Abstract: The aquatic plants are a promising renewable energy resource. Lake Fúquene polluting macrophytes, water hyacinth (Eichhornia crassipes C. Mart.) and Brazilian elodea (Egeria densa Planch.), were saccharifiedby different treatments and fermented to ethanol by native yeasts. Among the tested chemical and biological methods for the saccharification, Pleurotus ostreatus at 10% (m/v) was chosen as the best pre-treatment in both macrophytes (P
Abstract: We study a Dirichlet boundary value problem for Lane-Emden equation involving two fractional orders. Lane-Emden equation has been widely used to describe a variety of phenomena in physics and astrophysics, including aspects of stellar structure, the thermal history of a spherical cloud of gas, isothermal gas spheres,and thermionic currents. However, ordinary Lane-Emden equation does not provide the correct description of the dynamics for systems in complex media. In order to overcome this problem and describe dynamical processes in a fractalmedium, numerous generalizations of Lane-Emden equation have been proposed. One such generalization replaces the ordinary derivative by a fractional derivative in the Lane-Emden equation. This gives rise to the fractional Lane-Emden equation with a single index. Recently, a new type of Lane-Emden equation with two different fractional orders has been introduced which provides a more flexible model for fractal processes as compared with the usual one characterized by a single index. The contraction mapping principle and Krasnoselskiis fixed point theorem are applied to prove the existence of solutions of the problem in a Banach space. Ulam-Hyers stability for iterative Cauchy fractional differential equation is defined and studied.
Abstract: In this study tree types of multilayer gas barrier plastic packaging films were compared using life cycle assessment as a tool for resource efficient and environmentally low-impact materials selection. The first type of multilayer packaging film (PET-AlOx/LDPE) consists of polyethylene terephthalate with barrier layer AlOx (PET-AlOx) and low density polyethylene (LDPE). The second type of polymer film (PET/PE-EVOH-PE) is made of polyethylene terephthalate (PET) and co-extrusion film PE-EVOH-PE as barrier layer. And the third one type of multilayer packaging film (PET-PVOH/LDPE) is formed from polyethylene terephthalate with barrier layer PVOH (PET-PVOH) and low density polyethylene (LDPE).
All of analyzed packaging has significant impact to resource depletion, because of raw materials extraction and energy use and production of different kind of plastics. Nevertheless the impact generated during life cycle of functional unit of II type of packaging (PET/PE-EVOH-PE) was about 25% lower than impact generated by I type (PET-AlOx/LDPE) and III type (PET-PVOH/LDPE) of packaging.
Result revealed that the contribution of different gas barrier type to the overall environmental problem of packaging is not significant. The impact are mostly generated by using energy and materials during raw material extraction and production of different plastic materials as plastic polymers material as PE, LDPE and PET, but not gas barrier materials as AlOx, PVOH and EVOH.
The LCA results could be useful in different decision-making processes, for selecting resource efficient and environmentally low-impact materials.
Abstract: Takerbucht is the only cultivar of date palm known as being resistant to the bayoud disease, caused by Fusarium oxysporum f. sp. albedinis (F.o.a.). In the aim to understand more about the defense mechanisms implied, we realized phytochemical analyses of this cultivar leaflets and roots and this, for the first time, using gas chromatography-mass spectrometry (GC-MS).The examination of our results shows that fifty-four molecules have been detected, fourteen of which are common to leaflets and roots. This study revealed also the organs' richness in derivatives fatty acids: both saturated and unsaturated are represented mainly by methyl esters of Hexadecanoic and 9,12,15-Octadecatrienoic acids. 1-Dodecanethiol, derivative Dodecanoic acid is only present in roots. It’s of great interest to note that the screening revealed the steroidal saponins abundance, among which Yamogenin acetate and Diosgenin, exclusively detected in Takerbucht. They may play an essential role, in the date palm resistance to the bayoud disease.
Abstract: Hydrogen fuel is a zero-emission fuel which uses electrochemical cells or combustion in internal engines, to power vehicles and electric devices. Methods of hydrogen storage for subsequent use span many approaches, including high pressures, cryogenics and chemical compounds that reversibly release H2 upon heating. Most research into hydrogen storage is focused on storing hydrogen as a lightweight, compact energy carrier for mobile applications. With the accelerating demand for cleaner and more efficient energy sources, hydrogen research has attracted more attention in the scientific community. Until now, full implementation of a hydrogen-based energy system has been hindered in part by the challenge of storing hydrogen gas, especially onboard an automobile. New techniques being researched may soon make hydrogen storage more compact, safe and efficient. In this overview, few hydrogen storage methods and mechanism of hydrogen uptake in carbon nanotubes are summarized.
Abstract: No negative control nor control to prevent microbes from escaping was set when the S-shaped flask experiments were performed by Pasteur. Microscope was not used to observe the media in the flasks. Louis Pasteur’s S-shaped flask experiment was re-examined by using U-shaped flasks, modified S-shaped flasks and microscope. A mixture of microbes was isolated from the room air, from which one rod-shaped Bacillus species with proposed name Bacillus gaso-mobilis sp nov and one grape-shaped Staphylococcus species with proposed name of Staphylococcus gaso-mobilis sp nov were identified. Their penicillin and ampicillin resistant strains containing plasmids were isolated. These bacteria could change color, produce odor and automatically move in the air. They did not form colonies on solid media. They had a high suspension capacity in liquid media. Their light absorbance peaked at the wave length of 320 nm. It was concluded that there were flaws with Louis Pasteur’s S-shaped flask experiments.
Abstract: Fly ash is a waste material of coal firing thermal
plants that is released from thermal power plants. It was defined as
very fine particles that are drifted upward which are taken up by the
flue gases. The emerging amount of fly ash in the world is
approximately 600 million tons per year. In our country, it is
expected that will be occurred 50 million tons of waste ash per year
until 2020. The fly ashes can be evaluated by using as adsorbent
material. The purpose of this study is to investigate the possibility of
use of various fly ashes (Tuncbilek, Catalagzi, Orhaneli) like lowcost
adsorbents for heavy metal adsorption. First of all, fly ashes
were characterized. For this purpose; analyses such as XRD, XRF,
SEM and FT-IR were performed.
Abstract: Combustion of fuels in industrial and transport sector has lead to an alarming release of polluting gases to the atmosphere. Carbon monoxide is one such pollutant, which is formed as a result of incomplete oxidation of the fuel. In order to analyze the effect of catalyst on the reduction of CO emissions to the atmosphere, two catalysts Mn2O3 and Hopcalite are considered. A model was formed based on mass and energy balance equations. Results show that Hopcalite catalyst as compared to Mn2O3 catalyst helped in faster conversion of the polluting gas as the operating temperature of the hopcalite catalyst is much lower as compared to the operating temperature of Mn2O3 catalyst.
Abstract: Absorption spectra of infra-red (IR) radiation of the
disperse water medium absorbing the most important greenhouse
gases: CO2 , N2O , CH4 , C2H2 , C2H6 have been calculated by
the molecular dynamics method. Loss of the absorbing ability at the
formation of clusters due to a reduction of the number of centers
interacting with IR radiation, results in an anti-greenhouse effect.
Absorption of O3 molecules by the (H2O)50 cluster is investigated
at its interaction with Cl- ions. The splitting of ozone molecule on
atoms near to cluster surface was observed. Interaction of water
cluster with Cl- ions causes the increase of integrated intensity of
emission spectra of IR radiation, and also essential reduction of the
similar characteristic of Raman spectrum. Relative integrated
intensity of absorption of IR radiation for small water clusters was
designed. Dependences of the quantity of weight on altitude for
vapor of monomers, clusters, droplets, crystals and mass of all
moisture were determined. The anti-greenhouse effect of clusters was
defined as the difference of increases of average global temperature
of the Earth, caused by absorption of IR radiation by free water
molecules forming clusters, and absorption of clusters themselves.
The greenhouse effect caused by clusters makes 0.53 K, and the antigreenhouse
one is equal to 1.14 K. The increase of concentration of
CO2 in the atmosphere does not always correlate with the
amplification of greenhouse effect.
Abstract: Hydrogen diffusion is the main problem for corrosion fatigue in corrosive environment. In order to analyze the phenomenon, it is needed to understand their behaviors specially the hydrogen behavior during the diffusion. So, Hydrogen embrittlement and prediction its behavior as a main corrosive part of the fractions, needed to solve combinations of different equations mathematically. The main point to obtain the equation, having knowledge about the source of causing diffusion and running the atoms into materials, called driving force. This is produced by either gradient of electrical or chemical potential. In this work, we consider the gradient of chemical potential to obtain the property equation. In diffusion of atoms, some of them may be trapped but, it could be ignorable in some conditions. According to the phenomenon of hydrogen embrittlement, the thermodynamic and chemical properties of hydrogen are considered to justify and relate them to fracture mechanics. It is very important to get a stress intensity factor by using fugacity as a property of hydrogen or other gases. Although, the diffusive behavior and embrittlement event are common and the same for other gases but, for making it more clear, we describe it for hydrogen. This considering on the definite gas and describing it helps us to understand better the importance of this relation.
Abstract: This study was an investigation on the suitability of Lahar/HDPE composite as a primary material for low-cost smallscale biogas digesters. While sources of raw materials for biogas are abundant in the Philippines, cost of the technology has made the widespread utilization of this resource an indefinite proposition. Aside from capital economics, another problem arises with space requirements of current digester designs. These problems may be simultaneously addressed by fabricating digesters on a smaller, household scale to reach a wider market, and to use materials that may accommodate optimization of overall design and fabrication cost without sacrificing operational efficiency. This study involved actual fabrication of the Lahar/HDPE composite at varying composition and geometry, subsequent mechanical and thermal characterization, and implementation of Statistical Analysis to find intrinsic relationships between variables. From the results, Lahar/HDPE composite was found to be feasible for use as digester material from both mechanical and economic standpoints.
Abstract: The paper deals with the development of portable aerosol concentrator and its application for the determination of nitrites and nitrates. The device enables the continuous trapping of pollutants in the air. An extensive literature search has been elaborated which aims at the development of samplers and the possibilities of their application in the continuous determination of volatile organic compounds. The practical part of the paper is focused on the development of the portable aerosol concentrator. The device using the Aerosol Enrichment Unit has been experimentally verified and subsequently realized. It operates on the principle of equilibrium accumulation of pollutants from the gaseous phase using absorption liquid polydisperse aerosol. The device has been applied for monitoring nitrites and nitrates in the air. The chemiluminescence detector was used for detection; the achieved detection limit for nitrites was 28 ng/m3 and for nitrates 78 ng/m3.
Abstract: The deposition of diamond films on a Si3N4 substrate
is an attractive technique for industrial applications because of the
excellent properties of diamond. Pretreatment of substrate is very
important prior to diamond deposition to promote nucleation and
adhesion between coating and substrate. Deposition of
nanocrystalline diamonds films on silicon nitride substrate have been
carried out by HF-CVD technique using mixture of methane and
hydrogen gases. Different pretreatment of substrate including
chemical etching consists of hot acid etching and basic etching and
mechanical etching were used to study the quality of diamond formed
on the substrate. The structure and morphology of diamond coating
have been studied using X-ray Diffraction (XRD) and Scanning
Electron Microscope (SEM) while diamond film quality has been
characterized using Raman spectroscopy. AFM was used to
investigate the effect of chemical etching and mechanical
pretreatment on the surface roughness of the substrates and the
resultant morphology of nanocrystalline diamond. It was found that
diamond film deposited on as-received, basic etched and grinded
substrate shows the morphology of cauliflower while blasted and
acidic etched substrates produce smooth, continuous diamond film.
However, the Raman investigation did not show any deviation in
quality of diamond film for any pretreatment.
Abstract: The central recirculation zone (CRZ) in a swirl
stabilized gas turbine combustor has a dominant effect on the fuel air
mixing process and flame stability. Most of state of the art swirlers
share one disadvantage; the fixed swirl number for the same swirler
configuration. Thus, in a mathematical sense, Reynolds number
becomes the sole parameter for controlling the flow characteristics
inside the combustor. As a result, at low load operation, the
generated swirl is more likely to become feeble affecting the flame
stabilization and mixing process. This paper introduces a new swirler
concept which overcomes the mentioned weakness of the modern
configurations. The new swirler introduces air tangentially and
axially to the combustor through tangential vanes and an axial vanes
respectively. Therefore, it provides different swirl numbers for the
same configuration by regulating the ratio between the axial and
tangential flow momenta. The swirler aerodynamic performance was
investigated using four CFD simulations in order to demonstrate the
impact of tangential to axial flow rate ratio on the CRZ. It was found
that the length of the CRZ is directly proportional to the tangential to
axial air flow rate ratio.
Abstract: Enzymatic hydrolysis is one of the major steps involved in the conversion from sugarcane bagasse to yield ethanol. This process offers potential for yields and selectivity higher, lower energy costs and milder operating conditions than chemical processes. However, the presence of some factors such as lignin content, crystallinity degree of the cellulose, and particle sizes, limits the digestibility of the cellulose present in the lignocellulosic biomasses. Pretreatment aims to improve the access of the enzyme to the substrate. In this study sugarcane bagasse was submitted chemical pretreatment that consisted of two consecutive steps, the first with dilute sulfuric acid (1 % (v/v) H2SO4), and the second with alkaline solutions with different concentrations of NaOH (1, 2, 3 and 4 % (w/v)). Thermal Analysis (TG/ DTG and DTA) was used to evaluate hemicellulose, cellulose and lignin contents in the samples. Scanning Electron Microscopy (SEM) was used to evaluate the morphological structures of the in natura and chemically treated samples. Results showed that pretreatments were effective in chemical degradation of lignocellulosic materials of the samples, and also was possible to observe the morphological changes occurring in the biomasses after pretreatments.
Abstract: Any use of energy in industrial productive activities is combined with various environment impacts. Withintransportation,
this fact was not only found among land transport, railways and maritime transport, but also in the air transport industry. An effective climate protection requires strategies and measures for reducing all
greenhouses gas emissions, in particular carbon dioxide, and must
take into account the economic, ecologic and social aspects. It seem simperative now to develop and manufacture environmentally
friendly products and systems, to reduce consumption and use less
resource, and to save energy and power. Today-sproducts could
better serve these requirements taking into account the integration of
a power management system into the electrical power system.This
paper gives an overview of an approach ofpower management with
load prioritization in modernaircraft. Load dimensioning and load
management strategies on current civil aircraft will be presented and
used as a basis for the proposed approach.
Abstract: The Genetic Algorithm (GA) is one of the most important methods used to solve many combinatorial optimization problems. Therefore, many researchers have tried to improve the GA by using different methods and operations in order to find the optimal solution within reasonable time. This paper proposes an improved GA (IGA), where the new crossover operation, population reformulates operation, multi mutation operation, partial local optimal mutation operation, and rearrangement operation are used to solve the Traveling Salesman Problem. The proposed IGA was then compared with three GAs, which use different crossover operations and mutations. The results of this comparison show that the IGA can achieve better results for the solutions in a faster time.
Abstract: Probiotic bacteria especially Lactobacillus spp. and Bifidobacterium exert suppressive effect on Helicobacter pylori. Cinnamon and licorice have been traditionally used for the treatment of gastric ulcer. The objectives of this study were to determine the effects of herbs on yogurt fermentation, the level of probiotic bacteria in yogurt during 28 days storage and the effect of herbal yogurt on the growth of H. pylori in vitro. Cinnamon or licorice was mixed with milk and the mixture was fermented with probiotic bacteria to form herbal-yogurt. Changes of pH and total titratable acids were monitored and the viability of probiotic bacteria was evaluated during and after refrigerated storage. The in vitro inhibition of H. pylori growth was determined using agar diffusion and minimum inhibitory concentration (MIC) method. The presence of herbs did not affect the probiotic population during storage. There were no significant differences in pH and TTA between herbal-yogurts and plain-yogurt during fermentation and storage. Water extract of cinnamon-yogurt showed the highest inhibition effect (13.5mm) on H. pylori growth in comparison with licorice-yogurt (11.2mm). The present findings indicate cinnamon and licorice has bioactive components to decrease the growth of H. pylori.
Abstract: The protection of groundwater resources is the great
important many semiarid and arid environments. Baghan watershed
is located in the north of Kangan in the Boshehr province in Iran. The
groundwater resources have a vital role in supplying agricultural,
drinking, domestic and industrial water demand in Baghan
watershed. For our investigation into the water quality we collected
30 samples to chemical and physical analysis. The result showed the
marl and evaporation deposits that contain anhydrite and gypsum is
the main source of groundwater pollution, and one part of the
groundwater was polluted by oil and gas industrial. Another part of
the groundwater was contaminated by urban waste water. The
electrical conductivity and captions and anions increased around of
towns and gas refinery. Although the negative impact of untreated
domestic wastewater is relatively low but the results showed strongly
the negative impact of wastewater refinery is very considerable. This
negative impact increased in downstream due to shallow aquifer.
Additionally, the agents that adversely affect the quality of
groundwater come from a variety of sources, including geology,
domestic wastewater and the Jam refinery in Baghan watershed.
Abstract: The objective of this work was to examine the
changes in the microstructure and macro physical properties caused
by the carbonation of normalised CEM II mortar. Samples were
prepared and subjected to accelerated carbonation at 20°C, 65%
relative humidity and 20% CO2 concentration. On the microstructure
scale, the evolutions of the cumulative pore volume, pore size
distribution, and specific surface area during carbonation were
calculated from the adsorption desorption isotherms of nitrogen. We
also examined the evolution of macro physical properties such as the
porosity accessible to water, the gas permeability, and thermal
conductivity. The conflict between the results of nitrogen porosity
and water porosity indicated that the porous domains explored using
these two techniques are different and help to complementarily
evaluate the effects of carbonation. This is a multi-scale study where
results on microstructural changes can help to explain the evolution
of macro physical properties.