurements. Formation
of the spinel phase was confirmed in all samples. The average size of
the nanocrystals was determined from the PXRD data and by direct
particle size observation on HRTEM; both results were correlated.
The mean particle size (reviewed by HRTEM) was in the range from
∼4 to 46 nm. The results showed that the sol-gel method can be
effectively used for preparation of the spinel chromite nanoparticles
embedded in the silica matrix and the particle size is driven by the
type of the cation A2+ in the spinel structure and the temperature
of the final heat treatment. Magnetic properties of the nanocrystals
were found to be just moderately modified in comparison to the bulk
phases.
Abstract: Metal-enhanced Luminescence of silicon nanocrystals
(SiNCs) was determined using two different particle sizes of silver
nanoparticles (AgNPs). SiNCs have been characterized by scanning
electron microscopy (SEM), high resolution transmission electron
microscopy (HRTEM), Fourier transform infrared spectroscopy
(FTIR) and X-ray photoelectron spectroscopy (XPS). It is found that
the SiNCs are crystalline with an average diameter of 65 nm and FCC
lattice. AgNPs were synthesized using photochemical reduction of
AgNO3 with sodium dodecyl sulphate (SDS). The enhanced
luminescence of SiNCs by AgNPs was evaluated by confocal Raman
microspectroscopy. Enhancement up to x9 and x3 times were
observed for SiNCs that mixed with AgNPs which have an average
particle size of 100 nm and 30 nm, respectively. Silver NPs-enhanced
luminescence of SiNCs occurs as a result of the coupling between the
excitation laser light and the plasmon bands of AgNPs; thus this
intense field at AgNPs surface couples strongly to SiNCs.
Abstract: Voltage sags are the most common power quality
disturbance in the distribution system. It occurs due to the fault in the
electrical network or by the starting of a large induction motor and
this can be solved by using the custom power devices such as
Dynamic Voltage Restorer (DVR). In this paper DVR is proposed to
compensate voltage sags on critical loads dynamically. The DVR
consists of VSC, injection transformers, passive filters and energy
storage (lead acid battery). By injecting an appropriate voltage, the
DVR restores a voltage waveform and ensures constant load voltage.
The simulation and experimental results of a DVR using MATLAB
software shows clearly the performance of the DVR in mitigating
voltage sags.
Abstract: The paper presents the results of clusterization by
Kohonen self-organizing maps (SOM) applied for analysis of array of
Raman spectra of multi-component solutions of inorganic salts, for
determination of types of salts present in the solution. It is
demonstrated that use of SOM is a promising method for solution of
clusterization and classification problems in spectroscopy of multicomponent
objects, as attributing a pattern to some cluster may be
used for recognition of component composition of the object.
Abstract: In this study, a comparative analysis of the approaches
associated with the use of neural network algorithms for effective
solution of a complex inverse problem – the problem of identifying
and determining the individual concentrations of inorganic salts in
multicomponent aqueous solutions by the spectra of Raman
scattering of light – is performed. It is shown that application of
artificial neural networks provides the average accuracy of
determination of concentration of each salt no worse than 0.025 M.
The results of comparative analysis of input data compression
methods are presented. It is demonstrated that use of uniform
aggregation of input features allows decreasing the error of
determination of individual concentrations of components by 16-18%
on the average.
Abstract: The present environmental issues have made aircraft jet noise reduction a crucial problem in aero-acoustics research. Acoustic studies reveal that addition of chevrons to the nozzle reduces the sound pressure level reasonably with acceptable reduction in performance. In this paper comprehensive numerical studies on acoustic characteristics of different types of chevron nozzles have been carried out with non-reacting flows for the shape optimization of chevrons in supersonic nozzles for aerospace applications. The numerical studies have been carried out using a validated steady 3D density based, k-ε turbulence model. In this paper chevron with sharp edge, flat edge, round edge and U-type edge are selected for the jet acoustic characterization of supersonic nozzles. We observed that compared to the base model a case with round-shaped chevron nozzle could reduce 4.13% acoustic level with 0.6% thrust loss. We concluded that the prudent selection of the chevron shape will enable an appreciable reduction of the aircraft jet noise without compromising its overall performance. It is evident from the present numerical simulations that k-ε model can predict reasonably well the acoustic level of chevron supersonic nozzles for its shape optimization.
Abstract: In this paper, we have investigated the free convection MHD flow due to heat and mass transfer through porous medium bounded by an infinite vertical non-conducting porous plate with time dependent suction under the influence of uniform transverse magnetic field of strength H0. When Temperature (T) and Concentration (C) at the plate is oscillatory with time about a constant non-zero mean. The velocity distribution, the temperature distribution, co-efficient of skin friction and role of heat transfer is investigated. Here the partial differential equations are involved. Exact solution is not possible so approximate solution is obtained and various graphs are plotted.
Abstract: One of the most essential issues in software products is to maintain it relevancy to the dynamics of the user’s requirements and expectation. Many studies have been carried out in quality aspect of software products to overcome these problems. Previous software quality assessment models and metrics have been introduced with strengths and limitations. In order to enhance the assurance and buoyancy of the software products, certification models have been introduced and developed. From our previous experiences in certification exercises and case studies collaborating with several agencies in Malaysia, the requirements for user based software certification approach is identified and demanded. The emergence of social network applications, the new development approach such as agile method and other varieties of software in the market have led to the domination of users over the software. As software become more accessible to the public through internet applications, users are becoming more critical in the quality of the services provided by the software. There are several categories of users in web-based systems with different interests and perspectives. The classifications and metrics are identified through brain storming approach with includes researchers, users and experts in this area. The new paradigm in software quality assessment is the main focus in our research. This paper discusses the classifications of users in web-based software system assessment and their associated factors and metrics for quality measurement. The quality model is derived based on IEEE structure and FCM model. The developments are beneficial and valuable to overcome the constraints and improve the application of software certification model in future.
Abstract: Two multisensor system architectures for navigation
and guidance of small Unmanned Aircraft (UA) are presented and
compared. The main objective of our research is to design a compact,
light and relatively inexpensive system capable of providing the
required navigation performance in all phases of flight of small UA,
with a special focus on precision approach and landing, where Vision
Based Navigation (VBN) techniques can be fully exploited in a
multisensor integrated architecture. Various existing techniques for
VBN are compared and the Appearance-Based Navigation (ABN)
approach is selected for implementation. Feature extraction and
optical flow techniques are employed to estimate flight parameters
such as roll angle, pitch angle, deviation from the runway centreline
and body rates. Additionally, we address the possible synergies of
VBN, Global Navigation Satellite System (GNSS) and MEMS-IMU
(Micro-Electromechanical System Inertial Measurement Unit)
sensors, and the use of Aircraft Dynamics Model (ADM) to provide
additional information suitable to compensate for the shortcomings of
VBN and MEMS-IMU sensors in high-dynamics attitude
determination tasks. An Extended Kalman Filter (EKF) is developed
to fuse the information provided by the different sensors and to
provide estimates of position, velocity and attitude of the UA
platform in real-time. The key mathematical models describing the
two architectures i.e., VBN-IMU-GNSS (VIG) system and VIGADM
(VIGA) system are introduced. The first architecture uses VBN
and GNSS to augment the MEMS-IMU. The second mode also
includes the ADM to provide augmentation of the attitude channel.
Simulation of these two modes is carried out and the performances of
the two schemes are compared in a small UA integration scheme (i.e.,
AEROSONDE UA platform) exploring a representative cross-section
of this UA operational flight envelope, including high dynamics
manoeuvres and CAT-I to CAT-III precision approach tasks.
Simulation of the first system architecture (i.e., VIG system) shows
that the integrated system can reach position, velocity and attitude
accuracies compatible with the Required Navigation Performance
(RNP) requirements. Simulation of the VIGA system also shows
promising results since the achieved attitude accuracy is higher using
the VBN-IMU-ADM than using VBN-IMU only. A comparison of
VIG and VIGA system is also performed and it shows that the
position and attitude accuracy of the proposed VIG and VIGA
systems are both compatible with the RNP specified in the various
UA flight phases, including precision approach down to CAT-II.
Abstract: Indian food processing industry is one of the largest in the world in terms of production, consumption, exports and growth opportunities. SMEs play a crucial role within this. Large manufacturing firms largely dominate innovation studies in India. Innovation sources used by SMEs are often different from that of large firms. This paper focuses on exploring various sources of innovation adopted by food processing SMEs in Kerala, South India. Outcome suggests that SMEs use various sources like suppliers, competitors, employees, government/research institutions and customers to get new ideas.
Abstract: In the literature, Improved Recycling Folded Cascode (IRFC) Operational Transconductance Amplifier (OTA) is proposed for enhancing the DC gain and the Unity Gain Bandwidth (UGB) of the Recycling Folded Cascode (RFC) OTA. In this paper, an enhanced IRFC (EIRFC) OTA which uses positive feedback at the cascode node is proposed for enhancing the differential mode (DM) gain without changing the unity gain bandwidth (UGB) and lowering the Common mode (CM) gain. For the purpose of comparison, IRFC and EIRFC OTAs are implemented using UMC 90nm CMOS technology and studied through simulation. From the simulation, it is found that the DM gain and CM gain of EIRFC OTA is higher by 6dB and lower by 38dB respectively, compared to that of IRFC OTA for the same power and area. The slew rate of EIRFC OTA is also higher by a factor of 1.5.
Abstract: CO2 emissions from maritime transport operations represent a substantial part of the total greenhouse gas emission. Vessels are designed with better energy efficiency. Minimizing CO2 emission in maritime operations plays an important role in supply chain decarbonisation. This paper reviews the initiatives on slow steaming operations towards the reduction of carbon emission. It investigates the relationship and impact among slow steaming cost reduction, carbon emission reduction, and shipment delay. A scenario-based cost-driven decision support model is developed to facilitate the selection of the optimal slow steaming options, considering the cost on bunker fuel consumption, available speed, carbon emission, and shipment delay. The incorporation of the social cost of cargo is reviewed and suggested. Additional measures on the effect of vessels sizes, routing, and type of fuels towards decarbonisation are discussed.