Abstract: The paper presents the design concept of a unitselection
text-to-speech synthesis system for the Slovenian language.
Due to its modular and upgradable architecture, the system can be
used in a variety of speech user interface applications, ranging from
server carrier-grade voice portal applications, desktop user interfaces
to specialized embedded devices.
Since memory and processing power requirements are important
factors for a possible implementation in embedded devices, lexica
and speech corpora need to be reduced. We describe a simple and
efficient implementation of a greedy subset selection algorithm that
extracts a compact subset of high coverage text sentences. The
experiment on a reference text corpus showed that the subset
selection algorithm produced a compact sentence subset with a small
redundancy.
The adequacy of the spoken output was evaluated by several
subjective tests as they are recommended by the International
Telecommunication Union ITU.
Abstract: In this paper; we are interested in dynamic modelling of quadrotor while taking into account the high-order nonholonomic constraints as well as the various physical phenomena, which can influence the dynamics of a flying structure. These permit us to introduce a new state-space representation and new control scheme. We present after the development and the synthesis of a stabilizing control laws design based on sliding mode in order to perform best tracking results. It ensures locally asymptotic stability and desired tracking trajectories. Nonlinear observer is then synthesized in order to estimate the unmeasured states and the effects of the external disturbances such as wind and noise. Finally simulation results are also provided in order to illustrate the performances of the proposed controllers.
Abstract: Using DNA microarrays the comparative analysis of a
gene expression profiles is carried out in a liver and kidneys of pigs.
The hypothesis of a cross hybridization of one probe with different
cDNA sites of the same gene or different genes is checked up, and it
is shown, that cross hybridization can be a source of essential errors
at revealing of a key genes in organ-specific transcriptome. It is
reveald that distinctions in profiles of a gene expression are well coordinated
with function, morphology, biochemistry and histology of
these organs.
Abstract: A biocompatible ferrofluid have been prepared by coprecipitation
of FeCl2.4H2O and FeCl3.6H2O under ultrasonic
irradiation and with NaOH as alkaline agent. Cystein was also used
as capping agent in the solution. Magnetic properties of the produced
ferrofluid were then determined by VSM test and magnetite
nanoparticles were characterized by XRD and TEM techniques. The
effect of surfactant to Fe ion weight ratio was also studied during this
project by using two different amount of Dextran. Results showed the
presence of a biocompatible superparamagnetic ferrofluid including
magnetite nanoparticles with particle size ranging under 20 nm. The
increase in the surfactant content results in the narrowing of the size
distribution and reduction of the particle size and more solution
stability.
Abstract: Streaming Applications usually run in parallel or in
series that incrementally transform a stream of input data. It poses a
design challenge to break such an application into distinguishable
blocks and then to map them into independent hardware processing
elements. For this, there is required a generic controller that
automatically maps such a stream of data into independent processing
elements without any dependencies and manual considerations. In
this paper, Kahn Process Networks (KPN) for such streaming
applications is designed and developed that will be mapped on
MPSoC. This is designed in such a way that there is a generic Cbased
compiler that will take the mapping specifications as an input
from the user and then it will automate these design constraints and
automatically generate the synthesized RTL optimized code for
specified application.
Abstract: The paper describes the evaluation of quality of
control for cases of controlled non-minimal phase plants. Control
circuits containing non-minimal phase plants have different
properties, they manifest reversed reaction at the beginning of unit
step response. For these types of plants are developed special
criterion of quality of control, which considers the difference and can
be helpful for synthesis of optimal controller tuning. All results are
clearly presented using Matlab/Simulink models.
Abstract: Contemporary science and technologies largely widen
the gap between the spiritual and rational of the society. Industrial
and technological breakthroughs might radically affect most
processes in the society, thus losing the cultural heritage. The
thinkers recognized the dangers of the decadence in the first place. In
the present article the ways of preserving cultural heritage have been
investigated. Memory has always been a necessary condition for selfidentification,
- continuity is based on this. The authors have
supported the hypothesis that continuity and ethnic memory are the
very mechanisms that preserve cultural heritage. Such problemformulating
will facilitate another, new look at the material, spiritual
and arts spheres of the cultural heritage of numerous ethnic groups.
The fundamental works by major European and Kazakh scientists
have been taken as a basis for the research done.
Abstract: Thermal water hammer is a special type of water
hammer which rarely occurs in heat exchangers. In biphasic fluids, if
steam bubbles are surrounded by condensate, regarding lower
condensate temperature than steam, they will suddenly collapse. As a
result, the vacuum caused by an extreme change in volume lead to
movement of the condensates in all directions and their collision the
force produced by this collision leads to a severe stress in the pipe
wall. This phenomenon is a special type of water hammer. According
to fluid mechanics, this phenomenon is a particular type of transient
flows during which abrupt change of fluid leads to sudden pressure
change inside the tube. In this paper, the mechanism of abrupt failure
of 80 tubes of 481 tubes of a methanol heat exchanger is discussed.
Initially, due to excessive temperature differences between heat
transfer fluids and simultaneous failure of 80 tubes, thermal shock
was presupposed as the reason of failure. Deeper investigation on
cross-section of failed tubes showed that failure was, ductile type of
failure, so the first hypothesis was rejected. Further analysis and more
accurate experiments revealed that failure of tubes caused by thermal
water hammer. Finally, the causes of thermal water hammer and
various solutions to avoid such mechanism are discussed.
Abstract: In this paper, we propose a method of alter duration in
frequency domain that control prosody in real time after pitch
alteration. If there has a method to alteration duration freely among
prosody information, that may used in several fields such as speech
impediment person's pronunciation proof reading or language study.
The pitch alteration method used control prosody altered by PSOLA
synthesis method which is in time domain processing method.
However, the duration of pitch alteration speech is changed by the
frequency domain. In this paper, we altered the duration with the
method of duration alteration by Fast Fourier Transformation in
frequency domain. Consequently, the intelligibility of the pitch and
duration are controlled has a slight decrease than the case when only
pitch is changed, but the proposed algorithm obtained the higher MOS
score about naturalness.
Abstract: The paper presents an applied study of a multivariate AR(p) process fitted to daily data from U.S. commodity futures markets with the use of Bayesian statistics. In the first part a detailed description of the methods used is given. In the second part two BVAR models are chosen one with assumption of lognormal, the second with normal distribution of prices conditioned on the parameters. For a comparison two simple benchmark models are chosen that are commonly used in todays Financial Mathematics. The article compares the quality of predictions of all the models, tries to find an adequate rate of forgetting of information and questions the validity of Efficient Market Hypothesis in the semi-strong form.
Abstract: An efficient and green protocol for the synthesis of α-
aminonitriles derivatives by one-pot reaction of different aldehydes
with amines and trimethylsilyl cyanides has been developed using
natural alumina, alumina sulfuric acid (ASA), nano-γ-alumina, nanoalumina
sulfuric acid (nano-ASA) under microwave irradiation and
solvent-free conditions. The advantages of methods are short reaction
times, high yields, milder conditions and easy work up. The catalysts
can be recovered for the subsequent reactions and reused without any
appreciable loss of efficiency.
Abstract: This hypothesis shows that the induction and the
remanent of magnetic properties govern the mechanism processes of
DNA replication and the shortening of the telomere.
The solenoid–like formation of each parental DNA strand, which
exists at the initial stage of the replication process, enables an electric
charge transformation through the strand to produce a magnetic field.
The magnetic field, in turn, induces the surrounding medium to form
a new (replicated) strand by a remanent magnetisation. Through the
remanent [residual] magnetisation process, the replicated strand
possesses a similar information pattern to that of the parental strand.
In the same process, the remanent amount of magnetisation forms the
medium in which it has less of both repetitive and pattern
magnetisation than that of the parental strand, therefore the replicated
strand shows a shortening in the length of its telomeres.
Abstract: The aim of this study was to synthesize the single
walled carbon nanotubes (SWCNTs) and determine their hydrogen
storage capacities. SWCNTs were firstly synthesized by chemical
vapor deposition (CVD) of acetylene (C2H2) on a magnesium oxide
(MgO) powder impregnated with an iron nitrate (Fe(NO3)3·9H2O)
solution. The synthesis parameters were selected as: the synthesis
temperature of 800°C, the iron content in the precursor of 5% and the
synthesis time of 30 min. Purification process of SWCNTs was
fulfilled by microwave digestion at three different temperatures (120,
150 and 200 °C), three different acid concentrations (0.5, 1 and 1.5
M) and for three different time intervals (15, 30 and 60 min). Nitric
acid (HNO3) was used in the removal of the metal catalysts. The
hydrogen storage capacities of the purified materials were measured
using volumetric method at the liquid nitrogen temperature and gas
pressure up to 100 bar. The effects of the purification conditions such
as temperature, time and acid concentration on hydrogen adsorption
were investigated.
Abstract: The rate of production of main products of the Fischer-Tropsch reactions over Fe/HZSM5 bifunctional catalyst in a fixed bed reactor is investigated at a broad range of temperature, pressure, space velocity, H2/CO feed molar ratio and CO2, CH4 and water flow rates. Model discrimination and parameter estimation were performed according to the integral method of kinetic analysis. Due to lack of mechanism development for Fisher – Tropsch Synthesis on bifunctional catalysts, 26 different models were tested and the best model is selected. Comprehensive one and two dimensional heterogeneous reactor models are developed to simulate the performance of fixed-bed Fischer – Tropsch reactors. To reduce computational time for optimization purposes, an Artificial Feed Forward Neural Network (AFFNN) has been used to describe intra particle mass and heat transfer diffusion in the catalyst pellet. It is seen that products' reaction rates have direct relation with H2 partial pressure and reverse relation with CO partial pressure. The results show that the hybrid model has good agreement with rigorous mechanistic model, favoring that the hybrid model is about 25-30 times faster.
Abstract: benzo[b][1,4]oxazines have been synthesized in good
to excellent yields in the presence of the ionic liquid 1-butyl-3-
methylimidazolium bromide [bmim]Br under relatively mild
conditions without any added catalyst, the reaction workup is simple
and the ionic liquid can be easily separated from the product and
reused.
Abstract: Sol-gel method has been used to fabricate
nanocomposite films on glass substrates composed halloysite clay
mineral and nanocrystalline TiO2. The methodology for the synthesis
involves a simple chemistry method utilized nonionic surfactant
molecule as pore directing agent along with the acetic acid-based solgel
route with the absence of water molecules. The thermal treatment
of composite films at 450oC ensures elimination of organic material
and lead to the formation of TiO2 nanoparticles onto the surface of
the halloysite nanotubes. Microscopy techniques and porosimetry
methods used in order to delineate the structural characteristics of the
materials. The nanocomposite films produced have no cracks and
active anatase crystal phase with small crystallite size were deposited
on halloysite nanotubes. The photocatalytic properties for the new
materials were examined for the decomposition of the Basic Blue 41
azo dye in solution. These, nanotechnology based composite films
show high efficiency for dye’s discoloration in spite of different
halloysite quantities and small amount of halloysite/TiO2 catalyst
immobilized onto glass substrates. Moreover, we examined the
modification of the halloysite/TiO2 films with silver particles in order
to improve the photocatalytic properties of the films. Indeed, the
presence of silver nanoparticles enhances the discoloration rate of the
Basic Blue 41 compared to the efficiencies obtained for unmodified
films.
Abstract: The paper reports the preparation and photocatalytic
activity of ZnO/SnO2 and SnO2 nanoparticles. These nanoparticles
were synthesized by hydrothermal method. The products were
characterized by X-ray diffraction (XRD) and scanning electron
microscopy (SEM). Their grain sizes are about 50-100 nm. The
photocatalytic activities of these materials were investigated for
congo red removal from aqueous solution under UV light irradiation.
It was shown that the use of ZnO/SnO2 as photocatalyst have better
photocatalytic activity for degradation of congo red than SnO2 or
TiO2 (anatase, particle size: 30nm) alone.
Abstract: A lot of recent research have spoken on the relation
between the increase of the homocysteinemia and some kinds of
cancer . For that, our study was based on the research of a possible
relation between the increase of the concentration of this amino-acid
in the plasma and the appearance of the disease of the Acute
Lymphoblastic Leukaemia in a part of Algerian children with Berber
origin in the East of Algeria . The study has done on 47 ill persons
with an average age of (09±06 ) years , with whom the disease has
diagnosed by blood and marrow examination in the hospital of blood
diseases in the CHU of Batna, and on 194 healthy witnesses of the
same age. The two groups were benefited by a dosage of the
concentration of the homocysteine vitamin B9 ,vitamin B12 , and
also of the study of special polymorphisms of indispensable enzymes
in the metabolism of this acid , and that by the use of the method (
Light cycler ) Real time PCR , on the following enzymes : MS (
C2756G ), MSR ( A66G ) ,MTHFR1 ( C677T ) and MTHFR2
(A1298C). The obtained results have revealed that the rate of the
homozygote muted genotype is the less frequent in the two groups ,
and that exist at list one genotype of each enzyme in the ill group and
in which the percentage exceed with remarkable way the same
genotype in the healthy group and we notice specially the muted
genotype GG of -the methionine synthetase-and the form TT of the
enzyme – methyline tetra hydrofolate reductase – We notice the
existence of considerable number of genotypes in the ill group lied
with characteristic increase of this Amino-acid ,and that for the
reduction of the biologic activity of these enzymes which become
inefficient in the transfer of the homocysteine into the methionine
and cause the diminution of the biologic activity of these enzymes
and with consequence the reduction of the percentage of methylic
radicals in the DNA of studied genes and that lead to the increase of
the activity and the capacity of transcription , and it-s so probably
that this last one is one of the factors of this disease especially if we
know that the specific check-up of vitamins is normal and similar in
the two groups , which ovoid the hypothesis of the reduction of
vitamins . We notice also that the heterozygote genotype is the less in
the sick category except the MTHFR2. Wild genotype is more
frequent in the witness group except MSR. Even these results are
partials; they open a new way in the genetic diagnosis of this
malicious disease which allow a precocious diagnosis and the use of
an effective and appropriated treatment in the same time.
Abstract: A macroscopic constitutive equation is developed for a high-density cellulose insulation material with emphasis on the outof- plane stress relaxation behavior. A hypothesis is proposed where the total stress is additively composed by an out-of-plane visco-elastic isotropic contribution and an in-plane elastic orthotropic response. The theory is validated against out-of-plane stress relaxation, compressive experiments and in-plane tensile hysteresis, respectively. For large scale finite element simulations, the presented model provides a balance between simplicity and capturing the materials constitutive behaviour.
Abstract: Concatenative speech synthesis is a method that can
make speech sound which has naturalness and high-individuality of a
speaker by introducing a large speech corpus. Based on this method, in
this paper, we propose a voice conversion method whose conversion
speech has high-individuality and naturalness. The authors also have
two subjective evaluation experiments for evaluating individuality and
sound quality of conversion speech. From the results, following three
facts have be confirmed: (a) the proposal method can convert the
individuality of speakers well, (b) employing the framework of unit
selection (especially join cost) of concatenative speech synthesis into
conventional voice conversion improves the sound quality of
conversion speech, and (c) the proposal method is robust against the
difference of genders between a source speaker and a target speaker.